(1) Separate pieces, for example, of gold in one, silver in another, copper in the third, likewise tin, lead, etc.
(2) In other similar vessels I put pieces of the same metals in pairs, a more oxidizable and a less oxidizable metal in each pair' but separated from each other by strips of glass
(3) Finally, I put in other vessels pairs of different metals which were placed in immediate contact with each other.
The first two series suffered no marked change, while in the latter series the more oxidizable metal became visibly covered with oxide in a few instants after the contact was made.'
Fabroni found that under the above circumstances his oxidizable metals dissolved in the water, and in some cases salts were formed which crystallized out. He then compares the metals in contact with each other in water with the metals on the tongue when brought into contact, as in Sulzer's experiment, and the two metals touching each other by which different points on a nerve were touched to produce the muscular twitchings in Galvani's experiments, and concludes that the chemical action upon the metals was the same in each case, and that the other phenomena observed must have resulted from this chemical action. It is not strange that when Volta showed later that an electric current passed between the metals in all of tho above cases Fabroni should regard the chemical action which he had previously observed as the cause of this current.
Ten years after the publication of Fabroni's original paper, Volta wrote a letter to J. C. Delamethrie which was published in Vol. I of Nicholson's Journal. This letter was written after the chemical changes in the voltaic cell had received a great deal of attention by many experimenters, the most prominent of whom was Davy. To show that Volta's theory as to the source of the current was not affected by these investigations, a quotation from this letter is given below.
'You have requested me to give you an account of the experiments by which I demonstrate, in a convincing manner, what I have always maintained, namely, that the pretended agent, or GALVANIC FLUID, is nothing but common electrical FLUID, and that this fluid is incited and moved by the simple MUTUAL CONTACT OF DIFFERENT CONDUCTORS, particularly the metallic; strewing that two metals of different kinds, connected together, produce already a small quantity of true electricity, the force and kind of which I have determined; that the effects of my new apparatus (which might be termed electromotors), whether consisting of a pile, or in a row of glasses, which have so much excited the attention of philosophers, chemists, and physicians; that these so powerful and marvelous effects are absolutely no more than the sum total of the effects of a series of several similar metallic couples or pairs; and that the chemical phenomena themselves, which are obtained by them, of the decomposition of water and other liquids, the oxidation of metals, &c., are secondary effects; effects, I mean, of this electricity, of this continual current of electrical fluid, which by the above mentioned action of the connected metals, establishes itself as soon as we form a communication between the two extremities of the apparatus, by means of a conducting bow; and when once established, maintains itself, and continues as long as the circuit remains interrupted.'[3]
[3] This seems to be a misprint for uninterrupted.
Further along in the same letter Volta reiterates his conviction that the contact of the two metals furnishes the true motive power of the current. Thus he says (p. 138):
'As to the rest, the action which excites and gives motion to the electric fluid does not exert itself, as has been erroneously thought, at the contact of the wet substance with the metal, where it exerts so very small an action, that it may be disregarded in comparison with that which takes place, as all my experiments prove, at the place of contact of different metals with each other. Consequently the true element of my electromotive apparatus, of the pile, of cups, and others that may be constructed according to the same principles, is the simple metallic couple, or pair, composed of two different metals, and not a moist substance applied to a metallic one, or inclosed between two different metals, as most philosophers have pretended. The humid strata employed in these complicated apparatus are applied therefore for no other purpose than to effect a mutual communication between all the metallic pairs, each to each, ranged in such a manner as to impel the electric fluid in one direction, or in order to make them communicate, so that there may be no action in a direction contrary to the others.'