The semi-plastic method has many advantages where shales are used, although the bricks are not as strong nor as perfect as the best "plastic" bricks. The method, however, enables the brickmaker to make use of certain kinds of clay-rock, or shale, that would be impracticable for plastic bricks; and the weathering, tempering and "ageing" may be largely or entirely dispensed with. The plant required is heavier and more costly, but the brickyard becomes more compact, and the processes are simpler than with the "plastic" method.
The drying of bricks, which was formerly done in the open, is now, in most cases, conducted in a special shed heated by flues along which the heated gases from the kilns pass on their way to the chimney. It is important that the atmosphere of the drying-shed should be fairly dry, to which end suitable means of ventilation must be arranged (by fans or otherwise). If the atmosphere is too moist the surface of the brick remains damp for a considerable time, and the moisture from the interior passes to the surface as water, carrying with it the soluble salts, which are deposited on the surface as the water slowly evaporates. This deposit produces the "scum" already referred to. When the drying is done in a dry atmosphere the surface quickly dries and hardens, and the moisture from the interior passes to the surface as vapour, the soluble salts being left distributed through the whole mass, and consequently no "scum" is produced. Plastic bricks take much longer to dry than semi-plastic; they shrink more and have a greater tendency to warp or twist.
The burning or firing of bricks is the most important factor in their production; for their strength and durability depend very largely on the character and degree of the firing to which they have been subjected. The action of the heat brings about certain chemical decompositions and re-combinations which entirely alter the physical character of the dry clay. It is important, therefore, that the firing should be carefully conducted and that it should be under proper control. For ordinary bricks the firing atmosphere should be oxidizing, and the finishing temperature should be adjusted to the nature of the clay, the object being to produce a hard strong brick, of good shape, that will not be too porous and will withstand the action of frost. The finishing temperature ranges from 900° C. to 1250° C., the usual temperature being about 1050° C. for ordinary bricks. As before mentioned, lime-clays require a higher firing temperature (usually about 1150° C. to 1200° C.) in order to bring the lime into chemical combination with the other substances present.
It is evident that the best method of firing bricks is to place them in permanent kilns, but although such kilns were used by the Romans some 2000 years ago, the older method of firing in "clamps" is still employed in the smaller brickfields, in every country where bricks are made. These clamps are formed by arranging the unfired bricks in a series of rows or walls, placed fairly closely together, so as to form a rectangular stack. A certain number of channels, or firemouths, are formed in the bottom of the clamp; and fine coal is spread in horizontal layers between the bricks during the building up of the stack. Fires are kindled in the fire-mouths, and the clamp is allowed to go on burning until the fuel is consumed throughout. The clamp is then allowed to cool, after which it is taken down, and the bricks sorted; those that are under-fired being built up again in the next clamp for refiring. Sometimes the clamp takes the form of a temporary kiln, the outside being built of burnt bricks which are plastered over with clay, and the fire-mouths being larger and more carefully formed. There are many other local modifications in the manner of building up the clamps, all with the object of producing a large percentage of well-fired bricks. Clamp-firing is slow, and also uneconomical, because irregular and not sufficiently under control; and it is now only employed where bricks are made on a small scale.
Brick-kilns are of many forms, but they can all be grouped under two main types—Intermittent kilns and Continuous kilns. The intermittent kiln is usually circular in plan, being in the form of a vertical cylinder with a domed top. It consists of a single firing-chamber in which the unfired bricks are placed, and in the walls of which are contrived a number of fire-mouths where wood or coal is burned. In the older forms known as up-draught kilns, the products of combustion pass from the fire-mouth, through flues, into the bottom of the firing-chamber, and thence directly upwards and out at the top. The modern plan is to introduce the products of combustion near the top, or crown, of the kiln, and to draw them downwards through holes in the bottom which lead to flues connected with an independent chimney. These down-draught kilns have short chimneys or "bags" built round the inside wall in connexion with the fire-mouths, which conduct the flames to the upper part of the firing-chamber, where they are reverberated and passed down through the bricks in obedience to the pull of the chimney. The "bags" may be joined together, forming an inner circular wall entirely round the firing-chamber, except at the doorway; and a number of kilns may be built in a row or group having their bottom flues connected with the same tall chimney. Down-draught kilns usually give a more regular fire and a higher percentage of well-fired bricks; and they are more economical in fuel consumption than up-draught kilns, while the hot gases, as they pass from the kiln, may be utilized for drying purposes, being conducted through flues under the floor of the drying-shed, on their way to the chimney. The method of using one tall chimney to work a group of down-draught kilns naturally led to the invention of the "continuous" kiln, which is really made up of a number of separate kilns or firing-chambers, built in series and connected up to the main flue of the chimney in such a manner that the products of combustion from one kiln may be made to pass through a number of other kilns before entering the flue. The earliest form of continuous kiln was invented by Friedrich Hoffman, and all kilns of this type are built on the Hoffman principle, although there are a great number of modifications of the original Hoffman construction. The great principle of "continuous" firing is the utilization of the waste heat from one kiln or section of a kiln in heating up another kiln or section, direct firing being applied only to finish the burning. In practice a number of kilns or firing-chambers, usually rectangular in plan, are built side by side in two parallel lines, which are connected at the ends by other kilns so as to make a complete circuit. The original form of the complete series was elliptical in plan, but the tendency in recent years has been to flatten the sides of the ellipse and bring them together, thus giving two parallel rows joined at the ends by a chamber or passage at right angles. Coal or gas is burnt in the chamber or section that is being fired-up, the air necessary for the combustion being heated on its passage through the kilns that are cooling down, and the products of combustion, before entering the chimney flue, are drawn through a number of other kilns or chambers containing unfired bricks, which are thus gradually heated up by the otherwise waste-heat from the sections being fired. Continuous kilns produce a more evenly fired product than the intermittent kilns usually do, and, of course, at much less cost for fuel. Gas firing is now being extensively applied to continuous kilns, natural gas in some instances being used in the United States of America; and the methods of construction and of firing are carried out with greater care and intelligence, the prime objects being economy of fuel and perfect control of firing. Pyrometers are coming into use for the control of the firing temperature, with the result that a constant and trustworthy product is turned put. The introduction of machinery greatly helped the brickmaking industry in opening up new sources of supply of raw material in the shales and hardened clays of the sedimentary deposits of the older geologic formations, and, with the extended use of continuous firing plants, it has led to the establishment of large concerns where everything is co-ordinated for the production of enormous quantities of bricks at a minimum cost. In the United Kingdom, and still more in Germany and the United States of America, great improvements have been made in machinery, firing-plant and organization, so that the whole manufacture is now being conducted on more scientific lines, to the great advantage of the industry.
Blue Brick is a very strong vitreous brick of dark, slaty-blue colour, used in engineering works where great strength or impermeability is desirable. These bricks are made of clay containing front 7 to 10% of oxide of iron, and their manufacture is carried out in the ordinary way until the later stages of the firing process, when they are subjected to the strongly reducing action of a smoky atmosphere, which is produced by throwing small bituminous coal upon the fire-mouths and damping down the admission of air. The smoke thus produced reduces the red ferric oxide to blue-green ferrous oxide, or to metallic iron, which combines with the silica present to form a fusible ferrous silicate. This fusible "slag" partly combines with the other silicates present, and partly fills up the pores, and so produces a vitreous impermeable layer varying in thickness according to the duration and character of the smoking, the finishing temperature of the kiln and the texture of the brick. Particles of carbon penetrate the surface during the early stages of the smoking, and a small quantity of carbon probably enters into combination, tending to produce a harder surface and darker colour.
Floating Bricks were first mentioned by Strabo, the Greek geographer, and afterwards by Pliny as being made at Pitane in the Troad. The secret of their manufacture was lost for many centuries, but was rediscovered in 1791 by Fabroni, an Italian, who made them from the fossil meal (diatomaceous earth) found in Tuscany. These bricks are very light, fairly strong, and being poor conductors of heat, have been employed for the construction of powder-magazines on board ship, &c.
Mortar Bricks belong to the class of unburnt bricks, and are, strictly speaking, blocks of artificial stone made in brick moulds. These bricks have been made for many years by moulding a mixture of sand and slaked lime and allowing the blocks thus made to harden in the air. This hardening is brought about partly by evaporation of the water, but chiefly by the conversion of the calcium hydrate, or slaked lime, into calcium carbonate by the action of the carbonic acid in the atmosphere. A small proportion of the lime enters into combination with the silica and water present to form hydrated calcium silicate, and probably a little hydrated basic carbonate of lime is also formed, both of which substances are in the nature of cement. This process of natural hardening by exposure to the air was a very long one, occupying from six to eighteen months, and many improvements were introduced during the latter half of the 19th century to improve the strength of the bricks and to hasten the hardening.
Mixtures of sand, lime and cement (and of certain ground blast-furnace slags and lime) were introduced; the moulding was done under hydraulic presses and the bricks afterwards treated with carbon dioxide under pressure, with or without the application of mild heat. Some of these mixtures and methods are still in use, but a new type of mortar brick has come into use during recent years which has practically superseded the old mortar brick.
Sand-lime Bricks.—In the early 'eighties of the 19th century, Dr Michaelis of Berlin patented a new process for hardening blocks made of a mixture of sand and lime by treating them with high-pressure steam for a few hours, and the so-called sand-lime bricks are now made on a very extensive scale in many countries. There are many differences of detail in the manufacture, but the general method is in all cases the same. Dry sand is intimately mixed with about one-tenth of its weight of powdered slaked lime, the mixture is then slightly moistened with water and afterwards moulded into bricks under powerful presses, capable of exerting a pressure of about 60 tons per sq. in. After removal from the press the bricks are immediately placed in huge steel cylinders usually 60 to 80 ft. long and about 7 ft. in diameter, and are there subjected to the action of high-pressure steam (120 lb to 150 lb per sq. in.) for from ten to fifteen hours. The proportion of slaked lime to sand varies according to the nature of the lime and the purity and character of the sand, one of lime to ten of sand being a fair average. The following is an analysis of a typical German sand-lime brick: silica (SiO2), 84%; lime (CaO), 7%; alumina and oxide of iron, 2%; water, magnesia and alkalis, 7%. Under the action of the high-pressure steam the lime attacks the particles of sand, and a chemical compound of water, lime and silica is produced which forms a strong bond between the larger particles of sand. This bond of hydrated calcium silicate is evidently different from, and of better type than, the filling of calcium carbonate produced in the mortar-brick, and the sand-lime brick is consequently much stronger than the ordinary mortar-brick, however the latter may be made. The sand-lime brick is simple in manufacture, and with reasonable care is of constant quality. It is usually of a light-grey colour, but may be stained by the addition of suitable colouring oxides or pigments unaffected by lime and the conditions of manufacture.