the Mouths or Hands of those patients, to whom it may be allow'd, may be potently cool'd, and other such refreshments may be easily procur'd.
4. How far Sal Armoniack, mingl'd with Sand or Earth, and not dissolv'd, but only moistn'd with a little Water sprinkl'd on it, will keep Bottles of Wine or other liquors more coole, than the Earth or that Sand alone will do, I have not yet had opportunity by sufficient trials fully to satisfie my self, and therefore resign that Enquiry to the Curious.
5. For the cooling of Air, and Liquors, to adjust Weather-glasses (to be able to do which at all times of the year, was one of the chief aimes, that made me bethink my self of this Experiment;) or to give a small quantity of Beer &c. a moderate degree of coolness, it will not be requisite, to employ neer so much as a whole pound of Sal Armoniack at a time. For, you may easily observe by a seal'd Weather-glass, that a very few ounces, well pouder'd and nimbly dissolv'd in about 4. times the weight of Water, will serve well enough for many purposes.
6. And that you may the less, scruple at this, I shall tell you, that even before and after Midsummer, I have found the Cold producible by our Experiment to be considerable and useful for refrigerating of Drinks, &c. but if the Sal Armoniack be of the fittest sort (for I intimated above, that I suspected, 'tis not equally good) and if the season of the year do make no disadvantagious difference, the degree of Cold, that may be produced by no more than one pound (if not by less) of Sal Armoniack, may, within its own Sphere of Activity, be much more vehement, than, I presume, you yet imagine, and may afford us excellent Standards to adjust seal'd Weather glasses by; and for several other purposes, For I remember that in the Spring, about the end of March, or beginning of April, I was able with one pound of Sal Armoniack, and a requisite proportion of Water, to produce a degree of Cold much greater, than was necessary the preceding Winter, to make it frosty Weather abroad; nay I was able to produce real Ice in a space of time, almost incredibly short. To confirm which particulars, because they will probably seem strange to you, I will here annex the Transcript of an entry, that I find in a Note book of the Phænomena and success of one of those Experiments, as I then tryed it; though I should be asham'd to expose to your perusal a thing so rudely pen'd; if I did not hope, you would consider, that 'twas hastily written onely for my own Remembrance. And that you may not stop at any thing in the immediately annext Note, or the two, that follow, it will be requisite to premise this Account of the seal'd Thermoscope; (which was a good one) wherewith these Observations were made; That the length of the Cylindrical pipe was 16. Inches; the Ball, about the bigness of a somewhat large Walnut, and the Cavity of the Pipe by guess about an eight or ninth part of an inch Diameter.
The First Experiment is thus registered. March the 27th, in the Seal'd Weather glass, when first put into the Water, the tincted Spirit rested at 8⅝ inches; being suffered to stay there a good while, and now and then stirr'd to and fro in the Water; it descended at length a little beneath 7⅝ inches; then the Sal Armoniack being put in, within about a quarter of an hour or a little more it descended to 211/16 inches, but before that time, in half a
quarter of an hour it began manifestly to freeze the vapours and drops of water on the outside of the Glass. And when the frigorifick power was arriv'd at the height, I several times found, that water, thinly plac'd on the outside, whilst the mixture within was nimbly stirr'd up and down, would freeze in a quarter of a minute (by a Minute-watch.) At about ¾ of an hour after the infrigidating Body was put in, the Thermoscope, that had been taken out a while before, and yet was risen but to the lowest freezing mark, being again put in the liquor, fell an inch beneath the mark. At about 2½ houres from the first Solution of the Salt I found the tincted liquor to be in the midst between the freezing marks, whereof the one was at 5½ inches (at which height when the Tincture rested, it would usually be, some, though but a small, frost abroad;) and the other at 4¾ inches; which was the height, to which strong and durable Frosts had reduced the liquor in the Winter. At 3 hours after the beginning of the Operation, I found not the Crimson liquor higher than the upper Freezing mark newly mention'd; after which, it continued to rise very slowly for about an hour longer; beyond which time I had not occasion to observe it.
Thus far the Note-book; wherein there is mention made of a Circumstance of some former Experiments of the like kind, which I remember was very conspicuous in this newly recited. For, the frigorifick mixture having been made in a Glass body (as they call it) with a large and flattish bottom, a quantity of water, which I (purposely) spilt upon the Table, was by the operation of the mixture within the Glass, made to freeze, and that strongly enough, the bottom of the Cucurbite to the Table; that stagnant liquor being turn'd into solid ice, that continued a considerable while unthaw'd away, and was in some places about the thickness of a half Crown piece.
Another Observation, made the same Spring, but less solemn, as meant chiefly to shew the Duration of Cold in a high degree, is recorded in these terms: The first time, the Seal'd Weather-glass was put in, before it touch'd the common water, it stood at 8⅛, having been left there a considerable while, and once or twice agitated the water, the tincted liquor sunk but to 7⅞, or at furthest, 76/8; then the frigorifick liquor being put into the water with circumstances disadvantagious enough in (about) half a quarter of an hour the tincted liquor fell beneath 3¾, and the Thermoscope, being taken out, and then put in again, an hour after the water had been first infrigidated subsided beneath 5 inches, and consequently within ¼ of an inch of the mark of the strongly freezing weather.
7. Whereas the grand thing, that is like to keep this Experiment from being as generally Useful, as perhaps it will prove Luciferous, is the Dearness of Sal Armoniack, two things may be offered to lessen this Inconvenience. For first, Sal Armoniack might be made much cheaper, if instead of fetching it beyond-sea, our Country-men made it here at home; (which it may easily be and I am ready to give you the Receipt, which is no great Secret.) But next, I considered, that probably the infrigidating vertue of our mixture might depend upon the peculiar Texture of the Sal Armoniack whereby, whilest the Water is dissolving it, either some Frigorifick particles are extricated and excited or (rather) some particles which did before more agitate the minute parts of the water, are expell'd (or invited out by the ambient Bodies) or
come to be clogg'd in their motion: Whence it seem'd reasonable to expect that upon the Reunion of the Saline particles into such a Body, as they had constituted before, the redintegrated Sal Armoniack having, neer upon, the same Texture, would, upon its being redissolv'd, produce the same, or a not much inferior degree of Coldness: And hereupon, though I well enough foresaw that an Armoniack solution, being boyl'd up in Earthen vessels (for Glass ones are too chargeable) would, by piercing them, both lose some of the more subtle parts, and thereby somewhat impaire the texture of the rest; yet I was not deceiv'd in Expecting, that the dry Salt, remaining in the pipkins, being redissolv'd in a due proportion of water, would very considerably infrigidate it; as may further appear by the Notes, which for your greater satisfaction you will find here subjoyn'd, as soon as I have told you, that, though for want of other vessels I was first reduc'd to make use of Earthen ones, and the rather, because some Metallin Vessels will be injur'd by the dissolv'd Sal Armoniack, if it be boyl'd in them; yet I afterwards found some conveniencies in Vessels of other Mettall, as of Iron; whereof you may command a further Account.