Mr. Chance's process for the recovery of sulphur from the waste signalizes the centenary of the Leblanc process; Parnell and Simpson are following in his wake, and lately Mr. F. Gossage, of Widnes, has been working on a process for the production of alkali, which enables him to save the sulphur of the sulphuric acid. In his process a mixture of 70 parts Leblanc salt cake (sulphate of soda) and 30 parts common salt is mixed with coal and heated in a furnace, and so reduced to sulphide of sodium. The resulting "ash" is then dissolved in water and exposed to the action of carbonic acid, when sulphureted hydrogen is given off, to be dealt with as in Mr. Chance's sulphur process, while bicarbonate of soda is formed and separates by precipitation from the solution of undecomposed common salt.
Ere long it is expected this new method will be in active operation in some Leblanc works, the plant of which will, in all probability, be utilized. It has these great advantages: The absence of lime, the recovery of the sulphur used in the first instance and the consequent absence of the objectionable tank waste. Thus a bright promise is held out that the days of alkali waste are numbered, and that the air in certain parts of Lancashire will be more balmy than it has been in the memory of the oldest inhabitant.—Chemist and Druggist.
THE FUELS OF THE FUTURE.
It is undeniable that in this country, at least, we are accustomed to regard coal as the chief, and, indeed, the only substance which falls to be considered under the name of fuel. In other countries, however, the case is different. Various materials, ranging from wood to oil, come within the category of material for the production of heat. The question of fuel, it may be remarked, has a social, an antiquarian, and a chemical interest. In the first place, the inquiry whether or not our supplies of coal will hold out for say the next hundred thousand years, or for a much more limited period only, has been very often discussed by sociologists and by geological authorities.
Again, it is clear that as man advances in the practice of civilized arts, his dependence upon fuel becomes of more and more intimate character. He not merely demands fire wherewith to cook his food, and to raise his own temperature or that of his dwelling, but requires fuel for the thousand and one manufacturing operations in which he is perpetually engaged. It is obvious that without fuel civilized life would practically come to an end. We cannot take the shortest journey by rail or steamboat without a tacit dependence upon a fuel supply; and the failure of this supply would therefore mean and imply the extinction of all the comforts and conveniences on which we are accustomed to rely as aids to easy living in these latter days. Again, socially regarded, man is the only animal that practices the fire-making habit. Even the highest apes, who will sit round the fire which a traveler has just left, and enjoy the heat, do not appear to have developed any sense or idea of keeping up the fire by casting fresh fuel upon it. It seems fairly certain, then, that we may define man as being a "fuel-employing animal," and in so doing be within the bounds of certitude. He may be, and often is, approached by other animals in respect of many of his arts and practices. Birds weave nest materials, ants make—and maul—slaves, beavers build dams, and other animals show the germs and beginnings of human contrivances for aiding the processes of life, but as yet no animal save man lights and maintains a fire. That the fire-making habit must have dawned very early in human history appears to be proved by the finding of ashes and other evidences of the presence of fire among the remains and traces of primitive man.
All we know, also, concerning the history of savage tribes teaches us that humanity is skillful, even in very rude stages of its progress, in the making of fire. The contrivances for obtaining fire are many and curious in savage life, while, once attained, this art seems to have not only formed a constant accompaniment but probably also a determining cause in the evolution of civilization. Wood, the fat of animals, and even the oils expressed from plants, probably all became known to man as convenient sources of fuel in prehistoric times. From the incineration of wood to the use of peat and coal would prove an easy stage in the advance toward present day practices, and with the attainment of coal as a fuel the first great era in man's fire-making habits may be said to end.
Beyond the coal stage, however, lies the more or less distinctively modern one of the utilization of gas and oil for fuel. The existence of great natural centers, or underground stores, of gas and oil is probably no new fact. We read in the histories of classic chroniclers of the blazing gases which were wont to issue from the earth, and to inspire feelings of superstitious awe in the minds of beholders. Only within a few years, however, have geologists been able to tell us much or anything regarding these reservoirs of natural fuel which have become famous in America and in the Russian province of Baku.
For example, it is now known that three products—gas, oil, and salt or brine—lie within natural receptacles formed by the rock strata in the order of their weight. This law, as has well been said, forms the foundation of all successful boring experiments, and the search for natural fuel, therefore, becomes as easy and as reliable a duty as that for artesian water or for coal. The great oil fever of the West was attended at first, as Professor M'Gee tells us, with much waste of the product. Wells were sunk everywhere, and the oil overflowed the land, tainting the rivers, poisoning the air, and often driving out the prospectors from the field of discovery. In Baku accidents and catastrophes have, similarly, been of frequent occurrence. We read of petroleum flowing from the ground in jets 200 feet high, and as thick as a man's body; we learn how it swept away the huge cranes and other machinery, and how, as it flowed away from the orifices, its course was marked by the formation of rivers of oil many miles in length.
In America the pressure of rock gas has burst open stills weighing over a ton, and has rushed through huge iron tanks and split open the pipes wherewith it was sought to control its progress. The roar of this great stream of natural gas was heard for miles around as it escaped from the outlet, and when it was ignited the pillar of flame illumined the surrounding country over a radius extending in some cases to forty miles. It is clear that man having tapped the earth's stores of natural fuel, stood in danger of having unloosed a monster whose power he seemed unable to control. Yet, as the sequel will show, science has been able to tackle with success the problems of mastering the force and of utilizing the energy which are thus locked up within the crust of the globe.