There is a substance, the double nitrate of silver and thallium, which, while solid at ordinary temperatures, liquefies at 75° C. and then has a specific gravity of 4·5. Admixture with water lowers the density to any desired point.
If a glass cell is taken containing this liquid diluted to a density of about 3·6, and in it is thrown pieces of the above-named minerals, all those whose density is lower than 3·6 will rise to the surface, while the denser minerals will sink. If now a little water is carefully added with constantly stirring until the density of the liquid is reduced to that of the diamond, the heterogeneous collection sorts itself into three parts. The graphite, quartz, beryl, mica, and hornblende rise to the surface; the garnet, corundum, zircons, etc., sink to the bottom, while the diamonds float in the middle of the liquid. With a platinum landing-net I can skim off the swimmers and put them into one dish; with the same net I can fish out the diamonds and put them in a second dish, while by raising a sieve at the bottom I can remove the heavy minerals and put them into a third. The accurate separation of diamonds from the heterogeneous mixture can be effected in less time than is taken to describe the experiment.
The table shows that diamonds vary somewhat in density among themselves, between narrow limits. Occasionally, however, diamonds overpass these figures. Here is an illustration. In a test-tube of the same dense liquid are three selected diamonds. One rises to the top, another floats uncertain where to settle, rising and falling as the temperature of the sorting liquid is raised or lowered, whilst the third sinks to the bottom. Allowing the liquid to cool a degree or two slightly increases the density and sends all three to the surface.
Phosphorescence of Diamond
After exposure for some time to the sun many diamonds glow in a dark room. Some diamonds are fluorescent, appearing milky in sunlight. In a vacuum, exposed to a high-tension current of electricity, diamonds phosphoresce of different colours, most South African diamonds shining with a bluish light. Diamonds from other localities emit bright blue, apricot, pale blue, red, yellowish green, orange, and pale green light. The most phosphorescent diamonds are those which are fluorescent in the sun. One beautiful green diamond in the writer’s collection, when phosphorescing in a good vacuum, gives almost as much light as a candle, and you can easily read by its rays. But the time has hardly come when diamonds can be used as domestic illuminants! The emitted light is pale green, tending to white, and in its spectrum, when strong, can be seen bright lines, one at about λ 5370 in the green, one at λ 5130 in the greenish blue, and one at λ 5030 in the blue. A beautiful collection of diamond crystals belonging to Professor Maskelyne phosphoresces with nearly all the colours of the rainbow, the different faces glowing with different shades of colour. Diamonds which phosphoresce red generally show the yellow sodium line on a continuous spectrum. In one Brazilian diamond phosphorescing a reddish-yellow colour I detected in its spectrum the citron line characteristic of yttrium.
The rays which make the diamond phosphoresce are high in the ultra-violet. To illustrate this phosphorescence under the influence of the ultra-violet rays, arrange a powerful source of these rays, and in front expose a design made up of certain minerals, willemite, franklinite, calcite, etc.—phosphorescing of different colours. Their brilliant glow ceases entirely when a thin piece of glass is interposed between them and the ultra-violet lamp.
I now draw attention to a strange property of the diamond, which at first sight might seem to discount the great permanence and unalterability of this stone. It has been ascertained that the cause of phosphorescence is in some way connected with the hammering of the electrons, violently driven from the negative pole on to the surface of the body under examination, and so great is the energy of the bombardment, that impinging on a piece of platinum or even iridium, the metal will actually melt. When the diamond is thus bombarded in a radiant matter tube the result is startling. It not only phosphoresces, but becomes discoloured, and in course of time becomes black on the surface. Some diamonds blacken in the course of a few minutes, while others require an hour or more to discolour. This blackening is only superficial, and although no ordinary means of cleaning will remove the discolouration, it goes at once when the stone is polished with diamond powder. Ordinary oxidising reagents have little or no effect in restoring the colour.