"All the heat which a hot body loses when it is exposed in the air to cool is not given off to the air which comes into contact with it, but ... a large proportion of it escapes in rays, which do not heat the transparent air through which they pass, but, like light, generate heat only when and where they are stopped and absorbed."
Rumford then investigated the absorption of heat by different surfaces, and established the law that good radiators are good absorbers; and recommended that vessels in which water is to be heated should be blackened on the outside. In speculating on the use of the colouring matter in the skin of the negro, he shows his fondness for experiment:—
"All I will venture to say on the subject is that, were I called to inhabit a very hot country, nothing should prevent me from making the experiment of blackening my skin, or at least, of wearing a black shirt, in the shade, and especially at night, in order to find out if, by those means, I could contrive to make myself more comfortable."
In his experiments on the conduction of heat, Rumford employed a cylinder with one end immersed in boiling water and the other in melting ice, and determined the temperature at different points in the length of the cylinder. He found the difficulty which has recently been forcibly pointed out by Sir Wm. Thomson, in the article "Heat," in the "Encyclopædia Britannica," viz. that the circulation of the water was not sufficiently rapid to keep the temperature of the layer in contact with the metal the same as that of the rest of the water; and he also called attention to the arbitrary character of thermometer-scales, and recommended that more attention should be given to the scale of the air thermometer. It was in his visit to Edinburgh, in 1800, that, in company with some of the university professors, the count conducted some experiments in the university laboratory on the apparent radiation of cold. Rumford's views respecting frigorific rays have not been generally accepted, and Prevost's theory of exchanges completely explains the apparent radiation of cold without supposing that cold is anything else than the mere absence of heat.
We must pass over Rumford's papers on the use of steam as a vehicle of heat, on new boilers and stoves for the purpose of economizing fuel, and all the papers bearing on the nutritive value of different foods. The calorimeter with which he determined the amount of heat generated by the combustion, and the latent heat of evaporation, of various bodies has been already alluded to. Of the four volumes of Rumford's works published by the American Academy of Arts and Sciences, the third is taken up entirely with descriptions of fireplaces and of cooking utensils.
Before deciding on the best way to light the military workhouse at Munich, Rumford made a series of experiments on the relative economy of different methods, and for this purpose designed his well-known shadow-photometer. In the final form of this instrument the shadows were thrown on a plate of ground glass covered with paper, forming the back of a small box, from which all extraneous light was excluded. Two rods were placed in front of this screen, and the lights to be compared were so situated that the shadow of one rod thrown by the first light might be just in contact with that of the other rod thrown by the second light. By introducing coloured glasses in front of the lights, Rumford compared the illuminating powers of different sources with respect to light of a particular colour. The complementary tints exhibited by the shadows caused him to devise his theory of the harmony of complementary colours. One result is worthy of mention: it is a conclusion to which public attention has since been called in connection with "duplex" burners. Rumford found that with wax tapers the amount of light emitted per grain of wax consumed diminished with the diminution of the consumption, so that a small taper gave out only one-sixteenth as much light as an ordinary candle for the same consumption of wax. He says:—
"This result can be easily explained if we admit the hypothesis which supposes light to be analogous to sound.... The particles ... were so rapidly cooled ... that they had hardly time to shine one instant before they became too cold to be any longer visible."
An argand lamp, when compared with a lamp having a flat wick, gave more light in the ratio of 100 to 85 for the same consumption of oil.
One of the latest investigations of Rumford was that bearing on the effect of the width of the wheels on the draught of a carriage. To his own carriage, weighing, with its passengers, nearly a ton, he fitted a spring dynamometer by means of a set of pulleys attached to the under-carriage and the splinter-bar. He used three sets of wheels, respectively 1-3/4, 2-1/4, and 4 inches wide, and, introducing weights into the carriage to make up for the difference in the weights of the wheels, he found a very sensible diminution in the tractive force required as the width of the wheels was increased, and in a truly scientific spirit, despising the ridicule cast upon him, he persisted in riding about Paris in a carriage with four-inch tyres.
But the piece of work by which Rumford will be best known to future generations is that described in his paper entitled "An Inquiry concerning the Source of the Heat which is excited by Friction." It was while superintending the boring of cannon in the arsenal at Munich that Rumford was struck with the enormous amount of heat generated by the friction of the boring-bar against the metal. In order to determine whether the heat had come from the chips of metal themselves, he took a quantity of the abraded borings and an equal weight of chips cut from the metal with a fine saw, and, heating them to the temperature of boiling water, he immersed them in equal quantities of water at 59-1/2° Fahr. The change of temperature of the water was the same in both cases, and Rumford found that there was no change which he could discover in regard to its capacity for heat produced in the metal by the action of the borer.