Besides the above, there are various modes of silvering metal articles, or, as it is called, washing them with silver. All these are performed by different chemical preparations of this metal.
The article denominated shell-silver, used by painters, is prepared, by carefully grinding silver-leaf, with a little honey or gum water upon a slab, or in a mortar, and separating the honey or gum by means of water. When this is washed away, the silver may be put on paper, or kept in shells, for use. When it is to be used, it must again be diluted with gum water.
The application of silver-leaf for the silvering of paper or wood is similar to that of gold-leaf ([227]).
Silver, dissolved in aqua fortis (nitric acid, 30), yields crystals, which, afterwards melted in crucibles, form that grey mass usually called lunar caustic, and by chemists nitrat of silver. This preparation is of considerable use in surgical cases, being employed to keep down fungous or proud flesh, in wounds and ulcers, and also for the consuming of warts, small wens, and other excrescences upon the skin. It is likewise, though a most violent medicine, sometimes given internally, but in very small doses, to persons subject to epileptic fits. The liquid in which the silver is dissolved becomes excessively caustic. It gives to the skin, the hair, and almost all animal substances, an indelible black colour. Hence it is often used as a specific for dyeing the human hair. No person, however, would employ it for this purpose, who was acquainted with its injurious qualities, not only to the hair itself, but also to the skin, if permitted to come in contact with it.
The article called indelible, or permanent marking ink, for marking linen, and other wearing apparel, is formed by dissolving, in a glass mortar, two drachms of nitrat of silver, in six drachms of pure water, and then adding to them two drachms, by measure, of thick gum water. This is the ink for writing on the linen.—In another vessel dissolve half an ounce of salt of tartar, or of the subcarbonat of soda, of commerce, in four ounces of water; and add to the solution half an ounce, by measure, of thick gum water. This forms the preparatory liquor. With this the linen is to be thoroughly wetted at the part intended to be marked. The linen is to be dried, and then to be written upon by a clean pen dipped in the marking ink. The letters will at first be pale, but by exposure to light and heat, they will soon become black; and be so permanently fixed, that no washing nor bleaching can efface them.
The attention of the curious has of late been turned to a very extraordinary compound called fulminating silver, which explodes without heat, and with even the slightest degree of friction. Of this compound little fulminating balls have been made. These are globules of thin glass, each somewhat larger than a pea, and containing a grain or two of fulminating silver. After the silver is put in, it is secured by a piece of soft paper, pasted over the ball, so as completely to cover it. These balls explode by merely crushing them under the heel of the shoe. What are called fulminating bombs are similar balls, but of the size of hazel nuts. No one should attempt to explode these by crushing them with the shoe, as their explosive effect is so violent as sometimes to prove injurious.
Fulminating silver requires the utmost care. It should never be put into phials, nor should it be in any way handled so as to produce much friction. It is the most dangerous preparation that is known. The mere touch of a hard substance will sometimes explode it; and its very preparation is so hazardous that this ought never to be attempted without a mask upon the face with strong glass eyes.
The following are three pleasing experiments with preparations of silver:
1. Mix or amalgamate together four parts of silver leaf with two parts of mercury ([228]) and dissolve this in diluted aqua fortis. To the solution add as much water as will be equal to thirty times the weight of the metals employed. Pour a portion of the above mixture into a phial, and place at the bottom a small piece of silver. After it has stood awhile, little filaments of silver will be seen to shoot up from it somewhat in the form of a shrub. This apparent vegetation is popularly called the tree of Diana.
2. A production nearly similar may be obtained by adding a little quicksilver to a solution of nitrat of silver in water.