Nickel is found in Cornwall, and in some other counties of England; in Germany, Sweden, France, Spain, and several parts of Asia. The Chinese employ it in making white copper; and, in conjunction with copper and zinc, they manufacture it into various kinds of children’s toys. Nickel gives a certain degree of whiteness to iron. It is used, with advantage, by some of the Birmingham manufacturers, in combination with that metal, and by others in combination with brass. If it were possible to discover an easy method of working nickel, there can be little doubt but it would be found a very valuable metal for surgical instruments, for compass needles, and other articles, as it is not, like iron, liable to rust. When nickel is freely suspended, it points to the north and south, in precisely the same manner as the common magnetic needle.
Oxide of nickel is used for giving colours to enamels and porcelain. In different mixtures it produces brown, red, and grass-green tints.
241. ZINC, or SPELTER, as it is sometimes called, is a bluish white metal formed in thin plates adhering together. It has a very perceptible taste, is about seven times heavier than water, rather harder than silver; and possesses but a small degree of malleability and ductility, except under certain circumstances.
This metal is never found in a pure state; and the principal ores from which it is procured are known by the names of Calamine and Blende. Of these the former is an oxide ([21]) of zinc combined with carbonic acid ([26]), and the latter is a combination of zinc with sulphuric acid ([24]).
The ores of zinc are very abundant in many countries. We are informed that nearly the whole of Flintshire in North Wales abounds with calamine; and that, so entirely ignorant were the inhabitants of its use, as, till after the middle of the eighteenth century, to have even mended their roads with it. These roads, however, have since been turned up in many places, and the materials have been converted to more valuable purposes. Derbyshire affords a great quantity of the ores of zinc, particularly calamine. This is found at various depths, generally in beds of yellow, or reddish brown clay, and usually near some vein of lead ore.
The mode of extracting zinc from its ore is by distillation. The process adopted, in some parts of Saxony, is equally simple and ingenious. An inclined stone is placed near the anterior part of a furnace, in which the ore of lead containing zinc is fused. A great part of the zinc condenses upon this stone, and flows, in drops or globules, into a quantity of charcoal placed at the bottom to receive it. These globules are afterwards again melted, to run the metal into a mass.
When exposed to the air, the surface of zinc is soon tarnished, but it scarcely undergoes any other change. It has a certain degree of ductility. When heated a little above 218° of Fahrenheit, it is malleable; and, when annealed, may be passed through rollers, and formed into thin sheets or leaves. Although, previously to being thus heated, it is brittle; on now cooling, it continues soft, flexible, and ductile. The inconvenience arising from the brittleness of the zinc being removed, this metal is applicable to many useful purposes. It may even be drawn into wire, but the tenacity of this is not great: a piece of zinc wire, one tenth of an inch in diameter, will sustain only a weight of twenty-six pounds without breaking. It has been proposed to substitute zinc in the place of tin for the lining of copper vessels; but it has not hitherto been ascertained whether this can be done with effect, and without injury. Prizes have of late been offered, to a considerable extent, in France, for the ascertainment of this fact. In China, zinc is employed as a current coin of the country; and for this purpose it is used in the utmost purity. The Chinese also, as well as the artists of our own country, employ it to a great extent in various alloys. It is used in the manufacture of brass, pinchbeck or prince’s metal, and bronze, all of which consist of this metal in combination with different proportions of copper ([230]). Tutenag is a well known white metal, made principally of zinc, and used for forming candlesticks and other articles. When tutenag is well manufactured, it is of good colour, and not more disposed to tarnish than silver. Zinc is one of the metals employed to form the galvanic or voltaic apparatus; and its filings are mixed with gunpowder, to produce those brilliant stars and spangles which are seen in the best kinds of artificial fire-works. Preparations of zinc are occasionally used in medicine. If a thin plate of zinc be applied to the upper surface of the tongue, and a shilling to the lower surface, and both metals, after a little while, be brought into contact, a very peculiar taste will, at that instant, be perceived. The same sensation will be perceived, though in a weaker degree, if the silver be placed at the top and the zinc at the bottom.
If a silver probe be introduced high up one of the nostrils, and be brought into contact with a piece of zinc placed on the tongue, a sensation not unlike that of a strong flash of light will be produced in the corresponding eye. A similar perception will result, both at the moment of contact and that of separation, if one of the metals be applied as high as possible between the gums and upper lip, and the other in a similar situation with the under lip, or even under the tongue.
A white oxide ([21]) prepared from zinc, was, some years ago, proposed as a substitute for white lead in house painting. This oxide is not dangerous in its application; and does not become yellow when mixed with oil. But these advantages are counterbalanced by some defects, which have hitherto caused it to be rejected. It is lighter than white lead: does not cover the surface so equally, nor so well; and is of considerably higher price.
Calamine.—The principal use of calamine is in the manufacture of brass ([230]); and the mines of Derbyshire, and of Limbourg in the Netherlands, supply with this mineral nearly all the brass works in Europe. After the calamine is dug out of ground, it is reduced to pieces not in general larger than a nut. It is then roasted for five or six hours, in what is called a reverberating furnace. The large pieces are separated, and the small ones are passed through a sieve. It is washed; and, when dry, is ground in a mill. In this state it is sold. The principal demand for it is at Birmingham, for the different brass founderies in that town.