Photo-engraving, Photo-etching and Photo-lithography in Line and Half-tone / Also Collotype and Heliotype

by W. T. Wilkinson

The bath is now in proper working order, and if reinforced after each day’s work with a sufficient quantity of saturated solution of nitrate of silver (filtered), kept free from contamination with other chemicals, and carefully filtered occasionally, it will remain in good working order for at least six months, and then may be renewed by treating as directed on page [12.]

It will sometimes happen, notwithstanding that extreme care and cleanliness is exercised in the management of the bath, that it will not work properly, and the reason why cannot easily be discovered. In such a case, steps must be taken to put the solution into working order.

In the case of rectifying a disordered bath, there are many methods of procedure, but the simplest, and, as a rule, the most certain method, is to render the solution alkaline by the addition of liquor ammonia, adding the ammonia a little at a time; then, after well shaking, test it with red litmus paper and continue the addition of ammonia until the red litmus paper is turned blue. In this alkaline condition the solution should be poured into a large flat dish, and exposed to the action of the sun. That will speedily reduce and throw down in the form of a black precipitate, any organic matter that may be in the bath, and at the same time the heat of the sun will cause evaporation of the ether and alcohol left in the solution by the collodion plates.

The bath solution should be exposed to the sun for two or three days, or until such time as suffices to render the solution clear, and the precipitate entirely separated out. But this cannot take place unless the solution is decidedly alkaline, the presence of acid stopping the action of light.

Do not be in a hurry about doctoring a bath solution (in fact, it will be far best to have two solutions, one in use and one either resting or being doctored), but give the light plenty of time to reduce the organic matter, and also to {16} volatilize the ether and alcohol; then filter the solution through filtering paper (don’t use blotting-paper), as if it is attempted to filter through a pledget of cotton-wool the fine precipitate of organic matter quickly clogs the wool and stops the filtering.

The doctored solution being filtered, test it with a piece of perfectly fresh, blue litmus paper, and add nitric acid, drop by drop—shaking well between the additions of acid—until the blue litmus paper just turns red. Do not add acid sufficient to make the litmus turn violently red, unless the bath is for line negatives, as a bath for half-tone negatives must be only just acid, whereas a bath for line work must contain more acid.

If the color of the litmus paper shows that the alkali has been neutralized, a plate is collodionized, then immersed in the bath for five minutes, then drained, and placed in the dark slide, or in a dark box for five minutes, then flooded with the iron developer (page [17]); if, upon the application of this the film should turn black, add more nitric acid, stir up thoroughly, then try again, repeating the trials until, upon fixing the plate with the solution of cyanide of potassium, the film of collodion is left upon the glass plate as clear as it was before it was immersed in the silver bath.

A little above here it is stated that less nitric acid is required in the bath for half-tone negatives than for line work, and the question may well be asked where may the line be drawn? The reply is that, for half-tone work, a piece of blue litmus paper should, upon immersion into the solution, turn red very slowly, but when the bath is required for line negatives the blue litmus may at once indicate the presence of acid.

After a bath solution has been renovated in the above manner, it should be tested for strength, either by the volumetric method (by preference), or by means of the ordinary argentometer sold by the dealers, and, if, after testing, the strength is shown to be too great, dilute with a sufficiency of sunned water (page [13]); and if not sufficiently strong, add crystals of nitrate of silver to make up the strength to thirty or thirty-five grains per ounce.

A bath solution renovated as above, will generally be found to work cleaner, and yield brighter negatives than a new solution, and it will also, if carefully used, last longer; but it must be kept up to a proper working strength by the occasional addition of a little of a saturated solution of nitrate of silver.