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HUMAN FOODS
AND THEIR NUTRITIVE VALUE

BY

HARRY SNYDER, B.S.

New York
THE MACMILLAN COMPANY
1914
All rights reserved

Set up and electrotyped. Published November, 1908. Reprinted October, 1909; September, 1910; February, 1911; September, 1912; May, December, 1913; June, 1914.

Norwood Press J. S. Cushing Co.—Berwick & Smith Co. Norwood, Mass., U.S.A.

PREFACE

Since 1897 instruction has been given at the University of Minnesota, College of Agriculture, on human foods and their nutritive value. With the development of the work, need has been felt for a text-book presenting in concise form the composition and physical properties of foods, and discussing some of the main factors which affect their nutritive value. To meet the need, this book has been prepared, primarily for the author's classroom. It aims to present some of the principles of human nutrition along with a study of the more common articles of food. It is believed that a better understanding of the subject of nutrition will suggest ways in which foods may be selected and utilized more intelligently, resulting not only in pecuniary saving, but also in greater efficiency of physical and mental effort.

Prominence is given in this work to those foods, as flour, bread, cereals, vegetables, meats, milk, dairy products, and fruits, that are most extensively used in the dietary, and to some of the physical, chemical, and bacteriological changes affecting digestibility and nutritive value which take place during their preparation for the table. Dietary studies, comparative cost and value of foods, rational feeding of men, and experiments and laboratory practice form features of the work. Some closely related topics, largely of a sanitary nature, as the effect upon food of household sanitation and storage, are also briefly discussed. References are given in case more extended information is desired on some of the subjects treated. While this book was prepared mainly for students who have taken a course in general chemistry, it has been the intention to present the topics in such a way as to be understood by the layman also.

This work completes a series of text-books undertaken by the author over ten years ago, dealing with agricultural and industrial subjects: "Chemistry of Plant and Animal Life," "Dairy Chemistry," "Soils and Fertilizers," and "Human Foods and their Nutritive Value." It has been the aim in preparing these books to avoid as far as possible repetition, but at the same time to make each work sufficiently complete to permit its use as a text independent of the series.

One of the greatest uses that science can serve is in its application to the household and the everyday affairs of life. Too little attention is generally bestowed upon the study of foods in schools and colleges, and the author sincerely hopes the time will soon come when more prominence will be given to this subject, which is the oldest, most important, most neglected, and least understood of any that have a direct bearing upon the welfare of man.

HARRY SNYDER.

CONTENTS

HUMAN FOODS AND THEIR NUTRITIVE VALUE

CHAPTER I

GENERAL COMPOSITION OF FOODS

1. Water.—All foods contain water. Vegetables in their natural condition contain large amounts, often 95 per cent, while in meats there is from 40 to 60 per cent or more. Prepared cereal products, as flour, corn meal, and oatmeal, which are apparently dry, have from 7 to 14 per cent. In general the amount of water in a food varies with the mechanical structure and the conditions under which it has been prepared, and is an important factor in estimating the value, as the nutrients are often greatly decreased because of large amounts of water. The water in substances as flour and meal is mechanically held in combination with the fine particles and varies with the moisture content, or hydroscopicity, of the air. Oftentimes foods gain or lose water to such an extent as to affect their weight; for example, one hundred pounds of flour containing 12 per cent of water may be reduced in weight three pounds or more when stored in a dry place, or there may be an increase in weight from being stored in a damp place. In tables of analyses the results, unless otherwise stated, are usually given on the basis of the original material, or the dry substance. Potatoes, for example, contain 2½ per cent of crude protein on the basis of 75 per cent of water; or on a dry matter basis, that is, when the water is entirely eliminated, there is 10 per cent of protein.

The water of foods is determined by drying the weighed material in a water or air oven at a temperature of about 100° C, until all of the moisture has been expelled in the form of steam, leaving the dry matter or material free from water.[^[1]] The determination of dry matter, while theoretically a simple process, is attended with many difficulties. Substances which contain much fat may undergo oxidation during drying; volatile compounds, as essential oils, are expelled along with the moisture; and other changes may occur affecting the accuracy of the work. The last traces of moisture are removed with difficulty from a substance, being mechanically retained by the particles with great tenacity. When very accurate dry matter determinations are desired, the substance is dried in a vacuum oven, or in a desiccator over sulphuric acid, or in an atmosphere of some non-oxidizing gas, as hydrogen.

2. Dry Matter.—The dry matter of a food is a mechanical mixture of the various compounds, as starch, sugar, fat, protein, cellulose, and mineral matter, and is obtained by drying the material. Succulent vegetable foods with 95 per cent of water contain only 5 per cent of dry matter, while in flour with 12 per cent of water there is 88 per cent, and in sugar 99 per cent. The dry matter is obtained by subtracting the per cent of water from 100, and in foods it varies from 5 per cent and less in some vegetables to 99 per cent in sugar.

Fig. 1.—Apparatus used for the Determination of Dry Matter and Ash in Foods.

1, desiccator; 2, muffle furnace for combustion of foods and obtaining ash; 3, water oven for drying food materials.

3. Ash.—The ash, or mineral matter, is that portion obtained by burning or igniting the dry matter at the lowest temperature necessary for complete combustion. The ash in vegetable foods ranges from 2 to 5 per cent and, together with the nitrogen, represents what was taken from the soil during growth. In animal bodies, the ash is present mainly in the bones, but there is also an appreciable amount, one per cent or more, in all the tissues. Ash is exceedingly variable in composition, being composed of the various salts of potassium, sodium, calcium, magnesium, and iron, as sulphates, phosphates, chlorides, and silicates of these elements. There are also other elements in small amounts. In the plant economy these elements take an essential part and are requisite for the formation of plant tissue and the production in the leaves of the organic compounds which later are stored up in the seeds. Some of the elements appear to be more necessary than others, and whenever withheld plant growth is restricted. The elements most essential for plant growth are potassium, calcium, magnesium, iron, phosphorus, and sulphur.[^[1]]

In the animal body minerals are derived, either directly or indirectly, from the vegetable foods consumed. The part which each of the mineral elements takes in animal nutrition is not well understood. Some of the elements, as phosphorus and sulphur, are in organic combination with the nitrogenous compounds, as the nucleated albuminoids, which are very essential for animal life. In both plant and animal bodies, the mineral matter is present as mineral salts and organic combinations. It is held that the ash elements which are in organic combination are the forms mainly utilized for tissue construction. While it is not known just what part all the mineral elements take in animal nutrition, experiments show that in all ordinary mixed rations the amount of the different mineral elements is in excess of the demands of the body, and it is only in rare instances, as in cases of restricted diet, or convalescence from some disease, that special attention need be given to increasing the mineral content of the ration. An excess of mineral matter in foods is equally as objectionable as a scant amount, elimination of the excess entailing additional work on the body.

The composition of the ash of different food materials varies widely, both in amount, and form of the individual elements. When for any reason it is necessary to increase the phosphates in a ration, milk and eggs do this to a greater extent than almost any other foods. Common salt, or sodium chloride, is one of the most essential of the mineral constituents of the body. It is necessary for giving the blood its normal composition, furnishing acid and basic constituents for the production of the digestive fluids, and for the nutrition of the cells. While salt is a necessary food, in large amounts, as when the attempt is made to use sea water as a beverage, it acts as a poison, suggesting that a material may be both a food and a poison. When sodium chloride is entirely withheld from an animal, death from salt starvation ensues. Many foods contain naturally small amounts of sodium chloride.

4. Organic Matter.—That portion of a food material which is converted into gaseous or volatile products during combustion is called the organic matter. It is a mechanical mixture of compounds made up of carbon, hydrogen, oxygen, nitrogen, and sulphur, and is composed of various individual organic compounds, as cellulose, starch, sugar, albumin, and fat. The amount in a food is determined by subtracting the ash and water from 100. The organic matter varies widely in composition; in some foods it is largely starch, as in potatoes and rice, while in others, as forage crops consumed by animals, cellulose predominates. The nature of the prevailing organic compound, as sugar or starch, determines the nutritive value of a food. Each has a definite chemical composition capable of being expressed by a formula. Considered collectively, the organic compounds are termed organic matter. When burned, the organic compounds are converted into gases, the carbon uniting with the oxygen of the air to form carbon dioxide, hydrogen to form water, sulphur to form sulphur dioxide, and the nitrogen to form oxides of nitrogen and ammonia.

5. Classification of Organic Compounds.—All food materials are composed of a large number of organic compounds. For purposes of study these are divided into classes. The element nitrogen is taken as the basis of the division. Compounds which contain this element are called nitrogenous, while those from which it is absent are called non-nitrogenous.[^[2]] The nitrogenous organic compounds are composed of the elements nitrogen, hydrogen, carbon, oxygen, and sulphur, while the non-nitrogenous compounds are composed of carbon, hydrogen, and oxygen. In vegetable foods the non-nitrogenous compounds predominate, there being usually from six to twelve parts of non-nitrogenous to every one part of nitrogenous, while in animal foods the nitrogenous compounds are present in larger amount.

NON-NITROGENOUS COMPOUNDS

6. Occurrence.—The non-nitrogenous compounds of foods consist mainly of cellulose, starch, sugar, and fat. For purposes of study, they are divided into subdivisions, as carbohydrates, pectose substances or jellies, fats, organic acids, essential oils, and mixed compounds. In plants the carbohydrates predominate, while in animal tissue the fats are the chief non-nitrogenous constituents.

7. Carbohydrates.—This term is applied to a class of compounds similar in general composition, but differing widely in structural composition and physical properties. Carbohydrates make up the bulk of vegetable foods and, except in milk, are found only in traces in animal foods. They are all represented by the general formula CH_2n_2n, there being twice as many hydrogen as oxygen atoms, the hydrogen and oxygen being present in the same proportion as in water. As a class, the carbohydrates are neutral bodies, and, when burned, form carbon dioxide and water.

Fig. 2.—Cellular Structure
of Plant Cell.

8. Cellulose is the basis of the cell structure of plants, and is found in various physical forms in food materials.[^[3]] Sometimes it is hard and dense, resisting digestive action and mechanically inclosing other nutrients and thus preventing their being available as food. In the earlier stages of plant growth a part of the cellulose is in chemical combination with water, forming hydrated cellulose, a portion of which undergoes digestion and produces heat and energy in the body. Ordinarily, however, cellulose adds but little in the way of nutritive value, although it is often beneficial mechanically and imparts bulk to some foods otherwise too concentrated. The mechanical action of cellulose on the digestion of food is discussed in Chapter XV. Cellulose usually makes up a very small part of human food, less than 1 per cent. In refined white flour there is less than .05 of a per cent; in oatmeal and cereal products from .5 to 1 per cent, depending upon the extent to which the hulls are removed, and in vegetable foods from .1 to 1 per cent. The cellulose content of foods is included in the crude fiber of the chemist's report.

9. Starch occurs widely distributed in nature, particularly in the seeds, roots, and tubers of some plants. It is formed in the leaves of plants as a result of the joint action of chlorophyll and protoplasm, and is generally held by plant physiologists to be the first carbohydrate produced in the plant cell. Starch is composed of a number of overlapping layers separated by starch cellulose; between these layers the true starch or amylose is found. Starch from the various cereals and vegetables differs widely in mechanical structure; in wheat it is circular, in corn somewhat angular, and in parsnips exceedingly small, while potato starch granules are among the largest.[^[3]] The nature of starch can be determined largely from its mechanical structure as studied under the microscope. It is insoluble in cold water because of the protecting action of the cellular layer, but on being heated it undergoes both mechanical and chemical changes; the grains are partially ruptured by pressure due to the conversion into steam of the moisture held mechanically. The cooking of foods is beneficial from a mechanical point of view, as it results in partial disintegration of the starch masses, changing the structure so that the starch is more readily acted upon by the ferments of the digestive tract. At a temperature of about 120° C. starch begins to undergo chemical change, resulting in the rearrangement of the atoms in the molecule with the production of dextrine and soluble carbohydrates. Dextrine is formed on the crust of bread, or whenever potatoes or starchy foods are browned. At a still higher temperature starch is decomposed, with the liberation of water and production of compounds of higher carbon content. When heated in contact with water, it undergoes hydration changes; gelatinous-like products are formed, which are finally converted into a soluble condition. In cooking cereals, the hydration of the starch is one of the main physical and chemical changes that takes place, and it simply results in converting the material into such a form that other chemical changes may more readily occur. Before starch becomes dextrose, hydration is necessary. If this is accomplished by cooking, it saves the body just so much energy in digestion. Many foods owe their value largely to the starch. In cereals it is found to the extent of 72 to 76 per cent; in rice and potatoes in still larger amounts; and it is the chief constituent of many vegetables. When starch is digested, it is first changed to a soluble form and then gradually undergoes oxidation, resulting in the production of heat and energy, the same products—carbon dioxide and water—being formed as when starch is burned. Starch is a valuable heat-producing nutrient; a pound yields 1860 calories. See Chapter XV.

10. Sugar.—Sugars are widely distributed in nature, being found principally in the juices of the sugar cane, sugar beet, and sugar maple. They are divided into two large classes: the sucrose group and the dextrose group, the latter being produced from sucrose, starch, and other carbohydrates by inversion and allied chemical changes. Because of the importance of sugar in the dietary, Chapter V is devoted to the subject.

11. Pectose Substances are jelly-like bodies found in fruits and vegetables. They are closely related in chemical composition to the carbohydrates, into which form they are changed during digestion; and in nutrition they serve practically the same function. In the early stages of growth the pectin bodies are combined with organic acids, forming insoluble compounds, as the pectin in green apples. During the ripening of fruit and the cooking of vegetables, the pectin is changed to a more soluble and digestible condition. In food analysis, the pectin is usually included with the carbohydrates.

12. Nitrogen-free-extract.—In discussing the composition of foods, the carbohydrates other then cellulose, as starch, sugar, and pectin, are grouped under the name of nitrogen-free-extract. Methods of chemical analysis have not yet been sufficiently perfected to enable accurate and rapid determination to be made of all these individual carbohydrates, and hence they are grouped together as nitrogen-free-extract. As the name indicates, they are compounds which contain no nitrogen, and are extractives in the sense that they are soluble in dilute acid and alkaline solutions. The nitrogen-free-extract is determined indirectly, that is, by the method of difference. All the other constituents of a food, as water, ash, crude fiber (cellulose), crude protein, and ether extract, are determined; the total is subtracted from 100, and the difference is nitrogen-free-extract. In studying the nutritive value of foods, particular attention should be given to the nature of the nitrogen-free-extract, as in some instances it is composed of sugar and in others of starch, pectin, or pentosan (gum sugars). While all these compounds have practically the same fuel value, they differ in composition, structure, and the way in which they are acted upon by chemicals and digestive ferments.[^[1]]

Fig. 3.—Apparatus
used for the Determination
of Fat.

13. Fat.—Fat is found mainly in the seeds of plants, but to some extent in the leaves and stems. It differs from starch in containing more carbon and less oxygen. In starch there is about 44 per cent of carbon, while in fat there is 75 per cent. Hence it is that when fat is burned or undergoes combustion, it yields a larger amount of the products of combustion—carbon dioxid and water—than does starch. A gram of fat produces 2¼ times as much heat as a gram of starch. Fat is the most concentrated non-nitrogenous nutrient. As found in food materials, it is a mechanical mixture of various fats, among which are stearin, palmitin, and olein. Stearin and palmitin are hard fats, crystalline in structure, and with a high melting point, while olein is a liquid. In addition to these three, there are also small amounts of other fats, as butyrin in butter, which give character or individuality to materials. There are a number of vegetable fats or oils which are used for food purposes and, when properly prepared and refined, have a high nutritive value. Occasionally one fat of cheaper origin but not necessarily of lower nutritive value is substituted for another. The fats have definite physical and chemical properties which enable them to be readily distinguished, as iodine number, specific gravity, index of refraction, and heat of combustion. By iodine number is meant the percentage of iodine that will unite chemically with the fat. Wheat oil has an iodine number of about 100, meaning that one pound of wheat oil will unite chemically with one pound of iodine. Fats have a lower specific gravity than water, usually ranging from .89 to .94, the specific gravity of a fat being fairly constant. All fats can be separated into glycerol and a fatty acid, glycerol or glycerine being common constituents, while each fat yields its own characteristic acid, as stearin, stearic acid; palmitin, palmitic acid; and olein, oleic acid. The fats are soluble in ether, chloroform, and benzine. In the chemical analysis of foods, they are separated with ether, and along with the fat, variable amounts of other substances are extracted, these extractive products usually being called "ether extract" or "crude fat."[^[5]] The ether extract of plant tissue contains in addition to fat appreciable amounts of cellulose, gums, coloring, and other materials. From cereal products the ether extract is largely fat, but in some instances lecithin and other nitrogenous fatty substances are present, while in animal food products, as milk and meat, the ether extract is nearly pure fat.

14. Organic Acids.—Many vegetable foods contain small amounts of organic acids, as malic acid found in apples, citric in lemons, and tartaric in grapes. These give characteristic taste to foods, but have no direct nutritive value. They do not yield heat and energy as do starch, fat, and protein; they are, however, useful for imparting flavor and palatability, and it is believed they promote to some extent the digestion of foods with which they are combined by encouraging the secretion of the digestive fluids. Many fruits and vegetables owe their dietetic value to the organic acids which they contain. In plants they are usually in chemical combination with the minerals, forming compounds as salts, or with the organic compounds, producing materials as acid proteins. In the plant economy they take an essential part in promoting growth and aiding the plant to secure by osmotic action its mineral food from the soil. Organic acids are found to some extent in animal foods, as the various lactic acids of meat and milk. They are also formed in food materials as the result of ferment action. When seeds germinate, small amounts of carbohydrates are converted into organic acids. In general the organic acids are not to be considered as nutrients, but as food adjuncts, increasing palatability and promoting digestion.

15. Essential Oils.—Essential or volatile oils differ from fats, or fixed oils, in chemical composition and physical properties.[^[6]] The essential oils are readily volatilized, leaving no permanent residue, while the fixed fats are practically non-volatile. Various essential oils are present in small amounts in nearly all vegetable food materials, and the characteristic flavor of many fruits is due to them. It is these compounds which are used for flavoring purposes, as discussed in Chapter IV. The amount in a food material is very small, usually only a few hundredths of a per cent. The essential oils have no direct food value, but indirectly, like the organic acids, they assist in promoting favorable digestive action, and are also valuable because they impart a pleasant taste. Through poor methods of cooking and preparation, the essential oils are readily lost from some foods.

16. Mixed Compounds.—Food materials frequently contain compounds which do not naturally fall into the five groups mentioned,—carbohydrates, pectose substances, fats, organic acids, and essential oils. The amount of such compounds is small, and they are classed as miscellaneous or mixed non-nitrogenous compounds. Some of them may impart a negative value to the food, and there are others which have all the characteristics, as far as general composition is concerned, of the non-nitrogenous compounds, but contain nitrogen, although as a secondary rather than an essential constituent.

17. Nutritive Value of Non-nitrogenous Compounds.—The non-nitrogenous compounds, taken as a class, are incapable alone of sustaining life, because they do not contain any nitrogen, and this is necessary for producing proteid material in the animal body. They are valuable for the production of heat and energy, and when associated with the nitrogenous compounds, are capable of forming non-nitrogenous reserve tissue. It is equally impossible to sustain life for any prolonged period with the nitrogenous compounds alone. It is when these two classes are properly blended and naturally united in food materials that their main value is secured. For nutrition purposes they are mutually related and dependent. Some food materials contain the nitrogenous and non-nitrogenous compounds blended in such proportion as to enable one food alone to practically sustain life, while in other cases it is necessary, in order to secure the best results in the feeding of animals and men, to combine different foods varying in their content of these two classes of compounds.[^[7]]

NITROGENOUS COMPOUNDS

18. General Composition.—The nitrogenous compounds are more complex in composition than the non-nitrogenous. They are composed of a larger number of elements, united in different ways so as to form a much more complex molecular structure. Foods contain numerous nitrogenous organic compounds, which, for purposes of study, are divided into four divisions,—proteids, albuminoids, amids, and alkaloids. In addition to these, there are other nitrogenous compounds which do not naturally fall into any one of the four divisions.

Fig. 4.—Apparatus used for Determining Total Nitrogen and Crude Protein in Foods.

The material is digested in the flask (3) with sulphuric acid and the organic nitrogen converted into ammonium sulphate, which is later liberated and distilled at 1, and the ammonia neutralized with standard acid (2).]

Also in some foods there are small amounts of nitrogen in mineral forms, as nitrates and nitrites.

19. Protein.—The term "protein" is applied to a large class of nitrogenous compounds resembling each other in general composition, but differing widely in structural composition. As a class, the proteins contain about 16 per cent of nitrogen, 52 per cent of carbon, from 6 to 7 per cent of hydrogen, 22 per cent of oxygen, and less than 2 per cent of sulphur. These elements are combined in a great variety of ways, forming various groups or radicals. In studying the protein molecule a large number of derivative products have been observed, as amid radicals, various hydrocarbons, fatty acids, and carbohydrate-like bodies.[^[8]] It would appear that in the chemical composition of the proteins there are all the constituents, or simpler products, of the non-nitrogenous compounds, and these are in chemical combination with amid radicals and nitrogen in various forms. The nitrogen of many proteids appears to be present in more than one form or radical. The proteids take an important part in life processes. They are found more extensively in animal than in plant bodies. The protoplasm of both the plant and animal cell is composed mainly of protein.

Proteids are divided into various subdivisions, as albumins, globulins, albuminates, proteoses and peptones, and insoluble proteids. In plant and animal foods a large amount of the protein is present as insoluble proteids; that is, they are not dissolved by solvents, as water and dilute salt solution. The albumins are soluble in water and coagulated by heat at a temperature of 157° to 161° F. Whenever a food material is soaked in water, the albumin is removed and can then be coagulated by the action of heat, or of chemicals, as tannic acid, lead acetate, and salts of mercury. The globulins are proteids extracted from food materials by dilute salt solution after the removal of the albumins. Globulins also are coagulated by heat and precipitated by chemicals. The amount of globulins in vegetable foods is small. In animal foods myosin in meat and vitellin, found in the yolk of the egg, and some of the proteids of the blood, are examples of globulins. Albuminates are casein-like proteids found in both animal and vegetable foods. They are supposed to be proteins that are in feeble chemical combination with acid and alkaline compounds, and they are sometimes called acid and alkali proteids. Some are precipitated from their solutions by acids and others by alkalies. Peas and beans contain quite large amounts of a casein-like proteid called legumin. Proteoses and peptones are proteins soluble in water, but not coagulated by heat. They are produced from other proteids by ferment action during the digestion of food and the germination of seeds, and are often due to the changes resulting from the action of the natural ferments or enzymes inherent in the food materials. As previously stated, the insoluble proteids are present in far the largest amount of any of the nitrogenous materials of foods. Lean meat and the gluten of wheat and other grains are examples of the insoluble proteids. The various insoluble proteids from different food materials each has its own composition and distinctive chemical and physical properties, and from each a different class and percentage amount of derivative products are obtained.[^[1]] While in general it is held that the various proteins have practically the same nutritive value, it is possible that because differences in structural composition and the products formed during digestion there may exist notable differences in nutritive value. During digestion the insoluble proteids undergo an extended series of chemical changes. They are partially oxidized, and the nitrogenous portion of the molecule is eliminated mainly in the form of amids, as urea. The insoluble proteins constitute the main source of the nitrogenous food supply of both humans and animals.

20. Crude Protein.—In the analysis of foods, the term "crude protein" is used to designate the total nitrogenous compounds considered collectively; it is composed largely of protein, but also includes the amids, alkaloids, and albuminoids. "Crude protein" and "total nitrogenous compounds" are practically synonymous terms. The various proteins all contain about 16 per cent of nitrogen; that is, one part of nitrogen is equivalent to 6.25 parts of protein. In analyzing a food material, the total organic nitrogen is determined and the amount multiplied by 6.25 to obtain the crude protein. In some food materials, as cereals, the crude protein is largely pure protein, while in others, as potatoes, it is less than half pure protein, the larger portion being amids and other compounds. In comparing the crude protein content of one food with that of another, the nature of both proteids should be considered and also the amounts of non-proteid constituents. The factor 6.25 for calculating the protein equivalent of foods is not strictly applicable to all foods. For example, the proteids of wheat—gliadin and glutenin—contain over 18 per cent of nitrogen, making the nitrogen factor about 5.68 instead of 6.25. If wheat contains 2 per cent of nitrogen, it is equivalent to 12.5 per cent of crude protein, using the factor 6.25; or to 11.4, using the factor 5.7. The nitrogen content of foods is absolute; the protein content is only relative.[^[9]]

21. Food Value of Protein.—Because of its complexity in composition, protein is capable of being used by the body in a greater variety of ways than starch, sugar, or fat. In addition to producing heat and energy, protein serves the unique function of furnishing material for the construction of new muscular tissue and the repair of that which is worn out. It is distinctly a tissue-building nutrient. It also enters into the composition of all the vital fluids of the body, as the blood, chyme, chyle, and the various digestive fluids. Hence it is that protein is required as a nutrient by the animal body, and it cannot be produced from non-nitrogenous compounds. In vegetable bodies, the protein can be produced synthetically from amids, which in turn are formed from ammonium compounds. While protein is necessary in the ration, an excessive amount should be avoided. When there is more than is needed for functional purposes, it is used for heat and energy, and as foods rich in protein are usually the most expensive, an excess adds unnecessarily to the cost of the ration. Excess of protein in the ration may also result in a diseased condition, due to imperfect elimination of the protein residual products from the body.[^[10]]

22. Albuminoids differ from proteids in general composition and, to some extent, in nutritive value. They are found in animal bodies mainly in the connective tissue and in the skin, hair, and nails. Some of the albuminoids, as nuclein, are equal in food value to protein, while others have a lower food value. In general, albuminoids are capable of conserving the protein of the body, and hence are called "protein sparers," but they cannot in every way enter into the composition of the body, as do the true proteins.

23. Amids and Amines.—These are nitrogenous compounds of simpler structure than the proteins and albuminoids. They are sometimes called compound ammonia in that they are derived from ammonia by the replacement of one of the hydrogen atoms with an organic radical. In plants, amids are intermediate compounds in the production of the proteids, and in some vegetables a large portion of the nitrogen is amids. In animal bodies amids are formed during oxidation, digestion, and disintegration of proteids. It is not definitely known whether or not a protein in the animal body when broken down into amid form can again be reconstructed into protein. The amids have a lower food value than the proteids and albuminoids. It is generally held that, to a certain extent, they are capable, when combined with proteids, of preventing rapid conversion of the body proteid into soluble form. When they are used in large amounts in a ration, they tend to hasten oxidation rather than conservation of the proteids.

24. Alkaloids.—In some plant bodies there are small amounts of nitrogenous compounds called alkaloids. They are not found to any appreciable extent in food plants. The alkaloids, like ammonia, are basic in character and unite with acids to form salts. Many medicinal plants owe their value to the alkaloids which they contain. In animal bodies alkaloids are formed when the tissue undergoes fermentation changes, and also during disease, the products being known as ptomaines. Alkaloids have no food value, but act physiologically as irritants on the nerve centers, making them useful from a medicinal rather than from a nutritive point of view. To medical and pharmaceutical students the alkaloids form a very important group of compounds.

Fig. 5.—Graphic Composition of Flour.

1, flour; 2, starch; 3, gluten; 4, water; 5, fat; 6, ash.

25. General Relationship of the Nitrogenous Compounds.—Among the various subdivisions of the nitrogenous compounds there exists a relationship similar to that among the non-nitrogenous compounds. From proteids, amids and alkaloids may be formed, just as invert sugars and their products are formed from sucrose. Although glucose products are derived from sucrose, it is not possible to reverse the process and obtain sucrose or cane sugar from starch. So it is with proteins, while the amid may be obtained from the proteid in animal nutrition, as far as known the process cannot be reversed and proteids be obtained from amids. In the construction of the protein molecule of plants, nitrogen is absorbed from the soil in soluble forms, as compounds of nitrates and nitrites and ammonium salts. These are converted, first, into amids and then into proteids. In the animal body just the reverse of this process takes place,—the protein of the food undergoes a series of changes, and is finally eliminated from the body as an amid, which in turn undergoes oxidation and nitrification, and is converted into nitrites, nitrates, and ammonium salts. These forms of nitrogen are then ready to begin again in plant and animal bodies the same cycle of changes. Thus it is that nitrogen may enter a number of times into the composition of plant and animal tissues. Nature is very economical in her use of this element.[^[5]]

CHAPTER II

CHANGES IN COMPOSITION OF FOODS DURING COOKING AND PREPARATION

26. Raw and Cooked Foods Compared.—Raw and cooked foods differ in chemical composition mainly in the content of water. The amount of nutrients on a dry matter basis is practically the same, but the structural composition is affected by cooking, and hence it is that a food prepared for the table often differs appreciably from the raw material. Cooked meat, for example, has not the same percentage and structural composition as raw meat, although the difference in nutritive value between a given weight of each is not large. During cooking, foods are acted upon chemically, physically, and bacteriologically, and it is usually the joint action of these three agencies that brings about the desirable changes incident to their preparation for the table.

27. Chemical Changes during Cooking.—Each of the chemical compounds of which foods are composed is influenced to a greater or less extent by heat and modified in composition. The chemistry of cooking is mainly a study of the chemical changes that take place when compounds, as cellulose, starch, sugar, pectin, fat, and the various proteids, are subjected to the joint action of heat, moisture, air, and ferments. The changes which affect the cellulose are physical rather than chemical. A slight hydration of the cellular tissue, however, does take place. In human foods cellulose is not found to any appreciable extent. Many vegetables, as potatoes, which are apparently composed of cellular substances, contain but little true cellulose. Starch, as previously stated, undergoes hydration in the presence of water, and, at a temperature of 120° C., is converted into dextrine. At a higher temperature disintegration of the starch molecule takes place, with the formation of carbon monoxid, carbon dioxid, and water, and the production of a residue richer in carbon than is starch. On account of the moisture, the temperature in many cooking operations is not sufficiently high for changes other than hydration and preliminary dextrinizing. In Chapter XI is given a more extended account of the changes affecting starch which occur in bread making.

During the cooking process sugars undergo inversion to a slight extent. That is, sucrose is converted into levulose and dextrose sugars. At a higher temperature, sugar is broken up into its constituents—water and carbon dioxide. The organic acids which many fruits and vegetables contain hasten the process of inversion. When sugar is subjected to dry heat, it becomes a brown, caramel-like material sometimes called barley sugar. During cooking, sugars are not altered in solubility or digestibility; starches, however, are changed to a more soluble form, and pectin—a jelly-like substance—is converted from a less to a more soluble condition, as stated in Chapter I. Changes incident to the cooking of fruits and vegetables rich in pectin, as in the making of jellies, are similar to those which take place in the last stages of ripening.

The fats are acted upon to a considerable extent by heat. Some of the vegetable oils undergo slight oxidation, resulting in decreased solubility in ether, but since there is no volatilization of the fatty matter, it is a change that does not materially affect the total fuel value of the food.[^[11]]

There is a general tendency for the proteids to become less soluble by the action of heat, particularly the albumins and globulins. The protein molecule dissociates at a high temperature, with formation of volatile products, and therefore foods rich in protein should not be subjected to extreme heat, as losses of food value may result. During cooking, proteids undergo hydration, which is necessary and preliminary to digestion, and the heating need be carried only to this point, and not to the splitting up of the molecule. Prolonged high temperature in the cooking of proteids and starches is unnecessary in order to induce the desired chemical changes. When these nutrients are hydrated, they are in a condition to undergo digestion, without the body being compelled to expend unnecessary energy in bringing about this preliminary change. Hence it is that, while proper cooking does not materially affect the total digestibility of proteids or starches, it influences ease of digestion, as well as conserves available energy, thereby making more economical use of these nutrients.

Fig. 6.—Cells of
a Partially Cooked
Potato. (After König.)

28. Physical Changes.—The mechanical structure of foods is influenced by cooking to a greater extent than is the chemical composition. One of the chief objects of cooking is to bring the food into better mechanical condition for digestion.[^[12]] Heat and water cause partial disintegration of both animal and vegetable tissues. The cell-cementing materials are weakened, and a softening of the tissues results. Often the action extends still further in vegetable foods, resulting in disintegration of the individual starch granules. When foods are subjected to dry heat, the moisture they contain is converted into steam, which causes bursting of the tissues. A good example of this is the popping of corn. Heat may result, too, in mechanical removal of some of the nutrients, as the fats, which are liquefied at temperatures ranging from 100° to 200° F. Many foods which in the raw state contain quite large amounts of fat, lose a portion mechanically during cooking, as is the case with bacon when it is cut in thin slices and fried or baked until crisp. When foods are boiled, the natural juices being of somewhat different density from the water in which they are cooked, slight osmotic changes occur. There is a tendency toward equalization of the composition of the juices of the food and the water in which they are cooked. In order to achieve the best mechanical effects in cooking, high temperatures are not necessary, except at first for rupturing the tissues; softening of the tissues is best effected by prolonged and slow heat. At a higher temperature many of the volatile and essential oils are lost, while at lower temperatures these are retained and in some instances slightly developed. The cooking should be sufficiently prolonged and the temperature high enough to effectually disintegrate and soften all of the tissues, but not to cause extended chemical changes.

Fig. 7.—Cells of
Raw Potato, Showing Starch
Grains. (After König.)

There is often an unnecessarily large amount of heat lost through faulty construction of stoves and lack of judicious use of fuels, which greatly enhances the cost of preparing foods. Ovens are frequently coated with deposits of soot; this causes the heat to be thrown out into the room or lost through the chimney, rather than utilized for heating the oven. In an ordinary cook stove it is estimated that less than 7 per cent of the heat and energy of the fuel is actually employed in bringing about physical and chemical changes incident to cooking.[^[13]]

29. Bacteriological Changes.—The bacterial organisms of foods are destroyed in the cooking, provided a temperature of 150° F. is reached and maintained for several minutes. The interior of foods rarely reaches a temperature above 200° F., because of the water they contain which is not completely removed below 212°. One of the chief objects in cooking food is to render it sterile. Not only do bacteria become innocuous through cooking, but various parasites, as trichina and tapeworm, are destroyed, although some organisms can live at a comparatively high temperature. Cooked foods are easily re-inoculated, in some cases more readily than fresh foods, because they are in a more disintegrated condition.

In many instances bacteria are of material assistance in the preparation of foods, as in bread making, butter making, curing of cheese, and ripening of meat. All the chemical compounds of which foods are composed are subject to fermentation, each compound being acted upon by its special ferment body. Those which convert the proteids into soluble form, as the peptonizing ferments, have no action upon the carbohydrates. A cycle of bacteriological changes often takes place in a food material, one class of ferments working until their products accumulate to such an extent as to prevent their further activity, and then the process is taken up by others, as they find the conditions favorable for development. This change of bacterial flora in food materials is akin to the changes in the vegetation occupying soils. In each case, there is a constant struggle for possession. Bacteria take a much more important part in the preparation of foods than is generally considered. As a result of their workings, various chemical products, as organic acids and aromatic compounds, are produced. The organic acids chemically unite with the nutrients of foods, changing their composition and physical properties. Man is, to a great extent, dependent upon bacterial action. Plant life also is dependent upon the bacterial changes which take place in the soil and in the plant tissues. The stirring of seeds into activity is apparently due to enzymes or soluble ferments which are inherent in the seed. A study of the bacteriological changes which foods undergo in their preparation and digestion more properly belongs to the subject of bacteriology, and in this work only brief mention is made of some of the more important parts which microörganisms take in the preparation of foods.

30. Insoluble Ferments.—Insoluble ferments are minute, plant-like bodies of definite form and structure, and can be studied only with the microscope.[^[1]] They are developed from spores or seeds, or from the splitting or budding of the parent cells. Under suitable conditions they multiply rapidly, deriving the energy for their life processes from the chemical changes which they induce. For example, in the souring of milk the milk sugar is changed by the lactic acid ferments into lactic acid. In causing chemical changes, the ferment gives none of its own material to the reacting substance. These ferment bodies undergo life processes similar to plants of a higher order.

Fig. 8.—Lactic Acid
Bacteria, Much Enlarged.
(After Russell.)

All foods contain bacteria or ferments. In fact, it is impossible for a food stored and prepared under ordinary conditions, unless it has been specially treated, to be free from them. Some of them are useful, some are injurious, while others are capable of producing disease. The objectionable bacteria are usually destroyed by the joint action of sunlight, pure air, and water.

31. Soluble Ferments.—Many plant and animal cells have the power of secreting substances soluble in water and capable of producing fermentation changes; to these the term "soluble ferments," or "enzymes," is applied. These ferments have not a cell structure like the organized ferments. When germinated seed, as malted barley, is extracted, a soluble and highly nitrogenous substance, called the diastase ferment, is secured that changes starch into soluble forms. The soluble ferments induce chemical change by causing molecular disturbance or splitting up of the organic compounds, resulting in the production of derivative products. They take an important part in animal and plant nutrition, as by their action insoluble compounds are brought into a soluble condition so they can be utilized for nutritive purposes. In many instances ferment changes are due to the joint action of soluble and insoluble ferments. The insoluble ferment secretes an enzyme which induces a chemical change, modified by the further action of the soluble ferment. Many of the enzymes carry on their work at a low temperature, as in the curing of meat and cheese in cold storage.[^[14]]

32. General Relationship of Chemical, Physical, and Bacteriological Changes.—It cannot be said that the beneficial results derived from the cooking of foods are due to either chemical, physical, or bacteriological change alone, but to the joint action of the three. In order to secure a chemical change, a physical change must often precede, and a bacteriological change cannot take place without causing a change in chemical composition; the three are closely related and interdependent.

33. Esthetic Value of Foods.—Foods should be not only of good physical texture and contain the requisite nutrients, but they should also be pleasing to the eye and served in the most attractive manner. Some foods owe a part of their commercial value to color, and when they are lacking in natural color they are not consumed with a relish. There is no objection to the addition of coloring matter to foods, provided it is of a non-injurious character and does not affect the amount of nutrients, and that its presence and the kind of coloring material are made known. Some foods contain objectionable colors which are eliminated during the process of manufacture, as in the case of sugar and flour. As far as removal of coloring matter from foods during refining is concerned, there can be no objection, so long as no injurious reagents or chemicals are retained, as the removal of the color in no way affects the nutritive value or permits fraud, but necessitates higher purification and refining. The use of chemicals and reagents in the preparation and refining of foods is considered permissible in all cases where the reagents are removed by subsequent processes. In the food decisions of the United States Department of Agriculture, it is stated: "Not excluded under this provision are substances properly used in the preparation of food products for clarification or refining and eliminated in the further process of manufacture." [^[15]]

CHAPTER III

VEGETABLE FOODS

Fig. 9.—Transverse Section
of Potato. (After Cowden
and Bussard.) a, skin; b, cortical
layer; c, outer medullary
layer; d, inner medullary layer.

34. General Composition.—Vegetable foods, with the exception of cereals, legumes, and nuts, contain a smaller percentage of protein than animal food products. They vary widely in composition and nutritive value; in some, starch predominates, while in others, sugar, cellulose, and pectin bodies are most abundant. The general term "vegetable foods" is used in this work to include roots, tubers, garden vegetables, cereals, legumes, and all prepared foods of vegetable origin.

35. Potatoes contain about 75 per cent of water and 25 per cent of dry matter, the larger portion being starch. There is but little nitrogenous material in the potato, only 2.25 per cent, of which about half is in the form of proteids. There are ten parts of non-nitrogenous substance to every one part of nitrogenous; or, in other words, the potato has a wide nutritive ratio, and as an article of diet needs to be supplemented with foods rich in protein. The mineral matter, cellular tissue, and fat in potatoes are small in amount, as are also the organic acids. Mechanically considered, the potato is composed of three parts,—outer skin, inner skin, and flesh. The layer immediately beneath the outer skin is slightly colored, and is designated the fibro-vascular layer. The outer and inner skins combined make up about 10 per cent of the weight of the potato.

A large portion of the protein of the potato is albumin, which is soluble in water. When potatoes are peeled, cut in small pieces, and soaked in water for several hours before boiling, 80 per cent of the crude protein, or total nitrogenous material, is extracted, rendering the product less valuable as food. When potatoes are placed directly in boiling water, the losses of nitrogenous compounds are reduced to about 7 per cent, and, when the skins are not removed, to 1 per cent. Digestion experiments show that 92 per cent of the starch and 72 per cent of the protein are digested.[^[12]] Compared with other foods, potatoes are often a cheap source of non-nitrogenous nutrients. If used in excessive amounts, however, they have a tendency to make the ration unbalanced and too bulky.

Mechanical Composition of the Potato

Chemical Composition of the Potato

[A] Including a small amount of flesh.

[B] From an unpublished compilation of analyses of American food products.

[C] König, "Chemie der Nahrungs-und Genussmittel," 3d ed., II, p. 626.

36. Sweet Potatoes contain more dry matter than white potatoes, the difference being due mainly to the presence of about 6 per cent of sugar. There is approximately the same starch content, but more fat, protein, and fiber. As a food, they supply a large amount of non-nitrogenous nutrients.

37. Carrots contain about half as much dry matter as potatoes, and half of the dry matter is sugar, nearly equally divided between sucrose and levulose, or fruit sugar. Like the potato, carrots have some organic acids and a relatively small amount of proteids. In carrots and milk there is practically the same per cent of water. The nutrients in each, however, differ both as to kind and proportion. Experiments with the cooking of carrots show that if a large amount of water is used, 30 per cent or more of the nutrients, particularly of the more soluble sugar and albumin, are extracted and lost in the drain waters.[^[12]] The color of the carrot is due to the non-nitrogenous compound carrotin, C₂₆H₃₈. Carrots are valuable in a ration not because of the nutrients they supply, but for the palatability and the mechanical action which the vegetable fiber exerts upon the process of digestion.

38. Parsnips contain more solid matter than beets or carrots, of which 3 to 4 per cent is starch. The starch grains are very small, being only about one twentieth the size of the potato starch grains. There is 3 per cent of sugar and an appreciable amount of fat, more than in any other of the vegetables of this class, and seven times as much as in the potato. The mineral matter is of somewhat different nature from that in potatoes; in parsnips one half is potash and one quarter phosphoric acid, while in potatoes three quarters are potash and one fifth phosphoric acid.

Fig. 10.—Graphic
Composition of Cabbage.

39. Cabbage contains very little dry matter, usually less than 10 per cent. It is proportionally richer in nitrogenous compounds than many vegetables, as about two of the ten parts of dry matter are crude protein, which makes the nutritive ratio one to five. During cooking 30 to 40 per cent of the nutrients are extracted. Cabbage imparts to the ration bulk but comparatively little nutritive material. It is a valuable food adjunct, particularly used raw, as in a salad, when it is easily digested and retains all of the nutrients.[^[12]]

40. Cauliflower has much the same general composition as cabbage, from which it differs mainly in mechanical structure.

41. Beets.—The garden beet contains a little more protein than carrots, but otherwise has about the same general composition, and the statements made in regard to the losses of nutrients in the cooking of carrots and to their use in the dietary apply also to beets.

42. Cucumbers contain about 4 per cent of dry matter. The amount of nutrients is so small as to scarcely allow them to be considered a food. They are, however, a valuable food adjunct, as they impart palatability.

43. Lettuce contains about 7 per cent of solids, of which 1.5 is protein and 2.5 starch and sugar. While low in nutrients, it is high in dietetic value, because of the chlorophyll which it contains. It has been suggested that it is valuable, too, for supplying iron in an organic form, as there is iron chemically combined with the chlorophyll.

44. Onions are aromatic bulbs, valuable for condimental rather than nutritive purposes. They contain essential and volatile oils, which impart characteristic odor and flavor. In the onion there are about 1.5 per cent of protein and 9.5 per cent of non-nitrogenous material. Onions are often useful in stimulating the digestive tract to action.

45. Spinach is a valuable food, not to be classed merely as a relish. Its composition is interesting; for, although there is 90 per cent water, and less than 10 per cent dry matter, it still possesses high food value. Spinach contains 2.1 per cent crude protein, or about one part to every four parts of carbohydrates. In potatoes, turnips, and beets there are ten or more parts of carbohydrates to every one part of protein.

46. Asparagus is composed largely of water, about 93 per cent. The dry matter, however, is richer in protein than that of many vegetables. Asparagus contains, too, an amid compound, asparagin, which gives some of the characteristics to the vegetable.

47. Melons.—Melons contain from 8 to 10 per cent of dry matter, the larger portion of which is sugar and allied carbohydrates. The flavor is due to small amounts of essential oils and to organic acids associated with the sugars. Melons possess condimental rather than nutritive value.

Fig. 11.—Graphic
Composition Of Tomato.

48. Tomatoes.—The tomato belongs to the night-shade family, and for this reason was long looked upon with suspicion. It was first used for ornamental purposes and was called "love-apple." Gradually, as the idea of its poisonous nature became dispelled, it grew more and more popular as a food, until now in the United States it is one of the most common garden vegetables. It contains 7 per cent of dry matter, 4 per cent of which is sucrose, dextrose, and levulose. It also contains some malic acid, and a small amount of proteids, amids, cellulose, and coloring material. In the canning of tomatoes, if too much of the juice is excluded, a large part of the nutritive material is lost, as the sugars and albumins are all soluble and readily removed.[^[16]] If the seeds are objectionable, they may be removed by straining and the juice added to the fleshy portion. The product then has a higher nutritive value than if the juice had been discarded with the seeds.

49. Sweet Corn.—Fresh, soft, green, sweet corn contains about 75 per cent of water. The dry matter is half starch and one quarter sugar. The protein content makes up nearly 5 per cent, a larger proportional amount than is found in the ripened corn, due to the fact that the proteids are deposited in the early stages of growth and the carbohydrates mainly in the last stages. Sweet corn is a vegetable of high nutritive value and palatability.

50. Eggplant contains a high per cent of water,—90 per cent. The principal nutrients are starch and sugar, which make up about half the weight of the dry matter. It does not itself supply a large amount of nutrients, but the way in which it is prepared, by combination with butter, bread crumbs, and eggs, makes it a nutritious and palatable dish, the food value being derived mainly from the materials with which it is combined, the eggplant giving the flavor and palatability.

51. Squash and Pumpkin.—Squash has much the same general composition and food value as beets and carrots, although it belongs to a different family. Pumpkins contain less dry matter than squash. The dry matter of both is composed largely of starch and sugar and, like many other of the vegetables, they are often combined with food materials containing a large amount of nutrients, as in pumpkin and squash pies, where the food value is derived mainly from the milk, sugar, eggs, flour, and butter or other shortening used.

52. Celery.—The dry matter of celery is comparatively rich in nitrogenous material, although the amount is small, and the larger proportion is in non-proteid form. When grown on rich soil, celery may contain an appreciable quantity of nitrates and nitrites, which have not been converted into amids and proteids. The supposed medicinal value is probably due to the nitrites which are generally present. Celery is valuable from a dietetic rather than a nutritive point of view.

53. Sanitary Condition of Vegetables.—The conditions under which vegetables are grown have much to do with their value, particularly from a sanitary point of view. Uncooked vegetables often cause the spread of diseases, particularly those, as cholera and typhoid, affecting the digestive tract. Particles of dirt containing the disease-producing organisms adhere to the uncooked vegetable and find their way into the digestive tract, where the bacteria undergo incubation. When sewage has been used for fertilizing the land, as in sewage irrigation, the vegetables are unsound from a sanitary point of view. Such vegetables should be thoroughly cleaned and also well cooked, in order to render them sterile. Vegetables to be eaten in the raw state should be dipped momentarily into boiling water, to destroy the activity of the germs present upon the surface. They may then be immediately immersed in ice-cold water, to preserve the crispness.

54. Miscellaneous Compounds in Vegetables.—In addition to the general nutrients which have been discussed, many of the vegetables contain some tannin, glucosides, and essential oils; and occasionally those grown upon rich soils have appreciable amounts of nitrogen compounds, as nitrates and nitrites, which have not been built up into proteids. Vegetables have a unique value in the dietary, and while as a class they contain small amounts of nutrients, they are indispensable for promoting health and securing normal digestion of the food.

55. Canned Vegetables.—When sound vegetables are thoroughly cooked to destroy ferments, and then sealed in cans while hot, they can be kept for a long time without any material impairment of nutritive value. During the cooking process there is lost a part of the essential oils, which gives a slightly different flavor to the canned or tinned goods.[^[17]] In some canned vegetables preservatives are used, but the enactment and enforcement of national and state laws have greatly reduced their use. When the cans are made of a poor quality of tin, or the vegetables are of high acidity, some of the metal is dissolved in sufficient quantity to be objectionable from a sanitary point of view.[^[18]]

56. Edible Portion and Refuse of Vegetables.—Many vegetables have appreciable amounts of refuse,[^[19]] or non-edible parts, as skin, pods, seeds, and pulp, and in determining the nutritive value, these must be considered, as in some cases less than 50 per cent of the weight of the material is edible portion, which proportionally increases the cost of the nutrients. Ordinarily, the edible part is richer in protein than the entire material as purchased. In some cases, however, the refuse is richer in protein, but the protein is in a less available form. See comparison of potatoes and potato skins.

CHAPTER IV

FRUITS, FLAVORS, AND EXTRACTS

57. General Composition.—Fruits are characterized by containing a large amount of water and only a small amount of dry matter, which is composed mainly of sugar and non-nitrogenous compounds. Fruits contain but little fatty material and protein. A large portion of the total nitrogen is in the form of amid compounds. Organic acids, as citric, tartaric, and malic, are found in all fruits, and the essential oils form a characteristic feature. The taste of fruits is due mainly to the blending of the various organic acids, essential oils, and sugars. Although fruits contain a high per cent of water, they are nevertheless valuable as food.[^[20]] The constituents present to the greatest extent are sugars and acids. The sugar is not all like the common granulated sugar, but in ripe fruits a part is in the form known as levulose or fruit sugar, which is two and a half times sweeter than granulated sugar. Sugars are valuable for heat-and fat-producing purposes, but not for muscle repairing. Proteids are the muscle-forming nutrients. The organic acids, as malic acid in apples, citric acid in lemons and oranges, and tartaric acid in grapes, have characteristic medicinal properties. The sugar, proteid, and acid content of some of our more common fruits is given in the following table:[^[21]]

Composition of Fruits

In addition to sugars, acids, and proteids, there are a great many other compounds in fruits. Those which give the characteristic taste are called essential or volatile oils.

58. Food Value.—When the nutrients alone are considered, fruits appear to have a low food value, but they should not be judged entirely on this basis, because they impart palatability and flavor to other foods and exercise a favorable influence upon the digestive process. In the human ration fruits are a necessary adjunct.

59. Apples.—Apples vary in composition with the variety and physical characteristics of the fruit. In general they contain from 10 to 16 per cent of dry matter, of which 75 per cent, or more, is sugar or allied carbohydrates. Among the organic acids malic predominates, and the acidity ranges from 0.1 to 0.8 per cent. Apples contain but little protein, less than 1 per cent. There is some pectin, or jelly-like substance closely related to the carbohydrates. The flavor of the apple varies with the content of sugar, organic acids, and essential oils. During storage some apples appear to undergo further ripening, resulting in partial inversion of the sucrose, and there is a slight loss of weight, due to the formation of carbon dioxide. The apple is an important and valuable adjunct to the dietary.[^[22]]

60. Oranges contain nearly the same proportion of dry matter as apples, the larger part of which is sugar. Citric acid predominates and ranges in different varieties from 1 to 2.5 per cent. The amounts of protein, fat, and cellulose are small. In some varieties of oranges there is more iron and sulphur than is usually found in fruits. All fruits, however, contain small amounts, but not as much as is found in green vegetables. The average composition of oranges is as follows:

61. Lemons differ from oranges in containing more citric acid and less sucrose, levulose, and dextrose. The ash of the lemon is somewhat similar in general composition to the ash of the orange, but is larger in amount. The average composition of the lemon is as follows:

62. Grape Fruit.—The rind and seed of this fruit make up about 25 per cent, leaving 75 per cent as edible portion. The juice contains 14 per cent solids, of which nearly 10 per cent is sugar and 2.5 per cent is citric acid. There is more acid in grape fruit than in oranges and appreciably less than in lemons. The characteristic flavor is due to a glucoside-like material. Otherwise the composition and food value are about the same as of oranges.

Fig. 14.—Graphic
Composition of Strawberry.

63. Strawberries contain from 8 to 12 per cent of dry matter, mainly sugar and malic acid. The protein, fat, and ash usually make up less than 2 per cent. Essential oils and coloring substances are present in small amounts. It has been estimated that it would require 75 pounds of strawberries to supply the protein for a daily ration. Nevertheless they are valuable in the dietary. It has been suggested that the malic and other acids have antiseptic properties which, added to the appearance and palatability, make them a desirable food adjunct. Strawberries have high dietetic rather than high food value.

64. Grapes contain more dry matter than apples or oranges. There is no appreciable amount of protein or fat, and while they add some nutrients, as sugar, to the ration, they do not contribute any quantity. Their value, as in the case of other fruits, is due to palatability and indirect effect upon the digestibility of other foods. In the juice of grapes there is from 10 to 15 per cent or more of sugar, as sucrose, levulose, and dextrose. Grapes contain also from 1 to 1.5 per cent of tartaric acid, which, during the process of manufacture into wine, is rendered insoluble by the alcohol formed, and the product, known as argole, is used in the preparation of cream of tartar. Differences in flavor and taste of grapes are due to variations in the sugar, acid, and essential oil content.

65. Peaches contain about 12 per cent of dry matter, of which over 10 per cent is sugar and other carbohydrates. There is less than 1.5 per cent of protein, fat, and mineral matter and about 0.5 per cent of acid. The peach contains also a very small amount of hydrocyanic acid, which is more liberally present in the kernel than in the fruit. Flavor is imparted mainly by the sugar and essential oils. Peaches vary in composition with variety and environment.[^[23]]

66. Plums contain the most dry matter of any of the fruits, about 22 per cent, mainly sugar. About one per cent is acid and about 0.5 per cent are protein and ash. There are a great many varieties of plums, varying in composition. Dried plums (prunes) have mildly laxative properties.

67. Olives.—The ripe olive contains about 15 per cent of oil, exclusive of the pit, which makes up 20 per cent of the weight. In green, preserved olives there is considerably less oil. Because of the oil the olive has food value. Olive oil is slightly laxative and assists mechanically in the digestion of foods.

68. Figs.—Dried figs contain about 50 per cent of sugar and 3.5 per cent of protein. The fig has a mildly laxative action.

69. Dried Fruits.—Many fruits are prepared for market by drying. The dried fruit has a slightly different composition from the fresh fruit because of loss of the volatile and essential oils, and minor chemical changes which take place during the drying process. When free from preservatives, dried fruits are valuable adjuncts to the dietary and can be advantageously used when fresh fruits are not obtainable.

70. Canning and Preservation of Fruits.—To obtain the best results in canning, the fruit should not be overripe. After the ripened state has been reached fermentation and bacterial changes occur, and it is more difficult to preserve the fruit than when not so fully matured.[^[24]] When a fruit has begun to ferment, it is hard to destroy the ferment bodies and their spores so as to prevent further ferment action. The chemical changes that occur in the last stages of ripening are similar to those which take place during the cooking process whereby the pectin or jelly-like substances are rendered more soluble and digestible.

71. Adulterated Canned Fruits.—Analyses of a number of canned fruits, made by various Boards of Health, show the presence of small amounts of arsenic, tin, lead, and other poisonous metals. The quantity dissolved depends upon the kind, age, and condition of the canned goods and the state of the fruit when canned. The longer a can of fruit or vegetable has been kept in stock, the larger is the amount of tin or metal that has been dissolved. When fresh canned, there is usually very little dissolved tin, but in old goods the amount may be comparatively large. The tin used for the can is occasionally of poor quality and may contain some arsenic, which also is dissolved. The occasional use of canned goods preserved in tin is not objectionable, but they should not be used continually if it can be avoided. Preservatives, as borax, salicylic acid, benzoic acid, and sodium sulphate, are sometimes added to prevent fermentation and to preserve the natural appearance of the fruit or vegetable.[^[18]]

72. Fruit Flavors and Extracts.—Formerly all fruit extracts and flavors were obtained from vegetable sources; at present many are made in the chemical laboratory by synthetic methods; that is, by combining simpler organic compounds and radicals to produce the material having the desired flavor and odor. The various fruit flavors are definite chemical compounds, and can be produced in the laboratory as well as in the cells of plants. When properly made, there is no difference in chemical composition between the two. As prepared in the laboratory, however, traces of acids, alkalies, and other compounds, used in bringing about the necessary chemical combination, are often present, not having been perfectly removed. Hence it is that natural and artificial flavors differ mainly in the impurities which the artificial flavors may contain.

Some of the flavoring materials have characteristic medicinal properties, as the flavor of bitter almond, which contains hydrocyanic acid, a poisonous substance. Flavors and extracts should not be indiscriminately used. In small amounts they often exert a favorable influence upon the digestion of foods, and the value of some fruits is in a large measure due to the special flavors they contain. A study of the separate compounds which impart flavor to fruits, as the various aldehydes, ethers, and organic salts, belongs to organic chemistry rather than to foods. Some of the simpler compounds of which flavors are composed may exist in entirely different form or combination in food products; as for example, pineapple flavoring is ethyl butrate. This can be prepared by combination of butyric acid from stale butter with alcohol which supplies the ethyl radical. The chemical union of the two produces the new compound, ethyl butrate, the distinctive flavoring substance of the pineapple. Banana flavor can be made from stale butter, caustic soda, and chloroform. None of these materials, as such, go into the flavor, but an essential radical is taken from each. These manufactured products, when properly made, are in every essential similar to the flavor made by the plant and stored up in the fruit. The plant combines the material in the laboratory of the plant cell, and the manufacturer of essences puts together these same constituents in a chemical laboratory. In the fruit, however, the essential oil is associated with a number of other compounds.

CHAPTER V

SUGARS, MOLASSES, SYRUP, HONEY, AND CONFECTIONS

73. Composition of Sugars.—The term "sugar" is applied to a large class of compounds composed of the elements carbon, hydrogen, and oxygen. Sugars used for household purposes are derived mainly from the sugar cane and the sugar beet.[^[25]] At the present time about two fifths are obtained from the cane and about three fifths from the beet. When subjected to the same degree of refining, there is no difference in the chemical composition of the sugars from the two sources; they are alike in every respect and the chemist is unable to determine their origin. The production of sugar is an agricultural industry; the methods of manufacture pertain more to industrial chemistry than to the chemistry of foods, and therefore a discussion of them is omitted in this work.[^[26]]

Fig. 15.—Sugar Crystals.

74. Commercial Grades of Sugar.—Sugars are graded according to the size of the granule, the color and general appearance of the crystals, and the per cent of sucrose or pure sugar. Common granulated sugar is from 98.5 to 99.7 per cent pure sucrose. The impurities consist mainly of moisture and mineral matter. In the process of refining, sulphur fumes are frequently used for bleaching and clarifying the solution.[^[26]] The sulphurous acid formed is neutralized with lime, which is rendered insoluble and practically all removed in subsequent filtrations. There are, however, traces of sulphates and sulphites in ordinary sugar, but these are in such small amounts as not to be injurious to health. When sugar is burned, as in the bomb calorimeter, so as to permit collection of all of the products of combustion, granulated sugar yields about 0.01 of a per cent of sulphur dioxid.[^[13]] Occasionally coloring substances, as a small amount of indigo, are added to yellow tinged sugars to impart a white color, much on the same principle as the bluing of clothes. The amount used is usually extremely small, and the effect on health has never been determined. Occasionally, however, bluing is used to such an extent that a blue scum appears when the sugar is boiled with water. Sugar has high value for the production of heat and energy. Digestion experiments show that when it is used in the dietary in not excessive amounts, it is directly absorbed by the body and practically all available. It can advantageously be combined with other foods to form a part of the ration.[^[27]] When a ration contains the requisite amount of protein, sugar is used to the best advantage. Alone it is incapable of sustaining life, because it does not contain any nitrogen. When sugar was substituted for an excess of protein in a ration, it was found to produce heat and energy at much less expense. Many foods, as apples, grapes, and small fruits, contain appreciable amounts of sugar and owe their food value almost entirely to their sugar content. In the dietary, sugar is too frequently regarded as a condiment instead of a nutrient, to be used for imparting palatability rather than for purposes of nutrition. While valuable for improving the taste of foods, the main worth of sugar is as a nutritive substance; used in the preparation of foods it adds to the total heat and energy of the ration. Sugar is sometimes used in excessive amounts and, as is the case with any food or nutrient, when that occurs, nutrition disturbances result, due to misuse of the food. Statistics show that the average consumption of sugar in the United States is nearly 70 pounds a year per capita. In the dietary of the adult, sugar to the extent of four ounces per day can be consumed advantageously. The exclusion of sugar from the diet of children is a great mistake, as they need it for heat and energy and to conserve the protein for growth.

"Sugar is one of the most important forms in which carbohydrates can be added to the diet of children. The great reduction in the price of sugar which has taken place in recent years is probably one of the causes of the improved physique of the rising generation. The fear that sugar may injure children's teeth is, largely illusory. The negroes who live largely on sugar cane have the finest teeth the world can show. If injudiciously taken, sugar may, however, injure the child's appetite and digestion. The craving for sweets which children show is no doubt the natural expression of a physiological need, but they should be taken with, and not between, meals."[^[28]]

Fig. 16.—Nutrients of a Ration With Sugar.
The hacket parts represent the proportion of nutrients not digested.

75. Sugar in the Dietary.—Sugar has an important place in the dietary. It not only serves for the production of heat and energy in the body, but is also valuable in enabling the proteids to be used more economically. In reasonable amounts, it is particularly valuable in the dietary of growing children, as the proteids of the food are then utilized to better advantage for growth. The unique value of sugar depends upon its intelligent use and its proper combination with other foods, particularly with those rich in the nitrogenous compounds or proteids. Sugar alone is incapable of sustaining life, but combined with other foods is a valuable nutrient. The amount which can be advantageously used depends largely upon the individual. Ordinarily three to five ounces per day is sufficient, although some persons cannot safely consume as much as this. In the case of diabetes mellitus, the amount of sugar in the ration must be materially reduced. Persons in normal health and engaged in outdoor work can use sugar to advantage.[^[29]] Many of the "harvest drinks," made largely from molasses with a little ginger, and used extensively in some localities, are not without merit, as they contain an appreciable amount of nutrients. Milk contains more sugar as lactose or milk sugar than any other nutrient.

Fig. 17.—Nutrients of a Ration Without Sugar.
The hacket parts represent the proportion of nutrients not digested.

The craving for sugar by growing children and athletes is natural. Sugar, however, is often injudiciously used, and a perverted taste may be established which can be satisfied only by excessive amounts. This results in impaired digestion and malnutrition.

76. Maple Sugar.—Sugar obtained by evaporation from the sap of the maple tree (Acer saccharinum) is identical, except for the foreign substances which it contains, with that from the beet and sugar cane. The mottled appearance and characteristic color and taste of maple sugar are due to the various organic acids and other compounds present in the maple sap and recovered in the sugar. Maple sugar, as ordinarily prepared, has 0.4 of a per cent or more of ash or mineral matter, while refined cane sugar contains less than one tenth as much.[^[30]] Hence, when maple sugar is adulterated with cane and beet sugars, the ash content is noticeably lowered, as is also the content of organic acids. It is difficult, however, to determine with absolute certainty pure high grade maple sugar from the impure low grade to which a small amount of granulated sugar has been added.

77. Adulteration of Sugar.—Sugar at the present time is not materially adulterated. Other than the substances mentioned which are used for clarification and color, none are added during refining which remain in the sugar in appreciable amounts. Sugar does not readily lend itself to adulteration, as it has a definite crystalline structure, and materials that would be suitable for its adulteration are of entirely different physical character.[^[31]] Cane sugar is not easily blended with glucose, or starch sugar, because of the physical differences between the two. The question of the kind of sugar to use in the household, as granulated, loaf, or pulverized, is largely one of personal choice, as there is no appreciable difference in the nutritive value or purity of the different kinds.

78. Dextrose Sugars.—Products known as glucose and dextrose sugars are made from corn and other starches; they can also be prepared from cane sugar by the use of heat, chemicals, or ferments for carrying on the process known as inversion. The dextrose sugars differ from cane sugar in containing a dissimilar number of carbon, hydrogen, and oxygen atoms in the molecule. The formula of the dextrose sugars is C₆H₁₂O₆, while that of cane sugar is C₁₂H₂₂O₁₁. By the addition of one molecule of water, H₂O, to a molecule of sucrose, two molecules of invert sugar (dextrose and glucose) are produced:[^[1]] C₁₂H₂₂O₁₁ + H₂ = C₆H₁₂O₆ + C₆H₁₂O₆. In bringing about this change, acids are employed, but the acid in no way enters into the chemical composition of the final product; it is removed as described during the process of sugar manufacture. The action of the acid brings about a catalytic change, the acid being necessary only as a presence reagent to start the chemical reaction. When properly prepared and the acid product thoroughly removed, dextrose and glucose have practically the same food value as sugar. When they are digested, heat and energy are produced, and a given weight has about the same fuel value as an equal weight of sugar. Some of the glucose-yielding products can be made at less expense than sugar, and when they are sold under their right names there is no reason why they should not be used in the dietary, as they serve the same nutritive purpose.

79. Molasses is a by-product obtained in the refining of sugar. It is a mixture of cane sugar and invert sugars, as levulose and dextrose. When in sugar making the sucrose is removed by crystallization, a point is finally reached where the solution, or mother liquid, as it is called, refuses to give up any further crystals;[^[31]] then this product, consisting of various sugars and small amounts of organic acids and ash, is partially refined and clarified to form molasses. The term "New Orleans" molasses was formerly applied to the product obtained by the use of open kettles for the manufacture of sugar, but during recent years the vacuum pan process has been introduced, and "New Orleans" molasses is now an entirely different article. The terms first, second, and third molasses are applied to the liquids obtained after the removal of the first, second, and third crops of sugar crystals; first molasses being richer in sucrose, while third molasses is richer in dextrose and invert sugars. The ash in molasses ranges from 4 to 6.5 per cent. Some of the low grades of molasses are used in the preparation of animal foods.

The taste and physical characteristics of molasses are due largely to the organic acids and impurities that are present, as well as to the proportion in which the various sugars occur. When used with soda in cooking and baking operations, the organic acid of the molasses liberates carbon dioxide gas, which acts as a leavening agent. Because of the organic acids, molasses should not be stored in tin or metalware dishes, as the solvent action results in producing poisonous tin and other metallic salts.

The food value of molasses is dependent entirely upon the amount of dry matter and the per cent of sugar. A large amount of water is considered an adulterant; ordinarily molasses contains from 20 to 33 per cent. If a sample of molasses contains 75 per cent of dry matter, it has slightly less than three fourths of the nutritive value of the same weight of sugar.

Fig. 18.—Graphic
Composition of Syrup.

80. Syrups.—The term "syrup" is applied to natural products obtained by evaporation and purification of the saccharine juices of plants. Sorghum syrup is from the sorghum plant, which is pressed by machinery and the juice clarified and evaporated so as to contain about 25 per cent of water. In sorghum syrups there are from 30 to 45 per cent of cane sugar, and from 12 to 20 per cent of glucose and invert sugars. Cane syrup is made from the clarified juice of the sugar cane, and has about the same general composition as sorghum syrup. Maple syrup, prepared from the juice of the sugar maple, is characteristically rich in sucrose and contains but little glucose or reducing sugars. The flavor of all the syrups is due mainly to organic acids, ethereal products, and impurities. In some instances the essential flavor can be produced synthetically, or derived from other and cheaper materials; and by the use of these flavors, mixed syrups can be prepared closely resembling many of the natural products. When properly made, they are equal in nutritive value to natural syrups. When sold under assumed names, they are to be considered and classified as adulterated, and not as syrups from definite and specific products. Low-grade syrups and molasses are often used for making fuel alcohol. They readily undergo alcoholic fermentation and are valuable for this purpose, rendering it possible for a good grade of fuel alcohol to be produced at low cost. The manufacture of sugar, syrups, and molasses has been brought to a high degree of perfection through the assistance rendered by industrial chemistry. Losses in the process are reduced to a minimum, and the various steps are all controlled by chemical analysis. Sugar has the physical property of deflecting a ray of polarized light, the amount of deflection depending upon the quantity of sugar in solution. This is measured by the polariscope, an instrument by means of which the sugar content of sugar plants is rapidly determined.

81. Honey is composed largely of invert sugars gathered by the honeybee from the nectar of flowers. It varies in composition and flavor according to its source. The color depends upon the flower from which it came, white clover giving a light-colored, pleasant-flavored honey, while that from buckwheat and goldenrod is dark and has a slightly rank taste. The comb is composed largely of wax, which has somewhat the same general composition as fat, but contains ethereal instead of glycerol bodies. On account of the predominance of invert sugars, pure honey has a levulo or left-handed rotation when examined by the polariscope. Honey contains from 60 to 75 per cent of invert sugars, and from 12 to 20 per cent of water, while the ash content is small, less than one tenth of one per cent. Strained honey is easily adulterated with glucose products. Adulteration with cane sugar is readily detected, as pure honey contains only a very small amount of sucrose. Honey can be made by feeding bees on sugar; the sugar undergoes inversion, with the production of dextrose. Such honey, although not adulterated, is inferior in quality and lacking in natural flavor.[^[18]]

82. Confections.—By blending various saccharine products, confections are made. Usually sucrose (cane and beet sugar) is used as the basis for their preparation. Sucrose has definite physical properties, as crystalline structure, and forms chemical and mechanical combinations with acid, alkaline, and other substances; it also unites with water, and when heated undergoes changes in structural composition. The presence of small amounts of acid substances, or variations in the concentration of the sugar solution, materially affect the mechanical relation of the sugar particles to each other, and their crystallization. Usually crystallization takes place when there is less than 25 per cent of water present. The form, size, and arrangement of the crystals are influenced by agitation during cooling. To secure desired results, often small quantities of various other substances are employed for their mechanical action. Glucose is frequently used, and is said to be necessary for the production of some kinds of candy.

Candies are colored with various dyes and pigments, many of which are harmless, although some are injurious. Coal tar dyes are frequently employed for this purpose. Objection has generally been urged against their use, as it is believed many of them are injurious to health. It cannot be said, however, that all are poisonous, as some are known to be harmless. The use of a few coal tar dyes is allowed by the United States government. Mineral colors are now rarely, if ever, used.

Impure candies result from objectionable ingredients, as starch, paraffin, and large amounts of injurious coloring substances. Coal tar coloring materials are identified in the way described in Experiment No. 13. Confectionery, when properly prepared and unadulterated, has the same nutritive value as sugar and the other ingredients, and is entitled to a place in the dietary for the production of heat and energy. Much larger amounts of candies are sold and consumed during the winter than the summer months, suggesting that in cold weather candy is most needed in the dietary.

83. Saccharine is an artificial sweetening, five hundred times sweeter than cane sugar. It contains in its molecule, chemically united, benzine, sulphuric acid, and ammonia radicals. It is employed for sweetening purposes in cases of diabetes mellitus, where physicians advise against the use of sugar. It has no food value. A small amount is sometimes added to canned corn and tomatoes to impart a sweet taste. The physiological properties of saccharine have not been extensively investigated.

CHAPTER VI

LEGUMES AND NUTS

84. General Composition of Legumes.—Peas, beans, lentils, and peanuts are the legumes most generally used for human food. As a class, they are characterized by high protein content and a comparatively low per cent of starch and carbohydrates. They contain the largest amount of nitrogenous compounds of any of the vegetable foods, and hence are particularly valuable in the human ration as a substitute for meats.[^[32]] For feeding animals the legumes are highly prized, particularly the forage crops, clover and alfalfa. These secure their nitrogen, which is the characteristic element of protein, from the free nitrogen of the air, through the workings of bacterial organisms found in the nodules on the roots of the plants. The legumes appear to be the only plants capable of making use of the nitrogen of the air for food purposes.

85. Beans contain about 24 per cent of protein and but little fat, less than is found in any of the grain or cereal products. The protein of the bean differs from that of cereals in its general and structural composition. It is a globulin known as legumin, and is acted upon mainly by ferments working in alkaline solutions, as in the lower part of the digestive tract. Beans have about the same amount of ash as the cereals, but the ash is richer in potash and lime.

Fig. 19.—Graphic
Composition of Beans.
Hacked Part Indigestible.

86. Digestibility of Beans.—Beans are usually considered indigestible, but experiments show they are quite completely digested, although they require more work on the part of the digestive tract than many other foods. The digestibility was found to vary with individuals, 86 per cent of the protein being digested in one case, and only 72 per cent in another. The protein of beans is not as completely digested as that of meats. When beans were combined with other foods, forming a part of a ration, they were more completely digested than when used in large amounts and with only a few other foods. The presence of the skin is in part responsible for low digestibility. When in the preparation of beans the skins, which contain a large amount of cellulose, are removed, the beans are more completely digested. By cooking from twenty minutes to half an hour in rapidly boiling water containing a small amount of soda, the skins are softened and loosened and are then easily removed by rubbing in cold water. Some of the soda enters into combination with the legumin. Along with the skins a portion of the germ is lost. The germ readily ferments, which is probably the cause of beans producing flatulence with some individuals during digestion. After the skins are removed the nutrients are more susceptible to the action of the digestive fluids. Experiments show that 42 per cent of the protein of baked skinned beans is soluble in pepsin and pancreatin solutions, while under similar conditions there is only 3.85 per cent of the protein soluble from beans baked without removal of the skins.

87. Use of Beans in the Dietary.—There is no vegetable food capable of furnishing so much protein at such low cost as beans; from a pound costing five cents about one fifth of a pound of protein and three fifths of a pound of carbohydrates are obtained. Beans can, to a great extent, take the place of meats in the dietary. There is more protein in beans than in beef. Four ounces of uncooked beans or six ounces of baked beans are as much as can conveniently be combined in the dietary, and these will furnish a quarter of the protein of the ration. In the case of active out-of-door laborers over a pound of baked beans per day is often consumed with impunity.

Fig. 20.—Beans, Raw and Cooked. Skins, Wet and Dry.

88. String Beans.—String beans—green beans with pod—contain a large amount of water, 85 to 88 per cent. The dry matter is rich in protein, nearly 20 per cent, although in the green beans as eaten, containing 85 per cent water, there is less than 2½ per cent. Lima beans are richer in protein than string beans, as the green pod is not included. String beans are valuable both for the nutrients they contain and for the favorable influence they exert upon the digestibility of other foods.

89. Peas.—In general composition and digestibility, peas are quite similar to beans. They belong to the same family, Leguminosæ, and the protein of each is similar in quantity and general properties. The statements made in regard to the composition, digestibility, and use of beans in the dietary apply with minor modifications to peas. When used in the preparation of soups, they add appreciable amounts of nutrients.

Fig. 21.—Pea Starch Granules.

90. Canned Peas.—In order to impart a rich green color, copper sulphate has been used in the canning of peas. Physiologists differ as to its effect upon health. While a little may not be particularly injurious, much interferes with normal digestion of the food and forms insoluble copper proteids. In some countries a small amount of copper sulphate is tolerated, while in others it is prohibited.

91. Peanuts.—Peanuts differ from peas and beans in containing more fat. They should be considered a food, for at ordinary prices they furnish a large amount of protein and fat. Like the other members of the legume family, the peanut is rather slow of digestion and requires considerable intestinal work for completion of the process.

NUTS

92. General Composition.—Nuts should be regarded as food, for they contribute to a ration appreciable amounts of nutrients. The edible portion of nearly all is rich in fat; pecans, for example, contain as high as 70 per cent. In protein content nuts range from 3 per cent in cocoanuts to 30 per cent in peanuts. The carbohydrate content is usually comparatively low, less than 5 per cent in hickory nuts, although there is nearly 40 per cent in chestnuts. On account of high fat content, nuts supply a large amount of heat and energy.[^[33]]

93. Chestnuts are characterized by containing less fat and protein and much more carbohydrate material, especially starch, than is found in other nuts. In southern Europe chestnuts are widely used as food; the skins are removed, and the nuts are steamed, boiled, or roasted, and sometimes they are dried and ground into flour. Chestnuts are less concentrated in protein and fat, and form a better balanced food used alone than do other nuts.

94. The Hickory Nut, which is a characteristically American nut, contains in the edible portion about 15 per cent protein, 65 per cent fat, and 12 per cent carbohydrates.

95. The Almonds used in the United States come chiefly from southern Europe, although they are successfully raised in California. They contain about 55 per cent fat and 22 per cent protein. The flavor of almonds is due to a small amount of hydrocyanic acid.

96. Pistachio.—Some nuts are used for imparting color and flavor to food products, as the pistachio nut, the kernel of which is greenish in color and imparts a flavor suggestive of almonds. The pistachio has high food value, as it is rich in both fat and protein. It is employed in the manufacture of confectionery and in ice cream for imparting flavor and color.

97. Cocoanuts grow luxuriantly in many tropical countries, and have a high food value. They are characteristically rich in fat, one half of the edible portion being composed of this nutrient. For tropical countries they supply the fat of a ration at less expense than any other food. When used in large amounts they should be supplemented with foods rich in carbohydrates, as rice, and in proteids, as beans. Cocoanut milk is proportionally richer in carbohydrates and poorer in fat and protein than the meat of the cocoanut. In discussing the cocoanut, Woods states:[^[34]]

"The small, green, and immature nuts are grated fine for medicinal use, and when mixed with the oil of the ripe nut it becomes a healing ointment. The jelly which lines the shell of the more mature nut furnishes a delicate and nutritious food. The milk in its center, when iced, is a most delicious luxury. Grated cocoanut forms a part of the world-renowned East India condiment, curry. Dried, shredded (desiccated) cocoanut is an important article of commerce. From the oil a butter is made, of a clear, whitish color, so rich in fat, that of water and foreign substances combined there are but O.0068. It is better adapted for cooking than for table use. At present it is chiefly used in hospitals, but it is rapidly finding its way to the tables of the poor, particularly as a substitute for oleomargarine."

98. Use of Nuts in the Dietary.—When nuts can be secured at a low price per pound, ten cents or less, they compare favorably in nutritive value with other staple foods. Digestion experiments with rations composed largely of nuts show that they are quite thoroughly digested. Professor Jaffa of the California Experiment Station, in discussing the nutritive value of nuts and fruits, says:[^[35]]

"It is certainly an error to consider nuts merely as an accessory to an already heavy meal, and to regard fruit merely as something of value for its pleasant flavor, or for its hygienic or medicinal virtues. The agreement of one food or another with any person is more or less a personal idiosyncrasy, but it seems fair to say that those with whom nuts and fruits agree, can, if they desire, readily secure a considerable part of their nutritive material from such sources."

Average Composition of Nuts

(From Fifteenth Annual Report, Maine Agricultural Experiment Station.)

[A]Calculated from analyses.

[B]Including salt, 4.1.

CHAPTER VII

MILK AND DAIRY PRODUCTS

99. Importance in the Dietary.—There is no article of food which enters so extensively into the dietary as milk, and it is one of the few foods which supply all the nutrients,—fats, carbohydrates, and proteids.[^[36]] Milk alone is capable of sustaining life for comparatively long periods, and it is the chief article of food during many diseases. An exclusive milk diet for a healthy adult, however, would be unsatisfactory; in the case of young children, milk is essential, because the digestive tract has not become functionally developed for the digestion of other foods.

It is necessary to consider not only the composition and nutritive value of milk, but also its purity or sanitary condition.

100. General Composition.—Average milk contains about 87 per cent water and 13 per cent dry matter. The dry matter is composed approximately of:

Fat is the most variable constituent of milk. Occasionally it is found as low as 2 per cent and as high as 6 per cent or more. The poorest and richest milks differ mainly in fat content, as the sugar, ash, casein, and albumin, or "solids of the milk serum," are fairly constant in amount and composition. Variations in the content of fat are due to differences in feed and in the breed and individuality of the animal.

Fig. 22.—Milk Fat Globules.

101. Digestibility.—Milk is one of the most completely digested of foods, about 95 per cent of the protein and fat and 97 per cent of the carbohydrates being absorbed and utilized by the body.

In a mixed ration, the nutrients of milk are practically all absorbed. Milk also exerts a favorable influence upon the digestibility of other foods with which it is combined. This is doubtless due to the digestive action of the special ferments or enzymes which milk contains. In milk there is a soluble ferment material or enzyme which has the power of peptonizing proteids. It is this ferment which carries on the ripening process when cheese is cured in cold storage, and it is believed to be this body which promotes digestion of other foods with which milk is combined.[^[27]]

Milk is not easily digested by some persons. The tendency to costiveness caused by a milk diet can be largely overcome by the use of salt with the milk, or of some solid food, as toast or crackers, to prevent coagulation and the formation of masses resistant to the digestive fluids. Barley water and lime water in small amounts are also useful for assisting mechanically in the digestion of milk. Milk at ordinary prices is one of the cheapest foods that can be used.

Fig. 23.—Dirt in a Sample
of Unsanitary Milk.

102. Sanitary Condition of Milk.—Equally as important as composition is the sanitary condition or wholesomeness of milk. Milk is a food material which readily undergoes fermentation and is a medium for the distribution of germ diseases. The conditions under which it is produced and the way in which it is handled determine largely its sanitary value, and are of so much importance in relation to public health that during recent years city and state boards of health have introduced sanitary inspection and examination of milk along with the chemical tests for detecting its adulteration. Some of the more frequent causes of contaminated and unsound milk are: unhealthy animals, poor food and water, unsanitary surroundings of the animals, and lack of cleanliness and care in the handling and transporting of the milk. Outbreaks of typhoid and scarlet fevers and other germ diseases have frequently been traced to a contaminated milk supply.[^[37]]

103. Certified Milk.—When milk is produced under the most sanitary conditions, the number of bacterial bodies per cubic centimeter is materially reduced. In order to supply high grade milk containing but few bacteria, special precautions are taken in the care of the animals, and in the feeding and milking, and all sources of contamination of the milk are eliminated as far as possible. Such milk, when sold in sterilized bottles, is commonly called "certified milk," indicating that its purity is guaranteed by the producer and that the number of bacteria per unit does not exceed a certain standard, as 8000 per cubic centimeter. Ordinary market milk contains upwards of 50,000.

Fig. 24.—Pasteurizing Milk.

104. Pasteurized Milk.—In order to destroy the activity of the bacterial organisms, milk is subjected to a temperature of 157° F. for ten minutes or longer, which process is known as pasteurization. When milk is heated to a temperature above 180°, it is sterilized. Below 157°, the albumin is not coagulated. By pasteurizing, milk is much improved from a sanitary point of view, and whenever the milk supply is of unknown purity, it should be pasteurized.[^[38]] After the milk has been thus treated, the same care should be exercised in keeping it protected to prevent fresh inoculation or contamination, as though it were unpasteurized milk. For family use milk can be pasteurized in small amounts in the following way: Before receiving the milk, the receptacle should be thoroughly cleaned and sterilized with boiling water or dry heat, as in an oven. The milk is loosely covered and placed in a pan of water, a false bottom being in the pan so as to prevent unequal heating. The water surrounding the milk is gradually heated until a temperature of 159° F. is registered, and the milk is kept at this temperature for about ten minutes. It is then cooled and placed in the refrigerator.

105. Tyrotoxicon.—Tyrotoxicon is a chemical compound produced by a ferment body which finds its way into milk when kept in unsanitary surroundings. It induces digestion disorders similar to cholera, and when present in large amounts, may prove fatal. It sometimes develops in cream, ice cream, or cheese, but only when they have been kept in unclean places or produced from infected milk.

601. Color of Milk is often taken as a guide to its purity and richness in fat. While a yellow tinge is usually characteristic of milks rich in fat, it is not a hard and fast rule, for frequently light-colored milks are richer in fat than yellow-tinged ones. The coloring material is independent of the percentage of fat, and it is not always safe to judge the richness of milk on the basis of color.

107. Souring of Milk.—Souring of milk is due to the action of the lactic acid organism, which finds its way into the milk through particles of dust carried in the air or from unclean receptacles which contain the spores of the organism.[^[39]] When milk sours, a small amount of sugar is changed to lactic acid which reacts upon the casein, converting it from a soluble to an insoluble condition. When milk is exposed to the air at a temperature of from 70° to 90° F., lactic acid fermentation readily takes place. At a low temperature the process is checked, and at a high temperature the organisms and spores are destroyed. In addition to lactic acid ferments, there are large numbers of others which develop in milk, changing the different compounds of which milk is composed. In the processes of butter and cheese making, these fermentation changes are controlled so as to develop the flavor and secure the best grades of butter and cheese.

108. Use of Preservatives in Milk.—In order to check fermentation, boric acid, formalin, and other preservatives have been proposed. Physiologists object to their use because the quantity required to prevent fermentation is often sufficient to have a medicinal effect. The tendency is to use excessive amounts, which may interfere with normal digestion of the food. Milk that is cared for under the most sanitary conditions has a higher dietetic value and is much to be preferred to that which has been kept sweet by the use of preservatives.

109. Condensed Milk is prepared by evaporating milk in vacuum pans until it is reduced about one fourth in bulk, when it is sealed in cans, and it will then keep sweet for a long time. Occasionally some cane sugar is added to the evaporated product. When diluted, evaporated milk has much the same composition as whole milk. When a can of condensed milk has been opened, the same care should be exercised to prevent fermentation as if it were fresh milk.

110. Skim Milk differs in composition from whole milk in fat content. When the fat is removed by the separator, there is often left less than one tenth of a per cent. Skim milk has a much higher nutritive value than is generally conceded, and wherever it can be procured at a reasonable price it should be used in the dietary as a source of protein.

111. Cream ranges in fat content from 15 to 35 per cent. It is generally preferred to whole milk, although it is not as well balanced a food, because it is deficient in protein. Cream should contain at least 25 per cent of fat.

112. Buttermilk is the product left after removal of the fat from cream by churning. It has about the same amount of nutrients as skim milk. The casein is in a slightly modified form due to the development of lactic acid during the ripening of the cream, and on this account buttermilk is more easily digested and assimilated by many individuals than milk in other forms. The development of the acid generally reduces the number of species of other than the lactic organisms, and these are increased.

113. Goat's Milk is somewhat richer in solids than cow's milk, containing about one per cent more proteids, a little more fat, and less sugar. When used as a substitute for human or cow's milk, it generally needs to be slightly diluted, depending, however, upon the composition of the individual sample.

114. Koumiss is a fermented beverage made from milk by the use of yeast to secure alcoholic fermentation. Koumiss contains about one per cent each of lactic acid and alcohol, and the casein and other nutrients are somewhat modified by the fermentation changes. Koumiss is generally considered a non-alcoholic beverage possessing both food and dietetic value.

115. Prepared Milks.—Various preparations are made to resemble milk in general composition. These are mechanical mixtures of sugar, fats, and proteids. Milk sugar, casein, or malted proteids are generally the materials employed in their preparation. Often the dried and pulverized solids of skim milk are used. Many of the prepared milks are deficient in fat. While they are not equal to cow's milk, their use is often made necessary from force of circumstances.

116. Human Milk is not as rich in solid matter as cow's milk. It contains about the same amount of fat, one per cent more sugar, and one per cent less proteids. In human milk nearly one half of the protein is in the form of albumins, while in cow's milk there is about one fifth in this form. The fat globules are much smaller than those of cow's milk. In infant feeding it is often necessary to modify cow's milk by the addition of water, cream, and milk sugar, so as to make it more nearly resemble in composition human milk.

Fig. 25.—Apparatus Used in Testing Milk.

1, pipette; 2, lactometer; 3, acid measure; 4, centrifuge; 5, test bottle.

117. Adulteration of Milk.—Milk is not as extensively adulterated as it was before the passage and enforcement of the numerous state and municipal laws regulating its inspection and sale. The most frequent forms of adulteration are addition of water and removal of cream. These are readily detected from the specific gravity and fat content of the milk. The specific gravity of milk is determined by means of the lactometer, an instrument which sinks to a definite point in pure milk. In watered milk it sinks to greater depth, depending upon the amount of water added. The fat content of milk is readily and accurately determined by the Babcock test, in which the fat is separated by centrifugal action. For the detection of adulterated milk the student is referred to Chapter VI, "Chemistry of Dairying," by Snyder.

BUTTER

118. Composition.—Butter is made by the churning or agitation of cream and is composed mainly of milk fats and water, together with smaller amounts of ash, salt, casein, milk sugar, and lactic acid. Average butter has the following composition:

When butter contains an abnormal amount of water, it is considered adulterated. According to act of Congress standard butter should not contain over 16 per cent of water nor less than 82.5 per cent of fat.

119. Digestibility of Butter.—Digestion experiments show that practically all of the fat, 98 per cent, is digestible and available for use by the body. Butter is valuable only for the production of heat and energy. Alone, it is incapable of sustaining life, because it contains no proteid material. It is usually one of the more expensive items of food, but it is generally considered quite necessary in a ration.[^[5]] It has been suggested that it takes an important part mechanically in the digestion of food.

120. Adulteration of Butter.—In addition to containing an excess of water, butter is adulterated in other ways. Old, stale butter is occasionally melted, washed, salted, and reworked. This product is known as renovated butter, and has poor keeping qualities. Frequently preservatives are added to such butter to delay fermentation changes. Oleomargarine and butterine are made by mixing vegetable and animal fats.[^[40]] Highly colored stearin, cotton-seed oil, and lard are the usual materials from which oleomargarine is made. It has practically the same composition, digestibility, and food value as butter. When sold under its true name and not as butter, there is no objection, as it is a valuable food and supplies heat and energy at less cost than butter. The main objection to oleomargarine and butterine is that they are sold as butter.[^[41]]

The coloring of butter is not generally looked upon as adulteration, for butter naturally has a more or less yellow tinge. According to an act of Congress, butter colors of a non-injurious character are allowed to be used.

CHEESE

121. General Composition.—Cheese, is made by the addition of rennet to ripened milk, resulting in coagulation of the casein, which mechanically combines with the fat. It differs from butter in composition by containing, in addition to fat, casein and appreciable amounts of mineral matter. The composition varies with the character of the milk from which the cheese was made. Average milk produces cheese containing a larger amount of fat than proteids, while cheese from skimmed or partially skimmed milk is proportionally poorer in fat. Ordinarily there is about 35 per cent of water, 33 per cent of fat, and 27 per cent of casein, and albumin or milk proteids, the remainder being ash, salt, milk sugar, and lactic acid. Cheese is characterized by its large percentage of both fat and protein, and has high food value. It contains more fat and protein than any of the meats; in fact, there are but few foods which have such liberal amounts of these nutrients as cheese.

The odor and flavor of cheese are due to workings of bacteria which result in the production of aromatic compounds. The purity and condition of the milk, as well as the method of manufacture and the kind of ferment material used, determine largely the flavor and odor. Cheese is generally allowed to undergo a ripening or curing process before it is used as food. The changes resulting consist mainly in increased solubility of the proteids, with the formation of a small amount of amid and aromatic compounds.[^[42]]

122. Digestibility.—Cheese is popularly considered an indigestible food, but extended experiments show that it is quite completely digested, although in the case of some individuals not easily digested. In general, about 95 per cent of the fat and 92 per cent and more of the protein is digested, depending upon the general composition of the cheese and the digestive capacity of the individual. As far as total digestibility is concerned, there appears to be but little difference between green and well-cured cheese. So far as ease of digestion is concerned, it is probable that some difference exists. There is also but little difference in digestibility resulting from the way in which milk is made into cheese, the nutrients of Roquefort, Swiss, Camembert, and Cheddar being about equally digestible.[^[13]] The differences in odor and taste are due to variations in kind and amount of bacterial action. When combined with other foods, cheese may exercise a beneficial influence upon digestion in the same way as noted from the use of several foods in a ration. No material differences were observed in digestibility when cheese was used in small amounts, as for condimental purposes, or when used in large amounts to furnish nutrients. Artificial digestion experiments show that cheese is more readily acted upon by the pancreatic than by the gastric fluids, suggesting that cheese undergoes intestinal rather than gastric digestion. It is possible this is the reason that cheese is slow of digestion in the case of some individuals.

123. Use in the Dietary.—Cheese should be used in the dietary regularly and in reasonable amounts, rather than irregularly and then in large amounts. Cheese is not a luxury, but ordinarily it is one of the cheapest and most nutritious of human foods. A pound of cheese costing 15 cents contains about a quarter of a pound of protein and a third of a pound of fat; at the same price, beef yields only about half as much fat and less protein. Cheese at 18 cents per pound furnishes more available nutrients and energy than beef at 12 cents per pound. In the dietary of European armies, cheese to a great extent takes the place of beef. See Chapter XVI.

124. Cottage Cheese is made by coagulating milk and preparing the curd by mixing with it cream or melted butter and salt or sugar as desired. When milk can be procured at little cost, cottage cheese is one of the cheapest and most valuable foods.[^[43]]

125. Different Kinds of Cheese.—By the use of different kinds of ferments and variations in the process of manufacture different types or kinds of cheese are made, as Roquefort, Swiss, Edam, Stilton, Camembert, etc. In the manufacture of Roquefort cheese, which is made from goats' and ewes' milk, bread is added and the cheese is cured in caves, resulting in the formation of a green mold which penetrates the cheese mass, and produces characteristic odor and flavor. Stilton is an English soft, rich cheese of mild flavor, made from milk to which cream is usually added. It is allowed to undergo an extended process of ripening, often resulting in the formation of bluish green threads of fungus. Limburger owes its characteristic odor and flavor to the action of special ferment bodies which carry on the ripening process. Neufchatel is a soft cheese made from sweet milk to which the rennet is added at a high temperature. After pressing, it is kneaded and worked, and then put into packages and covered with tin foil.

126. Adulteration of Cheese.—The most common forms of adulteration are the manufacture of skim-milk cheese by the removal of the fat from the milk, and substitution of cheaper and foreign fats, making a product known as filled cheese. When not labeled whole milk cheese, or sold as such, there is no objection to skim-milk cheese. It has a high food value and is often a cheap source of protein. The manufacture of filled cheese is now regulated by the national government, and all such cheese must pay a special tax and be properly labeled. As a result, the amount of filled cheese upon the market has very greatly decreased, and cheese is now less adulterated than in former years. The national dairy law allows the use of coloring matter of a harmless nature in the manufacture of cheese.

127. Dairy Products in the Dietary.—The nutrients in milk are produced at less expense for grain and forage than the nutrients in beef, hence from a pecuniary point of view, dairy products, as milk and cheese, have the advantage. In the case of butter, however, the cost usually exceeds that of meat. In older agricultural regions, where the cost of beef production reaches the maximum, dairying is generally resorted to, as it yields larger financial returns, and as a result more cheese and less beef are used in the dietary. As the cost of meats is enhanced, dairy products, as cheese, naturally take their place.

CHAPTER VIII

MEATS AND ANIMAL FOOD PRODUCTS

128. General Composition.—Animal tissue is composed of the same classes of compounds as plant tissue. In each, water makes up a large portion of the weight, and the dry matter is composed of nitrogenous and non-nitrogenous compounds, and ash or mineral matter. Plants and animals differ in composition not so much as to the kinds of compounds, although there are differences, but more in the percentage amounts of these compounds. In plants, with the exception of the legumes, the protein rarely exceeds 14 per cent, and in many vegetable foods, when prepared for the table, there is less than 2 per cent. In meats the protein ranges from 15 to 20 per cent. The non-nitrogenous compounds of plants are present mainly in the form of starch, sugar, and cellulose, while in animal bodies there are only traces of carbohydrates, but large amounts of fat. Fat is the chief non-nitrogenous compound of meats; it ranges between quite wide limits, depending upon kind, age, and general condition of the animal. Meats contain the same general classes of proteins as the vegetable foods; in each the proteins are made up of albumins, glubulins, albuminates, peptone-like bodies, and insoluble proteids. The larger portion of the protein of meats and cereals is in insoluble forms. The meat juices, which contain the soluble portion of the proteins, constitute less than 5 percent of the nitrogenous compounds. Meats contain less amid substances than plants, in which the amids are produced from ammonium compounds and are supposed to be intermediate products in the formation of proteids, while in the animal body they are derived from the proteids supplied in the food and, it is generally believed, cannot form proteids. Albuminoids make up the connective tissue, hair, and skin, and are more abundant in animal than in plant tissue. One of the chief albuminoids is gelatine. Both plant and animal foods undergo bacterial changes resulting in the production of alkaloidal bodies known as ptomaines, of which there are a large number. These are poisonous and are what cause putrid and stale meat to be unwholesome. The protein in meat differs little in general composition from that of vegetable origin; differences in structure and cleavage products between the two are, however, noticeable.

Fig. 26.—Meat and Extractive Substances.

While meats from different kinds of animals have somewhat the same general composition, they differ in physical properties, and also in the nature of the various nutrients. For example, pork contains less protein than beef, but the protein of pork is materially different from that of beef, as a larger portion is in the form of soluble proteids, while in beef more is present in an insoluble form. Not only are differences in the percentage of individual proteins noticeable, but there are equally as great differences in the fats. As for example: some of the meats have a larger proportion of the fat as stearin than do others. Hence meats differ in texture and taste more than in nutritive value, due to the variations in the percentage of the different proteins, fats, and extractive material, rather than to differences in the total amounts of these compounds. The taste and flavor of meat is to a large extent influenced by the amount of extractive material.

While the nutrients of meats are divided into classes, as proteins and fats, there are a large number of separate compounds which make up each of the individual classes, and there are also small amounts of compounds which are not included in these groups.

Fig. 27.—Standard Cuts of Beef.

(From Office of Experiment Station Bulletin.)

129. Beef.—About one half of the weight of beef is water; the lean meat contains a much larger amount than the fat. As a rule, the parts of the animal that contain the most fat contain the least water. In some meats there is considerable refuse, 25 to 30 per cent. In average meat about 12 per cent of the butcher's weight is refuse and non-edible parts.[^[44]] A pound of average butcher's meat is about one half water, and over 10 per cent waste and refuse, which leaves less than 40 per cent fat and protein. Meat is generally considered to have a high nutritive value, due to the comparatively large amounts of fat and protein. Beef contains more protein than any vegetable food, except the legumes, and from 1 to 1.5 per cent mineral matter, exclusive of bone. Some of the mineral matter is chemically united with the protein and other compounds. While figures are given for average composition of beef, it is to be noted that wide variations are frequently to be met with, some samples containing a much larger amount of waste and trimmings than others, and this influences the percent of the nutritive substances. In making calculations of nutrients consumed, as in dietary studies, the figures for average composition of meat should be used only in cases where the samples do not contain an excess either of fat or trimmings.[^[45]] When very lean, there is often a large amount of refuse, and the meat contains less dry matter and is of poorer flavor than from animals in prime condition. In the case of very fat animals, a large amount of waste results, and the flavor is sometimes impaired.

130. Veal differs from beef in containing a smaller amount of dry matter, richer in protein, but poorer in fat. Animals differ in composition at different stages of growth in much the same way as plants. In the earlier stages protein predominates in the plant tissue, while later the carbohydrates are added in larger amounts, reducing the percentage content of protein. In animals the same is noticeable. Young animals are, pound for pound, richer in protein than old animals. While in the case of vegetables the increase in size, or rotundity, is due to starch and carbohydrates, in animals it is due to the addition of fat. But plants, like animals, observe the same general laws as to changes in composition at different stages of growth.

Fig. 28.—Standard Cuts of Mutton.

(From Office of Experiment Station Bulletin.)

131. Mutton.—There is about the same amount of refuse matter in mutton as in beef. In a side of mutton about 19 percent: are trimmings and waste, and in a side of beef 18.5 per cent. Mutton, as a rule, contains a little more fat and dry matter than beef, and somewhat less protein. A side of beef, as purchased, contains about 50 per cent of water, 14.5 per cent protein, and 16.8 per cent of fat, while a side of mutton, as purchased, contains 42.9 per cent water, 12.5 per cent protein, and 24.7 per cent fat. A pound of beef yields a smaller number of calories by 25 per cent than a pound of mutton. At the same price per pound more nutrients can be purchased as mutton than as beef. The differences in composition between lamb and mutton are similar to those between veal and beef; viz. a larger amount of water and protein and a smaller amount of fat in the same weight of the young animals. Differences in composition between the various cuts of lamb are noticeable. The leg contains the least fat and the most protein, while the chuck is richest in fat and poorest in protein. As in the case of beef, many of the cheaper cuts contain as much or more nutrients than the more expensive cuts. They are not, however, as palatable and differ as to toughness and other physical characteristics.

Fig. 29.—Standard Cuts of Pork.

(From Office of Experiment Station Bulletin.)

132. Pork is characterized by a high per cent of fat and a comparatively low per cent of protein. It is generally richest in fat of any of the meats. The per cent of water varies with the fatness of the animal; in very fat animals there is a smaller amount, while lean animals contain more. In lean salt pork there is about 20 per cent water, and in fat salt pork about 7 per cent. There is less refuse and waste in pork than in either beef or mutton. Ham contains from 14 to 15 per cent of refuse, and bacon about 7 per cent. Bacon has nearly twice as much fat and a smaller amount of protein than ham. A pound of bacon, as purchased, will yield nearly twice as much energy or fuel value as a pound of ham. Digestion experiments show that bacon is quite readily and completely digested and is often a cheaper source of fat and protein than other meats. There is about three times as much fat in bacon as in beef. When prepared for the table bacon contains, from 40 to 50 per cent of fat. A pound of high grade, lean bacon furnishes from 0.1 to 0.3 of a pound of digestible protein and from 0.4 to 0.6 of a pound of digestible fat, which is about two thirds as much fat as is found in butter. Bacon contains nearly as much digestible protein as other meats and from two to three times as much fat, making it, at the same price per pound, a cheaper food than other meats. In salt pork there is from 60 to 85 per cent of fat, and less protein than in bacon. The protein and fat of pork differ from those in beef not only in percentage amounts, but also in the nature of the individual proteins and fats. The composition of pork varies with the nature of the food that is consumed by the animal. Experiments show that it is possible by judicious feeding in the early stages of growth to produce pork with the maximum of lean meat and the minimum of fat. After the animal has passed a certain period, it is not possible by feeding to materially influence the percentage of nutrients in the meat. The flavor, too, of pork, as of other meats, is dependent largely upon the nature of the food the animal consumes. When there is a scant amount of available protein in the ration, the meat is dry, nearly tasteless, and contains less of the soluble nitrogenous compounds which impart flavor and individuality.

133. Lard is prepared from the fat of swine, and is separated from associated tissue by the action of heat. A large amount of fat is found lining the back of the abdominal cavity, and this is known as leaf lard. Slight differences are noticeable in the composition and quality of lard made from different parts of the hog. Leaf lard is usually considered the best. Lard is composed of the three fats, olein, stearin, and palmatin, and has a number of characteristic physical properties, as specific gravity, melting point, iodine absorption number, as well as behavior with various reagents, and these enable the mixing of other fats with lard to be readily detected. Lard is used in the preparation of oleomargarine, and it is also combined with various vegetable oils, as cotton-seed oil, in the making of imitation or compound lards.[^[46]] Lard substitutes differ little in general composition from pure lard, except in the structure of the crystals and the percentage of the various individual fats.

134. Texture and Toughness of Meats.—In discussing the texture of meats, Professor Woods states:[^[45]]

"Whether meats are tough or tender depends upon two things: the character of the walls of the muscle tubes and the character of the connective tissues which bind the tubes and muscles together. In young and well-nourished animals the tube walls are thin and delicate, and the connective tissue is small in amount. As the animals grow older or are made to work (and this is particularly true in the case of poorly nourished animals), the walls of the muscle tubes and the connective tissues become thick and hard. This is the reason why the flesh of young, well-fed animals is tender and easily masticated, while the flesh of old, hard-worked, or poorly fed animals is often so tough that prolonged boiling or roasting seems to have but little effect on it.

"After slaughtering, meats undergo marked changes in texture. These changes can be grouped under three classes or stages. In the first stage, when the meat is just slaughtered, the flesh is soft, juicy, and quite tender. In the next stage the flesh stiffens and the meat becomes hard and tough. This condition is known as rigor mortis, and continues until the third stage, when the first changes of decomposition set in. In hot climates the meat is commonly eaten in either the first or second stage. In cold climates it is seldom eaten before the second stage, and generally, in order to lessen the toughness, it is allowed to enter the third stage, when it becomes soft and tender, and acquires added flavor. The softening is due in part to the formation of lactic acid, which acts upon the connective tissue. The same effect may be produced, though more rapidly, by macerating the meat with weak vinegar. Meat is sometimes made tender by cutting the flesh into thin slices and pounding it across the cut ends until the fibers are broken."