To compensate a pendulum takes time and study of the clock, but if you follow out these instructions you will succeed in getting the clock to run regularly in both summer and winter.
Besides the oxidation, which is an admitted fault, there are two theoretical questions which have to do with construction in deciding between the metallic and mercurial forms of compensation. We will present the claims of each side, therefore, with the preliminary statement that (for all except the severest conditions of accuracy) either form, if well made will answer every purpose and that therefore, except in special circumstances, these objections are more theoretical than real.
The advocates of metallic compensation claim that where there are great differences of temperature, the compensated rod, with its long bars will answer more quickly to temperature changes as follows:
The mercurial pendulum, when in an unheated room and not subjected to sudden temperature changes, gives very excellent results, but should the opposite case occur there will then be observed an irregularity in the rate of the clock. The causes which produce these effects are various. As a principal reason for such a condition it may be stated that the compensating mercury occupies only about one-fifth the pendulum length, and it inevitably follows that when the upper strata of the air is warmer than the lower, in which the mercury is placed, the steel pendulum rod will expand at a different ratio than the mercury, as the latter is influenced by a different degree of temperature than the upper part of the pendulum rod. The natural effect will be a lengthening of the pendulum rod, notwithstanding the compensation, and therefore, a loss of time by the clock.
Two thermometers, agreeing perfectly, were placed in the case of a clock, one near the point of suspension, and the other near the middle of the ball, and repeated experiments, showed a difference between these two thermometers of 7° to 10½° F., the lower one indicating less than the higher one. The thermometers were then hung in the room, one at twenty-two inches above the floor, and the other three feet higher, when they showed a difference of 7° between them. The difference of 2.5° more which was found inside the case proceeds from the heat striking the upper part of the case; and the wood, though a bad conductor, gradually increases in temperature, while, on the contrary, the cold rises from the floor and acts on the lower part of the case. The same thermometers at the same height and distance in an unused room, which was never warmed, showed no difference between them; and it would be the same, doubtless, in an observatory.
From the preceding it is very evident that the decrease of rate of the clock since December 13 proceeded from the rod of the pendulum experiencing 7° to 10.5° F. greater heat than the mercury in the bob, thus showing the impossibility of making a mercurial pendulum perfectly compensating in an artificially heated room which varies greatly in temperature. I should remark here that during the entire winter the temperature in the case is never more than 68° F., and during the summer, when the rate of the clock was regular, the thermometer in the case has often indicated 72° to 77° F.
The gridiron pendulum in this case would seem preferable, for if the temperature is higher at the top than at the lower part, the nine compensating rods are equally affected by it. But in its compensating action it is not nearly as regular, and it is very difficult to regulate it, for in any room (artificially heated) it is impossible to obtain a uniform temperature throughout its entire length, and without that all proofs are necessarily inexact.
These facts can also be applied to pendulums situated in heated rooms. In the case of a rapid change in temperature taking place in the observatory rooms, under the domes of observatories, especially during the winter months, and which are of frequent occurrence, a mercurial compensation pendulum, as generally made, is not apt to give a reliable rate. Let us accept the fact, as an example, of a considerable fall in the temperature of the surrounding air; the thin pendulum rod will quickly accept the same temperature, but with the great mass of mercury to be acted upon the responsive effects will only occur after a considerable lapse of time. The result will be a shortening of the pendulum length and a gain in the rate until the mercury has had time to respond, notwithstanding the compensation.
Others who have expressed their views in writing seem to favor the idea that this inequality in the temperature of the atmosphere is unfavorable to the accurate action of the mercurial form of compensation; and however plausible and reasonable this idea may seem at first notice, it will not take a great amount of investigation to show that, instead of being a disadvantage, its existence is beneficial, and an important element in the success of mercurial pendulums.
It appears that the majority of those who have proposed, or have tried to improve Graham’s pendulum have overlooked the fact that different substances require different quantities of heat to raise them to the same temperature. In order to warm a certain weight of water, for instance, to the same degree of heat as an equal weight of oil, or an equal weight of mercury, twice as much heat must be given to the water as to the oil, and thirty times as much as to the mercury; while in cooling down again to a given temperature, the oil will cool twice as quick as the water, and the mercury thirty times quicker than the water. This phenomenon is accounted for by the difference in the amount of latent heat that exists in various substances. On the authority of Sir Humphrey Davy, zinc is heated and cooled again ten and three-quarters times quicker than water, brass ten and a half times quicker, steel nine times, glass eight and a half times, and mercury is heated and cooled again thirty times quicker than water.