Sulphides of antimony. Antimony resembles arsenic in that hydrogen sulphide precipitates it as a sulphide when conducted into an acidified solution containing an antimony compound:
2SbCl3 + 3H2S = Sb2S3 + 6HCl,
2SbCl5 + 5H2S = Sb2S5 + 10HCl.
The two sulphides of antimony are called the trisulphide and the pentasulphide respectively. When prepared in this way they are orange-colored substances, though the mineral stibnite is black.
Metallic properties of antimony. The physical properties of the element are those of a metal, and the fact that its sulphide is precipitated by hydrogen sulphide shows that it acts like a metal in a chemical way. Many other reactions show that antimony has more of the properties of a metal than of a non-metal. The compound Sb(OH)3, corresponding to arsenious acid, while able to act as a weak acid is also able to act as a weak base with strong acids. For example, when treated with concentrated hydrochloric acid antimony chloride is formed:
Sb(OH)3 + 3HCl = SbCl3 + 3H2O.
A number of elements act in this same way, their hydroxides under some conditions being weak acids and under others weak bases.
ALLOYS
Some metals when melted together thoroughly intermix, and on cooling form a homogeneous, metallic-appearing substance called an alloy. Not all metals will mix in this way, and in some cases definite chemical compounds are formed and separate out as the mixture solidifies, thus destroying the uniform quality of the alloy. In general the melting point of the alloy is below the average of the melting points of its constituents, and it is often lower than any one of them.
Antimony forms alloys with many of the metals, and its chief commercial use is for such purposes. It imparts to its alloys high density, rather low melting point, and the property of expanding on solidification. Such an alloy is especially useful in type founding, where fine lines are to be reproduced on a cast. Type metal consists of antimony, lead, and tin. Babbitt metal, used for journal bearings in machinery, contains the same metals in a different proportion together with a small percentage of copper.