These account for maleic acid readily yielding an anhydride, whereas fumaric acid does not, and for the behaviour of the acids towards bromine, fumaric acid yielding ordinary dibromsuccinic acid, and maleic acid the isomeric isodibromsuccinic acid.
FUMAROLE, a vent from which volcanic vapours issue, named indirectly from the Lat. fumariolum, a smoke-hole. The vapours from fumaroles were studied first by R.W. Bunsen, on his visit to Iceland, and afterwards by H. Sainte-Claire Deville and other chemists and geologists in France, who examined the vapours from Santorin, Etna, &c. The hottest vapours issue from dry fumaroles, at temperatures of at least 500° C., and consist chiefly of anhydrous chlorides, notably sodium chloride. The acid fumaroles yield vapours of lower temperature (300° to 400°) containing much water vapour, with hydrogen chloride and sulphur dioxide. The alkaline fumaroles are still cooler, though above 100°, and evolve ammonium chloride with other vapours. Cold fumaroles, below 100°, discharge principally aqueous vapour, with carbon dioxide, and perhaps hydrogen sulphide. The fumaroles of Mont Pelé in Martinique during the eruption of 1902 were examined by A. Lacroix, and the vapours analysed by H. Moissan, who found that they consisted chiefly of water vapour, with hydrogen chloride, sulphur, carbon dioxide, carbon monoxide, methane, hydrogen, nitrogen, oxygen and argon. These vapours issued at a temperature of about 400°. Armand Gautier has pointed out that these gases are practically of the same composition as those which he obtained on heating granite and certain other rocks. (See [Volcano]).
FUMIGATION (from Lat. fumigare, to smoke), the process of producing smoke or fumes, as by burning sulphur, frankincense, tobacco, &c., whether as a ceremony of incantation, or for perfuming a room, or for purposes of disinfection or destruction of vermin. In medicine the term has been used of the exposure of the body, or a portion of it, to fumes such as those of nitre, sal-ammoniac, mercury, &c.; fumigation, by the injection of tobacco smoke into the great bowel, was a recognized procedure in the 18th century for the resuscitation of the apparently drowned. “Fumigated” or “fumed” oak is oak which has been darkened by exposure to ammonia vapour.
FUMITORY, in botany, the popular name for the British species of Fumaria, a genus of small, branched, often climbing annual herbs with much-divided leaves and racemes of small flowers. The flowers are tubular with a spurred base, and in the British species are pink to purplish in colour. They are weeds of cultivation growing in fields and waste places. F. capreolata climbs by means of twisting petioles. In past times fumitory was in esteem for its reputed cholagogue and other medicinal properties; and in England, boiled in water, milk or whey, it was used as a cosmetic. The root of the allied species (Corydalis cava or tuberosa) is known as radix aristolochia, and has been used medicinally for various cutaneous and other disorders, in doses of 10 to 30 grains. Some eleven alkaloids have been isolated from it. The herbage of Fumaria officinalis and F. racemosa is used in China under the name of Tsze-hwa-ti-ting as an application for glandular swellings, carbuncles and abscesses, and was formerly valued in jaundice, and in cases of accidental swallowing of the beard of grain (see F. Porter Smith, Contrib. towards the Mat. Medica ... of China, p. 99, 1871). The name fumitory, Latin fumus terrae, has been supposed to be derived from the fact that its juice irritates the eyes like smoke (see Fuchs, De historia stirpium, p. 338, 1542); but The Grete Herball, cap. clxix., 1529, fol., following the De simplici medicina of Platearius, fo. xciii. (see in Nicolai Praepositi dispensatorium ad aromatarios, 1536), says: “It is called Fumus terre fume or smoke of the erthe bycause it is engendred of a cours fumosyte rysynge frome the erthe in grete quantyte lyke smoke: this grosse or cours fumosyte of the erthe wyndeth and wryeth out: and by workynge of the ayre and sonne it turneth into this herbe.”
FUNCHAL, the capital of the Portuguese archipelago of the Madeiras; on the south coast of Madeira, in 32° 37′ N. and 16° 54′ W. Pop. (1900) 20,850. Funchal is the see of a bishop, in the archiepiscopal province of Lisbon; it is also the administrative centre of the archipelago, and the residence of the governor and foreign consuls. The city has an attractive appearance from the sea. Its whitewashed houses, in their gardens full of tropical plants, are built along the curving shore of Funchal Bay, and on the lower slopes of an amphitheatre of mountains, which form a background 4000 ft. high. Numerous country houses (quintas), with terraced gardens, vineyards and sugar-cane plantations occupy the surrounding heights. Three mountain streams traverse the city through deep channels, which in summer are dry, owing to the diversion of the water for irrigation. A small fort, on an isolated rock off shore, guards the entrance to the bay, and a larger and more powerfully armed fort crowns an eminence inland. The chief buildings include the cathedral, Anglican and Presbyterian churches, hospitals, opera-house, museum and casino. There are small public gardens and a meteorological observatory. In the steep and narrow streets, which are lighted by electricity, wheeled traffic is impossible; sledges drawn by oxen, and other primitive conveyances are used instead (see [Madeira]). In winter the fine climate and scenery attract numerous invalids and other visitors, for whose accommodation there are good hotels; many foreigners engaged in the coal and wine trades also reside here permanently. The majority of these belong to the British community, which was first established here in the 18th century. Funchal is the headquarters of Madeiran industry and commerce (see [Madeira]). It has no docks and no facilities for landing passengers or goods; vessels are obliged to anchor in the roadstead, which, however, is sheltered from every wind except the south. Funchal is connected by cable with Carcavellos (for Lisbon), Porthcurnow (for Falmouth, England) and St Vincent in the Cape Verde Islands (for Pernambuco, Brazil).