Fig. 7. Fleshing Machine.
(Turner Tanning Machinery Co., Peabody, Mass.)
CHAPTER V
FUR DRESSING
Tanning Methods
After the pelts have gone through the preliminary operations of softening, washing and fleshing, they are ready to receive the treatment which will convert the easily decomposing skin into leather of more or less permanency, depending on the method used.
During the past century, considerable study has been made both by scientific and technical people, of the problem of leather formation. Numerous theories as to the nature of the process have been evolved, but even to this day, no satisfactory explanation has been given which would account for all the facts as they are now known, so the matter is still a subject of considerable controversy. Procter, who is one of the leading authorities on leather today discusses the development of the tanning theories as follows:
“The cause of the horny nature of dried skin is that the gelatinous and swollen fibres of which it is composed not merely stiffen on drying but adhere to a homogeneous mass, as is evidenced by its translucence. If in some way we can prevent the adhesion of the fibres while drying we shall have made a step in the desired direction, and this will be the more effective the more perfectly we have split the fibre-bundles into their constituent fine fibrils, and removed the substance which cements them. The separation of the fibres can be partially attained by purely mechanical means.... Knapp, to whom we owe our first intelligible theories of the tanning process, showed that by physical means the separation and drying of the fibres could be so far effected as to produce without any tanning agent a substance with all the outward characteristics of leather, although on soaking it returned completely to the raw hide state. He soaked the prepared pelt in absolute alcohol, which penetrated between, and separated the fibres and at the same time dried them by its strong affinity for water. More recently, Meunier has obtained a similar result by the use of a concentrated solution of potassium carbonate which is even more strongly dehydrating.
“Knapp made a further step by adding to his alcohol a small quantity of stearic acid which, as the alcohol evaporated, left a thin fatty covering on the fibres which completely prevented their adhesion, and reduced their tendency to absorb water; and he so produced a very soft and white leather. Somewhat similar are the principles of the many primitive methods which apply fatty and albuminous matters, grease, butter, milk, or brains to the wet skin, and by mechanical kneading and stretching, aided by capillarity, work these matters in between the fibres as the water evaporates. Such methods are still used, and enter into many processes in which other tanning agents are also employed.
“Building upon these facts, Prof. Knapp advanced the theory that the effect of all tanning processes was not to cause a change in the fibres themselves, chemical or otherwise, but merely to isolate and coat them with water-resisting materials which prevented their subsequent swelling and adhesion. True as this theory undoubtedly is in many cases, it can hardly be accepted as the whole truth, and it seems incontestable that frequently the fibres themselves undergo actual chemical changes which render them insoluble and nonadhesive.
“Before Knapp’s work, the prevalent theory, at least as regards vegetable tannage, had been a chemical one, started by Sir Humphrey Davy. If a solution of gelatine be mixed in proper proportion with one of tannin, both unite to form a voluminous curdy precipitate; and, according to Davy’s ideas, this was amorphous leather. Against this, it was urged that even the supposed ‘tannate of gelatine’ itself could not be a true chemical compound, since the proportions of its constituents were considerably varied by changes in the strength of the solutions, or by washing the precipitate with hot water; and further, that in chemical compounds, the form was changed, and no trace of the original constituents appeared in the compound; while in leather apart from some change of color and properties, the original fibrous structure remained unaltered.