VINCENT'S CHLORIDE OF METHYL ICE MACHINE.
Chloride of methyl was discovered in 1840 by Messrs. Dumas and Peligot, who obtained it by treating methylic alcohol with a mixture of sea salt and sulphuric acid. It is a gaseous product at ordinary temperature, but when compressed and cooled, easily liquefies and produces a colorless, neutral liquid which enters into ebullition at 237.7° above zero and under a pressure of 0.76 m.
VINCENTS ICE MACHINE. FIG. 1.--THE FREEZER (Longitudinal Section).
Up to recent times, chloride of methyl in a free state had received scarcely any industrial application, by reason of the difficulty of preparing it in a state of purity at a low price. Mr. C. Vincent, however, has made known a process which permits of this product being obtained abundantly and cheaply. It consists in submitting to the action of heat the hydrochlorate of trimethylamine, which is obtained as a by-product in the manufacture of potash of beets. The hydrochlorate is thus decomposed into free trimethylamine, ammonia, and chloride of methyl. A washing with hydrochloric acid takes away all traces of alkali, and the gas, which is gathered under a receiver full of water, may afterward be dried by means of sulphuric acid, and be liquefied by pressure.
VINCENTS ICE MACHINE. FIG. 2.--THE FREEZER (Transverse Section).
Pure liquid chloride of methyl is now an abundant product. There are two uses to which it is applied: first, for producing cold, and second, for manufacturing coal tar colors.
