Gold and silver are mixed in smaller quantities with ores of other metals.
All these are continually exposed to atmospheric agencies toward which they act very differently. The oxidized ores of iron and tin do not change their character. The sulphur compounds, at least when near the surface, are oxidized, and hand in hand with this process goes the partial reduction of certain metals to the metallic state. Gold and silver, and to a less extent copper, are subject to this change; they are unmasked and are exposed to day light, not as stones, but as brilliant, malleable metals. Finally, the heavy ores and metallic particles are loosened from the rocks by the destructive action of water, floated off, elutriated, and washed. In undisturbed mountain ranges the mineral treasures lie in masses before our eyes.
The native shining and malleable metals (gold, silver, and copper) naturally first attracted the attention of man. They may have used the separate nuggets for ornaments as they found them, or after hammering them together into plates. This was surely the first step in the use of metals. It can scarcely be supposed that this use of soft native metals contributed much to the progress of mankind, and it is highly probable that in those early times the noble metal had but little value. The shining particles, as long as the natural supply lasted, seemed like worthless tinsel. Copper, which can be made into tools and vessels, as well as soft, poor weapons, was more highly prized. Such materials were not, indeed, suitable and able to take the place of stone tools and weapons; nevertheless, this working of metals served as preparation for the more complicated work of later times. Man learned to hammer and shape metals, and he found out that the operation was much facilitated by heating the metal.
The discovery of iron meteorites may have had some value. In these the smith first became acquainted with the properties of a hard metal. But I would not attach too much importance to this. The art of working metals is not the possession of a people that have a few meteoric knives. In my opinion the metallurgical preparation of the hard metals from their ores is alone decisive on this point.
The volks' sagas frequently mention some god or hero, who discovered and taught metallurgy, yet there is scarcely any doubt that the "god," in most cases, was human ingenuity led by chance.
We have already seen that only certain metals are found native, while the hard metals under normal conditions remain in the form of oxide or mineral. They have a strong affinity for the oxygen of the air, and can only be separated and converted into metals by powerful chemical agents. There is one substance which has a still more powerful attraction for oxygen than those metals. This is ignited carbon, which, in its fight with the metallic oxides, robs them of their oxygen.
Carbon has been separated from the carbonic acid of the air by the life-giving force of the sun, and vegetable life dependent upon it. But the isolated element waits impatiently for the impulse that will enable it to unite with the vital air under flame and heat. Men that know how to utilize this process of nature possess the means of resurrecting those metallic treasures which, without its powerful assistance, would remain forever hidden from their eyes. But accident, as we have said, pointed out the way.
In numerous places visited by primeval man, as hunter and fisherman, and afterward as nomad, conflagrations broke out. Not unfrequently whole forests were burned, either intentionally or not. It could not be otherwise than that the earth's surface would get red hot in such places, and if a strong wind favored it, this would suffice to open these treasures. The glowing charcoal would rob the ores of their oxygen and leave the pure metal as melted drops or cakes.[17] Copper, tin, and iron ores could have been reduced in this way; mankind not only knew the result but also the method of reducing metals.
This process took place not once merely, but thousands of times in various parts of the earth, and thus, in my opinion, metallurgy may have become known to different races of people and at different times.
A simple trench in the ground, in which a heap of glowing coals and some pieces of ore could be subjected to a strong draught of air, suffices, under favorable circumstances, for the preparation of the metal; the oldest metallurgists had scarcely any more complete means at hand for their work.