Science in Short Chapters

by W. Mattieu Williams

The scoria thus formed will float upon the heavy metals below and protect them from cooling by resisting their radiation; but if in the course of contraction of this crust some fissures are formed reaching to the melted metals below, the pressure of the floating solid will inject the fluid metal upwards into these fissures to a height corresponding to the flotation depth of the solid, and thus form metallic veins permeating the lower strata of the crust. I need scarcely add that this would rudely but fairly represent what we know of the earth.

But it may be objected that I only describe an imaginary experiment. This is true as regards the whole of the materials united in a single fusion. Nobody has yet produced a complete model with platinum and gold in the centre, and all the other metals arranged in theoretical order with the oxidized, silicated, and carbonated crust outside; but with a limited number of elements this has been done, is being done daily, on a scale of sufficient magnitude to amply refute Sir William Thomson’s description of a fused earth solidifying from the centre outwards.

This refutation is to be seen in our blast furnaces, refining furnaces, puddling furnaces, Bessemer ladles, steel melting-pots, cupels, foundry crucibles; in fact, in almost every metallurgical operation down to the simple fusion of lead or solder in a plumber’s ladle, with its familiar floating crust of dross or oxide.

As an example I will, on account of its simplicity, take the open hearth finery and the refining of pig-iron. Here a metallic mixture of iron, silicon, carbon, sulphur, etc., is simply fused and exposed to the superficial action of atmospheric air. What is the result?

Oxidation of the more oxidizable constituents takes place, and these oxides at once arrange themselves according to their specific gravities. The oxidized carbon forms atmospheric matter and rises above all as carbonic acid, then the oxidized silicon, being lighter than the iron, floats above that, and combines with aluminium or calcium that may have been in the pig and with some of the iron; thus forming a silicious crust closely resembling the predominating material of the earth’s crust.

When the oxidation in the finery is carried far enough, the melted material is tapped out into a rectangular basin or mould, usually about 10 feet long and about 3 feet wide, where it settles and cools. During this cooling the silica and silicates—i.e., the rock matter—separate from the metallic matter and solidify on the surface as a thin crust, which behaves in a very interesting and instructive manner. At first a mere skin is formed. This gradually thickens, and as it thickens and cools becomes corrugated into mountain chains and valleys much higher and deeper, in proportion to the whole mass, than the mountain chains and valleys of our planet. After this crust has thickened to a certain extent volcanic action commences. Rifts, dykes, and faults are formed by the shrinkage of the metal below, and streams of lava are ejected. Here and there these lava streams accumulate around their vent and form insulated conical volcanic mountains with decided craters, from which the eruption continues for some time. These volcanoes are relatively far higher than Chimborazo. The magnitude of these actions varies with the quality of the pig-iron.

The open hearth finery is now but little used, but probably some are to be seen at work occasionally in the neighborhood of Glasgow, and I am sure that Sir William Thomson will find a visit to one of them very interesting. Failing this, he may easily make an experiment by tapping into a good-sized “cinder bogie” some melted pig-iron from a pudding furnace (taking it just before the iron “comes to nature”), and leaving the melted mixture to cool slowly and undisturbed.

The cinder of the blast furnace, which in like manner floats on the top of the melted pig-iron, resembles still more closely the prevailing rock-matter of the earth, on account of the larger proportion, and the varied compounds, of earth-metals it contains.

For the volcanic phenomena alone he need simply watch what occurs when in the ordinary course of puddling the cinder is run into a large bogie, and the bogie is left to cool standing upright. I need scarcely add that these phenomena strikingly illustrate and confirm Mr. Mallett’s theory of earthquakes, volcanoes, and mountain-formation.

In merely passing through an iron-making district one may see the results of what I have called the volcanic action, by simply observing the form of those oyster-shaped or cubical blocks of cinder that are heaped in the vicinity of every blast furnace that has been at work for some time. Radial ridges or consolidated miniature lava-streams are visible on the exposed face of nearly, if not quite all of these. They were ejected or squeezed up from below while the mass was cooling, when the outer crust had consolidated but the inner portion still remained liquid. Many of these are large enough, and sufficiently well-marked, to be visible from a railway carriage passing a cinder heap near the road.[12]