1. The amount of heat required to effect the change from the liquid to the vaporous state, commonly called the latent heat of vaporization.
2. The temperatures and pressures at which such change can be effected.
This latter attribute is of twofold importance; for, in order to avoid the renewal of the agent, it is necessary to deprive it of the heat acquired during vaporization, under such conditions as will cause it to assume the liquid form, and thus become again available for refrigeration. As this rejection of heat can only take place if the temperature of the vapor is somewhat above that of the cooling body which receives the heat, and which, for obvious reasons, is in all cases water, the liquefying pressure at the temperature of the cooling water, and the facility with which this pressure can be reached and maintained, is of great importance in the practical working of any refrigerating apparatus. Ammonia in its anhydrous form, the use of which is specially dealt with in this paper, is a liquid having at atmospheric pressure a latent heat of vaporization of 900, and a boiling point at the same pressure of 37½° below zero F. Water being unity, the specific gravity of the liquid at a temperature of 40° F. is 0.76, and the specific gravity of its vapor is 0.59, air being unity. In the use of ammonia, two distinct systems are employed. So far, however, as the mere evaporating or refrigerating part of the process is concerned, it is the same in both. The object is to evaporate the liquid anhydrous ammonia at such tension and in such quantity as will produce the required cooling effect. The actual tension under which this evaporation should be effected in any particular case depends entirely upon the temperature at which the acquirement of heat is to take place, or, in other words, on the temperature of the material to be cooled. The higher the temperature, the higher may be the evaporating pressure, and therefore the higher is the density of the vapor, the greater the weight of liquid evaporated in a given time, and the greater the amount of heat abstracted. On the other hand, it must be remembered that, as in the case of water, the lower the temperature of the evaporating liquid, the higher is the heat of vaporization. It is in the method of securing the rejection of heat during condensation of the vapor that the two systems diverge, and it will be convenient to consider each of these separately.
The Absorption Process.—The principle employed in this process is physical rather than mechanical. Ordinary ammonia liquor of commerce of 0.880 specific gravity, which contains about 38 per cent. by weight of pure ammonia and 62 per cent. of water, is introduced into a vessel named the generator. This vessel is heated by means of steam circulating through coils of iron piping, and a mixed vapor of ammonia and water is driven off. This mixed vapor is then passed into a second vessel, in order to be subjected to the cooling action of water. And here, owing to the difference between the boiling points of water and ammonia, fractional condensation takes place, the bulk of the water, which condenses first, being caught and run back to the generator, while the ammonia in a nearly anhydrous state is condensed and collected in the lower part of the vessel.
This process of fractional condensation is due to Rees Reece, and forms an important feature in the modern absorption machine. Prior to the introduction of this invention, the water evaporated in the generator was condensed with the ammonia, and interfered very seriously with the efficiency of the process by reducing the power of the refrigerating agent by raising its boiling point. In the improved form of apparatus, ammonia is obtained in a nearly anhydrous condition, and in this state passes on to the refrigerator. In this vessel, which is in communication with another vessel called the absorber, containing cold water or very weak ammonia liquor, evaporation takes place, owing to the readiness with which cold water or weak liquor absorbs the ammonia, water at 59° Fahr. absorbing 727 times its volume of ammonia vapor. The heat necessary to effect this vaporization is abstracted from brine or other liquid, which is circulated through the refrigerator by means of a pump. Owing to the absorption of ammonia, the weak liquor in the absorber becomes strengthened, and it is then pumped back into the generating vessel to be again dealt with as above described.
The absorption apparatus, as applied for cooling purposes, consists of a generator, which is a vessel of cast iron containing coils of iron piping to which steam at any convenient pressure is supplied; an analyzer, in which a portion of the water vapor is condensed, and from which it flows back immediately into the generator; a rectifier and condenser, in the upper portion of which a further condensation of water vapor and a little ammonia takes place, the liquid thus formed passing back by a pipe to the analyzer and thence to the generator, while in the lower portion the ammonia vapor is condensed and collected; and a refrigerator or cooler, into which the nearly anhydrous liquid obtained in the condenser is admitted by a pipe and regulating valve, and allowed to evaporate, the upper portion being in communication with the absorber.
Through this vessel weak liquor, which has been deprived of its ammonia in the generator, is continually circulated, after being first cooled in an economizer by an opposite current of strong cold liquor passing from the absorber to the generator, while, in addition, the liquor in the absorber, which would become heated by the liberation of heat due to the absorption and consequent liquefaction of the ammonia vapor, is still further cooled by the circulation of cold water. As the pressure in the absorber is much lower than that in the generator, the strong liquor has to be pumped into the latter vessel, and for this purpose pumps are provided. Though of necessity the various operations have been described separately, the process is a continuous one, strong liquor from the absorber being constantly pumped into the generator through the heater or economizer, while nearly anhydrous liquid ammonia is being continually formed in the condenser, then evaporated in the refrigerator and absorbed by the cool weak liquor passing through the absorber.
Putting aside the effect of losses from radiation, etc., all the heat expended in the generator will be taken up by the water passing through the condenser, less that portion due to the condensation of the water vapor in the analyzer, and plus the amount due to the difference between the temperature of the liquid as it enters the generator and the temperature at which it leaves the condenser. In the refrigerator the liquid ammonia, in becoming vaporized, will take up the precise quantity of heat that was given off during its cooling and liquefaction in the condenser, plus the amount due to the difference in heat of vaporization, owing to the lower pressure at which the change of state takes place in the refrigerator, and less the small amount due to the difference in temperature between the vapor entering the condenser and that leaving the refrigerator, less also the amount necessary to cool the liquid ammonia to the refrigerator temperature. When the vapor enters into solution with the weak liquor in the absorber, the heat taken up in the refrigerator is imparted to the cooling water, subject also to corrections for differences of pressure and temperature. The sources of loss in such an apparatus are:
a. Radiation and conduction of heat from all vessels and pipes above normal temperature, which can, to a large extent, be prevented by lagging.
b. Conduction of heat from without into all vessels and pipes that are below normal temperature, which can also to a large extent be prevented by lagging.