Preparation from compounds of nitrogen. Pure nitrogen may be obtained from certain compounds of the element. Thus, if heat is applied to the compound ammonium nitrite (NH4NO2), the change represented in the following equation takes place:
Physical properties. Nitrogen is similar to oxygen and hydrogen in that it is a colorless, odorless, and tasteless gas. One liter of nitrogen weighs 1.2501 g. It is almost insoluble in water. It can be obtained in the form of a colorless liquid having a boiling point of -195° at ordinary pressure. At -214° it solidifies.
Chemical properties. Nitrogen is characterized by its inertness. It is neither combustible nor a supporter of combustion. At ordinary temperatures it will not combine directly with any of the elements except under rare conditions. At higher temperatures it combines with magnesium, lithium, titanium, and a number of other elements. The compounds formed are called nitrides, just as compounds of an element with oxygen are called oxides. When it is mixed with oxygen and subjected to the action of electric sparks, the two gases slowly combine forming oxides of nitrogen. A mixture of nitrogen and hydrogen when treated similarly forms ammonia, a gaseous compound of nitrogen and hydrogen. Since we are constantly inhaling nitrogen, it is evident that it is not poisonous. Nevertheless life would be impossible in an atmosphere of pure nitrogen on account of the exclusion of the necessary oxygen.
Argon, helium, neon, krypton, xenon. These are all rare elements occurring in the air in very small quantities. Argon, discovered in 1894, was the first one obtained. Lord Rayleigh, an English scientist, while engaged in determining the exact weights of various gases, observed that the nitrogen obtained from the air is slightly heavier than pure nitrogen obtained from its compounds. After repeating his experiments many times, always with the same results, Rayleigh finally concluded that the nitrogen which he had obtained from the air was not pure, but was mixed with a small amount of some unknown gas, the density of which is greater than that of nitrogen. Acting on this assumption, Rayleigh, together with the English chemist Ramsay, attempted to separate the nitrogen from the unknown gas. Knowing that nitrogen would combine with magnesium, they passed the nitrogen obtained from the air and freed from all known substances through tubes containing magnesium heated to the necessary temperature. After repeating this operation, they finally succeeded in obtaining from the atmospheric nitrogen a small volume of gas which would not combine with magnesium and hence could not be nitrogen. This proved to be a new element, to which they gave the name argon. As predicted, this new element was found to be heavier than nitrogen, its density as compared with hydrogen as a standard being approximately 20, that of nitrogen being only 14. About 1% of the atmospheric nitrogen proved to be argon. The new element is characterized by having no affinity for other elements. Even under the most favorable conditions it has not been made to combine with any other element. On this account it was given the name argon, signifying lazy or idle. Like nitrogen, it is colorless, odorless, and tasteless. It has been liquefied and solidified. Its boiling point is -187°.
Helium was first found in the gases expelled from certain minerals by heating. Through the agency of the spectroscope it had been known to exist in the sun long before its presence on the earth had been demonstrated,—a fact suggested by the name helium, signifying the sun. Its existence in traces in the atmosphere has also been proven. It was first liquefied by Onnes in July, 1908. Its boiling point, namely -269°, is the lowest temperature yet reached.
The remaining elements of this group—neon, krypton, and xenon—have been obtained from liquid air. When liquid air is allowed to boil, the constituents which are the most difficult to liquefy, and which therefore have the lowest boiling points, vaporize first, followed by the others in the order of their boiling points. It is possible in this way to make at least a partial separation of the air into its constituents, and Ramsay thus succeeded in obtaining from liquid air not only the known constituents, including argon and helium, but also the new elements, neon, krypton, and xenon. These elements, as well as helium, all proved to be similar to argon in that they are without chemical activity, apparently forming no compounds whatever. The percentages present in the air are very small. The names, neon, krypton, xenon, signify respectively, new, hidden, stranger.
EXERCISES
1. How could you distinguish between oxygen, hydrogen, and nitrogen?