The widely increasing scope of usefulness of the internal-combustion motor has made it imperative that other fuels be applied in some instances because the supply of gasoline may in time become inadequate to supply the demand. In fact, abroad this fuel sells for fifty to two hundred per cent. more than it does in America because most of the gasoline used must be imported from this country or Russia. Because of this foreign engineers have experimented widely with other substances, such as alcohol, benzol, and kerosene, but more to determine if they can be used to advantage in motor cars than in airplane engines.
DISTILLATES OF CRUDE PETROLEUM
Crude petroleum is found in small quantities in almost all parts of the world, but a large portion of that produced commercially is derived from American wells. The petroleum obtained in this country yields more of the volatile products than those of foreign production, and for that reason the demand for it is greater. The oil fields of this country are found in Pennsylvania, Indiana, and Ohio, and the crude petroleum is usually in association with natural gas. This mineral oil is an agent from which many compounds and products are derived, and the products will vary from heavy sludges, such as asphalt, to the lighter and more volatile components, some of which will evaporate very easily at ordinary temperatures.
The compounds derived from crude petroleum are composed principally of hydrogen and carbon and are termed “Hydrocarbons.” In the crude product one finds many impurities, such as free carbon, sulphur, and various earthy elements. Before the oil can be utilized it must be subjected to a process of purifying which is known as refining, and it is during this process, which is one of destructive distillation, that the various liquids are separated. The oil was formerly broken up into three main groups of products as follows: Highly volatile, naphtha, benzine, gasoline, eight to ten per cent. Light oils, such as kerosene and light lubricating oils seventy to eighty per cent. Heavy oils or residuum five to nine per cent. From the foregoing it will be seen that the available supply of gasoline is determined largely by the demand existing for the light oils forming the larger part of the products derived from crude petroleum. New processes have been recently discovered by which the lighter oils, such as kerosene, are reduced in proportion and that of gasoline increased, though the resulting liquid is neither the high grade, volatile gasoline known in the early days of motoring nor the low grade kerosene.
PRINCIPLES OF CARBURETION OUTLINED
The process of carburetion is combining the volatile vapors which evaporate from the hydrocarbon liquids with certain proportions of air to form an inflammable gas. The quantities of air needed vary with different liquids and some mixtures burn quicker than do other combinations of air and vapor. Combustion is simply burning and it may be rapid, moderate or slow. Mixtures of gasoline and air burn quickly, in fact the combustion is so rapid that it is almost instantaneous and we obtain what is commonly termed an “explosion.” Therefore the explosion of gas in the automobile engine cylinder which produces the power is really a combination of chemical elements which produce heat and an increase in the volume of the gas because of the increase in temperature.
If the gasoline mixture is not properly proportioned the rate of burning will vary, and if the mixture is either too rich or too weak the power of the explosion is reduced and the amount of power applied to the piston is decreased proportionately. In determining the proper proportions of gasoline and air, one must take the chemical composition of gasoline into account. The ordinary liquid used for fuel is said to contain about eight-four per cent. carbon and sixteen per cent. hydrogen. Air is composed of oxygen and nitrogen and the former has a great affinity, or combining power, with the two constituents of hydro-carbon liquids. Therefore, what we call an explosion is merely an indication that oxygen in the air has combined with the carbon and hydrogen of the gasoline.
AIR NEEDED TO BURN GASOLINE
In figuring the proper volume of air to mix with a given quantity of fuel, one takes into account the fact that one pound of hydrogen requires eight pounds of oxygen to burn it, and one pound of carbon needs two and one-third pounds of oxygen to insure its combustion. Air is composed of one part of oxygen to three and one-half portions of nitrogen by weight. Therefore for each pound of oxygen one needs to burn hydrogen or carbon four and one-half pounds of air must be allowed. To insure combustion of one pound of gasoline which is composed of hydrogen and carbon we must furnish about ten pounds of air to burn the carbon and about six pounds of air to insure combustion of hydrogen, the other component of gasoline. This means that to burn one pound of gasoline one must provide about sixteen pounds of air.
While one does not usually consider air as having much weight, at a temperature of sixty-two degrees Fahrenheit about fourteen cubic feet of air will weigh a pound, and to burn a pound of gasoline one would require about two hundred cubic feet of air. This amount will provide for combustion theoretically, but it is common practice to allow twice this amount because the element nitrogen, which is the main constituent of air, is an inert gas and instead of aiding combustion it acts as a deterrent of burning. In order to be explosive, gasoline vapor must be combined with definite quantities of air. Mixtures that are rich in gasoline ignite quicker than those which have more air, but these are only suitable when starting or when running slowly, as a rich mixture ignites much quicker than a weak mixture. The richer mixture of gasoline and air not only burns quicker but produces the most heat and the most effective pressure in pounds per square inch of piston top area.