Fig. 126. The Electric Contact.Fig. 127. The Wiring System.
In order to take care of the hydrogen and thus insure the constant action of the battery, oxide of manganese is added to the contents of the cell, generally as a mixture with the carbon element. Manganese has the property of absorbing oxygen very rapidly and of giving it off quite easily. Therefore while the hydrogen is being formed on the zinc, it becomes an easy matter for it to leave the zinc and take its proper quantity of oxygen from the manganese and again form water, which is again decomposed by the zinc. As long as this cycle of chemical action takes place the battery will continue to give good satisfaction, and usually when a battery gives out it is because the depolarizer is exhausted, for the reason that the carbon is not affected at all and the zinc element forming the container is present in sufficient quantity to outlast the chemical action of the total mass.
There are great differences in the various makes of batteries; also in the methods of their construction. It would seem to be an easy matter for a chemist to figure out exactly how much depolarizer would serve the purpose for a given quantity of zinc and carbon and therefore to make a battery which should give an exact performance that could be anticipated. In reality, however, this is not the case, owing to the various conditions. There are three qualities of manganese in the market; the Japanese, which is the best and most costly; the German, which comes second, and the American, which is the cheapest and varies in quality so much as to be more or less a matter of guesswork. We must remember that in making batteries for the price at which they are now sold on the market we are obliged to take materials in commercial quantities and commercial qualities and cannot depend upon the chemically pure materials with which the chemists’ theories are always formulated. This therefore introduces several elements of uncertainty.
In practice the Japanese manganese will stand up for a far longer time than any other that is known and it is used in all special batteries where quality and length of life are considered of more importance than the price. The German manganese comes next. Then comes a mixture of American and German manganese, and finally the American manganese, which is used in making the cheaper batteries which are sorted afterwards, as we shall explain farther on. These batteries are sealed after having been made in large quantities, say five thousand or ten thousand in the lot, and kept for thirty days, after which they are tested. The batteries which are likely to give short-life will show a local action and consequent reduction of output in thirty days. They are, therefore, sorted out, much as eggs are candled on being received in a storage warehouse, for the reason that after a cell has been made and put together it would cost more to find out what was the matter with it and remedy that than it would to make a new cell. Many of the battery manufacturers, therefore, make up their batteries with an attempt to reach the highest standard. They are sorted for grade in thirty days and those which have attained the point desired are labeled as the factories’ best battery and are sold at the highest prices. The others have been graded down exclusively and labeled differently until those which are positively known to be short-lived are run out and disposed of as the factories’ cheapest product under still another label.
When buying batteries always look to see that the tops are not cracked, as if the seal on the cell is broken, chemical action induced from contact with the air as the battery dries out, will rapidly deteriorate the depolarizer and sulphate the zinc, both of which are of course a constant draft on the life of the battery, which contains only a stated quantity of energy in the beginning. Always examine the terminal connections to see that they are tight and solid.
Batteries when made up are always dated by the factory, but this does the purchaser little good, as the dates are in codes of letters, figures, or letters and figures, and are constantly changed so that even the dealers who are handling thousands of them are unable to read the code. This is done because many people are prone to blame the battery for other defects in the electrical system and many who are using great quantities would find an incentive to switch the covers on which the dates appear if they knew what it meant. This is perhaps rather harsh language, but a good many men would be tempted to send back a barrel of old batteries every now and then with the covers showing that they had not lasted three months, if they could read these signatures.
Practically the only means the jeweler has of obtaining a good cell, with long life, is to buy them of a large electrical supply house, paying a good price for them and making sure that that house has trade enough in that battery to insure their being continuously supplied with fresh stock.
The position of the battery also has to do with the length of life or amount of its output. Thus a battery lying on its side will not give more than seventy-five per cent of the output of a battery which is standing with the zinc and carbon elements perpendicular. Square batteries will not give the satisfaction that the round cell does. It has been found in practice by trials of numerous shapes and proportions that the ordinary size of 2½ × 6 inches will give better satisfaction than one of a different shape—wider or shorter, or longer and thinner; that is for the amount of material which it contains. The battery which has proved most successful in gas engine ignition work is 3¾ × 8 inches. That maintains the same proportions as above, or very nearly so, but owing to local action it will give on clock work only about fifty per cent longer life than the smaller size.
It has been a more or less common experience with purchasers of electric clocks to find that the batteries which came with the clock from the factory ran for two or three years (three years not being at all uncommon) and that they were then unable to obtain batteries which would stand up to the work for more than three weeks, up to six months. The difference is in the quality and freshness of the battery bought, as outlined above.