Explosives.—A great variety of explosives are in use for blasting purposes. Up to 1864, gunpowder was the only available explosive, but in that year Alfred Nobel first applied nitroglycerin for blasting, and in 1867 invented dynamite. This name was originally applied to his mixture of nitroglycerin with kieselguhr, but now includes also other mechanical mixtures or chemical compounds which develop a high explosive force as compared with gunpowder. Besides these there are the so-called flameless or safety explosives, used in collieries where inflammable gases are given off from the coal.
Gunpowder, or black powder, is seldom used for rock-blasting, except in quarrying building-stone, where slow explosives of relatively low power are desirable to avoid shattering the stone, and in such collieries as do not require the use of safety explosives. Gunpowder is exploded by deflagration, by means of a fuze, and exerts a comparatively slow and rending force. The high explosives, on the other hand, are exploded by detonation, through the agency of a fuze and fulminating cap, exerting a quick, shattering, rather than a rending force. Dynamites and flameless explosives are made in a variety of strengths, and are packed in waterproofed cartridges of different sizes. The grades of dynamite most commonly employed contain from 35 to 60% of nitroglycerin; the stronger are used for tough rock or deep holes, or for holes unfavourably placed in narrow mine workings, as sometimes in shaft-sinking or tunnelling. When of good quality high explosives are safer to handle than gunpowder, as they cannot be ignited by sparks and are not so easily exploded. The ordinary dynamites used in mining are about four times as powerful as gunpowder.
Nitroglycerin in its liquid form is now rarely used for blasting, partly because its full strength is not often necessary but chiefly because of the difficulty and danger of transporting, handling and charging it. If employed at all, it is charged in thin tinned plate cases or rubber-cloth cartridges.
Blasting with Black Powder.—The powder is coarse-grained, usually from 1⁄8 to 3⁄16 in. in size, and is charged in paper cartridges, 8 to 10 in. long and of a proper diameter to fit loosely in the drill hole. A piece of fuze, long enough to reach a little beyond the mouth of the hole, is inserted in the cartridge and tied fast. For wet holes paraffined paper is used, the miner waterproofing the joints with grease. When more than one cartridge is required for the blast, that which has the fuze attached is usually charged last. The cartridges are carefully rammed down by a wooden tamping bar and the remainder of the hole filled with tamping. This consists of finely broken rock, dry clay or other comminuted material, carefully compacted by the tamping bar on top of the charge. The fuze is a cord, having in the centre a core of gunpowder, enclosed in several layers of linen or hemp waterproofed covering. It is ignited by the miner’s candle or lamp, or by a candle end so placed at the mouth of the hole that the flame must burn its way through the fuze covering. As the fuze burns slowly, at the rate of 2 or 3 ft. per minute, the miner uses a sufficient length to allow him to reach a place of safety.
For blasting in coal, “squibs” instead of fuzes are often used. A squib is simply a tiny paper rocket, about 1⁄8 in. diameter by 3 in. long, containing fine gunpowder and having a sulphur slow-match at one end. It is fired into the charge through a channel in the tamping. This channel may be formed by a piece of ¼ in. gas pipe, tamped in the hole and reaching the charge; or a “needle,” a long taper iron rod, is laid longitudinally in the hole, with its point entering the charge, and after the tamping is finished, by carefully withdrawing the needle a little channel is left, through which the squib is fired. In this connexion it may be noted that for breaking ground in gassy collieries several substitutes for explosives have been used to a limited extent, e.g. plugs of dry wood driven tightly into a row of drill holes, and which on being wetted swell and split the coal; quicklime cartridges, which expand powerfully on the application of water; simple wedges, driven by hammer into the drill holes; multiple wedges, inserted in the holes and operated by hydraulic pressure from a small hand force-pump.
Blasting with High Explosives.—High explosives are fired either by ordinary fuze and detonating cap or by electric fuze. Detonating caps of ordinary strength contain 10 to 15 grains of fulminating mixture. The cap is crimped tight on the end of the fuze, embedded in the cartridge, and on being exploded by fire from the fuze detonates the charge. The number of cartridges charged depends on the depth of hole, the length of the line of least resistance, and the toughness and other characteristics of the rock. Each cartridge should be solidly tamped, and, to avoid waste spaces in the hole, which would reduce the effect of the blast, it is customary to split the paper covering lengthwise with a knife. This allows the dynamite to spread under the pressure of the tamping bar. The cap is often placed in the cartridge preceding the last one charged, but it is better to insert it last, in a piece of cartridge called a “primer.” Though the dynamites are not exploded by sparks, they should nevertheless always be handled carefully. It is not so essential to fill the hole completely and so thoroughly to compact the tamping, as in charging black powder, because of the greater rapidity and shattering force of the explosion of dynamite; tamping, however, should never be omitted, as it increases the efficiency of the blast. In exploding dynamite, strong caps, containing say 15 grains of fulminating powder, produce the best results. Weaker caps are not economical, as they do not produce complete detonation of the dynamite. This is specially true if the weather be cold. Dynamite then becomes less sensitive, and the cartridges should be gently warmed before charging, to a temperature of not more than 80° F. Poisonous fumes are often produced by the explosion of the nitroglycerin compounds. These are probably largely due to incomplete detonation, by which part of the nitroglycerin is vaporized or merely burned. This is most likely to occur when the dynamite is chilled, or of poor quality, or when the cap is too weak. There is generally but little inconvenience from the fumes, except in confined underground workings, where ventilation is imperfect.
Like nitroglycerin, the common dynamites freeze at a temperature of from 42° to 46° F. They are then comparatively safe, and so far as possible should be transported in the frozen state. At very low temperatures dynamite again becomes somewhat sensitive to shock. When it is frozen at ordinary temperatures even the strongest detonating caps fail to develop the full force. In thawing dynamite, care must be exercised. The fact that a small quantity will often burn quietly has led to the dangerously mistaken notion that mere heating will not cause explosion. It is chiefly a question of temperature. If the quantity ignited by flame be large enough to heat the entire mass to the detonating point (say 360° F.) before all is consumed, an explosion will result. Furthermore, dynamite, when even moderately heated, becomes extremely sensitive to shocks. There are several accepted modes of thawing dynamite: (1) In a water bath, the cartridges being placed in a vessel surrounded on the sides and bottom by warm water contained in a larger enclosing vessel. The warm water may be renewed from time to time, or the water bath placed over a candle or small lamp, not on a stove. (2) In two vessels, similar to the above, with the space between them occupied by air, provided the heat applied can be definitely limited, as by using a candle. (3) When large quantities of dynamite are used a supply may be kept on shelves in a wooden room or chamber, warmed by a stove, or by a coil of pipe heated by exhaust steam from an engine. Live steam should not be used, as the heat might become excessive. Thawing should always take place slowly, never before an open fire or by direct contact with a stove or steam pipes and care must be taken that the heat does not rise high enough to cause sweating or exudation of liquid nitroglycerin from the cartridges, which would be a source of danger.
For the storage of explosives at mines, &c., proper magazines must be provided, situated in a safe place, not too near other buildings, and preferably of light though fireproof construction. Masonry magazines, though safer from some points of view, may be the cause of greater damage in event of an explosion, because the brick or stones act as projectiles. Isolated and abandoned mine workings, if dry, are sometimes used as magazines.
| Fig 11. Electrical Fuze. |
Firing blasts by electricity has a wide application for both surface and underground work. An electrical fuze (fig. 11) consists of a pair of fine, insulated copper wires, several feet long and about 1⁄40 of an inch in diameter, with their bare ends inserted in a detonating cap. For firing, the fuze wires are joined to long leading wires, connected with some source of electric current. By joining the fuze wires in series or in groups, any number of holes may be fired simultaneously, according to the current available. A round of holes fired in this way, as for driving tunnels, sinking shafts, or in large surface excavations, produces better results, both in economy of explosive and effect of the blast, than when the holes are fired singly or in succession. Also, the miners are enabled to prepare for the blast with more care and deliberation, and then to reach a place of safety before the current is transmitted. Another advantage is that there is no danger of a hole “hanging fire,” which sometimes causes accidents in using ordinary fuzes.