2HCl + PtCl4 = H2PtCl6.
The potassium and ammonium salts of this acid are nearly insoluble in water and alcohol. The acid is therefore used as a reagent to precipitate potassium in analytical work. With potassium chloride the equation is
2KCl + H2PtCl6 = K2PtCl6 + 2HCl.
Other metals of the family. The other members of the family have few applications. Iridium is used in the form of a platinum alloy, since the alloy is much harder than pure platinum and is even less fusible. This alloy is sometimes used to point gold pens. Osmium tetroxide (OsO4) is a very volatile liquid and is used under the name of osmic acid as a stain for sections in microscopy.
GOLD
Occurrence. Gold has been found in many localities, the most famous being South Africa, Australia, Russia, and the United States. In this country it is found in Alaska and in nearly half of the states of the union, notably in California, Colorado, and Nevada. It is usually found in the native condition, frequently alloyed with silver; in combination it is sometimes found as telluride (AuTe2), and in a few other compounds.
Mining. Native gold occurs in the form of small grains or larger nuggets in the sands of old rivers, or imbedded in quartz veins in rocks. In the first case it is obtained in crude form by placer mining. The sand containing the gold is shaken or stirred in troughs of running waters called sluices. This sweeps away the sand but allows the heavier gold to sink to the bottom of the sluice. Sometimes the sand containing the gold is washed away from its natural location into the sluices by powerful streams of water delivered under pressure from pipes. This is called hydraulic mining. In vein mining the gold-bearing quartz is mined from the veins, stamped into fine powder in stamping mills, and the gold extracted by one of the processes to be described.
Extraction. 1. Amalgamation process. In the amalgamation process the powder containing the gold is washed over a series of copper plates whose surfaces have been amalgamated with mercury. The gold sticks to the mercury or alloys with it, and after a time the gold and mercury are scraped off and the mixture is distilled. The mercury distills off and the gold is left in the retort ready for refining.
2. Chlorination process. When gold occurs along with metallic sulphides it is often extracted by chlorination. The ore is first roasted, and is then moistened and treated with chlorine. This dissolves the gold but not the metallic oxides:
Au + 3Cl = AuCl3.