The most important American iron-making district is in and about Pittsburg, to whose cheap coal the rich Lake Superior ores are brought nearly 1000 m., about four-fifths of the distance in the large ore steamers of the Great Lakes. Chicago, nearer to the Lake ores, though rather far from the Pittsburg coal-field, is a very important centre for rail-making for the railroads of the western states. Ohio, the Lake Erie end of New York State, eastern Pennsylvania and Maryland have very important works, the ore for which comes in part from Lake Superior and in part from Pennsylvania, New York and Cuba, and the fuel from Pennsylvania and its neighbourhood. Tennessee and Alabama in the south rely on southern ore and fuel.
58. Germany gets about two-thirds of her total ore supply from the great Jurassic “Minette” ore deposit of Luxemburg and Lorraine, which reaches also into France and Belgium. In spite of its containing only about 36% of iron, this deposit is of very great value because of its great size, and of the consequent small cost of mining. It stretches through an area of about 8 m. wide and 40 m. long, and in some places it is nearly 60 ft. thick. There are valuable deposits also in Siegerland and in many other parts of the country.
59. Sweden has abundant, rich and very pure iron ores, but her lack of coal has restricted her iron manufacture chiefly to the very purest and best classes of iron and steel, in making which her thrifty and intelligent people have developed very rare skill. The magnetite ore bodies which supply this industry lie in a band about 180 m. long, reaching from a little north of Stockholm westerly toward the Norwegian frontier, between the latitudes 59° and 61° N. In Swedish Lapland, near the Arctic circle, are the great Gellivara, Kirunavara and Luossavara magnetite beds, among the largest in Europe. From these beds, which in some parts are about 300 ft. thick, much ore is sent to Germany and Great Britain.
60. Other Countries.—Spain has large, rich and pure iron ore beds, near both her northern and her southern sea coast. She exports about 90% of all the iron ore which she mines, most of it to England. France draws most of her iron ore from her own part of the great Minette ore deposit, and from those parts of it which were taken from her when she lost Alsace and Lorraine. Russia’s most valuable ore deposit is the very large and easily mined one of Krivoi Rog in the south, from which comes about half of the Russian iron ore. It is near the Donetz coal-field, the largest in Europe. There are also important ore beds in the Urals, near the border of Finland, and at the south of Moscow. In Austria-Hungary, besides the famous Styrian Erzberg, with its siderite ore bed about 450 ft. thick, there are cheaply mined but poor and impure ores near Prague, and important ore beds in both northern and southern Hungary. Algeria, Canada, Cuba and India have valuable ore bodies.
61. Richness of Iron Ores.—The American ores now mined are decidedly richer than those of most European countries. To make a ton of pig iron needs only about 1.9 tons of ore in the United States, 2 tons in Sweden and Russia, 2.4 tons in Great Britain and Germany, and about 2.7 tons in France and Belgium, while about 3 tons of the native British ores are needed per ton of pig iron.
62. The general scheme of iron manufacture is shown diagrammatically in fig. 6. To put the iron contained in iron ore into a state in which it can be used as a metal requires essentially, first its deoxidation, and second its separation from the other mineral matter, such as clay, quartz, &c. with which it is found associated. These two things are done simultaneously by heating and melting the ore in contact with coke, charcoal or anthracite, in the iron blast furnace, from which issue intermittently two molten streams, the iron now deoxidized and incidentally carburized by the fuel with which it has been in contact, and the mineral matter, now called “slag.” This crude cast iron, called “pig iron,” may be run from the blast furnace directly into moulds, which give the metal the final shape in which it is to be used in the arts; but it is almost always either remelted, following path 1 of fig. 6, and then cast into castings of cast iron, or converted into wrought iron or steel by purifying it, following path 2.
| Fig. 6.—General Scheme of Iron Manufacture. |
If it is to follow path 1, the castings into which it is made may be either (a) grey or (b) chilled or (c) malleable. Grey iron castings are made by remelting the pig iron either in a small shaft or “cupola” furnace, or in a reverberatory or “air” furnace, with very little change of chemical composition, and then casting it directly into suitable moulds, usually of either “baked,” i.e. oven-dried, or “green,” i.e. moist undried, sand, but sometimes of iron covered with a refractory coating to protect it from being melted or overheated by the molten cast iron. The general procedure in the manufacture of chilled and of malleable castings has been described in §§ 30 and 31.
If the pig iron is to follow path 2, the purification which converts it into wrought iron or steel consists chiefly in oxidizing and thereby removing its carbon, phosphorus and other impurities, while it is molten, either by means of the oxygen of atmospheric air blown through it as in the Bessemer process, or by the oxygen of iron ore stirred into it as in the puddling and Bell-Krupp processes, or by both together as in the open hearth process.
On its way from the blast furnace to the converter or open hearth furnace the pig iron is often passed through a great reservoir called a “mixer,” which acts also as an equalizer, to lessen the variation in composition of the cast iron, and as a purifier, removing part of the sulphur and silicon.