The tannins all give greyish to black shades with iron salts, and it is this fact which renders them important for fur dyeing.
2. Wood dyes
One of the most important of all the natural dye substances, especially for the production of blacks, is logwood. The color is really a red, but with the common mordants it forms blue, violet or black shades. Logwood, or campeachy wood, as it is sometimes called, is the product of a large tree growing in the West Indies, and Central and South America. When freshly cut, the wood is practically without color, but when exposed to the air it soon becomes a dark reddish-brown on the surface. The coloring principle of logwood is called hematoxylin, which is a colorless substance when pure, and is of itself incapable of dyeing; but when it is exposed to the air, especially when moist and in the presence of some alkaline substance, it is converted into hematein, which is the real coloring matter of logwood. To prepare the wood for use, the logs are chipped or rasped, the chips being heaped up and moistened with water. Fermentation occurs, and the heaps are frequently turned to allow free access of air to the wood, and to prevent overheating. As a result of this process, a great part of the hematoxylin is converted to the hematein. The logwood may be used for dyeing in this state as chips, but logwood extracts can now be obtained of a high degree of purity and are easier to work with. The commercial forms of the extract, are the liquid of 51 degrees Twaddell, and the solid extract. Hematein crystals can also be obtained. All these extracts contain mainly hematein, together with a small percentage of hematoxylin which is converted to the former during the dyeing process. Logwood is never used as a direct dye, but is used to form color lakes with the various mordants, the following colors being produced:
- Iron mordants give grey to black shades
- Copper mordants give green-blue to black shades
- Chrome mordants give blue to black shades
- Aluminum mordants give violet shades
- Tin mordants give purple shades
By combining several of the mordants, any desired shade of black can be obtained, and if other dyewoods are used in conjunction with the logwood, the range can be further increased.
Fustic, yellow-wood, or Cuba wood, as it is variously called, is obtained from a tree also growing in the West Indies, Central and South America. It is used either as wood chips, or as a paste extract of 51 degrees Twaddell, and occasionally as solid extract. Fustic contains two coloring matters, morintannic acid, possessing the characteristics of a tannin, and which is quite soluble in water, and morin, which is rather insoluble, and which settles out from the liquid extract. Fustic is the most important of the yellow dyes of natural origin, and is used considerably in fur dyeing with logwood for shading the blacks, or for producing compound shades. With the usual mordants fustic gives the following colors:
| With iron salts | dark olive |
| With copper salts | olive |
| With chrome salts | olive-yellow to brownish-yellow |
| With aluminum salts | yellow |
| With tin salts | bright yellow to orange-yellow |
Brazilwood, or redwood, is the product of a tree found in Brazil, and exists in several varieties, such as peach wood, Sapan wood, Lima wood, and Pernambuco wood. They all yield similar shades with the various mordants, and all seem to contain the same coloring principle, brasilin, which, like the hematoxylin, has no dyeing power, but by fermentation and oxidation it is converted to brasilein, corresponding to the formation of hematein. Brazilwood and the related woods are used either as chips or extract, but seldom alone, usually in conjunction with other dyewoods. By combining logwood, fustic and Brazilwood in various proportions, and by employing suitable mordants, all the shades required by the fur dyer can easily be produced.
Quercitron is the inner bark of a species of oak (Quercus tinctoria) found in the United States. It contains two coloring principles, quercetrin and quercetin. The fresh decoction of quercitron bark is a transparent dull orange-red which soon becomes turbid and deposits a yellow crystalline mass. It is generally used in conjunction with other dyes.
Cutch is the dried extract obtained from a species of acacia, the principal varieties being Bombay, Bengal, and Gambier cutch. It contains two coloring principles, catechin and catechu-tannic acid. Cutch acts as a tannin, and like other tannins discussed above, can be used for the production of grey or black shades with iron mordants. It is employed chiefly, however, for dyeing browns. Aluminum salts give with cutch a yellowish-brown, tin salts give a lighter yellow, copperas gives a brownish-grey, and chrome and copper salts give brown shades.