CHEVREUL'S BLACK.
T. O'CONOR SLOANE, PH.D.
The production of absolute black by a pigment or surface coloration has been shown by Chevreul to be an impossibility. No substance is known that does not possess the power of reflecting light to some extent. If paper is blackened, its surface will reflect rays that can act powerfully upon the sensitive plate in a camera, even if the eye, by convention and association, would determine it to be actually black. The same is to be said of black silk and velvet. The latter, more than any other substance, approaches real black. It is an object of common observation that all colors show much more strongly in velvet than in any other material. The reason for this is that, owing to the depth of the pile, the light undergoes multiple reflection. The percentage of white light is diminished with each reflection, and the colored rays become less and less contaminated with those of other hues. The same reasoning applies to black velvet. The light by multiple reflection from its substance is more and more absorbed, and the familiar intense black is the result. A piece of this material, placed upon cloth or silk, always appears, and is, the blacker. In choosing velvet for such experiments, care must be taken not to use a blue black. The dead black is the proper one to select.
CHEVREUL'S BLACK.
Black being the absence of color is producible by excluding light. The production of the velvet black, we have seen, depends on the mechanical texture of the goods. Nothing is so black as a perfectly dark room. Carrying out these principles, Chevreul devised the wonderfully ingenious way of producing a true black which we illustrate.
He lined the interior of a box with black. Pigment, black silk, or black velvet may be used. In the cover of the box he made a hole, not too large, but bearing a certain ratio to the area of the cover. The size should not exceed one-tenth this surface. The spot thus produced reflected no light, as there was no surface. The interior of the box, by color and shadow, was prevented from reflecting any light, so that absolute blackness resulted. The blackest velvet or silk placed alongside of this spot appears lighter in color.
In constructing the apparatus illustrated, a famous proverb was selected as a theme, in which a certain personage is stated not to be so black as he is painted. The author of "English as She is Spoke" renders this proverb, "He not so devil as he is black." The blackness of this image is absolute.
A pasteboard box is lined with black silk or velvet, and any desired figure is cut through the cover. This may then be painted as black as possible, or before the figure is cut out, silk or velvet may be pasted over it, and the figure cut through pasteboard and covering together.
Then, on putting the cover in place, holding the box so that a side light will fall upon it, thus preventing direct access of light rays to the interior, the figure will stand out strongly black against a background which, but for the contrast, would itself be pronounced absolutely black.
To apply the most rigorous test, a member of the Society of Amateur Photographers of New York made a photograph of such a box. A carbon B dry plate was used, with thirty-five minutes' exposure, with stop f-30. The result was a negative perfectly transparent where the figure came, but strongly affected by the black box cover. Part of the cover was coated with black silk and part was painted, but both reflected light enough to produce a full photograph upon the plate.