A cell whose resistance becomes greater as the battery power becomes greater, and vice versa, I call an "L B cell" signifying Like the Battery power. A "U B cell" is one whose resistance becomes greater as the battery power (or strength of current) becomes less, and vice versa, being Unlike the Battery power, or current strength.
These changes of resistance are not due to heating of the conductor or the selenium, and the following instance will illustrate this. I have one cell in which the selenium has about one-fourth inch square of surface melted on a brass block one inch thick. This cell measured, with 25 elements of Leclanche, 40,000 ohms. On changing the battery to 5 elements the resistance fell instantly to 30 ohms, and there remained. On again using the current from 25 elements, the resistance instantly returned to 40,000 ohms. Had these results been due in any degree to heating, the resistance would have changed gradually as the heat became communicated to the brass, whereas no such change occurred, the resistances being absolutely steady. Moreover, even the fusion of the selenium would not produce any such change.
The "U B" property does not ordinarily change the resistance of the cell to exceed ten times, i.e., the resistance with a weak current will not be over ten times as high as with a strong one. But I have developed the "L B" property to a far higher degree. Table C gives some recent results obtained with L B cells, including one whose resistance, with 25 elements Leclanche, was 11,381 times as high as with 8 elements, and which, after standing steadily at 123 ohms (and then at 325 ohms with 1 element), on receiving the current from 25 elements again returned to its previous figure of 1,400,000 ohms.
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TABLE C.
SENSITIVENESS TO CHANGE OF BATTERY POWER.
-----------------------+------------+------------+-------------
| Resistance | Resistance |
No. of cell. | with 25 | with 5 | Ratio of
| elements. | elements. | Change.
-----------------------+------------+------------+-------------
| ohms. | ohms. |
3/8 inch square, No. 1 | 40,000 | 30 | 1,333 to 1
3/8 " " " 2 | 13,000 | 40 | 325 "
1/4 " " " 1 | 1,400,000 | 123[⁵] | 11,381 "
1/2 " " " 2 | 500,000 | 62 | 8,064 "
1/2 " " " 5 | 3,500 | 21 | 167 "
Full size, No. 81 | 68,000 | 121 | 561 "
" " " 82 | 9,000 | 64 | 140 "
" " " 83 | 17,300 | 74 | 233 "
" " " 119 | 35,600 | 19 | 1,894 "
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The results in the table were obtained by changing the strength of current by throwing in more or less of the battery. Like results can be obtained by varying the current through the cell by any of the other methods before specified. The above measurements were in dark.
5. Dual state of selenium.—My cells, when first made seem to have two states or conditions. In one, their resistance is very low, in the other it is high. When in the low state they are usually not very sensitive, in any respect. I therefore raise the resistance, by sending an intermittent or an alternating current though the cells, and in their new condition they at once become extremely sensitive to light, currents, and other influences. In some cases they drop to the low state again, and require to be again brought up, until, after a number of such treatments, they remain in the sensitive state. Occasionally a cell will persist in remaining in the insensitive state. The before mentioned treatment raises it up for a moment, but, before the bridge can be balanced and the resistance measured, it again drops into the low or insensitive state. Some cells have been thus stimulated into the high or sensitive state repeatedly, and every means used to make them stay there, but without avail; and they have had to be laid aside as intractable.
In the earlier stages of my investigations, before the discovery of this dual state and the method of changing a cell from the insensitive to the sensitive condition, hundreds of cells were made, finished, and tested, only to be then ruthlessly destroyed and melted over, under the impression that they were worthless. Now, I consider nothing worthless, but expect sooner or later to make every cell useful for one purpose or another.
The most singular part of this phenomenon is the wide difference in the resistance of the cells in the two states. In the low state, it may be a few ohms, or even a few hundredths of an ohm. In the high state, it is the normal working resistance of the cell, usually between 5,000 and 200,000 ohms, but is often up among the millions. The spectacle of a little selenium being stimulated, by a few interruptions of the current through it, into changing its resistance from a fraction of an ohm up to a million or several millions of ohms, and repeatedly and instantly changing back and forth, up and down, through such a wide range, we might almost say changing from zero to infinity, and the reverse, instantly, is one which suggests some very far-reaching inquiries to the electrician and the physicist. What is the nature of electrical conductivity or resistance, and how is it so greatly and so suddenly changed?
6. Radio-electric current generators.—My cells can be so treated that will generate a current by simple exposure to light or heat. The light, for instance, passes through the gold and acts upon its junction with the selenium, developing an electromotive force which results in a current proceeding from the metal back, through the external circuit, to the gold in front, thus forming a photo-electric dry pile or battery. It should preferably be protected from overheating, by an alum water cell or other well known means.
The current thus produced is radiant energy converted into electrical energy directly and without chemical action, and flowing in the same direction as the original radiant energy, which thus continues its course, but through a new conducting medium suited to its present form. This current is continuous, constant, and of considerable electromotive force. A number of cells can be arranged in multiple arc or in series, like any other battery. The current appears instantly when the light is thrown upon the cell, and ceases instantly when the light is shut off. If the light is varied properly, by any suitable means, a telephonic or other corresponding current is produced, which can be utilized by any suitable apparatus, thus requiring no battery but the selenium cell itself. The strength of the current varies with the amount of light on the cell, and with the extent of the surface which is lighted.