When coating plates with collodion, it is not a wise plan to pour the surplus from the plate back into the bottle from which it was poured. Pour it into another, kept handy for the purpose, the contents of which, at the end of the day’s work, empty into the stock bottle after such a quantity as is sufficient for next day’s consumption has been decanted into the pourer.
The best bottle from which to pour the collodion upon the plate is the tall capped bottle sold by the dealers as collodion pourers. {12}
THE NITRATE OF SILVER BATH (1).
The silver bath is a most important factor in the production of good negatives. It must be compounded with care and used with skill.
To make it, dissolve 6 ounces of nitrate of silver in 10 ounces of water, then add 10 drops of collodion, and shake up well; then add 70 ounces of water, and let it stand all night; then filter through a pledget of cotton-wool packed loosely in the neck of a glass funnel, into a clean bottle or jug; then add 1 drachm of nitric acid and let stand all night before trying. Such bottle or jug, and also the glass funnel, must be kept solely for use with the silver bath.
The bath holder may be an upright vessel of the ordinary pattern, with a dipper with which to lower the plate into the solution; or it may be a flat dish with a cover to keep out light and dust, using a silver hook to lift the plate from the solution; if the former shape be chosen, let the dipper be of glass, porcelain, silver wire, or of wood soaked in melted paraffine, but on no account of ebonite, as such a dipper will cause spots, and derange the bath sooner or later.
If a flat dish be used, the best form is of wood lined with asphaltum, hanging on a cradle, the lower end being a well to hold the solution; in this form of bath the plate, after sensitizing, is drained thoroughly before taking it out. This is a great convenience, as not only is silver solution saved, but the dark slide will last much longer.
The bath solution made up as above will be the right strength for work, but as every plate sensitized therein, takes away its modicum of silver, after a certain time it must be strengthened, as it is essential for the production of good work that the solution be kept at a proper strength. The best way of doing this is to add a drachm or two of saturated solution of nitrate of silver, after each day’s work has been done, and if the solution be worked in a flat bath, it will be as well to pour it into a jug and filter it before using again; with an upright holder, this filtering will only require to be done about once or twice a week, as any particles of dust, etc., subside and have not the same chance of falling upon the film as in a flat bath; but the addition of the silver solution should be made, and the solution well stirred up with the dipper.
In course of time a silver bath will become contaminated with organic matter from various causes, and can also be supersaturated with ether and alcohol—with iodo-bromo or nitrate of zinc, and will either refuse to work, or only {13} yield imperfect films and thin images. In such cases the best plan will be to take 20 ounces of the solution, dilute it with clean water 60 ounces, filter, and add 6 ounces of nitrate of silver, and again filter, when a new bath will be the result.
The silver in the rejected portion of the old bath should be precipitated as a chloride, by the addition of a solution of common salt, the precipitate dried and sent to a refiner, together with the ashes of the filtering papers and blotting-paper used to drain the plates upon, or to wipe the backs of the plates after leaving the bath and before putting them into the dark slide.