Uses of water. The importance of water in its relation to life and commerce is too well known to require comment. Its importance to the chemist has also been pointed out. It remains to call attention to the fact that it is used as a standard in many physical measurements. Thus 0° and 100° on the centigrade scale are respectively the freezing and the boiling points of water under normal pressure. The weight of 1 cc. of water at its point of greatest density is the unit of weight in the metric system, namely, the gram. It is also taken as the unit for the determination of the density of liquids and solids as well as for the measurement of amounts of heat.
HYDROGEN DIOXIDE
Composition. As has been shown, 1 part by weight of hydrogen combines with 7.94 parts by weight of oxygen to form water. It is possible, however, to obtain a second compound of hydrogen and oxygen differing from water in composition in that 1 part by weight of hydrogen is combined with 2 × 7.94, or 15.88 parts, of oxygen. This compound is called hydrogen dioxide or hydrogen peroxide, the prefixes di- and per- signifying that it contains more oxygen than hydrogen oxide, which is the chemical name for water.
Preparation. Hydrogen dioxide cannot be prepared cheaply by the direct union of hydrogen and oxygen, and indirect methods must therefore be used. It is commonly prepared by the action of a solution of sulphuric acid on barium dioxide. The change which takes place may be indicated as follows:
| sulphuric acid | + | barium dioxide | = | barium sulphate | + | hydrogen dioxide |
| ——————— | ——————— | ——————— | ——————— | |||
| hydrogen | barium | barium | hydrogen | |||
| sulphur | oxygen | sulphur | oxygen | |||
| oxygen | oxygen |
In other words, the barium and hydrogen in the two compounds exchange places. By this method a dilute solution of the dioxide in water is obtained. It is possible to separate the dioxide from the water by fractional distillation. This is attended with great difficulties, however, since the pure dioxide is explosive. The distillation is carried on under diminished pressure so as to lower the boiling points as much as possible; otherwise the high temperature would decompose the dioxide.
Properties. Pure hydrogen dioxide is a colorless sirupy liquid having a density of 1.49. Its most characteristic property is the ease with which it decomposes into water and oxygen. One part by weight of hydrogen is capable of holding firmly only 7.94 parts of oxygen. The additional 7.94 parts of oxygen present in hydrogen dioxide are therefore easily evolved, the compound breaking down into water and oxygen. This decomposition is attended by the generation of considerable heat. In dilute solution hydrogen dioxide is fairly stable, although such a solution should be kept in a dark, cool place, since both heat and light aid in the decomposition of the dioxide.
Uses. Solutions of hydrogen dioxide are used largely as oxidizing agents. The solution sold by druggists contains 3% of the dioxide and is used in medicine as an antiseptic. Its use as an antiseptic depends upon its oxidizing properties.
EXERCISES
1. Why does the chemist use distilled water in making solutions, rather than filtered water?