By permission of
Dick, Kerr & Co. Ltd.
HYDRO-ELECTRIC POWER STATION.
In a voltaic cell the plates are at different potentials, so that when they are connected by a wire a current flows, and we say that the current leaves the cell at the positive terminal, and enters it again at the negative terminal. As shown in [Fig. 7], the current moves in opposite directions inside and outside the cell, making a complete round called a circuit, and if the circuit is broken anywhere the current ceases to flow. If the circuit is complete the current keeps on flowing, trying to equalize the electric pressure or potential, but it is unable to do this because the chemical action between the acid and the zinc maintains the difference of potential between the plates. This chemical action results in wasting of the zinc and weakening of the acid, and as long as it continues the current keeps on flowing. When we wish to stop the current we break the circuit by disconnecting the wire joining the terminals, and the cell then should be at rest; but owing to the impurities in ordinary commercial zinc chemical action still continues. In order to prevent wasting when the current is not required the surface of the zinc is coated with a thin film of mercury. The zinc is then said to be amalgamated, and it is not acted upon by the acid so long as the circuit remains broken.
The current from a simple voltaic cell does not remain at a constant strength, but after a short time it begins to weaken rapidly. The cell is then said to be polarized, and this polarization is caused by bubbles of hydrogen gas which accumulate on the surface of the copper plate during the chemical action. These bubbles of gas weaken the current partly by resisting its flow, for they are bad conductors, and still more by trying to set up another current in the opposite direction. For this reason the simple voltaic cell is unsuitable for long spells of work, and many cells have been devised to avoid the polarization trouble. One of the most successful of these is the Daniell cell. It consists of an outer vessel of copper, which serves as the copper plate, and an inner porous pot containing a zinc rod. Dilute sulphuric acid is put into the porous pot and a strong solution of copper sulphate into the outer jar. When the circuit is closed, the hydrogen liberated by the action of the zinc on the acid passes through the porous pot, and splits up the copper sulphate into copper and sulphuric acid. In this way pure copper, instead of hydrogen, is deposited on the copper plate, no polarization takes place, and the current is constant.
Other cells have different combinations of metals, such as silver-zinc, or platinum-zinc, and carbon is also largely used in place of one metal, as in the familiar carbon-zinc Leclanché cell, used for ringing electric bells. This cell consists of an inner porous pot containing a carbon plate packed round with a mixture of crushed carbon and manganese dioxide, and an outer glass jar containing a zinc rod and a solution of sal-ammoniac. Polarization is checked by the oxygen in the manganese dioxide, which seizes the hydrogen on its way to the carbon plate, and combines with it. If the cell is used continuously however this action cannot keep pace with the rate at which the hydrogen is produced, and so the cell becomes polarized; but it soon recovers after a short rest.
The so-called “dry” cells so much used at the present time are not really dry at all; if they were they would give no current. They are in fact Leclanché cells, in which the containing vessel is made of zinc to take the place of a zinc rod; and they are dry only in the sense that the liquid is taken up by an absorbent material, so as to form a moist paste. Dry cells are placed inside closely fitting cardboard tubes, and are sealed up at the top. Their chief advantage lies in their portability, for as there is no free liquid to spill they can be carried about and placed in any position.
We have seen that the continuance of the current from a voltaic cell depends upon the keeping up of a difference of potential between the plates. The force which serves to maintain this difference is called the electro-motive force, and it is measured in volts. The actual flow of electricity is measured in amperes. Probably all my readers are familiar with the terms volt and ampere, but perhaps some may not be quite clear about the distinction between the two. When water flows along a pipe we know that it is being forced to do so by pressure resulting from a difference of level. That is to say, a difference of level produces a water-moving or water-motive force; and in a similar way a difference of potential produces an electricity-moving or electro-motive force, which is measured in volts. If we wish to describe the rate of flow of water we state it in gallons per second, and the rate of flow of electricity is stated in amperes. Volts thus represent the pressure at which a current is supplied, while the current itself is measured in amperes.
We may take this opportunity of speaking of electric resistance. A current of water flowing through a pipe is resisted by friction against the inner surface of the pipe; and a current of electricity flowing through a circuit also meets with a resistance, though this is not due to friction. In a good conductor this resistance is small, but in a bad conductor or non-conductor it is very great. The resistance also depends upon length and area of cross-section; so that a long wire offers more resistance than a short one, and a thin wire more than a thick one. Before any current can flow in a circuit the electro-motive force must overcome the resistance, and we might say that the volts drive the amperes through the resistance. The unit of resistance is the ohm, and the definition of a volt is that electro-motive force which will cause a current of one ampere to flow through a conductor having a resistance of one ohm. These units of measurement are named after three famous scientists, Volta, Ampère, and Ohm.
