When it is desired to operate, the internal vessel, R, is filled with alcohol (3 quarts for the ordinary model). This serves as a refrigerant bath for the experiments to be made. The worm, S, having been put in communication with the carbonic acid cylinder, CO², the cock, Ro, of the latter is turned full on. The cock of the worm, which is closed, is opened slightly. The vaporization and expansion of the liquid carbonic acid cause it to congeal in the form of snow, which distributes itself and circulates in the worm, S, and then in R. The flakes thus coming in contact with the metallic sides of S rapidly return to the gaseous state and produce an energetic refrigeration. At the lower part of the annular space, R', are placed fragments of sponge impregnated with alcohol. The snow that has traversed the worm without vaporizing reaches R'. and dissolves in this alcohol, and the refrigeration that results therefrom completes the lowering of the temperature. The gas finally escapes at O, and then through the bent tube, T'.
The apparatus may be constructed with an inverse circulation, the carbonic acid then entering the annular vessel, R, directly, and afterward the worm, S, whence it escapes to the exterior of the apparatus. The expansion cock sometimes becomes obstructed by the solidification of the snow. It will then suffice to wait until the circulation becomes re-established of itself. It may be brought about by giving the cock, Ro', a few turns with the wooden handled key that serves to maneuver the latter. It is not necessary to have a large discharge of carbonic acid, and consequently the expansion cock needs to be opened but a little bit. A few minutes suffice to reduce the temperature of the alcohol bath to 70°, with an output of about from 4½ to 5½ lb. of liquid carbonic acid. When the circulation is arrested, the apparatus thus surrounded by its isolating protective jackets becomes heated again with extreme slowness. In one experiment, it was observed that at the end of nine hours the temperature of the alcohol had risen but from 70° to 22°. On injecting a very small quantity of liquid carbonic acid from time to time, a sensibly constant and extremely low temperature may be maintained indefinitely.--Le Genie Civil.
METHOD OF PRODUCING ALCOHOL.
In carrying out my improved process in and with the apparatus employed in ordinary commercial distilleries, says Mr. Alfred Springer, of Cincinnati, O.. I preferably employ separate vats or tubs for the nitric acid solution and the material to be treated, and a convenient arrangement is to locate the nitric acid tub directly under the grain tub, so that one may discharge into the other. In the upper vat is placed the farinaceous material, preferably ground, thoroughly steeped in three times its weight of water, and, where whole grain is used, preferably "cooked" in the ordinary manner. The vat into which the dilute acid is placed is an ordinary cooking tub of suitable material to resist the acid, provided with closed steam coils and also nozzles for the discharge of steam into the contained mass. Into this vat is placed for each one hundred parts of the grain to be treated one part of commercial nitric acid diluted with fifty parts of water and brought to a state of ebullition and agitation by the steam coils and the discharge through the nozzles, the latter being regulated so that the gain by condensation of steam approximately equals the loss by evaporation. The farinaceous contents of the upper vat are allowed to flow slowly into the nitric acid solution while the ebullition and agitation of the mass is continued. This condition is then maintained for six to eight hours, after which the mass is allowed to stand for one day or until the saccharification becomes complete. The conversion can be followed by the "iodine test" for intermediary dextrins and the "alcohol test" for dextrin. After the saccharification is complete I may partially or wholly neutralize the nitric acid, preferably with potassium or Ammonium carbonate, preferably employing only one-half the amount necessary to neutralize the original quantity of nitric acid used, so that the mass now ready to undergo fermentation has an acid reaction. The purpose in view here is to keep the peptones in solution also, because an acid medium is best adapted to the propagation of the yeast cells. It is not absolutely necessary to even partially neutralize the nitric acid, but it is preferable. Yeast is now added, and the remaining processes are similar to those generally employed in distilleries, excepting that just prior to distillation potassium carbonate sufficient to neutralize the remaining nitric acid is added, in order to avoid corrosion of the still and correct the acid reaction of the slop.
As a variant of the process I sometimes add to the usual amount of nitric acid an additional one one-hundredth part of phosphoric acid on account of its beneficial nutritive powers--that is to say, to one hundred parts of grain one part of nitric acid and one one-hundredth part of phosphoric acid.
While my improved process is based on the well-known converting power of acids on starch, I am not aware that it has ever been applied in the manner and for the purposes I have described. For example, sulphuric and hydrochloric, also sulphuric and nitric, acids have been employed in the manufacture of glucose; but in every such case the resulting products were not capable of superseding those obtained by the existing methods of saccharification used in distilleries. In my process, on the other hand, the product is so capable. Not only may malted grain be entirely omitted, but more fermentable products are formed and the products of fermentation are purer. The saccharification being more complete, there are less intermediary and nonfermentable dextrins, and the yield of spirits is therefore increased. Malted grain being omitted or used in reduced quantity, there is less lactic acid and few or foreign ferments to contaminate the fermenting mass; also, the formation of higher alcohols than the ethyl alcohol is almost totally suppressed. Consequently the final yield of spirits is purer in quality and requires little or no further purification. Also, further, the nitrates themselves acting as nutrients to the yeast cells, these become more active and require less nutrition to be taken from the grain.