There are about fifty patents for this object and with all of them before their eyes, the British Society for the Advancement of Art still hold the $5,000 reward for a pigment or covering which will perfectly protect from rust and fouling. However they may puff their products for selling, no one has the temerity to claim that they deserve the reward.
We think it would be difficult to find so many expedients ever before adopted for the accomplishment of any one object. These are all English patents, England having necessarily been obliged to use iron for vessels from its cheapness as well as its consequent first introduction there. In the United States no patents worth mentioning have been granted.
The first requisites for a pigment or coating for iron are, that it should not contain any copper--the corrosive action of that metal on iron being intense. Then if for work exposed to air it should form such a coating as to be impervious to that gaseous fluid, and be so constituted chemically as not to be oxidizable by it; if under water--especially sea water--to be impermeable to moisture, so elastic as not to crack, so insoluble as not to chloridize; to form a perfect, apparently hard, coating: and yet wear just enough to keep off incrustation, barnacles, or growth of grass. In fact, this slow wearing away is the only preventive of fouling in iron vessels. Wooden bottoms may be poisoned by solutions of copper--and that metal has no superior for such uses, especially when it is combined in mixture with mineral or resinous tars and spirits--these compounds, however, are not only useless on iron bottoms, but also injurious. What then is the substance: 1st. One of the oxides of lead (red lead). 2d. The purest oxide of iron to be found. If properly made these articles can be carried to no higher state of oxidation, and respectively, as to order named, they have no superiors for body and durability. By preference, 1st, red lead, either out of or under water; 2d, Prince's oxide of iron only, out of water. The color of these paints--the first red, the latter brown, may be hidden by a coat of white or tinted color. If there were to be had in combination as a white paint, an oxide of lead and an oxide of zinc, it would be immensely superior to either, but that such has not been produced is rather the fault of carelessness than of possibility. Zinc protects iron with great effect, but it is too rapidly worn in the effort to be of lasting value. Hence the great desideratum, the yet to be, the coming pigment is a white oxide of lead or a combined white oxide of lead and white oxide of zinc, without sulphates or chlorides.
Those materials answer very well for work exposed to atmospheric air, and perhaps nothing will ever be found better; but a different need is that for salt water. No mere protector of the iron from rust can be found superior to pure red lead and linseed oil. We have seen a natural combination of zinc, lead, and iron, which, in our experience, ranks next; but the zinc is acted on by the chloride of sodium, and wears away too much of the material. Red lead, however, while covering the iron perfectly and effectually preventing rust, and also having but little disposition to chloridize, when it does, will foul both with grass and barnacles. Hence, the first desideratum being obtained, how shall we accomplish the other. The prevention of fouling may be accomplished in two ways: First, cover the vessel's bottom with two or even three coats of red lead, and give each time to dry hard. Then melt in an iron pot a mixture of two parts beeswax, two parts tallow, and one part pine resin; mix thoroughly, and apply hot one or two coats. This mixture may be tinted with vermilion or chrome green. It is not necessary to use any poisonous substance, as it is only by its softness and gradual wear that it is kept clean. Second, mix red lead and granular metallic zinc, ground fine, or such a mineral as we have mentioned--crystalline and granular in its character. Put on two or three coats, and allow each to set--they will never dry hard. The zinc will slowly wear off, keeping the whole surface clean, while there will be left enough coating of the lead to preserve the iron from rust. The oil I would urge for these pigments is linseed--as little boiled as possible, to be thinned with spirits of turpentine. There seems to have been a mania for mixtures of tar and resins, their spirits and oils; my experience fails to show me any advantage for them on an iron bottom. They have neither elasticity nor durability, while linseed oil has both in a pre-eminent degree, and is no more likely to foul than they, when in a combination that does not dry hard. Besides they are difficult to grind, inconvenient to transport, and offensive to use.
Perhaps we have not, in the opinion of some, answered the want expressed in the first paragraph. No pigment with the requisites of durability and cheapness will resist the attacks of strong acids on iron. The first we have mentioned will--all such as may float in our air from factories or chemical works. Chemically it is converted by nitric acid and chlorine into an insoluble substance--plumbic acid or the cyanide of lead. An experience of more than three years, with almost unlimited means at our command for experiment, demonstrates to us that we have indicated the means of filling the other requisites asked for. It may be that something new will be discovered, but we doubt it. Let any one tread the road we have trod, investigate and experiment where and as much as we have, and, if that place is, where we have not, and their experience will be the same as ours.
THE BANANAS AND PLANTAINS OF THE TROPICS.
[For the Scientific American.]
Poets have celebrated the banana plant for its beauty, its luxuriance, the majesty of its leaves, and the delicacy of its fruit; but never have they sufficiently praised the utility of this tropical product. Those who have never lived in southern countries are unable to fully appreciate its value. Some look even with indifference upon the gigantic clusters of this fruit, as they are unloaded from the steamers and sailing vessels; and yet they deserve special attention and admiration, for they are to the inhabitants of the torrid zone, what bread and potatoes are to those of the north temperate zone.