In the Wm. Millar and Christian Fair Nichols patent for "Improvements in the means of accelerating the setting and hardening of cements," they take advantage of the hydraulicity of certain of the salts of magnesia, by which the cements set hard and quickly while wet. For accelerating the setting of cements they use carbonate of soda, alum, and carbonate of ammonia; for indurating or increasing the hardening properties of cements they use chloride of calcium, oxide of magnesia, and chloride of magnesia or bittern water; for obtaining an intense hardness they use oxychloride of magnesia. The inventors do not bind themselves to any fixed proportions, but give the following as the best within their knowledge. For colored concretes for casts or other purposes they use Carbonate of soda, 8.41; carbonate of ammonia, 1.12; chloride of magnesia, 0.28; borax, 0.56; water, 89.63; total, 100.00. For gray concrete for any purpose they use: Alum, 8.46; caustic soda, 0.28; whitening or chalk, 0.56; borax, 0.56; water, 90.14; total, 100.00. For floors or slabs in situ they add to cement, well mixed and incorporated with any required proportion of agglomerate for a base, liquid composition of the following proportions: Oxide of magnesia, 0.29; chloride of magnesia, 0.29; carbonate of soda or alum, 4.74; water, 94.68; total, 100.00. Articles manufactured by the invention are afterward wetted with chloride of calcium and placed in a bath containing a solution of silicate of soda or chloride of calcium. The strength of the chloride of calcium is equal to about 20 deg. specific gravity.
C.A. Wilkes and William Millar's improved "metallic compound for flooring, paving, and other purposes," has for its object to provide a paving compound which is not slippery or liable to soften in hot weather, which sets rapidly, and is durable. To three parts of blast furnace slag are added one part of hydraulic cement and enough water to give the proper consistency. To each gallon of water used is added one part of bittern water—the dregs from the manufacture of sea salt—or one part of brine, or about 5 per cent. of carbonate of soda, and 2½ per cent. of carbonate of ammonia. In the compound they sometimes use potash in the proportion of about 5 per cent. of the carbonate of ammonia and carbonate of soda, and when potash is used with bittern water or brine, the proportion of the latter is correspondingly reduced. The compound is of a blue gray color; but when a more striking color is desired, red or yellow oxide of iron may be added. When more speedy induration is necessary, they add about 1 oz. of copperas to every gallon of compound used. The claim is the admixture of bittern water, carbonate of soda, and carbonate of ammonia with the washed slag and cement.
Another improvement, by C.A. Wilkes, relates, in laying in situ any metallic or other materials for street roadways, to completing the convenience thereof by roughening or grooving the surfaces. The concrete is laid in a plastic condition upon a bed of hard core, broken stone, or preferably rough concrete. For footpaths the material may be laid in convenient sections, say 4 ft. to 8 ft. square and 2 in. to 4 in. thick; and in order to allow for the expansion of the material during the setting of the sections or subsequent variations in temperature, he packs the joints between the sections with a layer of felting cloth or other compressible material, thus forming expansion joints. Sometimes he slightly roughens the surface of the material, to give better foothold to pedestrians. Sometimes the grooving is made in imitation of ordinary granite paving sets. In tramway pavement there are grooves to give a grip to the horses' feet, and a slight camber between the rails. He states that a great advantage in laying a pavement by the method is that, when any repairs are necessary, a piece of the exact size can be manufactured at the works, and stamped to the same pattern as the adjoining pavement, then placed at once in position on the removal of the worn portion, thus saving the time necessary for the setting of the concrete on the spot.—The Engineer.
A NEW BLEACHING PROCESS.
In the spring of 1883 a Mr. J.B. Thompson, of New Cross, London, patented a new process of bleaching, the main feature of which consisted in the use of carbonic acid gas in a closed vessel to decompose the chloride of lime. The "chemicking" and "souring" operations he performed at one and the same time. The reactions which took place in his bleaching keir were stated by the inventor as follows:
Cl.\
1. Ca ) + CO₂ = CaCO₃ + Cl₂.
OCl./
2. OH₂ + Cl₂ = (ClH)₂ + O.
3. CaCO₃ + (ClH)₂ = CaCl₂ + CO₂ + H₂O.
That is, in 1 chloride of lime and carbonic acid react upon each other, producing chalk and nascent chlorine; in 2 the nascent chlorine reacts upon the water of the solution and decomposes it, producing hydrochloric acid and nascent oxygen, which bleaches; in 3 the hydrochloric acid just formed reacts upon chalk formed in 1, and produces calcium chloride and one equivalent of water, and at the same time frees the carbonic acid to be used again in the process of decomposing the chloride of lime.
When the process was first brought to the notice of the Lancashire bleachers, it met with an amount of opposition. Some bleaching chemists declared the process was not patentable, as fully half a century ago carbonic acid was known to decompose chloride of lime. The patentee's answer was emphatic, that carbonic acid gas had never been applied in bleaching before. After some delay one of the largest English cotton bleachers, Messrs. Ainsworth, Son & Co., Halliwell, Bolton, threw open their works for a fair test of the Thompson process on a commercial scale.