Tralles’s hydrometer differs from Gay-Lussac’s only in being graduated at 4° C. instead of 15° C., and taking alcohol of density .7939 at 15.5° C. for pure alcohol instead of .7947 as taken by Gay-Lussac (Keene’s Handbook of Hydrometry).
In Beck’s hydrometer the zero of the scale corresponds to density 1.000 and the division 30 to density .850, and equal divisions on the scale are continued as far as is required in both directions.
| Fig. 8.—Sike’s Hydrometer. |
In the centesimal hydrometer of Francœur the volume of the stem between successive divisions of the scale is always 1⁄100th of the whole volume immersed when the instrument floats in water at 4° C. In order to graduate the stem the instrument is first weighed, then immersed in distilled water at 4° C., and the line of flotation marked zero. The first degree is then found by placing on the top of the stem a weight equal to 1⁄100th of the weight of the instrument, which increases the volume immersed by 1⁄100th of the original volume. The addition to the top of the stem of successive weights, each 1⁄100th of the weight of the instrument itself, serves to determine the successive degrees. The length of 100 divisions of the scale, or the length of the uniform stem the volume of which would be equal to that of the hydrometer up to the zero graduation, Francœur called the “modulus” of the hydrometer. He constructed his instruments of glass, using different instruments for different portions of the scale (Francœur, Traité d’aréométrie, Paris, 1842).
Dr Boriés of Montpellier constructed a hydrometer which was based upon the results of his experiments on mixtures of alcohol and water. The interval between the points corresponding to pure alcohol and to pure water Boriés divided into 100 equal parts, though the stem was prolonged so as to contain only 10 of these divisions, the other 90 being provided for by the addition of 9 weights to the bottom of the instrument as in Clarke’s hydrometer.
The instrument which has now been exclusively used for revenue purposes for nearly a century is that associated with the name of Bartholomew Sikes, who was correspondent to the Board of Excise from 1774 to 1783, and for some time collector of excise for Hertfordshire.
Sikes’s hydrometer, on account of its similarity to that of Boriés, appears to have been borrowed from that instrument. It is made of gilded brass or silver, and consists of a spherical ball A (fig. 8), 1.5 in. in diameter, below which is a weight B connected with the ball by a short conical stem C. The stem D is rectangular in section and about 3½ in. in length. This is divided into ten equal parts, each of which is subdivided into five. As in Boriés’s instrument, a series of 9 weights, each of the form shown at E, serves to extend the scale to 100 principal divisions. In the centre of each weight is a hole capable of admitting the lowest and thickest end of the conical stem C, and a slot is cut into it just wide enough to allow the upper part of the cone to pass. Each weight can thus be dropped on to the lower stem so as to rest on the counterpoise B. The weights are marked 10, 20, ... 90; and in using the instrument that weight must be selected which will allow it to float in the liquid with a portion only of the stem submerged. Then the reading of the scale at the line of flotation, added to the number on the weight, gives the reading required. A small supernumerary weight F is added, which can be placed upon the top of the stem. F is so adjusted that when the 60 weight is placed on the lower stem the instrument sinks to the same point in distilled water when F is attached as in proof spirit when F is removed. The best instruments are now constructed for revenue purposes of silver, heavily gilded, because it was found that saccharic acid contained in some spirits attacked brass behind the gilding.
The following table gives the specific gravities corresponding to the principal graduations on Sikes’s hydrometer at 60° F. and 62° F., together with the corresponding strengths of spirits. The latter are based upon the tables of Charles Gilpin, clerk to the Royal Society, for which the reader is referred to the Phil. Trans. for 1794. Gilpin’s work is a model for its accuracy and thoroughness of detail, and his results have scarcely been improved upon by more recent workers. The merit of Sikes’s system lies not so much in the hydrometer as in the complete system of tables by which the readings of the instrument are at once converted into percentage of proof-spirit.
Table showing the Densities corresponding to the Indications of Sike’s Hydrometer.
| Sike’s Indications. | 60° F. | 62° F. | ||
| Density. | Proof Spirit per cent. | Density. | Proof Spirit per cent. | |
| 0 | .815297 | 167.0 | .815400 | 166.5 |
| 1 | .816956 | 166.1 | .817059 | 165.6 |
| 2 | .818621 | 165.3 | .818725 | 164.8 |
| 3 | .820294 | 164.5 | .820397 | 163.9 |
| 4 | .821973 | 163.6 | .822077 | 163.1 |
| 5 | .823659 | 162.7 | .823763 | 162.3 |
| 6 | .825352 | 161.8 | .825457 | 161.4 |
| 7 | .827052 | 160.9 | .827157 | 160.5 |
| 8 | .828759 | 160.0 | .828864 | 159.6 |
| 9 | .830473 | 159.1 | .830578 | 158.7 |
| 10 | .832195 | 158.2 | .832300 | 157.8 |
| 11 | .833888 | 157.3 | .833993 | 156.8 |
| 12 | .835587 | 156.4 | .835692 | 155.9 |
| 13 | .837294 | 155.5 | .837400 | 155.0 |
| 14 | .839008 | 154.6 | .839114 | 154.0 |
| 15 | .840729 | 153.7 | .840835 | 153.1 |
| 16 | .842458 | 152.7 | .842564 | 152.1 |
| 17 | .844193 | 151.7 | .844299 | 151.1 |
| 18 | .845936 | 150.7 | .846042 | 150.1 |
| 19 | .847685 | 149.7 | .847792 | 149.1 |
| 20 | .849442 | 148.7 | .849549 | 148.1 |
| 20B | .849393 | 148.7 | .849500 | 148.1 |
| 21 | .851122 | 147.6 | .851229 | 147.1 |
| 22 | .852857 | 146.6 | .852964 | 146.1 |
| 23 | .854599 | 145.6 | .854707 | 145.1 |
| 24 | .856348 | 144.6 | .856456 | 144.0 |
| 25 | .858105 | 143.5 | .858213 | 142.9 |
| 26 | .859869 | 142.4 | .859978 | 141.8 |
| 27 | .861640 | 141.3 | .861749 | 140.8 |
| 28 | .863419 | 140.2 | .863528 | 139.7 |
| 29 | .865204 | 139.1 | .865313 | 138.5 |
| 30 | .866998 | 138.0 | .867107 | 137.4 |
| 30B | .866991 | 138.0 | .867100 | 137.4 |
| 31 | .868755 | 136.9 | .868865 | 136.2 |
| 32 | .870526 | 135.7 | .870636 | 135.1 |
| 33 | .872305 | 134.5 | .872415 | 133.9 |
| 34 | .874090 | 133.4 | .874200 | 132.8 |
| 35 | .875883 | 132.2 | .873994 | 131.6 |
| 36 | .877684 | 131.0 | .877995 | 130.4 |
| 37 | .879492 | 129.8 | .879603 | 129.1 |
| 38 | .881307 | 128.5 | .881419 | 127.9 |
| 39 | .883129 | 127.3 | .883241 | 126.7 |
| 40 | .884960 | 126.0 | .885072 | 125.4 |
| 40B | .884888 | 126.0 | .885000 | 125.4 |
| 41 | .886689 | 124.8 | .886801 | 124.2 |
| 42 | .888497 | 123.5 | .888609 | 122.9 |
| 43 | .890312 | 122.2 | .890425 | 121.6 |
| 44 | .892135 | 120.9 | .892248 | 120.3 |
| 45 | .893965 | 119.6 | .894078 | 119.0 |
| 46 | .895803 | 118.3 | .895916 | 117.6 |
| 47 | .897647 | 116.9 | .897761 | 116.3 |
| 48 | .899509 | 115.6 | .899614 | 114.9 |
| 49 | .901360 | 114.2 | .901417 | 113.5 |
| 50 | .903229 | 112.8 | .903343 | 112.1 |
| 50B | .903186 | 112.8 | .903300 | 112.1 |
| 51 | .905024 | 111.4 | .905138 | 110.7 |
| 52 | .906869 | 110.0 | .906983 | 109.3 |
| 53 | .908722 | 108.6 | .908837 | 107.9 |
| 54 | .910582 | 107.1 | .910697 | 106.5 |
| 55 | .912450 | 105.6 | .912565 | 105.0 |
| 56 | .914326 | 104.2 | .914441 | 103.5 |
| 57 | .916209 | 102.7 | .916323 | 102.0 |
| 58 | .918100 | 101.3 | .918216 | 100.5 |
| 59 | .919999 | 99.7 | .820115 | 98.9 |
| 60 | .921906 | 98.1 | .922022 | 97.4 |
| 60B | .921884 | 98.1 | .922000 | 97.4 |
| 61 | .923760 | 96.6 | .923877 | 95.9 |
| 62 | .925643 | 95.0 | .925760 | 94.2 |
| 63 | .927534 | 93.3 | .927652 | 92.6 |
| 64 | .929433 | 91.7 | .929550 | 90.9 |
| 65 | .931339 | 90.0 | .931457 | 89.2 |
| 66 | .933254 | 88.3 | .933372 | 87.5 |
| 67 | .935176 | 86.5 | .935294 | 85.8 |
| 68 | .937107 | 84.7 | .937225 | 84.0 |
| 69 | .939045 | 82.9 | .939163 | 82.2 |
| 70 | .940991 | 81.1 | .941110 | 80.3 |
| 70B | .940981 | 81.1 | .941100 | 80.3 |
| 71 | .942897 | 79.2 | .943016 | 78.4 |
| 72 | .944819 | 77.3 | .944938 | 76.5 |
| 73 | .946749 | 75.3 | .946869 | 74.5 |
| 74 | .948687 | 73.3 | .948807 | 72.5 |
| 75 | .950634 | 71.2 | .950753 | 70.4 |
| 76 | .952588 | 69.0 | .952708 | 68.2 |
| 77 | .954550 | 66.8 | .954670 | 66.0 |
| 78 | .956520 | 64.4 | .956641 | 63.5 |
| 79 | .958498 | 61.9 | .958619 | 61.1 |
| 80 | .960485 | 59.4 | .960606 | 58.5 |
| 80B | .960479 | 59.4 | .960600 | 58.5 |
| 81 | .962433 | 56.7 | .962555 | 55.8 |
| 82 | .964395 | 53.9 | .964517 | 53.0 |
| 83 | .966366 | 50.9 | .966488 | 50.0 |
| 84 | .968344 | 47.8 | .968466 | 47.0 |
| 85 | .970331 | 44.5 | .970453 | 43.8 |
| 86 | .972325 | 41.0 | .972448 | 40.4 |
| 87 | .974328 | 37.5 | .974451 | 36.9 |
| 88 | .976340 | 34.0 | .976463 | 33.5 |
| 89 | .978359 | 30.6 | .978482 | 30.1 |
| 90 | .980386 | 27.2 | .980510 | 26.7 |
| 90B | .980376 | 27.2 | .980500 | 26.7 |
| 91 | .982371 | 23.9 | .982496 | 23.6 |
| 92 | .984374 | 20.8 | .984498 | 20.5 |
| 93 | .986385 | 17.7 | .986510 | 17.4 |
| 94 | .988404 | 14.8 | .988529 | 14.5 |
| 95 | .990431 | 12.0 | .990557 | 11.7 |
| 96 | .992468 | 9.3 | .992593 | 9.0 |
| 97 | .994512 | 6.7 | .994637 | 6.5 |
| 98 | .996565 | 4.1 | .996691 | 4.0 |
| 99 | .998626 | 1.8 | .998752 | 1.6 |
| 100 | 1.000696 | 0.0 | 1.000822 | 0.0 |