Coals and Bitumens.—At the first lesson we examined a sample of peat (specimen 8), and considered the general conditions of its formation, peat being in every instance simply partially decayed marsh vegetation. It was also stated that, as during the lapse of time the transformation becomes more complete, the peat is changed in succession to lignite, bituminous coal, anthracite, and graphite. The coals, indeed, make a very beautiful and perfect series, whether we consider the composition—there being a gradual, progressive change from the composition of ordinary woody fibre in the newest peat to the pure carbon in graphite,—or the degree of consolidation and mineralization—since there is a gradual passage from the light, porous peat, showing distinctly the vegetable forms, to the heavy crystalline graphite, bearing no trace of its vegetable origin. This relation is easily appreciated by a child, if a proper series of specimens is presented. The coals also make a chronological series, graphite and anthracite occurring only in the older formations, and lignite and peat in the newer, while bituminous coal is found in formations of intermediate age.
Bituminous coal is the typical, the representative coal; and from a good specimen of this variety we may learn two important facts:—
(1) That true coals, no less than peat, are of vegetable origin. To see this we must look at the flat or charcoal surfaces of the coal. These soil the fingers like charcoal, and usually show the vegetable forms distinctly.
(2) That coals are stratified rocks. These dirty charcoal surfaces always coincide with the stratification, being merely the successive layers of vegetation deposited and pressed together to build up the coal; and when we look at the edge of the specimen the stratification shows plainly enough.
The bitumens form a similar though less perfect series, beginning with the organic tissues, and ending, in the opinion of some of the best chemists and mineralogists, with diamond. In fact the coals and bitumens form two distinct but parallel series. The coals are exclusively of vegetable origin, while the bitumens are largely of animal origin. The organic tissues in which the two series originate are chemically similar,—the animal tissues, which produce the lighter forms of bitumen, however, containing more hydrogen and less carbon and oxygen than vegetable tissues; while the final terms, as just shown, are probably chemically identical, being pure carbon,—graphite for the coals and diamond for the bitumens; so that the entire process of change in each series is essentially carbonization, a gradual elimination of the gaseous elements, oxygen and hydrogen, until pure solid carbon alone remains.
The principal differences between the coals and bitumens are the following:—
Coals are rich in carbon, with some oxygen and little hydrogen.
Bitumens are rich in hydrogen, with some carbon and little or no oxygen.
Coals are entirely insoluble.
Bitumens are soluble in ether, benzole, turpentine, etc., and the solid forms are soluble in the more fluid, naphtha-like varieties.