Many ores other than oxides may be changed into oxides which can then be reduced by carbon. The conversion of such ores into oxides is generally accomplished by heating, and this process is called roasting. Many carbonates and hydroxides decompose directly into the oxide on heating. Sulphides, on the other hand, must be heated in a current of air, the oxygen of the air entering into the reaction. The following equations will serve to illustrate these changes in the case of the ores of iron:
FeCO3 = FeO + CO2,
2Fe(OH)3 = Fe2O3 + 3H2O,
2FeS2 + 11O = Fe2O3 + 4SO2.
2. Reduction of an oxide with aluminium. Not all oxides, however, can be reduced by carbon. In such cases aluminium may be used. Thus chromium may be obtained in accordance with the following equation:
Cr2O3 + 2 Al = 2 Cr + Al2O3.
This method is a comparatively new one, having been brought into use by the German chemist Goldschmidt; hence it is sometimes called the Goldschmidt method.
3. Electrolysis. In recent years increasing use is being made of the electric current in the preparation of metals. In some cases the separation of the metal from its compounds is accomplished by passing the current through a solution of a suitable salt of the metal, the metal usually being deposited upon the cathode. In other cases the current is passed through a fused salt of the metal, the chloride being best adapted to this purpose.
Electro-chemical industries. Most of the electro-chemical industries of the country are carried on where water power is abundant, since this furnishes the cheapest means for the generation of electrical energy. Niagara Falls is the most important locality in this country for such industries, and many different electro-chemical products are manufactured there. Some industries depend upon electrolytic processes, while in others the electrical energy is used merely as a source of heat in electric furnaces.