Encyclopaedia Britannica, 11th Edition, "Matter" to "Mecklenburg" / Volume 17, Slice 8

by Various

MATTER. Our conceptions of the nature and structure of matter have been profoundly influenced in recent years by investigations on the Conduction of Electricity through Gases (see [Conduction, Electric]) and on Radio-activity (q.v.). These researches and the ideas which they have suggested have already thrown much light on some of the most fundamental questions connected with matter; they have, too, furnished us with far more powerful methods for investigating many problems connected with the structure of matter than those hitherto available. There is thus every reason to believe that our knowledge of the structure of matter will soon become far more precise and complete than it is at present, for now we have the means of settling by testing directly many points which are still doubtful, but which formerly seemed far beyond the reach of experiment.

The Molecular Theory of Matter—the only theory ever seriously advocated—supposes that all visible forms of matter are collocations of simpler and smaller portions. There has been a continuous tendency as science has advanced to reduce further and further the number of the different kinds of things of which all matter is supposed to be built up. First came the molecular theory teaching us to regard matter as made up of an enormous number of small particles, each kind of matter having its characteristic particle, thus the particles of water were supposed to be different from those of air and indeed from those of any other substance. Then came Dalton’s Atomic Theory which taught that these molecules, in spite of their almost infinite variety, were all built up of still smaller bodies, the atoms of the chemical elements, and that the number of different types of these smaller bodies was limited to the sixty or seventy types which represent the atoms of the substance regarded by chemists as elements.

In 1815 Prout suggested that the atoms of the heavier chemical elements were themselves composite and that they were all built up of atoms of the lightest element, hydrogen, so that all the different forms of matter are edifices built of the same material—the atom of hydrogen. If the atoms of hydrogen do not alter in weight when they combine to form atoms of other elements the atomic weights of all elements would be multiples of that of hydrogen; though the number of elements whose atomic weights are multiples or very nearly so of hydrogen is very striking, there are several which are universally admitted to have atomic weights differing largely from whole numbers. We do not know enough about gravity to say whether this is due to the change of weight of the hydrogen atoms when they combine to form other atoms, or whether the primordial form from which all matter is built up is something other than the hydrogen atom. Whatever may be the nature of this primordial form, the tendency of all recent discoveries has been to emphasize the truth of the conception of a common basis of matter of all kinds. That the atoms of the different elements have a common basis, that they behave as if they consisted of different numbers of small particles of the same kind, is proved to most minds by the Periodic Law of Mendeléeff and Newlands (see [Element]). This law shows that the physical and chemical properties of the different elements are determined by their atomic weights, or to use the language of mathematics, the properties of an element are functions of its atomic weight. Now if we constructed models of the atoms out of different materials, the atomic weight would be but one factor out of many which would influence the physical and chemical properties of the model, we should require to know more than the atomic weight to fix its behaviour. If we were to plot a curve representing the variation of some property of the substance with the atomic weight we should not expect the curve to be a smooth one, for instance two atoms might have the same atomic weight and yet if they were made of different materials have no other property in common. The influence of the atomic weight on the properties of the elements is nowhere more strikingly shown than in the recent developments of physics connected with the discharge of electricity through gases and with radio-activity. The transparency of bodies to Röntgen rays, to cathode rays, to the rays emitted by radio-active substances, the quality of the secondary radiation emitted by the different elements are all determined by the atomic weight of the element. So much is this the case that the behaviour of the element with respect to these rays has been used to determine its atomic weight, when as in the case of Indium, uncertainty as to the valency of the element makes the result of ordinary chemical methods ambiguous.

The radio-active elements indeed furnish us with direct evidence of this unity of composition of matter, for not only does one element uranium, produce another, radium, but all the radio-active substances give rise to helium, so that the substance of the atoms of this gas must be contained in the atoms of the radio-active elements.

It is not radio-active atoms alone that contain a common constituent, for it has been found that all bodies can by suitable treatment, such as raising them to incandescence or exposing them to ultra-violet light, be made to emit negatively electrified particles, and that these particles are the same from whatever source they may be derived. These particles all carry the same charge of negative electricity and all have the same mass, this mass is exceedingly small even when compared with the mass of an atom of hydrogen, which until the discovery of these particles was the smallest mass known to science. These particles are called corpuscles or electrons; their mass according to the most recent determinations is only about 1⁄1700 of that of an atom of hydrogen, and their radius is only about one hundred-thousandth part of the radius of the hydrogen atom. As corpuscles of this kind can be obtained from all substances, we infer that they form a constituent of the atoms of all bodies. The atoms of the different elements do not all contain the same number of corpuscles—there are more corpuscles in the atoms of the heavier elements than in the atoms of the lighter ones; in fact, many different considerations point to the conclusion that the number of corpuscles in the atom of any element is proportional to the atomic weight of the element. Different methods of estimating the exact number of corpuscles in the atom have all led to the conclusion that this number is of the same order as the atomic weight; that, for instance, the number of corpuscles in the atom of oxygen is not a large multiple of 16. Some methods indicate that the number of corpuscles in the atom is equal to the atomic weight, while the maximum value obtained by any method is only about four times the atomic weight. This is one of the points on which further experiments will enable us to speak with greater precision. Thus one of the constituents of all atoms is the negatively charged corpuscle; since the atoms are electrically neutral, this negative charge must be accompanied by an equal positive one, so that on this view the atoms must contain a charge of positive electricity proportional to the atomic weight; the way in which this positive electricity is arranged is a matter of great importance in the consideration of the constitution of matter. The question naturally arises, is the positive electricity done up into definite units like the negative, or does it merely indicate a property acquired by an atom when one or more corpuscles leave it? It is very remarkable that we have up to the present (1910), in spite of many investigations on this point, no direct evidence of the existence of positively charged particles with a mass comparable with that of a corpuscle; the smallest positive particle of which we have any direct indication has a mass equal to the mass of an atom of hydrogen, and it is a most remarkable fact that we get positively charged particles having this mass when we send the electric discharge through gases at low pressures, whatever be the kind of gas. It is no doubt exceedingly difficult to get rid of traces of hydrogen in vessels containing gases at low pressures through which an electric discharge is passing, but the circumstances under which the positively electrified particles just alluded to appear, and the way in which they remain unaltered in spite of all efforts to clear out any traces of hydrogen, all seem to indicate that these positively electrified particles, whose mass is equal to that of an atom of hydrogen, do not come from minute traces of hydrogen present as an impurity but from the oxygen, nitrogen, or helium, or whatever may be the gas through which the discharge passes. If this is so, then the most natural conclusion we can come to is that these positively electrified particles with the mass of the atom of hydrogen are the natural units of positive electricity, just as the corpuscles are those of negative, and that these positive particles form a part of all atoms.

Thus in this way we are led to an electrical view of the constitution of the atom. We regard the atom as built up of units of negative electricity and of an equal number of units of positive electricity; these two units are of very different mass, the mass of the negative unit being only 1⁄1700 of that of the positive. The number of units of either kind is proportional to the atomic weight of the element and of the same order as this quantity. Whether this is anything besides the positive and negative electricity in the atom we do not know. In the present state of our knowledge of the properties of matter it is unnecessary to postulate the existence of anything besides these positive and negative units.

The atom of a chemical element on this view of the constitution of matter is a system formed by n corpuscles and n units of positive electricity which is in equilibrium or in a state of steady motion under the electrical forces which the charged 2n constituents exert upon each other. Sir J. J. Thomson (Phil. Mag., March 1904, “Corpuscular Theory of Matter”) has investigated the systems in steady motion which can be formed by various numbers of negatively electrified particles immersed in a sphere of uniform positive electrification, a case, which in consequence of the enormous volume of the units of positive electricity in comparison with that of the negative has much in common with the problem under consideration, and has shown that some of the properties of n systems of corpuscles vary in a periodic way suggestive of the Periodic Law in Chemistry as n is continually increased.

Mass on the Electrical Theory of Matter.—One of the most characteristic things about matter is the possession of mass. When we take the electrical theory of matter the idea of mass takes new and interesting forms. This point may be illustrated by the case of a single electrified particle; when this moves it produces in the region around it a magnetic field, the magnetic force being proportional to the velocity of the electrified particle.[1] In a magnetic field, however, there is energy, and the amount of energy per unit volume at any place is proportional to the square of the magnetic force at that place. Thus there will be energy distributed through the space around the moving particle, and when the velocity of the particle is small compared with that of light we can easily show that the energy in the region around the charged particle is μe2/3a, when v is the velocity of the particle, e its charge, a its radius, and μ the magnetic permeability of the region round the particle. If m is the ordinary mass of the particle, the part of the kinetic energy due to the motion of this mass is 1⁄2 mv2, thus the total kinetic energy is 1⁄2 (m + 2⁄3μe2/a). Thus the electric charge on the particle makes it behave as if its mass were increased by 2⁄3μe2/a. Since this increase in mass is due to the energy in the region outside the charged particle, it is natural to look to that region for this additional mass. This region is traversed by the tubes of force which start from the electrified body and move with it, and a very simple calculation shows that we should get the increase in the mass which is due to the electrification if we suppose that these tubes of force as they move carry with them a certain amount of the ether, and that this ether had mass. The mass of ether thus carried along must be such that the amount of it in unit volume at any part of the field is such that if this were to move with the velocity of light its kinetic energy would be equal to the potential energy of the electric field in the unit volume under consideration. When a tube moves this mass of ether only participates in the motion at right angles to the tube, it is not set in motion by a movement of the tube along its length. We may compare the mass which a charged body acquires in virtue of its charge with the additional mass which a ball apparently acquires when it is placed in water; a ball placed in water behaves as if its mass were greater than its mass when moving in vacuo; we can easily understand why this should be the case, because when the ball in the water moves the water around it must move as well; so that when a force acting on the ball sets it in motion it has to move some of the water as well as the ball, and thus the ball behaves as if its mass were increased. Similarly in the case of the electrified particle, which when it moves carries with it its lines of force, which grip the ether and carry some of it along with them. When the electrified particle is moved a mass of ether has to be moved too, and thus the apparent mass of the particle is increased. The mass of the electrified particle is thus resident in every part of space reached by its lines of force; in this sense an electrified body may be said to extend to an infinite distance; the amount of the mass of the ether attached to the particle diminishes so rapidly as we recede from it that the contributions of regions remote from the particle are quite insignificant, and in the case of a particle as small as a corpuscle not one millionth part of its mass will be farther away from it than the radius of an atom.

The increase in the mass of a particle due to given charges varies as we have seen inversely as the radius of the particle; thus the smaller the particle the greater the increase in the mass. For bodies of appreciable size or even for those as small as ordinary atoms the effect of any realizable electric charge is quite insignificant, on the other hand for the smallest bodies known, the corpuscle, there is evidence that the whole of the mass is due to the electric charge. This result has been deduced by the help of an extremely interesting property of the mass due to a charge of electricity, which is that this mass is not constant but varies with the velocity. This comes about in the following way. When the charged particle, which for simplicity we shall suppose to be spherical, is at rest or moving very slowly the lines of electric force are distributed uniformly around it in all directions; when the sphere moves, however, magnetic forces are produced in the region around it, while these, in consequence of electro-magnetic induction in a moving magnetic field, give rise to electric forces which displace the tubes of electric force in such a way as to make them set themselves so as to be more at right angles to the direction in which they are moving than they were before. Thus if the charged sphere were moving along the line AB, the tubes of force would, when the sphere was in motion, tend to leave the region near AB and crowd towards a plane through the centre of the sphere and at right angles to AB, where they would be moving more nearly at right angles to themselves. This crowding of the lines of force increases, however, the potential energy of the electric field, and since the mass of the ether carried along by the lines of force is proportional to the potential energy, the mass of the charged particle will also be increased. The amount of variation of the mass with the velocity depends to some extent on the assumptions we make as to the shape of the corpuscle and the way in which it is electrified. The simplest expression connecting the mass with the velocity is that when the velocity is v the mass is equal to 2⁄3μe2/a [1/(1 − v2/c2)1/2] where c is the velocity of light. We see from this that the variation of mass with velocity is very small unless the velocity of the body approaches that of light, but when, as in the case of the β particles emitted by radium, the velocity is only a few per cent less than that of light, the effect of velocity on the mass becomes very considerable; the formula indicates that if the particles were moving with a velocity equal to that of light they would behave as if their mass were infinite. By observing the variation in the mass of a corpuscle as its velocity changes we can determine how much of the mass depends upon the electric charge and how much is independent of it. For since the latter part of the mass is independent of the velocity, if it predominates the variation with velocity of the mass of a corpuscle will be small; if on the other hand it is negligible the variation in mass with velocity will be that indicated by theory given above. The experiment of Kaufmann (Göttingen Nach., Nov. 8, 1901), Bucherer (Ann. der Physik., xxviii. 513, 1909) on the masses of the β particles shot out by radium, as well as those by Hupka (Berichte der deutsch. physik. Gesell., 1909, p. 249) on the masses of the corpuscle in cathode rays are in agreement with the view that the whole of the mass of these particles is due to their electric charge.