The chemical agencies discussed were the following: sulphurous and sulphuric acids, discharged in vast quantities into the air of the city, by the combustion of coal and gas, the decomposition of street refuse and sewer gas, etc.; carbonic, nitric, and hydrochloric acids; carbolic, hippuric, and many other organic acids derived from smoke, street dust, sewer vapors, etc.; oxygen and ozone, ammonia, and sea salt.
The mechanical and physical agencies discussed were the following: frost; extreme variations in temperature, amounting in our climate to 120° F. in a year, and even 70° in a single day; wind and rain, most efficient on fronts facing the north, northeast, and east; crystallization by efflorescence; pressure of superincumbent masonry; friction; and fire.
The organic agencies consist of vegetable growths, mostly confervæ, etc., within the city, and lichens and mosses without, and of boring mollusks, sponges, etc.
The internal elements of durability in a stone depend, first, upon the chemical composition of its constituent minerals and of their cement. This involves a consideration of their solubility in atmospheric waters, e. g., the calcium-carbonate of a marble or limestone, the ferric oxide of certain sandstones, etc.; their tendency to oxidation, hydration, and decomposition, e. g., of the sulphides (especially marcasite) in a roofing slate or marble, the biotite and ferruginous orthoclase in a granyte or sandstone, etc.; the inclosure of fluids and moisture, e. g., as "quarry-sap," in chemical combination, as hydrated silicates (chlorite, kaolin, etc.), and iron oxides, and as fluid cavities locked up in quartz, etc.
The durability of a stone depends again upon its physical structure, in regard to which the following points were discussed: the size, form, and position of its constituent minerals; e. g., an excess of mica plates in parallel position may serve as an element of weakness; the porosity of the rock permitting the percolation of water through its interstices, especially important in the case of the soft freestones, and leading to varieties of discoloration upon the light-colored stones, which were described in detail; the hardness and toughness, particularly in relation to use for pavements, sidewalks, and stoops; the crystalline structure, which, if well-developed, increases the strength of its resistance; the tension of the grains, which appears to explain especially the disruption of many crystalline marbles; the contiguity of the grains and the proportion of cement in their interstices; and the homogeneity of the rock.
Again, the durability of a rock may depend upon the character of its surface, whether polished, smoothly dressed, or rough hewn, since upon this circumstance may rest the rapidity with which atmospheric waters are shed, or with which the deposition of soot, street dust, etc., may be favored; also upon the inclination and position of the surface, as affecting the retention of rainwater and moisture, exposure to northeast gales and to burning sun, etc.
IV. METHODS OF TRIAL OF BUILDING STONE.
In such methods, two classes may be distinguished, the natural and the artificial.
The former embrace, first, the examination of quarry outcrops, where the exposure of the surface of the rock during ages may give some indication of its power of resistance to decomposition, e. g., the dolomitic marbles of New York and Westchester counties, some of which present a surface crumbling into sand; and, secondly, the examination of old masonry. Few old buildings have survived the changes in our restless city, but many observations were presented in regard to the condition of many materials, usually after an exposure of less than half a century.
Another source of information, in this regard, was found in the study of the stones erected in our oldest cemeteries, e. g., that of Trinity Church. There could hardly be devised a superior method for thoroughly testing by natural means the durability of the stone than by its erection in this way, with partial insertion in the moist earth, complete exposure to the winds, rain, and sun on every side, its bedding lamination standing on edge, and several of its surfaces smoothed and polished and sharply incised with dates, inscriptions, and carvings, by which to detect and to measure the character and extent of its decay. In Trinity Churchyard, the stones are vertical, and stand facing the east. The most common material is a red sandstone, probably from Little Falls, N. J., whose erection dates back as far as 1681, and which remains, in most cases, in very fair condition. Its dark color, however, has led to a frequent tendency to splitting on the western side of the slabs, i. e., that which faces the afternoon sun. Other materials studied consisted of bluestone, probably from the Catskills, black slate, gray slate, green hydromicaceous schist, and white oolitic limestone, all in good condition, and white marble, in a decided state of decay.