THE BOY'S PLAYBOOK OF SCIENCE:

INCLUDING THE

Various Manipulations and Arrangements

OF

CHEMICAL AND PHILOSOPHICAL APPARATUS REQUIRED FOR THE SUCCESSFUL PERFORMANCE OF SCIENTIFIC EXPERIMENTS.

IN ILLUSTRATION OF THE ELEMENTARY BRANCHES OF CHEMISTRY AND NATURAL PHILOSOPHY.

BY

JOHN HENRY PEPPER,

F.C.S., A. INST. C.E.; LATE PROFESSOR OF CHEMISTRY AT THE ROYAL POLYTECHNIC, ETC. ETC. AUTHOR OF "THE PLAYBOOK OF METALS."

NEW EDITION.

Illustrated with 470 Engravings,
CHIEFLY EXECUTED FROM THE AUTHOR'S SKETCHES, BY H. G. HINE.

LONDON:

GEORGE ROUTLEDGE AND SONS,

THE BROADWAY, LUDGATE.
NEW YORK: 416, BROOME STREET.
1869.

LONDON.

SAVILL, EDWARDS AND CO., PRINTERS, CHANDOS STREET.
COVENT GARDEN.

Wheatstone's telephonic concert at the Polytechnic, in which the sounds and vibrations pass inaudible through an intermediate hall, and are reproduced in the lecture-room unchanged in their qualities and intensities. Frontispiece.

TO

PROFESSOR LYON PLAYFAIR, C.B., F.R.S.

PROFESSOR OF CHEMISTRY IN THE UNIVERSITY OF EDINBURGH.

Dear Sir,

I Dedicate these pages to your Children, whom I often had the pleasure of seeing at the Polytechnic during my direction of that Institution. I do so as a mark of respect and appreciation of your talent and zeal, and of your public-spirited advocacy of the Claims of Science in this great and commercial country.

Without making you responsible in any way for the shortcomings of this humble work on Elementary Science, allow me to subscribe myself,

Dear Sir,

Yours most respectfully,

JOHN HENRY PEPPER.

CONTENTS.

INTRODUCTION.

Although "The South Kensington Museum" now takes the lead, and surpasses all former scientific institutions by its vastly superior collection of models and works of art, there will be doubtless many thousand young people who may remember (it is hoped) with some pleasure the numerous popular lectures, illustrated with an abundance of interesting and brilliant experiments, which have been delivered within the walls of the Royal Polytechnic Institution during the last twenty years.

On many occasions the author has received from his young friends letters, containing all sorts of inquiries respecting the mode of performing experiments, and it has frequently occurred that even some years after a lecture had been discontinued, the youth, now become the young man, and anxious to impart knowledge to some "home circle" or country scientific institution, would write a special letter referring to a particular experiment, and wish to know how it was performed.

The following illustrated pages must be regarded as a series of philosophical experiments detailed in such a manner that any young person may perform them with the greatest facility. The author has endeavoured to arrange the manipulations in a methodical, simple, and popular form, and will indeed be rewarded if these experiments should arouse dormant talent in any of the rising generation, and lead them on gradually from the easy reading of the present "Boy's Book," to the study of the complete and perfect philosophical works of Leopold Gmelin, Faraday, Brande, Graham, Turner, and Fownes.

Every boy should ride "a hobby-horse" of some kind; and whilst play, and plenty of it, must be his daily right in holiday time, he ought not to forget that the cultivation of some branch of the useful Arts and Sciences will afford him a delightful and profitable recreation when satiated with mere play, or imprisoned by bad weather, or gloomy with the unamused tediousness of a long winter's evening.

The author recollects with pleasure the half-holidays he used to devote to Chemistry, with some other King's College lads, and in spite of terrible pecuniary losses in retorts, bottles, and jars, the most delightful amusement was enjoyed by all who attended and assisted at these juvenile philosophical meetings.

It has been well remarked by a clever author, that bees are geometricians. The cells are so constructed as, with the least quantity of material, to have the largest sized spaces and the least possible interstices. The mole is a meteorologist. The bird called the nine-killer is an arithmetician, also the crow, the wild turkey, and some other birds. The torpedo, the ray, and the electric eel are electricians. The nautilus is a navigator. He raises and lowers his sails, casts and weighs anchor, and performs nautical feats. Whole tribes of birds are musicians. The beaver is an architect, builder, and wood-cutter. He cuts down trees and erects houses and dams. The marmot is a civil engineer. He does not only build houses, but constructs aqueducts, and drains to keep them dry. The ant maintains a regular standing army. Wasps are paper manufacturers. Caterpillars are silk-spinners. The squirrel is a ferryman. With a chip or a piece of bark for a boat, and his tail for a sail, he crosses a stream. Dogs, wolves, jackals, and many others, are hunters. The black bear and heron are fishermen. The ants are day-labourers. The monkey is a rope dancer. Shall it, then, be said that any boy possessing the Godlike attributes of Mind and Thought with Freewill can only eat, drink, sleep, and play, and is therefore lower in the scale of usefulness than these poor birds, beasts, fishes, and insects? No! no! Let "Young England" enjoy his manly sports and pastimes, but let him not forget the mental race he has to run with the educated of his own and of other nations; let him nourish the desire for the acquisition of "scientific knowledge," not as a mere school lesson, but as a treasure, a useful ally which may some day help him in a greater or lesser degree to fight "The Battle of Life."

THE

BOY'S PLAYBOOK OF SCIENCE.

CHAPTER I.

THE PROPERTIES OF MATTER—IMPENETRABILITY.

In the present state of our knowledge it seems to be universally agreed, that we cannot properly commence even popular discussions on astronomy, mechanics, and chemistry, or on the imponderables, heat, light, electricity, and magnetism, without a definition of the general term "matter;" which is an expression applied by philosophers to every species of substance capable of occupying space, and, therefore, to everything which can be seen and felt.

The sun, the moon, the earth, and other planets, rocks, earths, metals, glass, wool, oils, water, alcohol, air, steam, and hosts of things, both great and small, all solids, liquids and gases, are included under the comprehensive term matter. Such a numerous and varied collection of bodies must necessarily have certain qualities, peculiarities, or properties; and hence we come in the first place to consider "The general powers or properties of matter." Thus, if we place a block of wood or stone in any position, we cannot take another substance and put it in the space filled by the wood or stone, until the latter be removed. Now this is one of the first and most simple of the properties of matter, and is called impenetrability, being the property possessed by all solid, liquid, and gaseous bodies, of filling a space to the exclusion of others until they be removed, and it admits of many amusing illustrations, both as regards the proof and modification of the property.

Thus, a block of wood fills a certain space: how is it (if impenetrable) that we can drive a nail into it? A few experiments will enable us to answer this question.

Into a glass (as depicted at fig. 1) filled with spirits of wine, a quantity of cotton wool many times the bulk of the alcohol may (if the experiment is carefully performed) be pushed without causing a drop to overflow the sides of the vessel.

Fig. 1.

Here we seem to have a direct contradiction of the simple and indisputable truth, that "two things cannot occupy the same space at once." But let us proceed with our experiments:—

We have now a flask full of water, and taking some very finely-powdered sugar, it is easy to introduce a notable quantity of that substance without increasing the bulk of the water; the only precaution necessary, is not to allow the sugar to fall into the flask in a mass, but to drop it in grain by grain, and very slowly, allowing time for the air-bubbles (which will cling to the particles of sugar) to pass off, and for the sugar to dissolve. Matter, in the experiments adduced, appears to be penetrable, and the property of impenetrability seems only to be a creation of fancy: reason, however, enables us to say that the latter is not the case.

Fig. 2.

A nail may certainly be hammered into wood, but the particles are thrust aside to allow it to enter. Cotton wool may be placed in spirits of wine because it is simply greatly extended and bulky matter, which, if compressed, might only occupy the space of the kernel of a nut, and if this were dropped into a half-pint measure full of alcohol, the increase of bulk would not cause the spirit to overflow. The cotton-wool experiment is therefore no contradiction of impenetrability. The experiment with the sugar is the most troublesome opponent to our term, and obliges us to amend and qualify the original definition, and say, that the ultimate or smallest particles or atoms of bodies only are impenetrable; and we may believe they are not in close contact with each other, because certain bulks of sugar and water occupy more space separately than when mixed.

Fig. 3.

If we compare the flask of water to a flask full of marbles, and the sugar to some rape-seed, it will be evident that we may almost pour another flask full of the latter amongst the marbles, because they are not in close contact with each other, but have spaces between them; and after pouring in the rape-seed, we might still find room for some fine sand.

The particles of one body may thus enter into the spaces left between those of another without increasing its volume; and hence, as has been before stated, "The atoms only of bodies are truly impenetrable."

This spreading, as it were, of matter through matter assumes a very important function when we come to examine the constitution of the air we breathe, which is chiefly a mechanical mixture of gases: seventy-nine parts by volume or measure of nitrogen gas, twenty-one parts of oxygen gas, and four parts of carbonic acid vapour in every ten thousand parts of air having the following relations as to weight:—

It might be expected that these gases would arrange themselves in our atmosphere in the above order, and if that were the case, we should have the carbonic-acid gas (a most poisonous one) at the bottom, and touching the earth, then the oxygen, and, last of all, the nitrogen; a state of things in which organized life could not exist. The gases do not, however, separate: indeed, they seem to act as it were like vacuums to one another, and "the diffusion of gases" has become a recognised fact, governed by fixed laws. This fact is curiously illustrated, as shown in our cut, by filling a bottle with carbonic acid, and another with hydrogen; and having previously fitted corks to the bottles, perforated so as to admit a tube, place the bottle containing the carbonic acid on the table, then take the other full of hydrogen, keeping the mouth downwards, and fit in the cork and tube: place this finally into the cork of the carbonic-acid bottle, which may be a little larger than the other, in order to make the arrangement stand firmer; and after leaving them for an hour or so, the carbonic acid, which is twenty-two times heavier than the hydrogen, will ascend to the latter, whilst the hydrogen will descend to the carbonic acid. The presence of the carbonic acid in the hydrogen bottle is easily proved by pouring in a wine-glassful of clear lime-water, which speedily becomes milky, owing to the production of carbonate of lime; whilst the proof of the hydrogen being present in the carbonic acid is established by absorbing the latter with a little cream of lime—i.e., slacked lime mixed to the consistence of cream with some water—and setting fire to the hydrogen that remains, which burns quietly with a yellowish flame if unmixed with air; but if air be admitted to the bottle, the mixture of air and hydrogen inflames rapidly, and with some noise.

Fig. 4.

One of the most elegant modes of showing the diffusion of gases is by taking a large round dry porous cell, such as would be employed in a voltaic battery, and having cemented a brass cap with a glass tube attached to its open extremity, it may then be supported by a small tripod of iron wire, and the end of the glass tube placed in a tumbler containing a small quantity of water coloured blue with sulphate of indigo. If a tolerably large jar containing hydrogen is now placed over the porous cell, bubbles of gas make their escape at the end of the tube, because the hydrogen diffuses itself more rapidly into the porous cell than the air which it already contains passes out. When the jar is removed, the reverse occurs, hydrogen diffuses out of the porous cell, and the blue liquid rises in the tube.

This diffusive force prevents the accumulation of the various noxious gases on the earth, and spreads them rapidly through the great bulk of the atmosphere surrounding the globe.

Fig. 5.

a. The porous cell. b. The jar of hydrogen. c. The brass cap and glass tube d, the end of which dips into the tumbler containing the solution of indigo e. f f. The wire and stand supporting the porous cell and tube in tumbler.

Although air and other gases are invisible, they possess the property of impenetrability, as may be easily proved by various experiments. Having opened a pair of common bellows, stop up the nozzle securely, and it is then impossible to shut them; or, fill a bladder with air by blowing into it, and tie a string fast round the neck; you then find that you cannot, without breaking the bladder, press the sides together.

It is customary to say that a vessel is empty when we have poured out the water which it contained. Having provided two glass vessels full of water, place each of them in an empty white pan, to receive the overflow, then lay an orange upon the surface of the water of one of them, and being provided with a cylindrical glass, open at one end, with a hole in the centre of the closed end, place your finger firmly over the orifice, and endeavour, by inverting the glass over the orange, and pressing upon the surface of the water, to make it enter the interior of the glass cylinder; the resistance of the air will now cause the water to overflow into the white pan, whilst the orange will not enter. The orange may now be transferred to the other vessel of water, and on removing the finger from the orifice of the cylindrical glass, and inverting it as before over the orange, the air will rush out and the orange and water will enter, whilst there will be no overflow as in the preceding experiment. The comparison of the two is very striking, and at once teaches the fact desired.

Whilst the vessels of water are still in use, another pretty experiment may be made with the metal potassium. First throw a small piece of the metal on the surface of the water, to show that it takes fire on contact with that fluid; then, having provided a gas-jar, fitted with a cap and stop-cock, and a little spoon screwed into the bottom of the stop-cock inside the gas-jar, place another piece of potassium in the little spoon, and, after closing the stop-cock, push the jar into one of the vessels of water: as before, the impenetrability of the air prevents the water flowing up to the potassium; but, on opening the stop-cock, the air escapes, the water rushes up, and directly it touches the potassium, combustion ensues.

Having sufficiently indicated the nature and meaning of impenetrability, we may proceed to discuss experimentally three other marked and special qualities of matter—viz., inertia, gravity, and weight.

INERTIA, OR PASSIVENESS.

Inertia is a power which (according to Sir Isaac Newton) is implanted in all matter of resisting any change from a state of rest. It is sometimes called vis inertiæ, and is that property possessed by all matter, of remaining at rest till set in motion, and vice versâ; and it expresses, in brief terms, resistance to motion or rest.

A pendulum clock wound up and ready to go, does not commence its movements, until the inertia of the pendulum is overcome, and motion imparted to it. On the other hand, when seated in a carriage, should any obstruction cause the horse to stop suddenly, it is only perhaps by a violent effort, if at all, that we can resist the onward movement of our bodies. To illustrate inertia, construct a metal tray, about three feet long, two feet wide, and two inches deep, with a glass bottom, and arrange it on a framework supported by legs, like a table, and having filled it with water, let the room be darkened, and then place under the tank a lighted candle, at a sufficient distance from the glass to prevent the heat cracking it. If a piece of calico or paper, stretched on a framework, be now held over the water at an angle of about thirty degrees, all that occurs on the surface of the water will be rendered visible on such screen. Attention may now be directed to the quiescence, or the inertia of the water, while the opposite condition of movement and formation of the waves may be beautifully shown by touching the surface of the water with the finger; the miniature waves being depicted on the screen, and continuing their motion till set at rest by striking against the sides of the tin tray.

Fig. 10.

Tin tray, with glass bottom, full of water; candle placed underneath.

Fig. 11.

Fig. 11. Same tray, with calico screen; showing the waves as they are produced by touching the surface of the water with the finger.

Should the above experiment be thought too troublesome or expensive to prepare, inertia may be demonstrated by filling a tea-cup or other convenient vessel with water, and after moving rapidly with it in any direction, if we stop suddenly, the rigidity of all parts of the cup we hold brings them simultaneously to a state of rest; but the mobility of the liquid particles allows of their continuing in motion in their original direction, and the liquid is spilled. Thus, carelessness in handing and spilling a cup of tea (though not to be recommended) serves to illustrate an important principle. The inertia of bodies in motion is further and lamentably illustrated by the accidents caused from the sudden stoppage of a railway train whilst in rapid motion, when heads and knees come in contact with frightful results.—It is more especially demonstrated by the earth, the moon, and the other planets continuing their motion for ever in the absence of any friction or resistance to oppose their onward progress. It is the friction arising from the roughness of the ground, the resistance of the air, and the force of the earth's attraction, which puts a stop to bodies set in motion about the surface of the earth.

GRAVITATION.

Inertia represents a passive force, gravitation, an active condition of matter; and this latter may truly be termed a force of attraction, because it acts between masses at sensible or insensible distances: it is illustrated by a stone, unsupported, falling to the ground; by the stone pressing with force on the earth, and requiring power to raise it from the ground: indeed, it is commonly reported that it was by an accident—"an apple falling from a tree"—that the great Newton was led to reflect on the universal law of gravitation, and to pronounce upon it in the following memorable words:—

"Every particle of matter in the universe attracts every other particle of matter with a force or power directly proportional to the quantity of matter in each, and decreasing as the squares of the distances which separate the particles increase."

These words may appear very obscure to our juvenile readers; but when dissected and examined properly, they clearly define the property of gravitation. For instance, "every particle attracts every other with a force proportional to the quantity of matter in each." This statement was verified some years back by Maskelyne, who, having sought out and discovered a steep, precipitous rock in the Schichallion mountains, in Scotland, suspended from it a metal weight by a cord, and going to a convenient distance with a telescope, and observing the weight, he found that it did not hang perpendicularly, like an ordinary plumb line, but was attracted, or impelled, to the sides of the rock by some kind of attraction, which, of course, could be no other than that indicated by Newton as the attraction of gravitation.

Fig. 12.

The Schichallion Rocks. The dotted line and weight a represent the ordinary position of a plumb line, whilst the line of the weight b indicates (of course, with some exaggeration) the attractive power of the mass of the rock drawing it from the perpendicular.

This truly wonderful power of attraction pervades all masses; and being, as before stated, proportional to the quantity of matter, if a man could be transported to the surface of the sun, he would become about thirty times heavier: he would be attracted, or impelled, to the sun with thirty times more gravitating force than on the surface of the earth, and would weigh about two tons. Of course, nursing a baby on the sun's surface would be a very serious affair with our ordinary strength; whilst on some of the smaller planets, such as Ceres and Pallas, we should probably gravitate with a force of a few pounds only, and with the same muscular power now possessed, we should quite emulate the exploits of those domestic little creatures sometimes called "the industrious fleas," and our jumping would be something marvellous.

There is no very good lecture-table experiment that will illustrate gravitation, although attention may be directed to the fact of a piece of potassium thrown on the surface of water in a plate generally rushing to the sides, and, as if attracted, attaching itself with great force to the substance of the pottery or porcelain; or, if a model ship, or lump of wood, be allowed to float at rest in a large tank of water, and a number of light chips of wood or bits of straw be thrown in, they generally collect and remain around the larger floating mass.

A very good idea, however, may be afforded of the universal action of gravity maintaining all things in their natural position on the earth by taking a hoop and arranging in and upon it balls, or a model ship, or other toy, and wires, as depicted in our diagram.

Fig. 13.

a. The centre ball, representing the earth's centre of gravity. w w w w. Four wires fixed into centre ball, and passing through and secured in the hoop, projecting about one foot from the circumference. b b b b. Two balls—a model ship and toy—working on the wires like beads, with vulcanized India-rubber straps attached to them and the circumference of the hoop.

With this simple apparatus we may illustrate the upward, downward, and sideway movement of bodies from the earth, and the counteraction by the force of gravitation of any tendency of matter to fall away from the globe, which is represented in the model by the india-rubber springs pulling the balls and toys back again to the circumference of the hoop.

The attraction of gravitation decreases (quoting the remainder of Newton's definition) as the squares of the distances which separate the particles increase—i.e., it obeys the principle called "inverse proportion"—viz., the greater the distance, the less gravitating power; the less the distance, the greater the power of gravitation. Gravitation is like the distribution of light and other radiant forces, and may be thus illustrated.

Fig. 14.

Place a lighted candle, marked a, at a certain distance from No. 1, a board one foot square; at double the distance the latter will shadow another board, No. 2, four feet square; at three times, No. 3, nine feet square; at four, No. 4, sixteen feet; and so on.

To make the comparison between the propagation of light and the attraction of gravitation, we have only to imagine the candle, a, to represent the point where the force of gravity exists in the highest degree of intensity; suppose it to be the sun—the great centre of this power in our planetary system. A body, as at No. 1, at any given distance will be attracted (like iron-filings to a magnet) with a certain force; at twice the distance, the square of two being four, and by inverse proportion, the attraction will be four times less; at thrice the distance, nine times less; at the fourth distance, sixteen times less; and so on. With the assistance of this law, we may calculate, roughly, the depth of a well, or a precipice, or a column, by ascertaining the time occupied in the fall of a stone or other heavy substance. A falling body descends about 16 feet in one second, 64 feet in two seconds, 144 feet in three seconds, 256 feet in four seconds, 400 feet in five seconds, 576 feet in six seconds; the spaces passed over being as the squares of the times.

Suppose a stone takes three seconds in falling to the surface of the water in a well, then 3 × 3 = 9 × 16 = 144 feet would be a rough estimate of the depth. The calculation will exceed the truth in consequence of the stone being retarded in its passage by the resistance of the air.

All bodies gravitate equally to the earth: for instance, if an open box, say one foot in length, two inches broad, and two inches deep, be provided with a nicely-fitted bottom, attached by a hinge, a number of substances, such as wood, cork, marble, iron, lead, copper, may be arranged in a row; and directly the hand is withdrawn, the moveable flap flies open, and if the manipulation with the disengagement of the trap-door is good, the whole of the substances are seen to proceed to the earth in a straight line, as shown in our drawing.

Fig. 15.

Fig. 16.

If a heavy substance, like gold, be greatly extended by hammering and beating into thin leaves, and then dropped from the hand, the resistance of the air becomes very apparent; and a gold coin and a piece of gold-leaf would not reach the earth at the same time if allowed to fall from any given height. This fact is easily displayed by the assistance of a long glass cylindrical vessel placed on the air-pump, with suitable apparatus arranged with little stages to carry the different substances; upon two of them may be placed a feather and a gold coin, and on the third, another gold coin and a piece of gold-leaf.

Fig. 17.

In arranging the experiment, great care ought to be taken that the little stages are all nicely cleaned, and free from any oil, grease, or other matter which might cause the feathers or the gold-leaf to cling to the stages when they are disengaged, by moving the brass stop round that works in the collar of leathers. Sometimes these leathers are oiled, and in that case, when the vacuum is made, the oil, by the pressure, is squeezed out, and, passing down, may reach the stages and spoil the experiment, by causing the feathers and gold-leaf to stick to the brass, producing great disappointment, as the illustration, usually called the "guinea and feather glass experiment" takes some time to prepare. The air-pump being in good order, the long glass is first greased on the lower welt or edge, and then placed firmly on the air-pump plate. The top edge, or welt, may now be greased, and the gold coins, feathers, and gold-leaf arranged in the drop-apparatus; this is carefully placed on the top of the glass, and firmly squeezed down. The author has always found a tallow candle, rolled in a sheet of paper (so as to leave about half the candle exposed), the best grease to smear the glass with for air-pump experiments; if the weather is cold, the candle may be placed for a few minutes before an ordinary fire to soften the tallow. Pomatum answers perfectly well when the surfaces of glass and brass are all nicely ground; but as air-pumps and glasses by use get scratched and rubbed, the tallow seems to fill up better all ordinary channels by which air may enter to spoil a vacuum.

Fig. 18.

The apparatus being now arranged, the air is pumped out; and here, again, care must be taken not to shake the gold off the stages. When a proper vacuum has been obtained, which will be shown by the pump-gauge, the stop is withdrawn from one of the stages, and the gold and feather are seen to fall simultaneously to the air-pump plate. Another stage, with the gold-leaf and coin, may now be detached; both showing distinctly, that when the resistance of the air is withdrawn, all bodies, whether called light or heavy, gravitate equally to the earth. Then, the screw at the bottom of the pump barrels being opened, attention may be directed to the whizzing noise the air makes on entering the vacuum, and when the air is once more restored to the long glass vessel, the last stage may be allowed to fall; and now, the gold coin reaches the pump-plate first, and the feather, lingering behind, loses (as it were) the race, and touches the plate after the gold coin; thus demonstrating clearly the resistance of the air to falling bodies.

Another, and perhaps less troublesome, mode of showing the same fact, is to use a long glass tube closed at each end with brass caps cemented on. One cap should have the largest possible aperture closed by a brass screw, and the other may fit a small hand-pump.

Fig. 19.

a b. Glass tube containing a piece of gold and a feather, which are placed in at the large aperture a. c. Small hand-pump.

If a piece of gold and a small feather are placed in the tube, it may be shown that the former reaches the bottom of the tube first, whilst it is full of air, and when the air is withdrawn by means of the pump, and the tube again inverted, both the gold and the feather fall in the same time.

For this reason, all attempts to measure heights or depths by observing the time occupied by a falling body in reaching the earth must be incorrect, and can only be rough approximations. An experiment tried at St. Paul's Cathedral, with a stone, which was allowed to fall from the cupola, indicated the time occupied in the descent to be four and a half seconds: now, if we square this time, and multiply by 16, a height of 324 feet is denoted; whereas the actual height is only 272 feet, and the difference of 52 feet shows how the stone was retarded in its passage through the air; for, had there been no obstacle, it would have reached the ground in 4-3/20ths seconds.

Fig. 20.

The force of gravitation is further demonstrated by the action of the sun and moon raising the waters of the ocean, and producing the tides; and also by the earth and moon, and other planets and satellites, being prevented from flying from their natural paths or orbits around the sun. It is also very clearly proved that there must be some kind of attractive force resident in the earth, or else all moveable things, the water, the air, the living and dead matters, would fly away from the surface of the earth in obedience to what is called "centrifugal force." Our earth is twenty-four hours in performing one rotation on its axis, which is an imaginary line drawn from pole to pole, and represented by the wire round which we cause a sphere to rotate. All objects, therefore, on the earth are moving with the planet at an enormous velocity; and this movement is called the earth's diurnal, or daily rotation. Now, it will be remembered, that mud or other fluid matter flies off, and is not retained by the circumference of a wheel in motion: when a mop is trundled, or a dog or sheep, after exposure to rain, shake themselves, the water is thrown off by what is called centrifugal force (centrum, a centre, fugio, to fly from).

CHAPTER II.

CENTRIFUGAL FORCE.

That power which drives a revolving body from a centre, and it may be illustrated by turning a closed parasol, or umbrella, rapidly round on its centre, the stick being the axis—the ribs fly out, and if there is much friction in the parts, the illustration is more certain by attaching a bullet to the end of each rib, as shown in our drawing.

Fig. 21.

The same fact may be illustrated by a square mahogany rod, say one inch square and three feet long, with two flaps eighteen inches in length, hanging by hinges, and parallel to the sides of the centre rod, which immediately fly out on the rotation of the long centre piece.

Fig. 22.

The toy called the centrifugal railway is also a very pretty illustration of the same fact. A glass of water, or a coin, may be placed in the little carriage, and although it must be twice hanging perpendicular in a line with the earth, the carriage does not tumble away from its appointed track, and the centrifugal force binds it firmly to the interior of the circle round which it revolves.

Fig. 23.

Another striking and very simple illustration is to suspend a hemispherical cup by three cords, and having twisted them, by turning round the cup, it may be filled with water, and directly the hand is withdrawn, the torsion of the cord causes the cup to rotate, and the water describes a circle on the floor, flying off at a tangent from the cup, as may be noticed in the accompanying cut.

Fig. 24.

A hoop when trundled would tumble on its side if the force of gravitation was not overcome by the centrifugal force which imparts to it a motion in the direction of a tangent (tango, to touch) to a circle. The same principle applies to the spinning-top—this toy cannot be made to stand upon its point until set in rapid motion.

Returning again to the subject of gravitation, we may now consider it in relation to other and more magnificent examples which we discover by studying the science of astronomy.

CHAPTER III.

THE SCIENCE OF ASTRONOMY.

In a work of this kind, professedly devoted to a very brief and popular view of the different scientific subjects, much cannot be said on any special branch of science; it will be better, therefore, to take up one subject in astronomy, and by discussing it in a simple manner, our young friends may be stimulated to learn more of those glorious truths which are to be found in the published works of many eminent astronomers, and especially in that of Mr. Hind, called "The Illustrated London Astronomy." One of the most interesting subjects is the phenomenon of the eclipse of the sun; and as 1858 is likely to be long remembered for its "annular eclipse," we shall devote some pages and illustrations to this subject.

Eclipses of the sun are of three kinds—partial, annular, and total. Many persons have probably seen large partial eclipses of the sun, and may possibly suppose that a total eclipse is merely an intensified form of a partial one; but astronomers assert that no degree of partial eclipse, even when the very smallest portion of the sun remains visible, gives the slightest idea of a total one, either in the solemnity and overpowering influence of the spectacle, or the curious appearances which accompany it.

The late Mr. Baily said of an eclipse (usually called that of Thales), which caused the suspension of a battle between the Lydians and Medes, that only a total eclipse could have produced the effect ascribed to it. Even educated astronomers, when viewing with the naked eye the sun nearly obscured by the moon in an annular eclipse, could not tell that any part of the sun was hidden, and this was remarkably verified in the annular eclipse of the 15th March of this year.

During the continuance of a total eclipse of the sun, we are permitted a hasty glance at some of those secrets of Nature which are not revealed at any other time—glories that hold in tremulous amazement even veteran explorers of the heavens and its starry worlds.

The general meaning of an eclipse may be shown very nicely by lighting a common oil, or oxy-hydrogen lantern in a darkened room, and throwing the rays which proceed from it on a three-feet globe. The lantern may be called the sun, and, of course, it is understood that correct comparative sizes are not attempted in this arrangement; if it were so, the globe representing the earth would have to be a mere speck, for if we make the model of the sun in proportion to a three-feet globe, no ordinary lecture hall would contain it. This being premised, attention is directed to the lantern, which, like the sun, is self-luminous, and is giving out its own rays; these fall upon the globe we have designated the earth, and illuminate one-half, whilst the other is shrouded in darkness, reminding us of the opacity of the earth, and teaching, in a familiar manner, the causes of day and night. Another globe, say six inches in diameter, and supported by a string, may be compared to the moon, and, like the earth, is now luminous, and shines only by borrowed light: the moon is simply a reflector of light; like a sheet of white cardboard, or a metallic mirror. When, therefore, the small globe is passed between the lantern and the large globe, a shadow is cast on the large globe: it is also seen that only the half of the small globe turned towards the lantern is illuminated, while the other half, opposite the large globe, is in shadow or darkness. And here we understand why the moon appears to be black while passing before the sun; so also by moving the small globe about in various curves, it is shown why eclipses are only visible at certain parts of the earth's surface; and as it would take (roughly speaking) fifty globes as large as the moon to make one equal in size to our earth, the shadow it casts must necessarily be small, and cannot obscure the whole hemisphere of the earth turned towards it. An eclipse of the sun is, therefore, caused by the opaque mass of moon passing between the sun and the earth. Whilst an eclipse of the moon is caused by the earth moving directly between the sun and the moon: the large shadow cast by the earth renders a total eclipse of the moon visible to a greater number of spectators on that half of the earth turned towards the moon. All these facts can be clearly demonstrated with the arrangement already described, of which we give the following pictorial illustration:—

Fig. 25.

In using this apparatus, it should be explained that if the moon were as large as the sun, the shadow would be cylindrical like the figure 1, and of an unlimited length. If she were of greater magnitude, it would precisely resemble the shadow cast in the experiment already adduced with the lantern and shown at No. 2. But being so very much smaller than the sun, the moon projects a shadow which converges to a point as shown in the third diagram.

Fig. 26.

Fig. 27.

Fig. 28.

In order to comprehend the difference between an annular and a total eclipse of the sun, it is necessary to mention the apparent sizes of the sun and moon: thus, the former is a very large body—viz., eight hundred and eighty-seven thousand miles in diameter; but then, the sun is a very long way off from the earth, and is ninety millions of miles distant from us; therefore, he does not appear to be very large: indeed, the sun seems to be about the same size as the moon; for, although the sun's diameter is (roughly speaking) four hundred times greater than that of the moon, he is four hundred times further away from us, and, consequently, the sun and moon appear to be the same size, and when they come in a straight line with the eye, the nearer and smaller body, the moon, covers the larger and more distant mass, the sun; and hence, we have either an annular, or a total eclipse, showing how a small body may come between the eye and a larger body, and either partially or completely obscure it.

With respect to an annular eclipse, it must be remembered, that the paths of all bodies revolving round others are elliptical; i.e., they take place in the form of an ellipse, which is a figure easily demonstrated; and is, in fact, one of the conic sections.

If a slice be taken off a cone, parallel with the base, we have a circle thus—

Fig. 29.

If it be cut obliquely, or slanting, we see at once the figure spoken of, and have the ellipse as shown in this picture.

Fig. 30.

Now, the ellipse has two points within it, called "the foci," and these are easily indicated by drawing an ellipse on a diagram-board, in which two nails have been placed in a straight line, and about twelve inches apart. Having tied a string so as to make a loop, or endless cord, a circle may first be drawn by putting the cord round one of the nails, and holding a piece of chalk in the loop of the string, it may be extended to its full distance, and a circle described; here a figure is produced round one point, and to show the difference between a circle and an ellipse, the endless cord is now placed on the two nails, and the chalk being carried round inside the string, no longer produces the circle, but that familiar form called the oval. As a gardener would say, an oval has been struck; and the two points round which it has been described, are called the foci. This explanation enables us to understand the next diagram, showing the motion of the earth round the sun; the latter being placed in one of the foci of a very moderate ellipse, and the various points of the earth's orbit designated by the little round globes marked a, b, c, d, where it is evident that the earth is nearer to the sun at b than at d. In this diagram the ellipse is exaggerated, as it ought, in fact, to be very nearly a circle.

We are about three millions of miles nearer to the sun in the winter than we are in the summer; but from the more oblique or slanting direction of the rays of the sun during the winter season, we do not derive any increased heat from the greater proximity. The sun, therefore, apparently varies in size; but this seeming difference is so trifling that it is of no importance in the discussion: and here we may ask, why does the earth move round the sun? Because it is impelled by two forces, one of which has already been fully explained, and is called the centrifugal power, and the other, although termed the centripetal force, is only another name for the "attraction of gravitation."

Fig. 33.

To show their mutual relations, let us suppose that, at the creation of the universe, the earth, marked a, was hurled from the hand of its Maker; according to the law of inertia, it would continue in a straight line, a c, for ever through space, provided it met with no resistance or obstruction. Let us now suppose the earth to have arrived at the point b, and to come within the sphere of the attraction of the sun s; here we have at once contending forces acting at right angles to each other; either the earth must continue in its original direction, a c, or fall gradually to the sun. But, mark the beauty and harmony of the arrangement: like a billiard-ball, struck with equal force at two points at right angles to each other, it takes the mean between the two, or what is termed the diagonal of the parallelogram (as shown in our drawing of a billiard-table), and passes in the direction of the curved line, b d; having reached d, it is again ready to fly off at a tangent; the centrifugal force would carry it to e, but again the gravitating force controls the centripetal, and the earth pursues its elliptical path, or orbit, till the Almighty Author who bade it move shall please to reverse the command.

Fig. 34.

Fig. 35.

The mutual relations of the centripetal and centrifugal forces may be illustrated by suspending a tin cylindrical vessel by two strings, and having filled it with water, the vessel may be swung round without spilling a single drop; of course, the movement must be commenced carefully, by making it oscillate like a pendulum.

Fig. 36.

The cord which binds it to the finger may be compared to the centripetal force, whilst the centrifugal power is illustrated by the water pressing against the sides and remaining in the vessel. Upon the like principles the moon revolves about the earth, but her orbit is more elliptical than that of the earth around the sun; and it is evident from our diagram that the moon is much further from the earth at a than at b. As a natural consequence, the moon appears sometimes a little larger and sometimes smaller than the sun; the apparent mean diameter of the latter being thirty-two minutes, whilst the moon's apparent diameter varies from twenty-nine and a half to thirty-three and a half minutes. Now, if the moon passes exactly between us and the sun when she is apparently largest, then a total eclipse takes place; whereas, if she glides between the sun and ourselves when smallest—i.e., when furthest off from the earth—then she is not sufficiently large to cover the sun entirely, but a ring of sunlight remains visible around her, and what is called an annular eclipse of the sun occurs. This fact may be shown in an effective manner by placing the oxy-hydrogen lantern before a sheet, or other white surface, and throwing a bright circle of light upon it, which may be called the sun; then, if a round disc of wood be passed between the lantern and the sheet, at a certain distance from the nozzle of the lantern, all the light is cut off, the circle of light is no longer apparent, and we have a resemblance to a total eclipse.

Fig. 37.

By taking the round disc of wood further from the lantern, and repeating the experiment, it will be found that the whole circle of light is not obscured, but a ring of light appears around the dark centre, corresponding with the phenomenon called the annular (ring-shaped) eclipse.

If a bullet be placed very near to one eye whilst the other remains closed, a large target may be wholly shut out from vision; but if the bullet be adjusted at a greater distance from the eye, then the centre only will be obscured, and the outer edge or ring of the target remains visible.

When the advancing edge, or first limb, as it is termed, of the moon approaches very near to the second limb of the sun, the two are joined together for a time by alternations of black and white points, called Baily's beads.

This phenomenon is supposed to be caused partly by the uneven and mountainous edge of the moon, and partly by that inevitable fault of telescopes, and of the nervous system of the eye, which tends to enlarge the images of luminous objects, producing what is called irradiation. It is exceedingly interesting to know that, although the clouds obscured the annular eclipse of 1858, in many parts of England, we are yet left the recorded observations of one fortunate astronomer, Mr. John Yeats, who states that—

"All the phenomena of an annular eclipse were clearly and beautifully visible on the Fotheringay-Castle-mound, which is a locality easily identified. Baily's beads were perfectly plain on the completion of the annulus, which occurrence took place, according to my observation, at about seventy seconds after 1 o'clock; it lasted about eighty seconds. The 'beads,' like drops of water, appeared on the upper and under sides of the moon, occupying fully three-fourths of her circumference.

"Prior to this, the upper edge of the moon seemed dark and rough, and there were no other changes of colour. At 12.43, the cusps, for a few moments, bore a very black aspect.

"There was nothing like intense darkness during the eclipse, and less gloom than during a thunderstorm. Bystanders prognosticated rain; but it was the shadow of a rapidly-declining day. At 12 o'clock, a lady living on the farm suddenly exclaimed, 'The cows are coming home to be milked!' and they came, all but one; that followed, however, within the hour. Cocks crowed, birds flew low or fluttered about uneasily, but every object far and near was well defined to the eye.

"A singular broadway of light stretched north and south for upwards of a quarter of an hour; from about 12.54 to 1.10 p.m."

Fig. 38.

Fig. 39.

If the annular eclipse of the sun be a matter for wonderment, the total eclipse of the same is much more surprising; no other expression than that of awfully grand, can give an idea of the effects of totality, and of the suddenness with which it obscures the light of heaven. The darkness, it is said, comes dropping down like a mantle, and as the moment of full obscuration approaches, people's countenances become livid, the horizon is indistinct and sometimes invisible, and there is a general appearance of horror on all sides. These are not simply the inventions of active human imaginations, for they produce equal, if not greater effects, upon the brute creation. M. Arago quotes an instance of a half-starved dog, who was voraciously devouring some food, but dropped it the instant the darkness came on. A swarm of ants, busily engaged, stopped when the darkness commenced, and remained motionless till the light reappeared. A herd of oxen collected themselves into a circle and stood still, with their horns outward, as if to resist a common enemy; certain plants, such as the convolvulus and silk-tree acacia, closed their leaves. The latter statement was corroborated during the annular eclipse of the 15th of March, 1858, by Mr. E. S. Lane, who states, that crocuses at the Observatory, Beeston, had their blossoms expanded before the eclipse; they commenced closing, and were quite shut at about one minute previous to the greatest darkness; and the flowers opened partially about twenty minutes afterwards. A "total eclipse" of the sun has always impressed the human mind with terror and wonder in every age: it was always supposed to be the forerunner of evil; and not only is the mind powerfully impressed, as darkness gradually shuts out the face of the sun, but at the moment of totality, a magnificent corona, or glory of light, is visible, and prominences, or flames, as they are often termed, make their appearance at different points round the circle of the dark mass. This glory does not flash suddenly on the eye; but commencing at the first limb of the sun, passes quickly from one limb to the other. Our illustration shows "the corona" and the "rose-coloured prominences," whose nature we shall next endeavour to explain. Professor Airy describes the change from the last narrow crescent of light to the entire dark moon, surrounded by a ring of faint light, as most curious, striking, and magical in effect. The progress of the formation of the corona was seen distinctly. It commenced on the side of the moon opposite to that at which the sun disappeared, and in the general decay and disease which seemed to oppress all nature, the moon and the corona appeared almost like a local sore in that part of the sky, and in some places were seen double. Its texture appeared as if fibrous, or composed of entangled threads; in other places brushes, or feathers of light proceeded from it, and one estimate calculated the light at about one-seventh part of a full moon light. The question, whether the corona is concentric with the sun and moon, was specially mooted by M. Arago, and Professor Baden Powell has produced such excellent imitations of the "corona" by making opaque bodies occult, or conceal, very bright points, that it cannot be considered as material or real, although it ought to be remembered that the best theory of the zodiacal light represents it to be a nebulous mass, increasing in density towards the sun, and yet no portion of this nebulous mass was seen during the totality. But by far the most remarkable of all the appearances connected with a "total eclipse" are the rose-coloured prominences, mountains, or flames, projecting from the circumference of the moon to the inner ring of the corona; and, although they had been observed by Vaserius (a Swedish astronomer) in 1733, they took the modern astronomers entirely by surprise in 1842, and they were not prepared with instruments to ascertain the nature of these strange and almost portentous forms. In 1851, however, great preparations were made to throw further light on the subject. Professor Airy went to make his observations, and he says, "That the suddenness of the darkness in 1851 appeared much more striking than in 1842, and the forms of the rose-coloured mountains were most curious. One reminded him of a boomerang (that curious weapon thrown so skilfully by the aborigines of Australia); this same figure has been spoken of by others as resembling a Turkish scimitar, strongly coloured with rose-red at the borders, but paler in the centre. Another form was a pale-white semicircle based on the moon's limbs; a third figure was a red detached cloud, or balloon, of nearly circular form, separated from the moon by nearly its own breadth; a fourth appeared like a small triangle, or conical red mountain, perhaps a little white in the interior;" and the Professor proceeds to say, "I employed myself in an attempt to draw roughly the figures, and it was impossible, after witnessing the increase in height of some, and the disappearance of another, and the arrival of new forms, not to feel convinced that the phenomena belonged to the sun, and not to the moon."

Still the question remains unanswered, what are these "rose-coloured prominences?" If they belong to the sun, and are mountains in that luminary, they must be some thirty or forty thousand miles in height.

M. Faye has formally propounded the theory, that they are caused by refraction, or a kind of mirage, or the distortion of objects caused by heated air. This phenomenon is not peculiar to any country, though most frequently observed near the margin of lakes and rivers, and on hot sandy plains. M. Monge, who accompanied Buonaparte in his expedition to Egypt, witnessed a remarkable example between Alexandria and Cairo, where, in all directions, green islands appeared surrounded by extensive lakes of pure, transparent water. M. Monge states that "Nothing could be conceived more lovely or picturesque than the landscape. In the tranquil surface of the lake, the trees and houses with which the islands are covered were strongly reflected with vivid and varied hues, and the party hastened forward to enjoy the refreshment apparently proffered them; but when they arrived, the lake, on whose bosom the images had floated—the trees, amongst whose foliage they arose, and the people who stood on the shore, as if inviting their approach, had all vanished, and nothing remained but the uniform and irksome desert of sand and sky, with a few naked and ragged Arabs."

If M. Monge and his party had not been undeceived, by actually going to the spot, they would, one and all, have been firmly convinced that these visionary trees, lakes, and buildings had a real existence. This kind of mirage is known in Persia and Arabia by the name of "serab" or miraculous water, and in the western districts of India by that of "scheram." This illusion is the effect of unusual refraction, and M. Faye attempts to account for the rose-coloured mountains by something of a similar nature.

It is right, however, to mention, that learned astronomers do not consider this theory of any value.

Lieutenant Patterson, one of the observers of the eclipse of 1851, says, that "It is very remarkable that the flames or prominences correspond exactly (at least as far as he could judge) with the spots on the sun's surface." Taking this statement with that of M. Faye, it may be assumed, as a new idea, and nothing more, that these prominences are, after all, mere aerial pictures of these openings in the sun's atmosphere, or what are called "sun spots." In the "Edinburgh Philosophical Journal," it is said, that although it has lately been shown in the Edinburgh Observatory that it is possible to produce, by certain optical experiments, red flames on the sun's limb of precisely the rose-coloured tint described, yet, on weighing the whole of the evidence, there does seem a great preponderance in favour of the eclipse flames being real appendages of the sun, and in that case they must be masses of such vast size as to play no unimportant part in the economy of that stupendous orb.

During the last eclipse great disappointment was felt that the darkness was so insignificant, although, when we consider the enormous light-giving power of the sun, and know that it was not wholly obscured, we could hardly have expected any other result. There can be no doubt that a decided change in the amount of light is only to be observed during a total eclipse of the sun, one of which occurred on the 7th of September, 1858; but, unfortunately, it was only visible in South America; we must therefore content ourselves with the descriptions of those astronomers who can be fully relied on. From the graphic account given by Professor Piazzi Smyth, the astronomer-royal for Scotland, of a total eclipse as seen by him on the western coast of Norway, we may form some notion of the imposing appearance of the surrounding country when obscured during the occurrence of this rare astronomical phenomenon.

The Professor remarks, "To understand the scene more fully, the reader must fancy himself on a small, rocky island on a mountainous coast, the weather calm, and the sky at the beginning of the eclipse seven-tenths covered with thin and bright cirro-strati clouds. As the eclipse approaches, the clouds gradually darken, the rays of the sun are no longer able to penetrate them through and through, and drench them with living light as before, but they become darker than the sky against which they are seen. The air becomes sensibly colder, the clouds still darker, and the whole atmosphere murkier.

"From moment to moment as the totality approaches, the cold and darkness advance apace; and there is something peculiarly and terribly convincing in the two different senses, so entirely coinciding in their indications of an unprecedented fact being in course of accomplishment. Suddenly, and apparently without any warning (so immensely greater were its effects than those of anything else which had occurred), the totality supervenes, and darkness comes down. Then came into view lurid lights and forms, as on the extinction of candles. This was the most striking point of the whole phenomenon, and made the Norse peasants about us flee with precipitation, and hide themselves for their lives.

"Darkness reigned everywhere in heaven and earth, except where, along the north-eastern horizon, a narrow strip of unclouded sky presented a low burning tone of colour, and where some distant snow-covered mountains, beyond the range of the moon's shadow, reflected the faint mono-chromatic light of the partially eclipsed sun, and exhibited all the detail of their structure, all the light, and shade, and markings of their precipitous sides with an apparently supernatural distinctness. After a little time, the eyes seemed to get accustomed to the darkness, and the looming forms of objects close by could be discerned, all of them exhibiting a dull-green hue; seeming to have exhaled their natural colour, and to have taken this particular one, merely by force of the red colour in the north.

"Life and animation seemed, indeed, to have now departed from everything around, and we could hardly but fear, against our reason, that if such a state of things was to last much longer, some dreadful calamity must happen to us all; while the lurid horizon, northward, appeared so like the gleams of departing light in some of the grandest paintings by Danby and Martin, that we could not but believe, in spite of the alleged extravagances of these artists, that Nature had opened up to the constant contemplation of their mind's-eye some of those magnificent revelations of power and glory which others can only get a glimpse of on occasions such as these."

It can be easily imagined, that under such peculiar and awful circumstances, the careful observation of these effects must be somewhat difficult, and the only wonder is that the astronomical observations are conducted with any certainty at all.

In the eclipse of 1842, it was not only the vivacious Frenchman who was carried away in the impulse of the moment, and had afterwards to plead that "he was no more than a man" as an excuse for his unfulfilled part in the observations, but the same was the case with the grave Englishman and the more stolid German. In 1851, much the same failure in the observations occurred; and on some person asking a worthy American, who had come with his instruments from the other side of the world expressly to observe the eclipse, what he had succeeded in doing? he merely answered, with much quiet impressiveness, "That if it was to be observed over again, he hoped he would be able to do something, but that, as it was, he had done nothing: it had been too much for him." This is not quite so bad as the fashionable lady who had been invited to look at an eclipse of the sun through a grand telescope, but arriving too late, inquired whether "it could not be shown over again."

With this brief glance at the science of astronomy, we once more return to the term "gravity," which will introduce to us some new and interesting facts, under the head of what is called "centre of gravity."

CHAPTER IV.

CENTRE OF GRAVITY.

That point about which all the parts of a body do, in any situation, exactly balance each other.

The discovery of this fact is due to Archimedes, and it is a point in every solid body (whatever the form may be) in which the forces of gravity may be considered as united. In our globe, which is a sphere, or rather an oblate spheroid, the centre of gravity will be the centre. Thus, if a plummet be suspended on the surface of the earth, it points directly to the centre of gravity, and, consequently, two plummet-lines suspended side by side cannot, strictly speaking, be parallel to each other.

Fig. 40.

f. The centre. a b c d e. Plummet-lines, all pointing to the centre, and therefore diverging from each other.

If it were possible to bore or dig a gallery through the whole substance of the earth from pole to pole, and then to allow a stone or the fabled Mahomet's coffin to fall through it, the momentum—i.e., the force of the moving body, would carry it beyond the centre of gravity. This force, however, being exhausted, there would be a retrograde movement, and after many oscillations it would gradually come to rest, and then, unsupported by anything material, it would be suspended by the force of gravitation, and now enter into and take part in the general attracting force; and being equally attracted on every side, the stone or coffin must be totally without weight.

Momentum is prettily illustrated by a series of inclined planes cut in mahogany, with a grooved channel at the top, in imitation of the famous Russian ice mountains: and if a marble is allowed to run down the first incline, the momentum will carry it up the second, from which it will again descend and pass up and down the third and last miniature mountain.

Fig. 41.

p p p. Inclined planes, gradually decreasing in height, cut out of inch mahogany, with a groove at the top to carry an ordinary marble. b b b. Different positions of the marble, which starts from b a.

In a sphere of uniform density, the centre of gravity is easily discovered, but not so in an irregular mass; and here, perhaps, an explanation of terms may not be altogether unacceptable.

Mass, is a term applied to solids, such as a mass of lead or stone.

Bulk, to liquids, such as a bulk of water or oil.

Volume, to gases, such as a volume of air or oxygen.

Fig. 42.

a b d, The three points of suspension. c, The point of intersection, and, therefore, the centre of gravity. p, The line of plummet.

To find the centre of gravity of any mass, as, for example, an ordinary school-slate, we must first of all suspend it from any part of the frame; then allow a plumb-line to drop from the point of suspension, and mark its direction on the slate. Again, suspend the slate at various other points, always marking the line of direction of the plummet, and at the point where the lines intersect each other, there will be the centre of gravity.

If the slate be now placed (as shown in Fig. 43) on a blunt wooden point at the spot where the lines cross each other, it will be found to balance exactly, and this place is called the centre of gravity, being the point with which all other particles of the body would move with parallel and equable motion during its fall. The equilibrium of bodies is therefore much affected by the position of the centre of gravity. Thus, if we cut out an elliptical figure from a board one inch in thickness, and rest it on a flat surface by one of its edges (as at No. 1, fig. 44), this point of contact is called the point of support, and the centre of gravity is immediately above it.

Fig. 43.

In this case, the body is in a state of secure equilibrium, for any motion on either side will cause the centre of gravity to ascend in these directions, and an oscillation will ensue. But if we place it upon the smaller end, as shown at No. 2 (fig. 44), the position will be one of equilibrium, but not stable or secure; although the centre of gravity is directly above the point of support, the slightest touch will displace the oval and cause its overthrow. The famous story of Columbus and the egg suggests a capital illustration of this fact; and there are two modes in which the egg may be poised on either of the ends.

Fig. 44.

The point of support. c, The centre of gravity.

The one usually attributed to the great discoverer, is that of scraping or slightly breaking away a little of the shell, so as to flatten one of the ends, thus—

Fig. 45.

a Represents the egg in its natural state, and, therefore, in unstable equilibrium; b, another egg, with the surface, s, flattened, by which the centre of gravity is lowered, and if not disturbed beyond the extent of the point of support the equilibrium is stable.

The most philosophical mode of making the egg stand on its end and without disturbing the exterior shell is to alter the position of the yolk, which has a greater density than the white, and is situated about the centre. If the egg is now shaken so as to break the membrane enclosing the yolk, and thus allow it to sink to the bottom of the smaller end, the centre of gravity is lowered; there is a greater proportion of weight concentrated in the small end, and the egg stands erect, as depicted at fig. 46.

Fig. 46.

No. 1. Section of egg. c. Centre of gravity. y. The yolk. w. The white. No. 2. c. Centre of gravity, much lowered. y. The yolk at the bottom of the egg.

It is this variable position of the centre of gravity in ivory balls (one part of which may be more dense than another) that so frequently annoys even the best billiard-players; and on this account a ball will deviate from the line in which it is impelled, not from any fault of the player, but in consequence of the ivory ball being of unequal density, and, therefore, not having the centre corresponding with the centre of gravity. A good billiard-player should, therefore, always try the ball before he engages to play for any large sum.

The toy called the "tombola" reminds us of the egg-experiment, as there is usually a lump of lead inserted in the lower part of the hemisphere, and when the toy is pushed down it rapidly assumes the upright position because the centre of gravity is not in the lowest place to which it can descend; the latter position being only attained when the figure is upright.

Fig. 47.

No. 1. c. Centre of gravity in the lowest place, figure upright. No. 2. c. Centre of gravity raised as the figure is inclined on either side, but falling again into the lowest place as the figure gradually comes to rest.

There is a popular paradox in mechanics—viz., "a body having a tendency to fall by its own weight, may be prevented from falling by adding to it a weight on the same side on which it tends to fall," and the paradox is demonstrated by another well-known child's toy as depicted in the next cut.

Fig. 48.

The line of direction falling beyond the base; the bent wire and lead weight throwing the centre of gravity under the table and near the leaden weight; the hind legs become the point of support, and the toy is perfectly balanced.

Fig. 49.

No. 1. Sword balanced on handle: the arc from c to d is very small, and if the centre, c, falls out of the line of direction it is not easily restored to the upright position. No 2. Sword balanced on the point: the arc from c to d much larger, and therefore the sword is more easily balanced.

After what has been explained regarding the improvement of the stability of the egg by lowering the situation of the centre of gravity, it may at first appear singular that a stick loaded with a weight at its upper extremity can be balanced perpendicularly with greater ease and precision than when the weight is lower down and nearer the hand; and that a sword can be balanced best when the hilt is uppermost; but this is easily explained when it is understood that with the handle downwards a much smaller arc is described as it falls than when reversed, so that in the former case the balancer has not time to re-adjust the centre, whilst in the latter position the arc described is so large that before the sword falls the centre of gravity may be restored within the line of direction of the base.

For the same reason, a child tripping against a stone will fall quickly; whereas, a man can recover himself; this fact can be very nicely shown by fixing two square pieces of mahogany of different lengths, by hinges on a flat base or board, then if the board be pushed rapidly forward and struck against a lead weight or a nail put in the table, the short piece is seen to fall first and the long one afterwards; the difference of time occupied in the fall of each piece of wood (which may be carved to represent the human figure) being clearly denoted by the sounds produced as they strike the board.

Fig. 50.

No. 1. The two pieces of mahogany, carved to represent a man and a boy, one being 10 and the other 5 inches long, attached to board by hinges at h h.

Fig. 51.

No. 2. The board pushed forward, striking against a nail, when the short piece falls first, and the long one second.

Boat-accidents frequently arise in consequence of ignorance on the subject of the centre of gravity, and when persons are alarmed whilst sitting in a boat, they generally rise suddenly, raise the centre of gravity, which falling, by the oscillation of the frail bark, outside the line of direction of the base, cannot be restored, and the boat is upset; if the boat were fixed by the keel, raising the centre of gravity would be of little consequence, but as the boat is perfectly free to move and roll to one side or the other, the elevation of the centre of gravity is fatal, and it operates just as the removal of the lead would do, if changed from the base to the head of the "tombola" toy.

A very striking experiment, exhibiting the danger of rising in a boat, maybe shown by the following model, as depicted at Nos. 1 and 2, figs. 52 and 53.

Fig. 52.

No. 1. Sections of a toy-boat floating in water. b b b. Three brass wires placed at regular distances and screwed into the bottom of the boat, with cuts or slits at the top so that when the leaden bullets, l l l, which are perforated and slide upon them like beads, are raised to the top, they are retained by the brass cuts springing out; when the bullets are at the bottom of the lines they represent persons sitting in a boat, as shown in the lower cuts, and the centre of gravity will be within the vessel.

We thus perceive that the stability of a body placed on a base depends upon the position of the line of direction and the height of the centre of gravity.

Security results when the line of direction falls within the base. Instability when just at the edge. Incapability of standing when falling without the base.

Fig. 53.

No. 2. The leaden bullets raised to the top now show the result of persons suddenly rising, when the boat immediately turns over, and either sinks or floats on the surface with the keel upwards.

The leaning-tower of Pisa is one hundred and eighty-two feet in height, and is swayed thirteen and a half feet from the perpendicular, but yet remains perfectly firm and secure, as the line of direction falls considerably within the base. If it was of a greater altitude it could no longer stand, because the centre of gravity would be so elevated that the line of direction would fall outside the base. This fact may be illustrated by taking a board several feet in length, and having cut it out to represent the architecture of the leaning-tower of Pisa, it may then be painted in distemper, and fixed at the right angle with a hinge to another board representing the ground, whilst a plumb-line may be dropped from the centre of gravity; and it may be shown that as long as the plummet falls within the base, the tower is safe; but directly the model tower is brought a little further forward by a wedge so that the plummet hangs outside, then, on removing the support, which may be a piece of string to be cut at the right moment, the model falls, and the fact is at once comprehended.

Fig. 54.

f. Board cut and painted to represent the leaning-tower of Pisa. g. The centre of gravity and plummet line suspended from it. h. The hinge which attaches it to the base board. i. The string, sufficiently long to unwind and allow the plummet to hang outside the base, so that, when cut, the model falls in the direction of the arrow.

The leaning-towers of Bologna are likewise celebrated for their great inclination; so also (in England) is the hanging-tower, or, more correctly, the massive wall which has formed part of a tower at Bridgenorth, Salop; it deviates from the perpendicular, but the centre of gravity and the line of direction fall within the base, and it remains secure; indeed, so little fears are entertained of its tumbling down, that a stable has been erected beneath it.

Fig. 55.

No. 1. Two billiard-cues arranged for the experiment and fixed to a board: the ball is rolling up. No. 2. Sections showing that the centre of gravity, c, is higher at a than at b, which represents the thick end of the cues; it therefore, in effect, rolls down hill.

One of the most curious paradoxes is displayed in the ascent of a billiard-ball from the thin to the thick ends of two billiard-cues placed at an angle, as in our drawing above; here the centre of gravity is raised at starting, and the ball moves in consequence of its actually falling from the high to the low level.

Much of the stability of a body depends on the height through which the centre of gravity must be elevated before the body can be overthrown. The greater this height, the greater will be the immovability of the mass. One of the grandest examples of this fact is shown in the ancient Pyramids; and whilst gigantic palaces, with vast columns, and all the solid grandeur belonging to Egyptian architecture, have succumbed to time and lie more or less prostrate upon the earth, the Pyramids, in their simple form and solidity, remain almost as they were built, and it will be noticed, in the accompanying sketch, how difficult, if not impossible, it would be to attempt to overthrow bodily one of these great monuments of ancient times.

Fig. 56.

c. Centre of gravity, which must be raised to d before it can be overthrown.

The principles already explained are directly applicable to the construction or secure loading of vehicles; and in proportion as the centre of gravity is elevated above the point of support (that is, the wheels), so is the insecurity of the carriage increased, and the contrary takes place if the centre of gravity is lowered. Again, if a waggon be loaded with a very heavy substance which does not occupy much space, such as iron, lead, or copper, or bricks, it will be in much less danger of an overthrow than if it carries an equal weight of a lighter body, such as pockets of hops, or bags of wool or bales of rags.

Fig. 57.

No. 1. The centre of gravity is near the ground, and falls within the wheels. No. 2. The centre of gravity is much elevated, and the line of direction is outside the wheels.

In the one instance, the centre of gravity is near the ground, and falls well within the base, as at No. 1, fig. 57. In the other, the centre of gravity is considerably elevated above the ground, and having met with an obstruction which has raised one side higher than the other, the line of direction has fallen outside the wheels, and the waggon is overturning as at No. 2.

The various postures of the human body may be regarded as so many experiments upon the position of the centre of gravity which we are every moment unconsciously performing.

To maintain an erect position, a man must so place his body as to cause the line of direction of his weight to fall within the base formed by his feet.

Fig. 58.

The more the toes are turned outwards, the more contracted will be the base, and the body will be more liable to fall backwards or forwards; and the closer the feet are drawn together, the more likely is the body to fall on either side. The acrobats, and so-called "India-Rubber Brothers," dancing dogs, &c., unconsciously acquire the habit of accurately balancing themselves in all kinds of strange positions; but as these accomplishments are not to be recommended to young people, some other marvels (such as balancing a pail of water on a stick laid upon a table) may be adduced, as illustrated in fig. 59.

Fig. 59.

Let a b represent an ordinary table, upon which place a broomstick, c d, so that one-half shall lay upon the table and the other extend from it; place over the stick the handle of an empty pail (which may possibly require to be elongated for the experiment) so that the handle touches or falls into a notch at h; and in order to bring the pail well under the table, another stick is placed in the notch e, and is arranged in the line g f e, one end resting at g and the other at e. Having made these preparations, the pail may now be filled with water; and although it appears to be a most marvellous result, to see the pail apparently balanced on the end of a stick which may easily tilt up, the principles already explained will enable the observer to understand that the centre of gravity of the pail falls within the line of direction shown by the dotted line; and it amounts in effect to nothing more than carrying a pail on the centre of a stick, one end of which is supported at e, and the other through the medium of the table, a b.

This illustration may be modified by using a heavy weight, rope, and stick, as shown in our sketch below.

Fig. 60.

Before we dismiss this subject it is advisable to explain a term referring to a very useful truth, called the centre of percussion; a knowledge of which, gained instinctively or otherwise, enables the workman to wield his tools with increased power, and gives greater force to the cut of the swordsman, so that, with some physical strength, he may perform the feat of cutting a sheep in half, cleaving a bar of lead, or neatly dividing, à la Saladin, in ancient Saracen fashion, a silk handkerchief floating in the air. There is a feat, however, which does not require any very great strength, but is sufficiently startling to excite much surprise and some inquiry—viz., the one of cutting in half a broomstick supported at the ends on tumblers of water without spilling the water or cracking or otherwise damaging the glass supports.

Fig. 61.

These and other feats are partly explained by reference to time: the force is so quickly applied and expended on the centre of the stick that it is not communicated to the supports; just as a bullet from a pistol may be sent through a pane of glass without shattering the whole square, but making a clean hole through it, or a candle may be sent through a plank, or a cannon-ball pass through a half opened door without causing it to move on its hinges. But the success of the several feats depends in a great measure on the attention that is paid to the delivery of the blows at the centre of percussion of the weapon; this is a point in a moving body where the percussion is the greatest, and about which the impetus or force of all parts is balanced on every side. It may be better understood by reference to our drawing below. Applying this principle to a model sword made of wood, cut in half in the centre of the blade, and then united with an elbow-joint, the handle being fixed to a board by a wire passed through it and the two upright pieces of wood, the fact is at once apparent, and is well shown in Nos. 1, 2, 3, fig. 62.

Fig. 62.

No. 1, is the wooden sword, with an elbow-joint at c. No. 2. Sword attached to board at k, and being allowed to fall from any angle shown by dotted-line, it strikes the block, w, outside the centre of percussion, p, and as there is unequal motion in the parts of the sword it bends down (or, as it were, breaks) at the elbow-joint, c. No. 3 displays the same model; but here the blow has fallen on the block, w, precisely at the centre of percussion of the sword, p, and the elbow-joint remains perfectly firm.

When a blow is not delivered with a stick or sword at the centre of percussion, a peculiar jar, or what is familiarly spoken of as a stinging sensation, is apparent in the hand; and the cause of this disagreeable result is further elucidated by fig. 63, in which the post, a, corresponds with the handle of the sword.

Fig. 63.

a. The post to which a rope is attached. b and c are two horses running round in a circle, and it is plain that b will not move so quick as c, and that the latter will have the greatest moving force; consequently, if the rope was suddenly checked by striking against an object at the centre of gravity, the horse c would proceed faster than b, and would impart to b a backward motion, and thus make a great strain on the rope at a. But if the obstacle were placed so as to be struck at a certain point nearer c, viz., at or about the little star, the tendency of each horse to move on would balance and neutralize the other, so that there would be no strain at a. The little star indicates the centre of percussion.

All military men, and especially those young gentlemen who are intended for the army, should bear in mind this important truth during their sword-practice; and with one of Mr. Wilkinson's swords, made only of the very best steel, they may conquer in a chance combat which might otherwise have proved fatal to them. To Mr. Wilkinson, of Pall Mall, the eminent sword-cutler, is due the great merit of improving the quality of the steel employed in the manufacture of officers' swords; and with one of his weapons, the author has repeatedly thrust through an iron plate about one-eighth of an inch in thickness without injuring the point, and has also bent one nearly double without fracturing it, the perfect elasticity of the steel bringing the sword straight again. These, and other severe tests applied to Wilkinson's swords, show that there is no reason why an officer should not possess a weapon that will bear comparison with, nay, surpass, the far-famed Toledo weapon, instead of submitting to mere army-tailor swords, which are often little better than hoops of beer barrels; and, in dire combat with Hindoo or Mussulman fanatics' Tulwah, may show too late the folly of the owner.

Fig. 64.

CHAPTER V.

SPECIFIC GRAVITY.

It is recorded of the great Dr. Wollaston, that when Sir Humphry Davy placed in his hand, what was then considered to be the scientific wonder of the day—viz., a small bit of the metal potassium, he exclaimed at once, "How heavy it is," and was greatly surprised, when Sir Humphry threw the metal on water, to see it not only take fire, but actually float upon the surface; here, then, was a philosopher possessing the deepest learning, unable, by the sense of touch and by ordinary handling, to state correctly whether the new substance (and that a metal), was heavy or light; hence it is apparent that the property of specific gravity is one of importance, and being derived from the Latin, means species, a particular sort or kind; and gravis, heavy or weight—i.e., the particular weight of every substance compared with a fixed standard of water.

Fig. 65.

a. A large cylindrical vessel containing water, in which the egg sinks till it reaches the bottom of the glass. b. A similar glass vessel containing half brine and half water, in which the egg floats in the centre—viz., just at the point where the brine and water touch.

Fig. 66.

A vessel half full of water, and as the brine is poured down the tube the egg gradually rises.

We are so constantly in the habit of referring to a standard of perfection in music and the arts of painting and sculpture, that the youngest will comprehend the office of water when told that it is the philosopher's unit or starting-point for the estimation of the relative weights of solids and liquids. A good idea of the scope and meaning of the term specific gravity, is acquired by a few simple experiments, thus: if a cylindrical glass, say eighteen inches long, and two and a half wide, is filled with water, and another of the same size is also filled, one half with water and the other half with a saturated solution of common salt, or what is commonly termed brine, a most amusing comparison of the relative weights of equal bulks of water and brine, can be made with the help of two eggs; when one of the eggs is placed in the glass containing water, it immediately sinks to the bottom, showing that it has a greater specific gravity than water; but when the other egg is placed in the second glass containing the brine, it sinks through the water till it reaches the strong solution of salt, where it is suspended, and presents a most curious and pretty appearance; seeming to float like a balloon in air, and apparently suspended upon nothing, it provokes the inquiry, "whether magnetism has anything to do with it?" The answer, of course, is in the negative, it merely floats in the centre, in obedience to the common principle, that all bodies float in others which are heavier than themselves; the brine has, therefore, a greater weight than an equal bulk of water, and is also heavier than the egg. A pleasing sequel to this experiment may be shown by demonstrating how the brine is placed in the vessel without mixing with the water above it; this is done by using a glass tube and funnel, and after pouring away half the water contained in the vessel (Fig. 65), the egg can be floated from the bottom to the centre of the glass, by pouring the brine down the funnel and tube. The saturated solution of salt remains in the lower part of the vessel and displaces the water, which floats upon its surface like oil on water, carrying the egg with it.

The water of the Dead Sea is said to contain about twenty-six per cent. of saline matter, which chiefly consists of common salt. It is perfectly clear and bright, and in consequence of the great density, a person may easily float on its surface, like the egg on the brine, so that if a ship could be heavily laden whilst floating on the water of the Dead Sea, it would most likely sink if transported to the Thames. This illustration of specific gravity is also shown by a model ship, which being first floated on the brine, will afterwards sink if conveyed to another vessel containing water. One of the tin model ships sold as a magnetic toy answers nicely for this experiment, but it must be weighted or adjusted so that it just floats in the brine, a; then it will sink, when placed, in another vessel containing only water.

Fig. 67.

a. Vessel containing brine, upon which the little model floats. b. Vessel containing water, in which the ship sinks.

Another amusing illustration of the same kind is displayed with goldfish, which swim easily in water, floating on brine, but cannot dive to the bottom of the vessel, owing to the density of the saturated solution of salt. If the fish are taken out immediately after the experiment, and placed in fresh water, they will not be hurt by contact with the strong salt water.

These examples of the relative weights of equal bulks, enable the youthful mind to grasp the more difficult problem of ascertaining the specific gravity of any solid or liquid substance; and here the strict meaning of terms should not be passed by. Specific weight must not be confounded with Absolute weight; the latter means the entire amount of ponderable matter in any body: thus, twenty-four cubic feet of sand weigh about one ton, whilst specific weight means the relation that subsists between the absolute weight and the volume or space which that weight occupies. Thus a cubic foot of water weighs sixty-two and a half pounds, or 1000 ounces avoirdupois, but changed to gold, the cubic foot weighs more than half a ton, and would be equal to about 19,300 ounces—hence the relation between the cubic foot of water and that of gold is nearly as 1 to 19.3; the latter is therefore called the specific gravity of gold.

Such a mode of taking the specific gravity of different substances—viz., by the weight of equal bulks, whether cubic feet or inches, could not be employed in consequence of the difficulty of procuring exact cubic inches or feet of the various substances which by their peculiar properties of brittleness or hardness would present insuperable obstacles to any attempt to fashion or shape them into exact volumes. It is therefore necessary to adopt the method first devised by Archimedes, 600 b.c., when he discovered the admixture of another metal with the gold of King Hiero's crown.

This amusing story, ending in the discovery of a philosophical truth, may be thus described:—King Hiero gave out from the royal treasury a certain quantity of gold, which he required to be fashioned into a crown; when, however, the emblem of power was produced by the goldsmith, it was not found deficient in weight, but had that appearance which indicated to the monarch that a surreptitious addition of some other metal must have been made.

It may be assumed that King Hiero consulted his friend and philosopher Archimedes, and he might have said, "Tell me, Archimedes, without pulling my crown to pieces, if it has been adulterated with any other metal?" The philosopher asked time to solve the problem, and going to take his accustomed bath, discovered then specially what he had never particularly remarked before—that, as he entered the vessel of water, the liquid rose on each side of him—that he, in fact, displaced a certain quantity of liquid. Thus, supposing the bath to have been full of water, directly Archimedes stepped in, it would overflow. Let it be assumed that the water displaced was collected, and weighed 90 pounds, whilst the philosopher had weighed, say 200 pounds. Now, the train of reasoning in his mind might be of this kind:—"My body displaces 90 pounds of water; if I had an exact cast of it in lead, the same bulk and weight of liquid would overflow; but the weight of my body was, say 200 pounds, the cast in lead 1000 pounds; these two sums divided by 90 would give very different results, and they would be the specific gravities, because the rule is thus stated:—'Divide the gross weight by the loss of weight in water, the water displaced, and the quotient gives the specific gravity.'" The rule is soon tested with the help of an ordinary pair of scales, and the experiment made more interesting by taking a model crown of some metal, which may be nicely gilt and burnished by Messrs. Elkington, the celebrated electro-platers of Birmingham. For convenience, the pan of one scale is suspended by shorter chains than the other, and should have a hook inserted in the middle; upon this is placed the crown, supported by very thin copper wire. For the sake of argument, let it be supposed that the crown weighs 17½ ounces avoirdupois, which are duly placed in the other scale-pan, and without touching these weights, the crown is now placed in a vessel of water. It might be supposed that directly the crown enters the water, it would gain weight, in consequence of being wetted, but the contrary is the case, and by thrusting the crown into the water, it may be seen to rise with great buoyancy so long as the 17½ ounces are retained in the other scale-pan; and it will be found necessary to place at least two ounces in the scale-pan to which the crown is attached before the latter sinks in the water; and thus it is distinctly shown that the crown weighs only about 15½ ounces in the water, and has therefore lost instead of gaining weight whilst immersed in the liquid. The rule may now be worked out:

The quotient 8¾ demonstrates that the crown is manufactured of copper, because it would have been about 19¼ if made of pure gold.

Fig. 68.

a. Ordinary pair of scales. b. Scale-pan, containing 17½ ounces, being the weight of the crown in air. c. Pan, with hook and crown attached, which is sunk in the water contained in the vessel d; this pan contains the two ounces, which must be placed there to make the crown sink and exactly balance b.

Table of the Specific Gravities of the Metals in common use.

The simple rule already explained may be applied to all metals of any size or weight, and when the mass is of an irregular shape, having various cavities on the surface, there may be some difficulty in taking the specific gravity, in consequence of the adhesion of air-bubbles; but this may be obviated either by brushing them away with a feather, or, what is frequently much better, by dipping the metal or mineral first into alcohol, and then into water, before placing it in the vessel of water, by which the actual specific gravity is to be taken.

The mode of taking the specific gravity of liquids is very simple, and is usually performed in the laboratory by means of a thin globular bottle which holds exactly 1000 grains of pure distilled water at 60° Fahrenheit. A little counterpoise of lead is made of the exact weight of the dry globular bottle, and the liquid under examination is poured into the bottle and up to the graduated mark in the neck; the bottle is then placed in one scale-pan, the counterpoise and the 1000-grain weight in the other; if the liquid (such as oil of vitriol) is heavier than water, then more weight will be required—viz., 845 grains—and these figures added to the 1000 would indicate at once that the specific gravity of oil of vitriol was 1.845 as compared with water, which is 1.000. When the liquid, such as alcohol, is lighter than water, the 1000-grain weight will be found too much, and grain weights must be added to the same scale-pan in which the bottle is standing, until the two are exactly balanced. If ordinary alcohol is being examined, it will be found necessary to place 180 grains with the bottle, and these figures deducted from the 1000 grains in the other scale-pan, leave 820, which, marked with a dot before the first figure (sic .820), indicates the specific gravity of alcohol to be less than that of water.

The difference in the gravities of various liquids is displayed in a very pleasing manner by an experiment devised by Professor Griffiths, to whom chemical lecturers are especially indebted for some of the most ingenious and beautiful illustrations which have ever been devised. The experiment consists in the arrangement of five distinct liquids of various densities and colours, the one resting on the other, and distinguished not only by the optical line of demarcation, but by little balls of wax, which are adjusted by leaden shot inside, so as to sink through the upper strata of liquids, and rest only upon the one that it is intended to indicate.

The manipulation for this experiment is somewhat troublesome, and is commenced by procuring some pure bright quicksilver, upon which an iron bullet (black-leaded, or painted of any colour) is placed, or one of those pretty glass balls which are sold in such quantities at the Crystal Palace.

Secondly. Put as much white vitriol (sulphate of zinc) into a half pint of boiling water as it will dissolve, and, when cold, pour off the clear liquid, make up a ball of coloured wax (say red), and adjust it by placing little shot inside, until it sinks in a solution of sulphate of copper and floats on that of the white vitriol.

Thirdly. Make a solution of sulphate of copper in precisely the same manner, and adjust another wax ball to sink in water, and float on this solution.

Fourthly. Some clear distilled water must be provided.

Fifthly. A little cochineal is to be dissolved in some common spirits of wine (alcohol), and a ball of cork painted white provided.

Finally. A long cylindrical glass, at least eighteen inches high, and two and a half or three inches diameter, must be made to receive these five liquids, which are arranged in their proper order of specific gravity by means of a long tube and funnel.

The four balls—viz., the iron, the two wax, and the cork balls, are allowed to slide down the long glass, which is inclined at an angle; and then, by means of the tube and funnel, pour in the tincture of cochineal, and all the balls will remain at the bottom of the glass. The water is poured down next, and now the cork ball floats up on the water, and marks the boundary line of the alcohol and water. Then the solution of blue vitriol, when a wax ball floats upon it. Thirdly, the solution of white vitriol, upon which the second wax ball takes its place; and lastly, the quicksilver is poured down the tube, and upon this heavy metallic fluid the iron or glass ball floats like a cork on water.

Fig. 69.

Long cylindrical glass, 18 × 3 inches, containing the five liquids.

The tube may now be carefully removed, pausing at each liquid, so that no mixture take place between them; and the result is the arrangement of five liquids, giving the appearance of a cylindrical glass painted with bands of crimson, blue, and silver; and the liquids will not mingle with each other for many days.

A more permanent arrangement can be devised by using liquids which have no affinity, or will not mix with each other—such as mercury, water, and turpentine.

The specific weight or weights of an equal measure of air and other gases is determined on the same principle as liquids, although a different apparatus is required. A light capped glass globe, with stop-cock, from 50 to 100 cubic inches capacity, is weighed full of air, then exhausted by an air-pump, and weighed empty, the loss being taken as the weight of its volume of air; these figures are carefully noted, because air instead of water is the standard of comparison for all gases. When the specific gravity of any other gas is to be taken, the glass globe is again exhausted, and screwed on to a gas jar provided with a proper stop-cock, in which the gas is contained; and when perfect accuracy is required, the gas must be dried by passing it over some asbestos moistened with oil of vitriol, and contained in a glass tube, and the gas jar should stand in a mercurial trough. (Fig. 70.) The stop-cocks are gradually turned, and the gas admitted to the exhausted globe from the gas jar; when full, the cocks are turned off, the globe unscrewed, and again weighed, and by the common rule of proportion, as the weight of the air first found is to the weight of the gas, so is unity (1.000, the density of air) to a number which expresses the density of the gas required. If oxygen had been the gas tried, the number would be 1.111, being the specific gravity of that gaseous element. If chlorine, 2.470. Carbonic acid, 1.500. Hydrogen being much less than air, the number would only be 69, or decimally 0.069.

Fig. 70.

a. Glass globe to contain the gas. b. Gas jar standing in the mercurial trough, d. c. Tube containing asbestos moistened with oil of vitriol.

A very good approximation to the correct specific gravity (particularly where a number of trials have to be made with the same gas, such as ordinary coal gas) is obtained by suspending a light paper box, with holes at one end, on one arm of a balance, and a counterpoise on the other. The box can be made carefully, and should have a capacity equal to a half or quarter cubic foot; it is suspended with the holes downward, and is filled by blowing in the coal gas until it issues from the apertures, and can be recognised by the smell. The rule in this case would be equally simple: as the known weight of the half or quarter cubic foot of common air is to the weight of the coal gas, so is 1.000 to the number required. (Fig. 71.)

Fig. 71.

a. The balance. b. The paper box, of a known capacity. c. Gas-pipe blowing in coal-gas, the arrows showing entrance of gas and exit of the air.

Fig. 72.

Inverted large glass shade, containing half carbonic acid and half common air.

As an illustration of the different specific weights of the gases, a small balloon, containing a mixture of hydrogen and air, may be so adjusted that it will just sink in a tall glass shade inverted and supported on a pad made of a piece of oilcloth shaped round and bound with list. On passing in quickly a large quantity of carbonic acid, the little balloon will float on its surface; and if another balloon, containing only hydrogen, is held in the top part of the open shade, and a sheet of glass carefully slid over the open end, the density of the gases (although they are perfectly invisible) is perfectly indicated; and, as a climax to the experiment, a third balloon can be filled with laughing gas, and may be placed in the glass shade, taking care that the one full of pure hydrogen does not escape; the last balloon will sink to the bottom of the jar, because laughing gas is almost as heavy as carbonic acid, and the weight of the balloon will determine its descent. (Fig. 72.)

Fig. 73.

a. Inverted glass shade, containing the material, b, for generating carbonic acid gas. c. The soap-bubble. d d. The glass tube for blowing the bubbles. e. Small lantern, to throw a bright beam of light from the oxy-hydrogen jet upon the thin soap-bubble, which then displays the most beautiful iridescent colours.

A soap-bubble will rest most perfectly on a surface of carbonic acid gas, and the aerial and elastic cushion supports the bubble till it bursts. The experiment is best performed by taking a glass shade twelve inches broad and deep in proportion, and resting it on a pad; half a pound of sesquicarbonate of soda is then placed in the vessel, and upon this is poured a mixture of half a pint of oil of vitriol and half a pint of water, the latter being previously mixed and allowed to cool before use. An enormous quantity of carbonic acid gas is suddenly generated, and rising to the edge, overflows at the top of the glass shade. A well-formed soap-bubble, detached neatly from the end of a glass-tube, oscillates gently on the surface of the heavy gas, and presents a most curious and pleasing appearance. The soapy water is prepared by cutting a few pieces of yellow soap, and placing them in a two-ounce bottle containing distilled water. (Fig. 73.) The specific gravity of the gases, may therefore be either greater, or less than atmospheric air, which has been already mentioned as the standard of comparison, and examined by this test the vapours of some of the compounds of carbon and hydrogen are found to possess a remarkably high gravity; in proof of which, the vapour of ether may be adduced as an example, although it does not consist only of the two elements mentioned, but contains a certain quantity of oxygen. In a cylindrical tin vessel, two feet high and one foot in diameter, place an ordinary hot-water plate, of course full of boiling water; upon this warm surface pour about half an ounce of the best ether; and, after waiting a few minutes until the whole is converted into vapour, take a syphon made of half-inch pewter tube, and warm it by pouring through it a little hot water, taking care to allow the water to drain away from it before use. After placing the syphon in the tin vessel, a light may be applied to the extremity of the long leg outside the tin vessel, to show that no ether is passing over until the air is sucked out as with the water-syphon; and after this has been done, several warm glass vessels may be filled with this heavy vapour of ether, which burns on the application of flame. Finally, the remainder of the vapour may be burnt at the end of the syphon tube, demonstrating in the most satisfactory manner that the vapour is flowing through the syphon just as spirit is removed by the distillers from the casks into cellars of the public-houses. (Fig. 74.)

Fig. 74.

a. Tin vessel containing the hot-water plate, b, upon which the ether is poured. c. The syphon. d. Glass to receive the vapour. e. Combustion of the ether vapour in another vessel.

Before dismissing the important subject of specific gravity (or, as it is termed by the French savants, "density"), it may be as well to state that astronomers have been enabled, by taking the density of the earth and by astronomical observations, to calculate the gravity of the planets belonging to our solar system; and it is interesting to observe that the density of the planet Venus is the only one approaching the gravity of the earth:—

CHAPTER VI.

ATTRACTION OF COHESION.

In previous chapters one kind of attraction—viz., that of gravitation, has been discussed and illustrated in a popular manner, and pursuing the examination of the invisible, active, and real forces of nature, the attraction of cohesion will next engage our attention. There is a peculiar satisfaction in pursuing such investigations, because every step is attended by a reasonable proof; there is no ghostly mystery in philosophic studies; the mind is not suddenly startled at one moment with that which seems more than natural; it is not carried away in an ecstasy of wonder and awe, as in the so-called spirit-rapping experiments, to be again rudely brought back to the material by the disclosure of trickeries of the most ludicrous kind, such as those lately exposed by M. Jobert de Lamballe, at the Academy of Sciences at Paris. This gentleman has unmasked the effrontery of the spirit-rappers by merely stripping the stocking from the heel of a young girl of fourteen. M. Velpeau declares that the rapping is produced by the muscles of the heel and knee acting in concert, and quotes the case of a lady once celebrated as a medium, who has the power of producing the most curious and interesting music with the tendons of the thigh. This music is said to be loud enough to be heard from one end of a long room to the other, and has often played a conspicuous part in the revelations made by the medium. M. Jules Clocquet also explained the method by which the famous girl pendulum had so long abused the credulity of the Paris public. This girl, whose self-styled faculty is that of striking the hour at any time of the day or night, was attended at the Hospital St. Louis by M. Clocquet, who states that the vibrations in this case were produced by a rotatory motion in the lumbar regions of the vertebral column. The sound of these (à la rattlesnake) was so powerful, that they might be distinctly heard at a distance of twenty-five feet.

In studying the powers of nature, which the most sceptical mind allows must exist, there is an abundant field for experiment without attempting the exploits of Macbeth's witches, or the fanciful powers of Manfred; and, returning to the theme of our present chapter, it may be asked, how is cohesion defined? and the answer may be given, by directing attention to the three physical conditions of water, which assumes the form of ice, water, or steam.

In the Polar regions, and also in the Alpine and other mountains where glaciers exist, there the traveller speaks of ice twenty, thirty, forty, nay, three hundred feet in thickness. Here the withdrawal of a certain quantity of heat from the water evidently allows a new force to come into full play. We may call it what we like; but cohesion, from the Latin cum, together, and hæreo, I stick or cleave, appears to be the best and most rational term for this power which tends to make the atoms or particles of the same kind of matter move towards each other, and to prevent them being separated or moved asunder. That it is not merely hypothetical is shown by the following experiments.

Fig. 75.

a a. Two pieces of lead, scraped clean at the surfaces b b. c. Stand, supporting the two pieces of lead attached to each other by cohesion.

If two pieces of lead are cast, and the ends nicely scraped, taking care not to touch the surfaces with the fingers, they may by simple pressure be made to cohere, and in that state of attraction may be lifted from the table by the ring which is usually inserted for convenience in the upper piece of lead; they may be hung for some time from a proper support, and the lower bit of lead will not break away from the upper one; they may even be suspended, as demonstrated by Morveau, in the vacuum of an air-pump, to show that the cohesion is not mistaken for the pressure of the atmosphere, and no separation occurs. And when the union is broken by physical force, it is surprising to notice the limited number of points, like pin points, where the cohesion has occurred; whilst the weight of the lump of lead upheld against the force of gravitation reminds one forcibly of the attraction of a mass of soft iron by a powerful magnet, and leads the philosophic inquirer to speculate on the principle of cohesion being only some masked form of magnetic or electrical attraction. (Fig. 75.)

A fine example of the same force is shown in the use of a pair of flat iron surfaces, planed by the celebrated Whitworth, of Manchester. These surfaces are so true, that when placed upon each other, the upper one will freely rotate when pushed round, in consequence of the thin film of air remaining between the surfaces, which acts like a cushion, and prevents the metallic cohesion. When, however, the upper plate is slid over the lower one gradually, so as to exclude the air, then the two may be lifted together, because cohesion has taken place. (Fig. 76.)

Fig. 76.

a. Whitworth's planes, with film of air between them. b. Film of air excluded when cohesion occurs.

A glass vessel is a good example of cohesion. The materials of which it is composed have been soft and liquid when melted in the fire, and on the removal of the excess of heat it has become hard and solid, in consequence of the attractive force of cohesion binding the particles together; in the absence of such a power, of course, the material would fall into the condition of dust, and a mere shapeless heap of silicates of potash and lead would indicate the place where the moulded and coherent glass would otherwise stand.

A lump of lead, six inches long by four broad, and half an inch thick, may be supported by dexterously taking off a thick shaving with a proper plane, and after pressing an inch or more of the strip on the planed surface of the large lump of lead, the cohesion is so powerful that the latter may be lifted from the table by the strip of metal.

The bullets projected from Perkins' steam-gun, at the rate of three hundred per minute, are thrown with such violence, that, when received on a thick plate of lead backed up with sheet iron, a cold welding takes place between the two surfaces of metal in the most perfect manner, just as two soft pieces of the metal potassium may be squeezed and welded together. The surfaces of an apple torn asunder will not readily cohere, but if cut with a sharp knife, cohesion easily occurs; so with a wound produced by a jagged surface, it is difficult to make the parts heal, whereas some of the most desperate sabre-cuts have been healed, the cohesion of the surfaces of cut flesh being very rapid; hence, if the top of a finger is cut off, it may be replaced, and will grow, in consequence of the natural cohesion of the parts.

The art of plating copper with silver, which is afterwards gilt, and then drawn out into flattened wire for the manufacture of gold lace and epaulets, usually termed bullion, is another example of the wonderful cohesion of the particles of gold, of which a single grain may be extended over the finest plate wire measuring 345 feet in length.

The process of making wax candles is a good illustration of the attraction of cohesion; they are not generally cast in moulds, as most persons suppose, but are made by the successive applications of melted wax around the central plaited wick. Other examples of cohesion are shown by icicles, and also stalagmites; which latter are produced by the gradual dropping of water containing chalk (carbonate of lime) held in solution by the excess of carbonic acid gas; the solvent gradually evaporates, and leaves a series of calcareous films, and these cohere in succession, producing the most fantastic forms, as shown in various remarkable caverns, and especially in the cave of Arta, in the island of Majorca.

In metallic substances the cohesion of the particles assumes an important bearing in the question of relative toughness and power of resisting a strain; hence the term cohesion is modified into that of the property of "tenacity."

The tenacity of the different metals is determined by ascertaining the weight required to break wires of the same length and gauge. Iron appears to possess the property of tenacity in the greatest, and lead in the least degree. (Fig. 77.)

Fig. 77.

b. Pan supported by leaden wire broken by a weight which the iron wire at a easily supports.

The tenacity of iron is taken advantage of in the most scientific manner by the great engineers who have constructed the Britannia Tube, and that eighth wonder of the world, the Leviathan, or Great Eastern steam-ship. In both of these sublime embodiments of the genius and industrial skill of Great Britain the advantage of the cellular principle is fully recognised. The magnitude of this colossal ship is better realized when it is remembered that the Great Eastern is six times the size of the Duke of Wellington line-of-battle ship, that her length is more than three times that of the height of the Monument, while in breadth it is equal to the width of Pall Mall, and that a promenade round the deck will afford a walk of more than a quarter of a mile. Up to the water-mark the hull is constructed with an inner and outer shell, two feet ten inches apart, each of three-quarter-inch plate; and between them, at intervals of six feet, run horizontal webs of iron plates, which convert the whole into a series of continuous cells or iron boxes. (Fig. 78.)

Fig. 78.

Transverse section of Great Eastern, showing the cellular construction from keel to water-line, a a.

This double ship is useful in various ways; in the first place, the danger arising from collision is diminished, as it is supposed that the outer web only would be broken through or damaged; so that the water would not then rush into the steam-ship, but merely fill the space between the shells. In the second place, if there should be any difficulty in procuring ballast, the space can be filled with 2500 tons of water, or again pumped out, according to the requirements of the vessel. The strength of a continued cellular construction can be easily imagined, and may be well illustrated by a thin sheet of common tin plate. If the ends be rested on blocks of wood, so as to lap over the wood about one inch, they are easily displaced, and the mimic bridge broken down from its supports by the addition to the centre of a few ounce weights; whilst the same tin plate rolled up in the figure of a tube, and again rested on the same blocks, will now support many pounds weight without bending or breaking down. (Fig. 79.)

Fig. 79.

a. Flat tin plate, breaking down with a few ounce weights. b. Same tin plate rolled up supports a very heavy weight.

The deck of the ship is double or cellular, after the plan of Stephenson in the Britannia Tubular Bridge, and is 692 feet in length. The tonnage register is 18,200 tons, and 22,500 tons builder's measure; the hull of the Great Eastern is considered to be of such enormous tenacity, that, if it were supported by massive blocks of stone six feet square, placed at each end, at stem and stern, it would not deflect, curve, or bend down in the middle more than six inches even with all her machinery, coals, cargo, and living freight.

In adducing remarkable instances of the adhesive power and tenacity of inorganic matter, it may not be altogether out of place to allude to the strength and force of living matter, or muscular power. It is stated that Dr. George B. Winship, of Roxbury in America, a young physician, twenty-five years old, and weighing 143 pounds, is the strongest man alive; in fact, quite the Samson of the nineteenth century. He can raise a barrel of flour from the floor to his shoulders; can raise himself with either little finger till his chin is half a foot above it; can raise 200 pounds with either little finger; can put up a church bell of 141 pounds; can lift with his hands 926 pounds dead weight without the aid of straps or belts of any kind. As compared with Topham, the Cornish strong man, who could raise 800 pounds, or the Belgic one, his power is greater; and as the use of straps and belts increases the power of lifting by about four times, it is stated that Winship could lift at least 2500 pounds weight.

Fig. 80.

a. Ordinary glass water hammer. b. Copper tube ditto, showing exhausting syringe at d, the height of the water at b, and the end to be placed in the fire at c.

With these illustrations of cohesion we may return again to the abstract consideration of this power with reference to water, in which we have noticed that the antagonist to this kind of attraction is the force or power termed caloric or heat. The latter influence removes the frozen bands of winter and converts the ice to the next condition, water. In this state cohesion is almost concealed, although there is just a slight excess to hold even the particles of water in a state of unity, and this fact is beautifully illustrated by the formation of the brilliant diamond drops of dew on the surfaces of various leaves, as also in the force and power exercised by great volumes of water, which exert their mighty strength in the shape of breaker-waves, dashing against rocks and lighthouses, and making them tremble to their very base by the violence of the shock; here there must be some unity of particles, or the collective strength could not be exerted, it would be like throwing a handful of sand against a window—a certain amount of noise is produced, but the glass is not fractured; whilst the same sand united by any glutinous material, would break its way through, and soon fracture the brittle glass. It is so usual to see the particles of water easily separated, that it becomes difficult to recognise the presence of cohesion; but this bond of union is well illustrated in the experiment of the water hammer. The little instrument is generally made of a glass tube with a bulb at one end; in this bulb the water which it contains is boiled, and as the steam issues from the other extremity, drawn out to a capillary tube, the opening is closed by fusion with the heat of a blowpipe flame. As the water cools the steam condenses, and a vacuum, so far as air is concerned, is produced; if now the tube is suddenly inverted, the whole of the water falls en masse, collectively, and striking against the bottom of the tube, produces a metallic ring, just as if a piece of wood or metal were contained within the tube. If the end to which the water falls is not well cushioned by the palm of the hand, the water hammers itself through and breaks away that part of the glass tube. Hence it is better to construct the water hammer of copper tube, about three-quarters of an inch in diameter and three feet long; at one end a female screw-piece is inserted, into which a stop-cock is fitted; when the tube is filled to the height of about six inches with water, and shaken, the air divides the descending volume of water, and the ordinary splashing sound is heard; there is no unity or cohesion of the parts; if, however, the end of the copper tube is thrust into a fire and the water boiled so that steam issues from the cock, which is then closed, and the tube removed and cooled, a smart blow is given, and distinctly heard when the copper tube is rapidly inverted or shaken so as to cause the water to rise and fall. The experiment may be rendered still more instructive by turning the cock and admitting the air, which rushes in with a whizzing sound, and on shaking the tube the metallic ring is no longer heard, but it may be again restored by attaching a small air syringe or hand pump, and removing the air by exhaustion. (Fig. 80.)

In the fluid condition water still possesses a surplus of cohesion over the antagonistic force of heat; when, however, the latter is applied in excess, then the quasi-struggle terminates; the heat overpowers the cohesive attraction, and converts the water into the most willing slave which has ever lent itself to the caprices of man—viz., into steam—glorious, useful steam: and now the other end of the chain is reached, where heat triumphs; whilst in solids, such as ice, cohesion is the conqueror, and the intermediate link is displayed in the fluid state of water. If any fact could give an idea of the gigantic size of the Great Eastern, it is the force of the steam which will be employed to move it at the rate of about eighteen miles per hour with a power estimated at the nominal rate of 2600 horses, but absolutely of at least 12,000 horses. This steam power, coupled with the fact that she has been enormously strengthened in her sharp, powerful bows, by laying down three complete iron decks forward, extending from the bows backward for 120 feet, will demonstrate that in case of war the Great Eastern may prove to be a powerful auxiliary to the Government. These decks will be occupied by the crew of 300 or 400 men, and with this large increase of strength forward, the Great Eastern, steaming full power, could overtake and cut in two the largest wooden line-of-battle ship that ever floated. Should war unhappily spread to peaceful England, and the enormous power of this vessel be realized, her name would not inappropriately be changed from the Great Eastern to the Great Terror of the ocean. The Times very properly inquires, "What fleet could stand in the way of such a mass, weighing some 30,000 tons, and driven through the water by 12,000 horse-power, at the rate of twenty-two or twenty-three miles per hour. To produce the steam, 250 tons of coal per diem will be required, and great will be the honourable pride of the projectors when they see her fairly afloat, and gliding through the ocean to the Far West."

A good and striking experiment, displaying the change from the liquid to the vapour state, is shown by tying a piece of sheet caoutchouc over a tin vessel containing an ounce or two of water. When this boils, the india-rubber is distended, and breaks with a loud noise; or in another illustration, by pouring some ether through a funnel carefully into a flask placed in a ring stand. If flame is applied to the orifice, no vapour issues that will ignite, provided the neck of the flask has not been wetted with the ether. When, however, the heat of a spirit-lamp is applied, the ether soon boils, and now on the application of a lighted taper, a flame some feet in length is produced, which is regulated by the spirit-lamp below, and when this is removed, the length of the flame diminishes immediately, and is totally extinguished if the bottom of the flask is plunged into cold water; the withdrawal of the heat restores the power of cohesion. Another illustration of the vast power of steam will be shortly displayed in the Steam Ram; and, "Supposing," says the Times, "the new steam ram to prove a successful design, the finest specimens of modern men-of-war will be reduced by comparison to the helplessness of cock boats. Conceive a monstrous fabric floating in mid-channel, fire proof and ball proof, capable of hurling broadsides of 100 shot to a distance of six miles; or of clapping on steam at pleasure and running down everything on the surface of the sea with a momentum utterly irresistible.

"This terrible engine of destruction is expected to be itself indestructible. We are told that she may be riddled with shot (supposing any shot could pierce her sides), that she may have her stem and her stern cut to pieces, and be reduced apparently to a shapeless wreck, without losing her buoyancy or power. Supposing that she relies upon the shock of her impact instead of fighting her guns, it is calculated that she would sink a line-of-battle ship in three minutes, so that a squadron as large as our whole fleet now in commission would be destroyed in about one hour and a quarter."

CHAPTER VII.

ADHESIVE ATTRACTION.

The term cohesion must not be confounded with that of adhesion, which refers to the clinging to or attraction of bodies of a dissimilar kind. The late Professor Daniell defines cohesion to be an attraction of homogeneous (ὁμος, like, and γενος, kind) or similar particles; adhesion to be an attraction subsisting between particles of a heterogeneous, ετερος, different, and γενος, kind.

There are numerous illustrations of adhesion, such as mending china, and the use of glue, or paste, in uniting different surfaces, or mortar, in building with bricks; it is also well shown at the lecture table by means of a pair of scales, one scale-pan of which being well cleaned with alkali at the bottom, may then be rested on the surface of water contained in a plate; the adhesion between the water and the metal is so perfect, that many grain weights may be placed in the other pan before the adhesion is broken; and after breakage, if the pan be again placed on the water, and a few grains removed from the other, so as to adjust the two pans, and make them nearly equal, a drop of oil of turpentine being added, instantly spreads itself over the water, and breaking the adhesion between the latter and the metal, the scale-pan is immediately and again broken away, as the adhesion between the turpentine and the metal is not so great as that of water and metal. The adhesion of air and water is well displayed in an apparatus recommended for ventilating mines, in which a constant descending stream of water carries with it a quantity of air, which being disengaged, is then forced out of a proper orifice. The same kind of adhesion between air and water is displayed in the ancient Spanish Catalan forge, where the blast is supplied to the iron furnace on a similar principle, only, a natural cascade is taken advantage of instead of an artificial fall of water through a pipe.

The adhesion of air and water becomes of some value when a river flows through a large and crowded city, because the water in its passage to and fro, must necessarily drag with it, a continuous column of air, and assist in maintaining that constant agitation of the air which is desirable as a preventive to any accumulation of noxious air charged with fœtid odours, arising from mud banks or from other causes. The fact of adhesion, existing between water and air, is readily shown, by resting one end of a long glass tube, of at least one inch diameter, on a block of wood one foot high. If water is allowed to flow down the tube, so as to leave a sufficient space of air above it, the adhesion between the two ancient elements becomes apparent, directly a little smoke is produced, near the top end of the glass tube resting on the block of wood. The smoke, which has a greater tendency to rise than to fall, is dragged down the glass tube, and accompanies the water as it flows from the higher to the lower level. The same truth is also illustrated in horizontal troughs or tubes through which water is caused to flow.

The adhesion between air and glass is so great, that it is absolutely necessary to boil the mercury in the tubes of the best barometers; and if this is not carefully attended to, the adhering air between the glass and mercury gradually ascends to, and destroys, the Torricellian vacuum at the top of the barometer tube. Even after the mercury is boiled, the air will creep up in course of years; and in order to prevent its passage between the glass and quicksilver, it has been recommended, that a platinum ring should be welded on to the end of the glass tube, because mercury has the power of wetting or enfilming the metal platinum, and the two being in close contact, would, as it were, shut the only door by which the air could enter the barometer tube.

Fig. 81.

Model of the apparatus for drawing down air. a, cistern of water, supplied by ball-cock, and kept at one level, so that the water just runs down the sides of the tube, and draws down the air in the centre, b c. The vessel to which the air and water are conveyed by a gutta-percha tube, t. There is another ball-cock to permit the waste water to run away when it reaches a certain level; the end of the pipe always dips some inches into this water, whilst the air escapes from the jet, d.

CHAPTER VIII.

CAPILLARY ATTRACTION.

This kind of attraction is termed capillary, in consequence of tubes, of a calibre, or bore, as fine as hair, attracting and retaining fluids.

If water is poured into a glass, the surface is not level, but cupped at the edges, where the solid glass exerts its adhesive attraction for the liquid, and draws it from the level. If the glass be reduced to a very narrow tube, having a hair-like bore, the attraction is so great that the water is retained in the tube, contrary to the force of gravitation. Two pieces of flat glass placed close together, and then opened like a book, draw up water between them, on the same principle. A mass of salt put on a plate containing a little water coloured with indigo displays this kind of attraction most perfectly, and the water is quickly drawn up, as shown by the blue colour on the salt. A little solution of the ammonio-sulphate of copper imparts a finer and more distinct blue colour to the salt. A piece of dry Honduras mahogany one inch square, placed in a saucer containing a little turpentine, is soon found to be wet with the oil at the top, which may then be set on fire.

Almost every kind of wood possesses capillary tubes, and will float, on account of these minute vessels being filled with air; if, however, the air is withdrawn, then the wood sinks, and by boiling a ball made of beech wood in water, and then placing it under the vacuum of an air pump in other cold water, it becomes so saturated with water that it will no longer float. A remarkable instance of the same kind is mentioned by Scoresby, in which a boat was pulled down by a whale to a great depth in the ocean, and after coming to the surface it was found that the wood would neither swim nor burn, the capillary pores being entirely filled with salt water.

A piece of ebony sinks in water on account of its density, closeness, and freedom from air. A gauge made of a piece of oak, with a hole bored in it of one inch diameter, accurately receives a dry plug of willow wood which will not enter the orifice after it is wetted. Millstones are split by inserting wedges of dry hard wood, which are afterwards wetted and swelled, and burst the stone asunder. One of the most curious instances of capillary attraction is shown in the currying of leather, a process which is intended to impart a softness and suppleness to the skin, in order that it may be rendered fit for the manufacture of boots, harness, machine bands, &c. The object of the currier is to fill the pores of the leather with oil, and as this cannot be done by merely smearing the surface, he prepares the way for the oil by wetting the leather thoroughly with water, and whilst the skin is damp, oil is rubbed on, and it is then exposed to the air; the water evaporates at ordinary temperatures, but oil does not; the consequence is that the pores of the leather give up the water, which disappears in evaporation, and the oil by capillary attraction is then drawn into the body of the leather, the oil in fact takes the place vacated by the water, and renders the material very supple, and to a considerable extent waterproof. In paper making, the pores of this material, unless filled up or sized, cause the ink to blot or spread by capillary attraction. The porosity of soils is one of the great desideratums of the skilful agriculturist, and drainage is intended to remove the excess of water which would fill the pores of the earth, to the exclusion of the more valuable dews and rains conveying nutritious matter derived from manures and the atmosphere.

A cane is an assemblage of small tubes, and if a piece of about six inches in length (cut off, of course, from the joints) be placed in a bottle of turpentine, the oil is drawn up and may be burnt at the top; it is on this principle that indestructible wicks of asbestos, and wire gauze rolled round a centre core, are used in spirit lamps. Oil, wax, and tallow, all rise by capillary attraction in the wicks to the flame, where they are boiled, converted into gas, and burnt.

Fig. 82.

Geber's filter. a. The solution of acetate of lead. b. The dilute sulphuric acid. c. The clear liquid, separated from the sulphate of lead in b.

The capillary attraction of skeins of cotton for water was known and appreciated by the old alchemists; and Geber, one of the most ancient of these pioneers of science, and who lived about the seventh century, describes a filter by which the liquid is separated from the solid. This experiment is well displayed by putting a solution of acetate of lead into a glass, which is placed on the highest block of a series of three, arranged as steps. Into this glass is placed the short end of a skein of lamp cotton, previously wetted with distilled water; the long end dips into another glass below, containing dilute sulphuric acid, and as the solution of lead passes into it, a solid white precipitate of sulphate of lead is formed; then another skein of wetted cotton is placed in this glass, the long end of which passes into the last glass, so that the clear liquid is separated and the solid left behind. (Fig. 82.)

Fig. 83.

Prawn syphon.

In this filter the lamp cotton acts as a syphon through the capillary pores which it forms. On the same principle, a prawn may be washed in the most elegant manner (as first shown by the late Duke of Sussex), by placing the tail, after pulling off the fan part, in a tumbler of water, and allowing the head to hang over, when the water is drawn up by capillary attraction, and continues to run through the head. (Fig. 83.)

The threads of which linen, cotton, and woollen cloths are made are small cords, and the shrinkage of such textile fabrics, is well known and usually inquired about, when a purchase is made; here again capillary attraction is exerted, and the fabric contracts in the two directions of the warp and woof threads; thus, twenty-seven yards of common Irish linen will permanently shrink to about twenty-six yards in cold water. In these cases the water is attracted into the fibres of the textile material, and causing them to swell, must necessarily shorten their length, just as a dry rope strained between two walls for the purpose of supporting clothes, has been known to draw the hooks after being suddenly wetted and shortened by a shower of rain.

In order to tighten a bandage, it is only necessary to wind the dry linen round the limbs as close as possible, and then wet it with water, when the necessary shrinkage takes place.

If a piece of dry cotton cloth is tied over one end of a lamp glass, the other may be thrust into, or removed from the basin of water very easily, but when the cotton is wetted, the fibres contract and prevent air from entering, so that the glass retains water just as if it were an ordinary gas jar closed with a glass stopper.

Fig. 84.

a. Basin of water. b. Cylinder of wire gauze closed at both ends with gauze. When full of water it may be lifted from the basin by the handle, c.

A Spanish proverb, expressing contempt, says, "go to the well with a sieve," but even this seeming impossibility is surmounted by using a cylinder of wire gauze, which may be filled with water, and by means of the capillary attraction between the meshes of the copper-wire gauze and the water, the whole is retained, and may be carefully lifted from a basin of water; the experiment only succeeds when the air is completely driven out of the interstices of the gauze, and the little cylinder completely filled with water; this may be done by repeatedly sinking and drawing out the cylinder, or still more effectually, by first wetting it with alcohol and then dipping the cylinder in water.

A balloon, made of cotton cloth, cannot be inflated by means of a pair of bellows, but if the balloon is wetted with water, then it may be swelled out with air just as if it had been made of some air-tight material; hence the principle of varnishing silk or filling the pores with boiled oil, when it is required in the manufacture of balloons.

Biscuit ware, porous tubes for voltaic batteries, alcarrazas, or water coolers, are all examples of the same principle.

Whilst speaking most favourably of the benevolent labours of many gentlemen (beginning with Mr. Gurney) who have erected "Drinking Fountains" in London's dusty atmosphere and crowded streets, it must not be forgotten that pious Mohammedans have, in bygone times, already set us the example in this respect; and in the palmy days of many of the Moorish cities, the thirsty citizen could always be refreshed by a draught of cool water from the porous bottles provided and endowed by charitable Mussulmans, and placed in the public streets.

Fig 85.

Moorish niche and porous earthenware bottle, containing water.

CHAPTER IX.

CRYSTALLIZATION.

Fig. 86.

Crystals of snow.

It has been already stated that the force of cohesion binds the similar particles of substances together, whether they be amorphous or shapeless, crystalline or of a regular symmetrical and mathematical figure. The term crystal was originally applied by the ancients to silica in the form of what is usually termed rock crystal, or Brazilian pebble; and they supposed it to be water which had been solidified by a remarkable intensity of cold, and could not be thawed by any ordinary or summer heat. Indeed, this idea of the ancients has been embodied (to a certain extent) in the shape of artificial ice made by crystallizing large quantities of sulphate of soda, which was made as flat as possible, and upon which skaters were invited to describe the figure of eight, at the usual admittance fee, representing twelve pence. A crystal is now defined to be an inorganic body, which, by the operation of affinity, has assumed the form of a regular solid terminated by a certain number of planes or smooth surfaces.

Thousands of minerals are discovered in the crystallized state—such as cubes of iron pyrites (sulphuret of iron) and of fluor spar (fluoride of calcium), whilst numerous saline bodies called salts are sold only in the form of crystals. Of these salts we have excellent examples in Epsom salts (sulphate of magnesia), nitre (nitrate of potash), alum (sulphate of alumina), and potash; the term salt being applied specially to all substances composed of an acid and a base, as also to other combinations of elements which may or may not take a crystalline form. Thus, nitre is composed of nitric acid and potash; the first, even when much diluted, rapidly changes paper, dipped in tincture of litmus and stained blue, to a red colour, whilst potash shows its alkaline nature, by changing paper, stained yellow with tincture of turmeric, to a reddish-brown. The latter paper is restored to its original yellow by dipping it into the dilute nitric acid, whilst the litmus paper regains its delicate blue colour by being passed into the alkaline solution. An acid and an alkali combine and form a neutral salt, such as nitre, which has no action whatever on litmus or turmeric; whilst the element iodine, which is not an acid, unites with the metallic element potassium, and therefore not an alkali, and forms a salt that crystallizes in cubes called iodide of potassium. Again, cane sugar, which is composed of charcoal, oxygen, and hydrogen, crystallizes in hard transparent four-sided and irregular six-sided prisms, but is not called a salt. Silica or sand is found crystallized most perfectly in nature in six-sided pyramids, but is not a salt; it is an acid termed silicic-acid. Sand has no acid taste, because it is insoluble in water, but when melted in a crucible with an alkali, such as potash, it forms a salt called silicate of potash. Magnesia, from being insoluble, or nearly so, in water, is all but tasteless, and has barely any alkaline reaction, yet it is a very strong alkaline base; 20.7 parts of it neutralize as much sulphuric acid as 47 of potash. A salt is not always a crystallizable substance, and vice versa. The progress of our chemical knowledge has therefore demanded a wider extension and application of the term salt, and it is not now confined merely to a combination of an acid and an alkali, but is conferred even on compounds consisting only of sulphur and a metal, which are termed sulphur salts.

So also in combinations of chlorine, iodine, bromine, and fluorine, with metallic bodies, neither of which are acid or alkaline, the term haloid salts has been applied by Berzelius, from the Greek ( αλς, sea salt, and ειδος form), because they are analogous in constitution to sea salt; and the mention of sea salt again reminds us of the wide signification of the term salt, originally confined to this substance, but now extended into four great orders, as defined by Turner:—

Order I. The oxy-salts.—This order includes no salt the acid or base of which is not an oxidised body (ex., nitrate of potash).

Order II. The hydro-salts.—This order includes no salt the acid or base of which does not contain hydrogen (ex., chloride of ammonium).

Order III. The sulphur salts.—This order includes no salt the electro-positive or negative ingredient of which is not a sulphuret (ex., hydrosulphuret of potassium).

Order IV. The haloid salts.—This order includes no salt the electro-positive or negative ingredient of which is not haloidal. (Exs., iodide of potassium and sea salt). To fix the idea of salt still better in the youthful mind, it should be remembered that alabaster, of which works of art are constructed, or marble, or lime-stone, or chalk, are all salts, because they consist of an acid and a base.

In order to cause a substance to crystallize it is first necessary to endow the particles with freedom of motion. There are many methods of doing this chemically or by the application of heat, but we cannot by any mechanical process of concentration, compression, or division, persuade a substance to crystallize, unless perhaps we except that remarkable change in wrought or fibrous iron into crystalline or brittle iron, by constant vibration, as in the axles of a carriage, or by attaching a piece of fibrous iron to a tilt hammer.

If we powder some alum crystals they will not again assume their crystalline form; if brought in contact there is no freedom of motion. It is like placing some globules of mercury on a plate. They have no power to create motion; their inertia keeps them separated by certain distances, and they do not coalesce; but incline the plate, give them motion, and bring them in contact, they soon unite and form one globule. The particles of alum are not in close contact, and they have no freedom of motion unless they are dissolved in water, when they become invisible; the water by its chemical power destroys the mechanical aggregation of the solid alum far beyond any operation of levigation. The solid alum has become liquid, like water; the particles are now free to move without let or hindrance from friction. A solution, (from the Latin solvo, to loosen) is obtained. The alum must indeed be reduced to minute particles, as they are alike invisible to the eye whether assisted by the microscope or not. No repose will cause the alum to separate; the solvent power of the water opposes gravitation; every part of the solution is equally impregnated with alum, and the particles are diffused at equal distances through the water; the heavy alum is actually drawn up against gravity by the water.

How, then, is the alum to be brought back again to the solid state? The answer is simple enough. By evaporating away the excess of water, either by the application of heat or by long exposure to the atmosphere in a very shallow vessel, the minute atoms of the alum are brought closer together, and crystallization takes place. The assumption of the solid state is indicated by the formation of a thin film (called a pellicle) of crystals, and is further and still more satisfactorily proved by taking out a drop of the solution and placing it on a bit of glass, which rapidly becomes filled with crystals if the evaporation has been carried sufficiently far (Fig. 87).

After evaporating away sufficient water, the dish is placed on one side and allowed to cool, when crystals of the utmost regularity of form are produced, and, denoted by a geometrical term, are called octohedral or eight-sided crystals, when in the utmost state of perfection (Fig. 88).

Fig. 87.

r r. Ring-stand. s s. Spirit-lamps. a. Flask containing boiling solution of alum.—Solution. b. Funnel, with a bit of lamp-cotton stuffed in the bottom.—Filtration. c. Evaporating dish.—Evaporation. d. Drop on glass.—Crystallization.

Fig. 88.

The science of crystallography is too elaborate to be discussed at length in a work of this kind; the various terms connected with crystals will therefore only be explained, and experiments given in illustration of the formation of various crystals.

When the apices—i.e., the tips or points of crystals—are cut off, they are said to be truncated; and the same change occurs on the edges of numerous crystals.

If some of the salt called chloride of calcium in the dry and amorphous state is exposed to the air, it soon absorbs water, or what is termed deliquesces: the same thing occurs with the crystals of carbonate of potash, and if four ounces are weighed out in an evaporating dish, and then exposed for about half an hour to the air, a very perceptible increase in weight is observed by the assistance of the scales and grain weights. Deliquescence is a term from the Latin deliqueo, to melt, and is in fact a gradual melting, caused by the absorption of water from the atmosphere. The reverse of this is illustrated with various crystals, such as Glauber's salt (sulphate of soda), or common washing soda (carbonate of soda); if a fine clear crystal is taken out of the solution, called the mother liquor, in which it has been crystallized, wiped dry, and placed under a glass shade, this salt may remain for a long period without change, but if it receive one scratch from a pin, the door is opened apparently for the escape of the water which it contains, chemically united with the salt, and called water of crystallization; the white crystal gradually swells out, the little quasi sore from the pin-scratch spreads over the whole, which becomes opaque, and crumbling down falls into a shapeless mass of white dust; this change is called efflorescence, from effloresco, to blow as a flower—caused by the abstraction from them of chemically-combined water by the atmosphere. With reference to the preservation of crystals, Professor Griffiths recommends them to be oiled and wiped, and placed under a glass shade, if of a deliquescent nature; or if efflorescent, they are perfectly preserved by placing them under a glass shade with a little water in a cup to keep the air charged with moisture and prevent any drying up of the crystal.

Deliquescent crystals may be preserved by placing them, when dry, in naphtha, or any liquor in which they are perfectly insoluble. Some salts, like Glauber's salts, contain so much water of crystallization that when subjected to heat they melt and dissolve in it, and this liquefaction of the solid crystal is called "watery fusion." Other salts, such as bay salt, chlorate of potash, &c., when heated, fly to pieces, with a sharp crackling noise, which is due sometimes, to the unequal expansion of the crystalline surface, or the sudden conversion of the water (retained in the crystal by capillary attraction) into steam; thus nitre behaves in this manner, and frequently retains water in capillary fissures, although it is an anhydrous salt, or salt perfectly free from combined water. The crackling sound is called decrepitation, and is well illustrated by throwing a handful of bay salt on a clear fire; but this property is destroyed by powdering the crystals.

Many substances when melted and slowly cooled concrete into the most perfect crystals; in these cases heat alone, the antagonist to cohesion, is the solvent power. Thus, if bismuth be melted in a crucible, and when cooling, and just as the pellicle (from pellis, a skin or crust) is forming on the surface, if two small holes are instantly made by a rod of iron and the liquid metal poured out from the inside (one of the holes being the entrance for the air, the other the exit for the metal); on carefully breaking the crucible, the bismuth is found to be crystallized in the most lovely cubes. Sulphur, again, may be crystallized in prismatic crystals by pursuing a similar plan; and the great blocks of spermaceti exhibited by wax chandlers in their windows, are crystallized in the interior and prepared on the same principle.

There are other modes of conferring the crystalline state upon substances—viz., by elevating them into a state of vapour by the process called sublimation (from sublimis, high or exalted), the lifting up and condensation of the vapour in the upper part of a vessel; a process perfectly distinct from that of distillation, which means to separate drop by drop. Both of these processes are very ancient, and were invented by the Arabian alchemists long antecedent to the seventh century. Examples of sublimation are shown by heating iodine, and especially benzoic acid; with the latter, a very elegant imitation of snow is produced, by receiving the vapour, on some sprigs of holly or other evergreen, or imitation paper snowdrops and crocuses, placed in a tasteful manner under a glass vessel. The benzoic acid should first be sublimed over the sprigs or artificial flowers in a gas jar, which may be removed when the whole is cold, and a clear glass shade substituted for it. (Fig. 89.)

Fig. 89.

a. Gas-jar, with stopper open at first, to be shut when the lamp is withdrawn. b. Wooden stand, with hole to carry the cup c, containing the benzoic acid, heated below by the spirit-lamp, s. f. Flowers or sprigs arranged on pieces of rock or mineral.

All electro deposits on metals are more or less crystalline; and copper or silver may be deposited in a crystalline form by placing a scraped stick of phosphorus in a solution of sulphate of copper or of nitrate of silver. The phosphorus takes away the oxygen from the metal, or deoxidizes the solution, and the copper or silver reappears in the metallic form. The surface of the phosphorus must not be scraped in the air, but under water, when the operation is perfectly safe.

A singular and almost instantaneous crystallization can be produced by saturating boiling water with Glauber's salt, of which one ounce and a half of water will usually dissolve about two ounces; having done this, pour the solution, whilst boiling hot, into clean oil flasks, or vials of any kind, previously warmed in the oven, and immediately cork them, or tie strips of wetted bladder, over the orifices of the flasks or vials, or pour into the neck a small quantity of olive oil, or close the neck with a cork through which a thermometer tube has been passed. When cold, no crystallization occurs until atmospheric air is admitted; and it was formerly believed that the pressure of the air effected this object, until some one thought of the oil, and now the theory is modified, and crystallization is supposed to occur in consequence of the water dissolving some air which causes the deposit of a minute crystal, and this being the turning point, the whole becomes solid. However the fact may be explained, it is certain that when the liquid refuses to crystallize on the admission of air, the solidification occurs directly a minute crystal of sulphate of soda, or Glauber's salt, is dropped into the vessel.

When the crystallization is accomplished, the whole mass is usually so completely solidified, that on inverting the vessel, not a drop of liquid falls out.

It may be observed that the same mass of salt will answer any number of times the same purpose. All that is necessary to be done, is to place the vial or flask, in a saucepan of warm water, and gradually raise it to the boiling point till the salt is completely liquefied, when the vessel must be corked and secured from the air as before. When the solidification is produced much heat is generated, which is rendered apparent by means of a thermometer, or by the insertion of a copper wire into the pasty mass of crystal in the flask, and then touching an extremely thin shaving or cutting of phosphorus, dried and placed on cotton wool. Solidification in all cases produces heat. Liquefaction produces cold.

Fig. 90.

a. The inner cylinder which contains the freezing mixture. b b. The outer one containing spring water. c c. The ice slipping away from the inner cylinder.

In Masters's freezing apparatus certain measured quantities of crystallized sal-ammoniac, nitre, and nitrate of ammonia, are placed in a metallic cylinder, surrounded with a small quantity of spring water contained in an outer vessel. Directly the crystals are liquefied by the addition of water, intense cold is produced, which freezes the water and forms an exact cast of the inner cylinder in ice, and this may afterwards be removed, by pouring away the liquefied salts, and filling the inner cylinder, with water of the same temperature as the air, which rapidly thaws the surrounding ice, and allows it to slip off into any convenient vessel ready to receive it. (Fig. 90.)

For an ingenious method of obtaining large and perfect crystals of almost any size, experimentalists are indebted to Le Blanc. His method consists in first procuring small and perfect crystals—say, octohedra of alum—and then placing them in a broad flat-bottomed pan, he pours over the crystals a quantity of saturated solution of alum, obtained by evaporating a solution of alum until a drop taken out crystallizes on cooling. The positions of the crystals are altered at least once a day with a glass rod, so that all the faces may be alternately exposed to the action of the solution, for the side on which the crystal rests, or is in contact with the vessel, never receives any increment. The crystals will thus gradually grow or increase in size, and when they have done so for some time, the best and most symmetrical, may be removed and placed separately, in vessels containing some of the same saturated solution of alum, and being constantly turned they may be obtained of almost any size desired.

Unless the crystals are removed to fresh solutions, a reaction takes place, in consequence of the exhaustion of the alum from the water, and the crystal is attacked and dissolved. This action is first perceptible on the edges and angles of the crystal; they become blunted and gradually lose their shape altogether. By this method crystals may be made to grow in length or breadth—the former when they are placed upon their sides, the latter if they be made to stand upon their bases.

On Le Blanc's principle, beautiful crystal baskets are made with alum, sulphate of copper, and bichromate of potash. The baskets are usually made of covered copper wire, and when the salts crystallize on them as a nucleus or centre, they are constantly removed to fresh solutions, so that the whole is completely covered, and red, white, and blue sparkling crystal baskets formed. They will retain their brilliancy for any time, by placing them under a glass shade, with a cup containing a little water.

The sketch below affords an excellent illustration of some of Nature's remarkable concretions in the peculiar columnar structure of basalt.

Fig. 91.

The Giant's Causeway.

CHAPTER X.

CHEMISTRY.

Fig 92

Alchemists at work

There is hardly any kind of knowledge which has been so slowly acquired as that of chemistry, and perhaps no other science has offered such fascinating rewards to the labour of its votaries as the philosopher's stone, which was to produce an unfailing supply of gold; or the elixir of life, that was to give the discoverer of the gold-making art the time, the prolonged life, in which he might spend and enjoy it.

Hundreds of years ago Egypt was the great depository of all learning, art, and science, and it was to this ancient country that the most celebrated sages of antiquity travelled.

Hermes, or Mercurius Trismegistus, the favourite minister of the Egyptian king Osiris, has been celebrated as the inventor of the art of alchemy, and the first treatise upon it has been attributed to Zosymus, of Chemnis or Panopolis. The Moors who conquered Spain were remarkable for their learning, and the taste and elegance with which they designed and carried out a new style of architecture, with its lovely Arabesque ornamentation. They were likewise great followers of the art of alchemy, when they ceased to be conquerors, and became more reconciled to the arts of peace. Strange that such a people, thirsting as they did in after years for all kinds of knowledge, should have destroyed, in the persons of their ancestors, the most numerous collection of books that the world had ever seen: the magnificent library of Alexandria, collected by the Ptolemies with great diligence and at an enormous expense, was burned by the orders of Caliph Omar; whilst it is stated that the alchemical works had been previously destroyed by Diocletian in the fourth century, lest the Egyptians should acquire by such means sufficient wealth to withstand the Roman power, for gold was then, as it is now, "the sinews of war."

Eastern historians relate the trouble and expense incurred by the succeeding Caliphs, who, resigning the Saracenic barbarism of their ancestors, were glad to collect from all parts the books which were to furnish forth a princely library at Bagdad. How the learned scholar sighs when he reads of seven hundred thousand books being consigned to the ignominious office of heating forty thousand baths in the capital of Egypt, and of the magnificent Alexandrian Library, a mental fuel for the lamp of learning in all ages, consumed in bath furnaces, and affording six months' fuel for that purpose. The Arabians, however, made amends for these barbarous deeds in succeeding centuries, and when all Europe was laid waste under the iron rule of the Goths, they became the protectors of philosophy and the promoters of its pursuits; and thus we come to the seventh century, in which Geber, an Arabian prince lived, and is stated to be the earliest of the true alchemists whose name has reached posterity.

Without attempting to fill up the alchemical history of the intervening centuries, we leap forward six hundred years, and now find ourselves in imagination in England, with the learned friar, Roger Bacon, a native of Somersetshire, who lived about the middle of the thirteenth century; and although the continual study of alchemy had not yet produced the "stone," it bore fruit in other discoveries, and Roger Bacon is said, with great appearance of truth, to have discovered gunpowder, for he says in one of his works:—"From saltpetre and other ingredients we are able to form a fire which will burn to any distance;" and again alluding to its effects, "a small portion of matter, about the size of the thumb, properly disposed, will make a tremendous sound and coruscation, by which cities and armies might be destroyed." The exaggerated style seems to have been a favourite one with all philosophers, from the time of Roger Bacon to that of Muschenbroek of the University of Leyden, who accidentally discovered the Leyden jar in the year 1746, and receiving the first shock, from a vial containing a little water, into which a cork and nail had been fitted, states that "he felt himself struck in his arms, shoulders, and breast, so that he lost his breath, and was two days before he recovered from the effects of the blow and the terror;" adding, that "he would not take a second shock for the kingdom of France." Disregarding the numerous alchemical events occurring from the time of Roger Bacon, we again advance four hundred years—viz., to the year 1662, when, on the 15th of July, King Charles II. granted a royal charter to the Philosophical Society of Oxford, who had removed to London, under the name of the Royal Society of London for Promoting Natural Knowledge, and in the year 1665 was published the first number of the Philosophical Transactions; this work contains the successive discoveries of Mayow, Hales, Black, Leslie, Cavendish, Lavoisier, Priestley, Davy, Faraday; and since the year 1762 has been regularly published at the rate of one volume per annum. With this preface proceed we now to discuss some of the varied phenomena of chemical attraction, or what is more correctly termed

CHEMICAL AFFINITY.

The above title refers to an endless series of changes brought about by chemical combinations, all of which can be reduced to certain fixed laws, and admit of a simple classification and arrangement. A mechanical aggregation, however well arranged, can be always distinguished from a chemical one. Thus, a grain of gunpowder consists of nitre, which can be washed away with boiling water, of sulphur, which can be sublimed and made to pass away as vapour, of charcoal, which remains behind after the previous processes are complete; this mixture has been perfected by a careful proportion of the respective ingredients, it has been wetted, and ground, and pressed, granulated, and finally dried; all these mechanical processes have been so well carried out that each grain, if analysed, would be similar to the other; and yet it is, after all, only a mechanical aggregation, because the sulphur, the charcoal, and the nitre are unchanged. A grain of gunpowder moistened, crushed, and examined by a high microscopic power, would indicate the yellow particles of sulphur, the black parts of charcoal, whilst the water filtered from the grain of powder and dried, would show the nitre by the form of the crystal. On the other hand, if some nitre is fused at a dull red heat in a little crucible, and two or three grains of sulphur are added, they are rapidly oxidized, and combine with the potash, forming sulphate of potash; and after this change a few grains of charcoal may be added in a similar manner, when they burn brightly, and are oxidized and converted into carbonic acid, which also unites in like manner with the potash, forming carbonate of potash; so that when the fused nitre is cooled and a few particles examined by the microscope, the charcoal and sulphur are no longer distinguishable, they have undergone a chemical combination with portions of the nitre, and have produced two new salts, perfectly different in taste, gravity, and appearance from the original substances employed to produce them. Hence chemical combination is defined to be "that property which is possessed by one or more substances, of uniting together and producing a third or other body perfectly different in its nature from either of the two or more generating the new compound."

To return to our first experiment with the gunpowder: take sulphur, place some in an iron ladle, heat it over a gas flame till it catches fire, then ascend a ladder, and pour it gently, from the greatest height you can reach, into a pail of warm water: if this experiment is performed in a darkened room a magnificent and continuous stream of fire is obtained, of a blue colour, without a single break in its whole length, provided the ladle is gradually inclined and emptied. The substance that drops into the warm water is no longer yellow and hard, but is red, soft, and plastic; it is still sulphur, though it has taken a new form, because that element is dimorphous (δις twice, and μορφη a form), and, Proteus-like, can assume two forms. Take another ladle, and melt some nitre in it at a dull red heat, then add a small quantity of sulphur, which will burn as before; and now, after waiting a few minutes, repeat the same experiment by pouring the liquid from the steps through the air into water; observe it no longer flames, and the substance received into the water is not red and soft and plastic, but is white, or nearly so, and rapidly dissolves away in the water. The sulphur has united with the oxygen of the nitre and formed sulphuric acid, which combines with the potash and forms sulphate of potash; here, then, oxygen, sulphur, and potassium, have united and formed a salt in which the separate properties of the three bodies have completely disappeared; to prove this, it is only necessary to dissolve the sulphate of potash in water, and after filtering the solution, or allowing it to settle, till it becomes quite clear and bright, some solution of baryta may now be added, when a white precipitate is thrown down, consisting of sulphate of baryta, which is insoluble in nitric or other strong acids. The behaviour of a solution of sulphate of potash with a nitrate of baryta may now be contrasted with that of the elements it contains; on the addition of sulphur to a solution of nitrate of baryta no change whatever takes place, because the sulphur is perfectly insoluble. If a stream of oxygen gas is passed from a bladder and jet through the same test, no effect is produced; the nitrate of baryta has already acquired its full proportion of oxygen, and no further addition has any power to change its nature; finally, if a bit of the metal potassium is placed in the solution of nitrate of baryta it does not sink, being lighter than water, and it takes fire; but this is not in any way connected with the presence of the test, as the same thing will happen if another bit of the metal is placed in water—it is the oxygen of the latter which unites rapidly with the potassium, and causes it to become so hot that the hydrogen, escaping around the little red-hot globules, takes fire; moreover, the fact of the combustion of the potassium under such circumstances is another striking proof of the opposite qualities of the three elements—sulphur, oxygen, and potassium—as compared with the three chemically combined and forming sulphate of potash. The same kind of experiment may be repeated with charcoal; if some powdered charcoal is made red-hot, and then puffed into the air with a blowing machine, numbers of sparks are produced, and the charcoal burns away and forms carbonic acid gas, a little ash being left behind; but if some more nitre be heated in a ladle, and charcoal added, a brilliant deflagration (deflagro, to burn) occurs, and the charcoal, instead of passing away in the air as carbonic acid, is now retained in the same shape, but firmly and chemically united with the potash of the nitre, forming carbonate of potash, or pearl-ash, which is not black and insoluble in water and acids like charcoal, but is white, and not only soluble in water, but is most rapidly attacked by acids with effervescence, and the carbon escapes in the form of carbonic acid gas. Thus we have traced out the distinction between mechanical aggregation and chemical affinity, taking for an example the difference between gunpowder as a whole (in which the ingredients are so nicely balanced that it is almost a chemical combination), and its constituents, sulphur, charcoal, and nitre, when they are chemically combined; or, in briefer language, we have noticed the difference between the mechanical mixture, and some of the chemical combinations, of three important elements. Our very slight and partial examination of three simple bodies does not, however, afford us any deep insight into the principles of chemistry; we have, as it were, only mastered the signification of a few words in a language; we might know that chien was the French for dog, or cheval horse, or homme man; but that knowledge would not be the acquisition of the French language, because we must first know the alphabet, and then the combination of these letters into words; we must also acquire a knowledge of the proper arrangement of these words into sentences, or grammar, both syntax and prosody, before we can claim to be a French scholar: so it is with chemistry—any number of isolated experiments with various chemical substances would be comparatively useless, and therefore the "alphabet of chemistry," or "table of simple elements," must first be acquired. These bodies are understood to be solids, fluids, and gases, which have hitherto defied the most elaborate means employed to reduce them into more than one kind of matter. Even pure light is separable into seven parts—viz., red, orange, yellow, green, blue, indigo, and violet; but the elements we shall now enumerate are not of a compound, but, so far as we know, of an absolutely simple or single nature; they represent the boundaries, not the finality, of the knowledge that may be acquired respecting them.

The elements are sixty-four in number, of which about forty are tolerably plentiful, and therefore common; whilst the remainder, twenty-four, are rare, and for that reason of a lesser utility: whenever Nature employs an element on a grand scale it may certainly be called common, but it generally works for the common good of all, and fulfils the most important offices.

CLASSIFICATION OF THE ALPHABET OF CHEMISTRY.

13 Non-Metallic Bodies.

(N.B. The elements printed in italics are at present unimportant.)

[A] From the mineral Wolfram, and now exceedingly valuable, as when alloyed with iron it is harder than, and will bore through steel.

A few words will suffice to explain the meaning of the terms which head the names, letters, and numbers of the Table of Elements. The names of the elements have very interesting derivations, which it is not the object of this work to go into; the symbols are abbreviations, ciphers of the simplest kind, to save time and trouble in the frequent repetition of long words, just as the signs + plus, and - minus, are used in algebraic formulæ. For instance—the constant recurrence of water in chemical combinations must be named, and would involve the most tedious repetition; water consists of oxygen and hydrogen, and by taking the first letter of each word we have an instructive symbol, which not only gives us an abbreviated term for water, but also imparts at once a knowledge of its composition by the use of the letters, HO.

Again, to take a more complex example, such as would occur in the study of organic chemistry—a sentence such as the hydrated oxide of acetule, is written at once by C₄H₄O₂, the figures referring to the number of equivalents of each element—viz., 4 equivalents of C, the symbol for carbon, 4 of H (hydrogen), and 2 of O (oxygen).

The long word paranaphthaline, a substance contained in coal tar, is disposed of at once with the symbols and figures C₃₀H₁₂.

The figures in the third column are, however, the most interesting to the precise and mathematically exact chemist. They represent the united labours of the most painstaking and learned chemists, and are the exact quantities in which the various elements unite. To quote one example: if 8 parts by weight of oxygen—viz., the combining proportions of that element—are united with 1 part by weight of hydrogen, also its combining number, the result will be 9 parts by weight of water; but if 8 parts of oxygen and 2 parts of hydrogen were used, one only of the latter could unite with the former, and the result would be the formation again of 9 parts of water, with an overplus of 1 equivalent of hydrogen.

It is useless to multiply examples, and it is sufficient to know that with this table of numbers the figures of analysis are obtained. Supposing a substance contained 27 parts of water, and the oxygen in this had to be determined, the rule of proportion would give it at once, 9: 27:: 8: 24. 9 parts of water are to 27 parts as 8 of oxygen (the quantity contained in 9 parts of water) are to the answer required—viz., 24 of oxygen. The names, symbols, and combining proportions being understood, we may now proceed with the performance of many interesting

CHEMICAL EXPERIMENTS.

As the permanent gases head the list, they will first engage our attention, beginning with the element oxygen—Symbol O, combining proportion 8. There is nothing can give a better idea of the enormous quantity of oxygen present in the animal, vegetable, and mineral kingdoms, than the statement that it represents one-third of the weight of the whole crust of the globe. Silica, or flint, contains about half its weight of oxygen; lime contains forty per cent.; alumina about thirty-three per cent. In these substances the element oxygen remains inactive and powerless, chained by the strong fetters of chemical affinity to the silicium of the flint, the calcium of the lime, and the aluminum of the alumina. If these substances are heated by themselves they will not yield up the large quantity of oxygen they contain.

Nature, however, is prodigal in her creation, and hence we have but to pursue our search diligently to find a substance or mineral containing an abundance of oxygen, and part of which it will relinquish by what used to be called by the "old alchemists" the torture of heat. Such a mineral is the black oxide of manganese, or more correctly the binoxide of manganese, which consists of one combining proportion of the metal manganese—viz., 27.6, and two of oxygen—viz., 8 × 2 = 16. If three proportions of the binoxide of manganese are heated to redness in an iron retort, they yield one proportion (equal to 8) of oxygen, and all that has just been explained by so many words is comprehended in the symbols and figures below:—

3 MnO₂ = Mn₃O₄ + O.

Thus the 3 MnO₂ represent the three proportions of the binoxide of manganese before heat is applied, whilst the sign =, the sign of equation (equal to), is intended to show that the elements or compounds placed before it produce those which follow it; hence the sequel Mn₃O₄ + O shows that another compound of the metal and oxygen is produced, whilst the + O indicates the liberated oxygen gas. The iron retort employed to hold the mineral should be made of cast iron in preference to wrought iron, as the latter is very soon worn out by contact with oxygen at a red heat. A gun-barrel will answer the purpose for an experiment on the small scale, to which must be adapted a cock and piece of pewter tubing. Such a make-shift arrangement may do very well when nothing better offers; but as a question of expense, it is probably cheaper in the end to order of Messrs. Simpson and Maule, or of Messrs. Griffin, or of Messrs. Bolton, a cast-iron bottle, or cast-iron retort, as it is termed, of a size sufficient to prepare two gallons of oxygen from the binoxide of manganese, which, with four feet of iron conducting-pipe, and connected to the bottle with a screw, does not cost more than six shillings—an enormous dip, perhaps, in the juvenile pocket, and therefore we shall indicate presently a still cheaper apparatus for the same purpose. (Fig. 93.)

Fig. 93.

a. The iron bottle, containing the black oxide of manganese, with pipe passing to the pneumatic trough, b b, in which is fixed a shelf, c, perforated with a hole, under which the end of the pipe is adjusted, and the gas passes into the gas-jar, d.

The oxygen is conveyed to a square tin box provided with a shelf at one end, perforated with several holes at least one inch in diameter, called the pneumatic trough; any wooden trough, butter or wash-tub, foot-pan or bath, provided with a shelf, may be raised by the same title to the dignity of a piece of chemical apparatus. The gas jar must be filled with water by withdrawing the stopper and pressing it down into the trough, and when the neck is below the level of the water, the stopper is again inserted, and the jar with the water therein contained lifted steadily on to the shelf, the entry of atmospheric air being prevented by keeping the lower part of the gas jar, called the welt, under the water. Sometimes the pneumatic trough contains so small a quantity of water that on raising the gas jar to the shelf the liquid does not cover the bottom, and the air rushes up in large bubbles. Under these circumstances it is better to provide a gallon stone jug full of water, so that when the jar is being raised to the shelf it may be thrust into the trough (on the same principle as the crow and the pitcher in the fable), and thus by its bulk (as the stones in the pitcher) raise the water to the proper level. When the gas jar is about half filled with gas the jug may be withdrawn. This arrangement saves the trouble of constantly adding and baling out water from the pneumatic trough. (Fig. 94.)

Fig. 94.

a a. Pneumatic trough, with gas jar raised to shelf; bubbles of air are rushing in at b, as the level of the water is below the shelf—viz., at c c. d d. Same trough and gas jar with water kept over the shelf by the introduction of the stone pitcher e, full of water.

There are other solid oxygenized bodies in which the affinities are less powerful, and hence a lower degree of heat suffices to liberate the oxygen gas, and one of the most useful in this respect is the salt termed chlorate of potash. If the substance is heated by itself, the temperature required to expel the oxygen is almost as high as that demanded for the black oxide of manganese; but, strange to say, if the two substances are reduced to powder, and mixed in equal quantities by weight, then a very moderate increase of heat is sufficient to cause the chlorate of potash to give up its oxygen, whilst the oxide of manganese undergoes no change whatever. It seems to fulfil only a mechanical office—possibly that of separating each particle of chlorate of potash from the other, so that the heat attacks the substance in detail, just as a solid square of infantry might repel almost any attack, whilst the same body dispersed over a large space might be of little use; so with the chlorate of potash, which undergoes rapid decomposition when mixed with and divided amongst the particles of the oxide of manganese; less so with the red oxide of iron, and still less with sand or brick-dust. (Fig. 95.)

Fig. 95.

Preparation of oxygen from chlorate of potash and oxide of manganese.

KO.ClO₅ = KCl + O₆.

This curious fact is explained usually by reference to what is called catalytic action, or decomposition by contact (κατα, downwards, and λυω, I unloosen), being a power possessed by a body of resolving another into a new compound without undergoing any change itself. To make this term still clearer, we may notice another example in linen rags, which may be exposed for any length of time to the action of water without fear of conversion into sugar; if, however, oil of vitriol is first added to the linen rags, and they are subsequently digested at a proper temperature with water, then the rags are converted into sugar (the author has seen a specimen made of an "old shirt"); but, curious to relate, the oil of vitriol is unchanged in the process, and if the process be commenced with a pound of acid, the same quantity is discoverable at the end of the chemical decomposition of the linen rags, and their conversion into sugar.

If a mixture of equal parts of oxide of manganese and chlorate of potash is placed in a clean Florence flask, with a cork, and pewter, or glass tube attached, great quantities of oxygen are quickly liberated, on the application of the heat of a spirit lamp. Such a retort would cost about fourpence, and if the flask is broken in the operation it can be easily replaced by another, value one penny, as the same cork and tube will generally suit a number of these cheap glass vessels. Corks may always be softened by using either a proper cork squeezer, or by placing them under a piece of board or a flat surface, and rolling and pressing the cork till quite elastic.

Whilst fitting the latter into the neck of a flask, it is perhaps safer to hold the thin and fragile vessel in a cloth, so that if the flask breaks the chemical experiment may not be arrested for many days by the severe cutting and wounding of the fingers. After the cork is fitted, it is to be removed from the flask and bored with a cork borer. This useful tool is sold in complete sets to suit all sizes of glass tubes, and the pewter or glass being inserted, the flask and tube will be ready for use, provided the tube is bent to the proper curve. This is easy enough to perform with the pewter, but not quite so easy with the glass tube, which must be held over the flame of a spirit lamp till soft, and then bent very gradually to the proper curve. If a short length of the glass tube is heated, it bends too sharply, and the convexity of the glass is flattened, whilst the internal diameter of the tube is lessened, so that at least three inches in length should be warmed, and the heat must not be continued in one place only, but should be maintained in the direction of the bend, the whole manipulation being conducted without any hurry. (Fig. 96.)

Fig. 96.

a. The cork squeezer. b. The cork borers. c. The operation of bending the glass tube over the flame of the spirit-lamp. d. The neck of the flask, with cork and tube bent and fitted complete for use.

Having filled a gas jar with oxygen, it may be removed from the pneumatic trough by sliding it into a plate under the surface of the water, and to prevent the stopper being thrust out accidentally from the jar by the upward pressure of the gas, whilst a little compressed, during the act of passing it into the plate, it is advisable to hold the stopper of the jar firmly but gently, so that it cannot slip out of its place. A number of jars of oxygen may be prepared and arranged in plates, all of which of course must contain a little water, and enough to cover the welt of the jar.

EXPERIMENTS WITH OXYGEN GAS.

This gas was originally discovered by Priestley, in August, 1774, and was first obtained by heating red precipitate—i.e., the red oxide of mercury.

HgO = Hg + O.

We leave these symbols and figures to be deciphered by the youthful philosopher with the aid of the table of elements, &c., and return to the experiments.

There are certain thin wax tapers like waxed cord, called bougies, which can be bent to any shape, and are very convenient for experiments with the gases. If one of these tapers is bent as in Fig. 97, then lighted and allowed to burn for some minutes, a long snuff is gradually formed, which remains in a state of ignition when the flame of the taper is blown out. On plunging this into a jar of oxygen, it instantly re-lights with a sort of report, and burns with greatly-increased brilliancy, as described by Dr. Priestley in his first experiment with this gas, and so elegantly repeated by Professor Brande in his refined dissertation on the progress of chemical science.

Fig. 97.

"The 1st of August, 1774, is a red-letter day in the annals of chemical philosophy, for it was then that Dr. Priestley discovered dephlogisticated air. Some, sporting in the sunshine of rhetoric, have called this the birthday of pneumatic chemistry; but it was even a more marked and memorable period; it was then (to pursue the metaphor) that this branch of science, having eked out a sickly and infirm infancy in the ill-managed nursery of the early chemists, began to display symptoms of an improving constitution, and to exhibit the most hopeful and unexpected marks of future importance. The first experiment, which led to a very satisfactory result, was concluded as follows:—A glass jar was filled with quicksilver, and inserted in a basin of the same; some red precipitate of quicksilver was then introduced, and floated upon the quicksilver in the jar; heat was applied to it in this situation with a burning-lens, and to use Priestley's own words, I presently found that air was expelled from it very readily. Having got about three or four times as much as the bulk of my materials, I admitted water into it, and found that it was not imbibed by it. But what surprised me more than I can well express was, that a candle burned in this air with a remarkably vigorous flame, very much like that enlarged flame with which a candle burns in nitrous air exposed to iron or lime of sulphur (i.e., laughing gas); but as I had got nothing like this remarkable appearance from any kind of air besides this peculiar modification of nitrous air, and I knew no nitrous acid was used in the preparation of mercurius calcinatus, I was utterly at a loss how to account for it." (Fig. 98.)

Fig. 98.

a. Glass vessel full of mercury, containing the red precipitate at the top, and standing in the dish b, also containing mercury. c. The burning-glass concentrating the sun's rays on the red precipitate, being Priestley's original experiment.

Second Experiment.

The term oxygen is derived from the Greek (οζυς, acid, and γενναω, I give rise to), and was originally given to this element by Lavoisier, who also claimed its discovery; and if this honour is denied him, surely he has deserved equal scientific glory in his masterly experiments, through which he discovered that the mixture of forty-two parts by measure of azote, with eight parts by measure of oxygen, produced a compound precisely resembling our atmosphere. The name given to oxygen was founded on a series of experiments, one of which will now be mentioned.

Fig. 99.

a. The deflagrating spoon, b. The cork. c. The zinc, or brass, or tin plate. d d. The gas jar.

Place some sulphur in a little copper ladle attached to a wire, and called a deflagrating spoon, passed through a round piece of zinc or brass plate and cork, so that the latter acts as an adjusting arrangement to fix the wire at any point required. The combustion of the sulphur, previously feeble, now assumes a remarkable intensity, and a peculiar coloured light is generated, whilst the sulphur unites with the oxygen, and forms sulphurous acid gas. It produces, in fact, the same gas which is formed by burning an ordinary sulphur match. This compound is valuable as a disinfectant, and is a very important bleaching agent, being most extensively employed in the whitening of straw employed in the manufacture of straw bonnets. It is an acid gas, as Lavoisier found, and this property may be detected by pouring a little tincture of litmus into the bottom of the plate in which the gas jar stands. The blue colour of the litmus is rapidly changed to red, and it might be thought that no further argument could possibly be required to prove that oxygen was the acidifying agent, the more particularly as the result is the same in the next illustration.

Third Experiment.

Cut a small piece from an ordinary stick of phosphorus under water, take care to dry it properly with a cloth, and after placing it in a deflagrating spoon, remove the stopper from the gas-jar, as there is no fear of the oxygen rushing away, because it is somewhat heavier than atmospheric air; and then, after placing the spoon with the phosphorus in the neck of the jar, apply a heated wire and pass the spoon at once into the middle of the oxygen; in a few seconds a most brilliant light is obtained, and the jar is filled with a white smoke; as this subsides, being phosphoric acid, and perfectly soluble in water, the same litmus test may be applied, when it is in like manner changed to red. The acid obtained is one of the most important constituents of bone.

Fourth Experiment.

A bit of bark-charcoal bound round with wire is set on fire either by holding it in the flame of a spirit-lamp, or by attaching a small piece of waxed cotton to the lower part, and igniting this; the charcoal may then be inserted into a bottle of oxygen, when the most brilliant scintillations occur. After the combustion has ceased and the whole is cool, a little tincture of litmus may also be poured in and shaken about, when it likewise turns red, proving for the third time the generation of an acid body, called carbonic acid—an acid, like the others already mentioned, of great value, and one which Nature employs on a stupendous scale as a means of providing plants, &c., with solid charcoal. Carbonic acid, a virulent poison to animal life, is, when properly diluted, and as contained in atmospheric air, one of the chief alimentary bodies required by growing and healthy plants.

In three experiments acid bodies have been obtained; can we speculate on the result of the next?

Fifth Experiment.

Into a deflagrating spoon place a bit of potassium, set this on fire by holding it in the spoon in the flame of a spirit-lamp, and then rapidly plunge the burning metal into a bottle of oxygen. A brilliant ignition occurs in the deflagrating spoon for a few seconds, and there is little or no smoke in the jar. The product this time is a solid, called potash, and if this be dissolved in water and filtered, it is found to be clear and bright, and now on the addition of a little tincture of litmus to one half of the solution, it is wholly unaffected, and remains blue; but if with the other half a small quantity of tincture of turmeric is mixed, it immediately changes from a bright yellow solution to a reddish-brown, because turmeric is one of the tests for an alkali; and thus is ascertained by the help of this and other tests that the result of the combustion is not an acid, but an alkali. The experiment is made still more satisfactory by burning another bit of potassium in oxygen and dissolving the product in water, and if any portion of the reddened liquid derived from the sulphurous, phosphoric, and carbonic acids taken from the previous experiments, be added to separate portions of the alkaline solution, they are all restored to their original blue colour, because an acid is neutralized by an alkali; and the experiment is made quite conclusive by the restoration of the reddened turmeric to a bright yellow on the addition of a solution of either of the three acids already named. Moreover, an acid need not contain a fraction of oxygen, as there is a numerous class of hydracids, in which the acidifying principle is hydrogen instead of oxygen, such as the hydrochloric, hydriodic, hydro-bromic, and hydrofluoric acids.

Sixth Experiment.

A piece of watch-spring is softened at one end, by holding it in the flame of a spirit-lamp, and allowing it to cool. A bit of waxed cotton is then bound round the softened end, and after being set on fire, is plunged into a gas jar containing oxygen; the cotton first burns away, and then the heat communicates to the steel, which gradually takes fire, and being once well ignited, continues to burn with amazing rapidity, forming drops of liquid dross, which fall to the bottom of the plate—and also a reddish smoke, which condenses on the sides of the jar; neither the dross which has dropped into the plate, nor the reddish matter condensed on the jar, will affect either tincture of litmus or turmeric; they are neither acid nor alkaline, but neutral compounds of iron, called the sesquioxide of iron (Fe₂O₃), and the magnetic oxide (Fe₃O₄ = FeO.Fe₂O₃).

Seventh Experiment.

Some oxygen gas contained in a bladder provided with a proper jet may be squeezed out, and upon, some liquid phosphorus contained in a cup at the bottom of a finger glass full of boiling water, when a most brilliant combustion occurs, proving that so long as the principle is complied with—viz., that of furnishing oxygen to a combustible substance—it will burn under water, provided it is insoluble, and possesses the remarkable affinity for oxygen which belongs to phosphorus. The experiment should be performed with boiling water, to keep the phosphorus in the liquid state; and it is quite as well to hold a square foot of wire gauze over the finger glass whilst the experiment is being performed. (Fig. 100.)

Fig. 100.

a. Bladder containing oxygen, provided with a stop-cock and jet leading to, b, b. Finger glass containing boiling water. c. The cup of melted phosphorus under the water. The gas escapes from the bladder when pressed.

Eighth Experiment.

Oxygen is available from many substances when they are mixed with combustible substances, and hence the brilliant effects produced by burning a mixture of nitre, meal powder, sulphur, and iron or steel filings; the metal burns with great brilliancy, and is projected from the case in most beautiful sparks, which are long and needle-shaped with steel, and in the form of miniature rosettes with iron filings; it is the oxygen from the nitre that causes the combustion of the metal, the other ingredients only accelerate the heat and rate of ignition of the brilliant iron, which is usually termed a gerb.

Ninth Experiment.

A mixture of nitrate of potash, powdered charcoal, sulphur, and nitrate of strontium, driven into a strong paper case about two inches long, and well closed at the end with varnish, being quite waterproof, may be set on fire, and will continue to burn under water until the whole is consumed; the only precaution necessary being to burn the composition from the case with the mouth downward, and if the experiment is tried in a deep glass jar it has a very pleasing effect. (Fig. 101.)

Fig. 101.

a. Case of red fire burning downwards, and attached by a copper wire to a bit of leaden pipe b, to sink it. c c. Jar containing water.

The red-fire composition is made by mixing nitrate of strontia 40 parts by weight, flowers of sulphur 13 parts, chlorate of potash 5 parts, sulphuret of antimony 4 parts. These ingredients must first be well powdered separately, and then mixed carefully on a sheet of paper with a paper-knife. They are liable to explode if rubbed together in a mortar, on account of the presence of sulphur and chlorate of potash, and the composition, if kept for any time, is liable to take fire spontaneously.

Tenth Experiment.

Some zinc is melted in an iron ladle, and made quite red hot; if a little dry nitre is thrown upon the surface, and gently stirred into the metal, it takes fire with the production of an intense white light, whilst large quantities of white flakes ascend, and again descend when cold, being the oxide of zinc, and called by the alchemists the "Philosopher's Wool" (ZnO). In this experiment the oxygen from the nitre effects the oxidation of the metal zinc.

Eleventh Experiment.

A mixture of four pounds of nitre with two of sulphur and one and a half of lamp black produces a most beautiful and curious fire, continually projected into the air as sparks having the shape of the rowel of a spur, and one that may be burnt with perfect safety in a room, as the sparks consume away so rapidly, in consequence of the finely divided condition of the charcoal, that they may be received on a handkerchief or the hand without burning them. The difficulty consists in effecting the complete mixture of the charcoal. The other two ingredients must first be thoroughly powdered separately, and again triturated when mixed, and finally the charcoal must be rubbed in carefully, till the whole is of a uniform tint of grey and very nearly black, and as the mixture proceeds portions must be rammed into a paper case, and set on fire; if the stars or pinks come out in clusters, and spread well without other and duller sparks, it is a sign that the whole is well mixed; but if the sparks are accompanied with dross, and are projected out sluggishly, and take some time to burn, the mixture and rubbing in the mortar must be continued; and even that must not be carried too far, or the sparks will be too small. N.B.—If the lamp-black was heated red hot in a close vessel, it would probably answer better when cold and powdered.

Twelfth Experiment.

Into a tall gas jar with a wide neck project some red-hot lamp-black through a tin funnel, when a most brilliant flame-like fire is obtained, showing that finely divided charcoal with pure oxygen would be sufficient to afford light; but as the atmosphere consists of oxygen diluted with nitrogen, compounds of charcoal with hydrogen, are the proper bodies to burn, to produce artificial light.

Thirteenth Experiment. The Bude Light.

This pretty light is obtained by passing a steady current of oxygen gas (escaping at a very low pressure) through and up the centre pipe of an argand oil lamp, which must be supplied with a highly carbonized oil and a very thick wick, as the oxygen has a tendency to burn away the cotton unless the oil is well supplied, and allowed to overflow the wick, as it does in the lamps of the lighthouses. The best whale oil is usually employed, though it would be worth while to test the value of Price's "Belmontine Oil" for the same purpose. (Fig. 102.)

Fig. 102.

a. Reservoir of oil. b. The flexible pipe conveying oxygen to centre of the argand lamp.

Fourteenth Experiment. A Red Light.

Clear out the oil thoroughly from the Bude light apparatus; or, what is better, have two lamps, one for oil, and the other for spirit; fill the apparatus with a solution of nitrate of strontia and chloride of calcium in spirits of wine, and let it burn from the cotton in the same way as the oil, and supply it with oxygen gas.

Fifteenth Experiment. A Green Light.

Dissolve boracic acid and nitrate of baryta in spirits of wine, and supply the Bude lamp with this solution.

Sixteenth Experiment. A Yellow Light.

Dissolve common salt in spirits of wine, and burn it as already described in the Bude light apparatus.

Seventeenth Experiment. The Oxy-calcium Light.

This very convenient light is obtained in a simple manner, either by using a jet of oxygen as a blowpipe to project the flame of a spirit lamp on to a ball of lime; or common coal-gas is employed instead of the spirit lamp, being likewise urged against a ball of lime. By this plan one bag containing oxygen suffices for the production of a brilliant light, not equal, however, to the oxy-hydrogen light, which will be explained in the article on hydrogen. (Fig. 103.)

Fig. 103.

No. 1. a. Oxygen jet. b. The ball of lime, suspended by a wire. c. Spirit lamp. No. 2. d. Oxygen jet. e. Gas (jet connected with the gas-pipe in the rear by flexible pipe) projected on to ball of lime, f.

Eighteenth Experiment.

To show the weight of oxygen gas, and that it is heavier than air, the stoppers from two bottles containing it may be removed, one bottle may be left open for some time and then tested by a lighted taper, when it will still indicate the presence of the gas, whilst the other may be suddenly inverted over a little cup in which some ether, mixed with a few drops of turpentine, may be burning—the flame burns with much greater brilliancy at the moment when the oxygen comes in contact with it.

Nineteenth Experiment.

The theory of the effect of oxygen upon the system when inhaled would be an increase in the work of the respiratory organs; and it is stated that after inhaling a gallon or so of this gas, the pulse is raised forty or fifty beats per minute: the gas is easily inhaled from a large india-rubber bag through an amber mouthpiece; it must of course be quite pure, and if made from the mixture of chlorate of potash and oxide of manganese, should be purified by being passed through lime and water, or cream of lime.

Twentieth Experiment.

There are certain colouring matters that are weakened or destroyed by the action of light and other causes, which deprive them of oxygen gas or deoxidize them. A weak tincture of litmus, if long kept, often becomes colourless, but if this colourless fluid is shaken in a bottle with oxygen gas it is gradually restored; and if either litmus, turmeric, indigo, orchil, or madder, paper, or certain ribbons dyed with the same colouring matters, have become faded, they may be partially restored by damping and placing them in a bottle of oxygen gas. The effect of the oxygen is to reverse the deoxidizing process, and to impart oxygen to the colouring matters. By a peculiar process indigo may be obtained quite white, and again restored to its usual blue colour, either by exposure to the air or by passing a stream of oxygen through it.

Twenty-first Experiment.

Messrs. Matheson, of Torrington-street, Russell-square, prepare in the form of wire some of the rarest metals, such as magnesium, lithium, &c. A wire of the metal magnesium burns magnificently in oxygen gas, and forms the alkaline earth magnesia. The metal lithium, to which such a very low combining proportion belongs—viz., 6.5, can also be procured in the state of wire, and burns in oxygen gas with an intense white light into the alkaline lithia, which dissolved in alcohol with a little acetic acid, and burnt, affords a red flame, making a curious contrast between the effects of colour produced by the metallic and oxidized state of lithium.

THE ALLOTROPIC CONDITION OF OXYGEN GAS.

The term allotropy (from αλλοτροπος, of a different nature) was first used by the renowned chemist Berzelius. Dimorphism, or diversity in crystalline form, is therefore a special case of allotropy, and is most amusingly illustrated with the iodide of mercury (HgI), which is made either by rubbing together equal combining proportions of mercury and iodine (both of which are to be found in the Table of Elements, [page 86], or by carefully precipitating a solution of corrosive sublimate (chloride of mercury (HgCl)) with one of iodide of potassium, just enough and no more of the latter being added to precipitate the metal, or else the iodide of mercury is redissolved by the excess of the precipitant. It is first of a dirty yellow, and then gradually changes when stirred to a scarlet; if this be collected on a filter, and washed and drained, it is a beautiful scarlet, and when some of this substance is rubbed across a sheet of paper, a bright scarlet is apparent, which may be rapidly changed to a lemon-yellow by heating the paper over the flame of a spirit lamp; and the iodide of mercury is again brought back to a scarlet colour by rubbing down the yellow crystals with the fingers. This experiment may be repeated over and over again with the like results. If some of the scarlet iodide of mercury is sublimed from one bit of glass to another, it forms crystals, derived from the right rhombic prism; when these are scratched with a pin they change again to the scarlet state, the latter when crystallized being in the form of the square-based octohedron.

Other cases of dimorphism may be mentioned—viz., with sulphur, carbonate of lime, and lead, and many others, whilst allotropy is curiously illustrated in the various conditions of charcoal, which, in the more numerous examples, is black and opaque, and in another instance transparent like water. Lamp-black is soft, but the diamond is the hardest natural substance. The allotropic state of sulphur has been already alluded to; phosphorus, again, exists in three modifications: 1st, Common phosphorus, which shines in the dark and emits a white smoke. 2nd, White phosphorus. 3rd, Red or amorphous phosphorus, which does not shine or emit white smoke when exposed to the air, and is so altered in its properties that it may be safely carried in the pocket.

Enough evidence has therefore been offered to show that the allotropic property is not confined to one element or compound, but is discoverable in many bodies, and in no one more so than in the allotropic state of the element oxygen called

OZONE.

The Greek language has again been selected by the discoverer, Schönbein, of Basle, for the title or name of this curious modification of oxygen, and it is so termed from οξειν, to smell. The name at once suggests a marked difference between ozone and oxygen, because the latter is perfectly free from odour, whilst the former has that peculiar smell which is called electric, and is distinguishable whenever an electrical machine is at work, or if a Leyden jar is charged by the powerful Rhumkoff, or Hearder coil; it is also apparent when water is decomposed by a current of electricity and resolved into its elements, oxygen and hydrogen. When highly concentrated it smells like chlorine; and the author recollects seeing the first experiments by Schönbein, in England, at Mr. Cooper's laboratory in the Blackfriars-road. Ozone is prepared by taking a clean empty bottle, and pouring therein a very little distilled water, into which a piece of clean scraped phosphorus is introduced, so as to expose about one-half of its diameter to the air in the bottle, whilst the other is in contact with the water. (Fig. 104.)

For the sake of precaution, the bottle may stand in a basin or soup plate, so that if the phosphorus should take fire, it may be instantly extinguished by pouring cold water into the bottle, and should this crack and break, the phosphorus is received into the plate.

Fig. 104.

a. A quart bottle, with the stopper loosely placed therein. b. The stick of clean phosphorus. c. The water level just to half the thickness of the phosphorus. d d. A soup-plate.

When the ozone is formed the phosphorus can be withdrawn, and the phosphorous-acid smoke washed out by shaking the bottle; it is distinguishable by its smell, and also by its action on test paper, prepared by painting with starch containing iodide of potassium on some Bath post paper; when this is placed in the bottle containing ozone, it changes the test blue, or rather a purplish blue.

Ozone is a most energetic body, and a powerful bleaching agent; if a point is attached to the prime conductor of an electrical machine, and the electrified air is received into a bottle, it will be found to smell, and has the power of bleaching a very dilute solution of indigo. Ozone is not a mere creation of fancy, as it can not only be produced by certain methods, but may be destroyed by a red heat. If a point is prepared with a loop of platinum wire, and this latter, after being connected with a voltaic battery, made red hot, and the whole placed on an insulating stool, and connected with the prime conductor of an electrical machine, it is found that the electrified air no longer smells, the ozone is destroyed; on the other hand, if the voltaic battery is disconnected, and the electrified air again allowed to pass from the cold platinum wire, the smell is again apparent, the air will bleach, and if caused to impinge at once upon the iodide of starch test, changes it in the manner already described. (Fig. 105.)

Fig. 105.

v. A small voltaic battery standing on the stool with glass legs, s s, and capable of heating a thin length of platinum wire about two inches long, and bent to form a point between the conducting wires, w w.—N.B. The voltaic current can be cut off at pleasure, so as to cool the wire when necessary. a is the prime conductor of an ordinary cylinder electrical machine. b is the wire conveying the frictional electricity to the conducting wires of the voltaic battery, where the point p being the sharpest point in the arrangement, delivers the electrified and ozonized air.

Ozone is insoluble in water, and oxidizes silver and lead leaf, finely powdered arsenic and antimony; it is a poison when inhaled in a concentrated state, whilst diluted, and generated by natural processes, it is a beneficent and beautiful provision against those numerous smells originating from the decay of animal and vegetable matter, which might produce disease or death: ozone is therefore a powerful disinfectant. The test for ozone is made by boiling together ten parts by weight of starch, one of iodide of potassium, and two hundred of water; it may either be painted on Bath post paper, and used at once, or blotting paper may be saturated with the test and dried, and when required for use it must be damped, either before or after testing for ozone, as it remains colourless when dry, but becomes blue after being moistened with water.

Paper prepared with sulphate of manganese is an excellent test for ozone, and changes brown rapidly by the oxidation of the proto-salt of manganese, and its conversion into the binoxide of the metal.

Ozone is also prepared by pouring a little sulphuric ether into a quart bottle, and then, after heating a glass rod in the flame of the spirit lamp, it may be plunged into the bottle, and after remaining there a few minutes ozone may be detected by the ordinary tests.

NITROGEN, OR AZOTE.

Νιτρον, nitre; γενναω, I form; α, privative; ζωη, life. Symbol, N; combining proportion, 14. Also termed by Priestley, phlogisticated air.

In the year 1772, Dr. Rutherford, Professor of Botany in the University of Edinburgh, published a thesis in Latin on fixed air, in which he says:—"By the respiration of animals healthy air is not merely rendered mephitic (i.e., charged with carbonic acid gas), but also suffers another change. For after the mephitic portion is absorbed by a caustic alkaline lixivium, the remaining portion is not rendered salubrious; and although it occasions no precipitate in lime-water, it nevertheless extinguishes flame and destroys life." Such is the doctor's account of the discovery of nitrogen, which may be separated from the oxygen in the air in a very simple manner. The atmosphere is the great storehouse of nitrogen, and four-fifths of its prodigious volume consist of this element.

Composition of Atmospheric Air.

The usual mode of procuring nitrogen gas is to abstract or remove the oxygen from a given portion of atmospheric air, and the only point to be attended to, is to select some substance which will continue to burn as long as there is any oxygen left. Thus, if a lighted taper is placed in a bottle of air, it will only burn for a certain period, and is gradually and at last extinguished; not that the whole of the oxygen is removed or changed, because after the taper has gone out, some burning sulphur may be placed in the vessel, and will continue to burn for a limited period; and even after these two combustibles have, as it were, taken their fill of the oxygen, there is yet a little left, which is snapped up by burning phosphorus, whose voracious appetite for oxygen is only appeased by taking the whole. It is for this reason that phosphorus is employed for the purpose of removing the oxygen, and also because the product (phosphoric acid) is perfectly soluble in water, and thus the oxygen is first combined, and then washed out of a given volume of air, leaving the nitrogen behind.

First Experiment.

To prepare nitrogen gas, it is only necessary to place a little dry phosphorus in a Berlin porcelain cup on a wine glass, and to stand them in a soup plate containing water. The phosphorus is set on fire with a hot wire, and a gas jar or cylindrical jar is then carefully placed over it, so that the welt of the jar stands in the water in the soup plate. At first, expansion takes place in consequence of the heat, but this effect is soon reversed, as the oxygen is converted into a solid by union with the phosphorus, forming a white smoke, which gradually disappears. (Fig. 106.)

Fig. 106.

a. Cylindrical glass vessel, open at one end, and inverted over b, the wine-glass, supporting c, the cup containing the burning phosphorus, and the whole standing in a soup-plate, d d, containing water.

Supposing two grains of phosphorus had been placed in a platinum tube, and just enough atmospheric air passed over it to convert the whole into phosphoric acid, the weight of the phosphorus would be increased to 4½ grains by the addition of 2½ grains of oxygen; now one cubic inch of oxygen weighs 0.3419, or about 1/3rd of a grain, hence 7.3 cubic inches of oxygen disappear, which weigh as nearly as possible 2½ grains, so that as 36.5 cubic inches of air contain 7.3 cubic inches of oxygen, that quantity of air must have passed over the 2 grains of phosphorus to convert it into 4½ grains of phosphoric acid.

For very delicate purposes, nitrogen is best prepared by passing air over finely-divided metallic copper heated to redness; this metal absorbs the whole of the oxygen and leaves the nitrogen. The finely-divided copper is procured by passing hydrogen gas over pure black oxide of copper.

Second Experiment.

Fig. 107.

a. Glass jar, with collar of leather, through which the stamper, c, works. b b. The tube containing the finely-divided lead, part of which falls out, and is ignited, and retained by the little tray just below, being part of the iron stand, d d, with crutches supporting the ends of the glass tube, and the whole stands in the dish of water, e e.

A very instructive experiment is performed by heating a good mass of tartrate of lead in a glass tube which is hermetically sealed, and being placed on an iron support, is then covered by a capped air jar with a sliding rod and stamper, the whole being arranged in a plate containing water. When the stamper is pushed down upon the glass the latter is broken (Fig. 107), and the air gradually penetrates to the finely divided lead, when ignition occurs, and the oxygen is absorbed, as demonstrated by the rise of the water in the jar. On the same principle, if a bottle is filled about one-third full with a liquid amalgam of lead and mercury, and then stopped and shaken for two hours or more, the finely divided lead absorbs the oxygen and leaves pure nitrogen. Or if a mixture of equal weights of sulphur and iron filings, is made into a paste with water in a thin iron cup, and then warmed and placed under a gas jar full of air standing on the shelf of the pneumatic trough, or in a dish full of water, the water gradually rises in the jar in about forty-eight hours, in consequence of the absorption of the oxygen gas.

Third Experiment.

Nitrogen is devoid of colour, taste, smell, of alkaline or acid qualities; and, as we shall have occasion to notice presently, it forms an acid when chemically united with oxygen, and an alkali in union with hydrogen. A lighted taper plunged into this gas is immediately extinguished, while its specific gravity, which is lighter than that of oxygen or air, is demonstrated by the rule of proportion.

And its levity may be shown very prettily by a simple experiment. Select two gas jars of the same size, and after filling one with oxygen gas and the other with nitrogen gas, slide glass plates over the bottoms of the jars, and proceed to invert the one containing oxygen, placing the neck in a stand formed of a box open at the top; then place the jar containing nitrogen over the mouth of the first, withdrawing the glass plates carefully; and if the table is steady the top gas jar will stand nicely on the lower one. Then (having previously lighted a taper so as to have a long snuff) remove the stopper from the nitrogen jar and insert the lighted taper, which is immediately extinguished, and as quickly relighted by pushing it down to the lower jar containing the oxygen. This experiment may be repeated several times, and is a good illustration of the relative specific gravities of the two gases, and of the importance of the law of universal diffusion already explained at p. 6, by which these gases mix, not combine together, and the atmosphere remains in one uniform state of composition in spite of the changes going on at the surface of the earth. Omitting the aqueous vapour, or steam, ever present in variable quantities in the atmosphere, ten thousand volumes of dry air contain, according to Graham:—

Fig. 108.

a. Gas jar containing nitrogen, n, standing on b, another jar full of oxygen, o. The taper, c, is extinguished at n, and relighted at o. d d. Stand supporting the jars.

Fourth Experiment.

It was the elegant, the accomplished, but ill-fated Lavoisier who discovered, by experimenting with quicksilver and air, the compound nature of the atmosphere; and it was the same chemist who gave the name of azote to nitrogen; it should, however, be borne in mind that it does not necessarily follow because a gas extinguishes flame that it is a poison. Nitrogen extinguishes flame, but we inhale enormous quantities of air without any ill effects from the nitrogen or azote that it contains; on the other hand, many gases that extinguish flame are specific poisons, such as carbonic acid, carbonic oxide, cyanogen, &c.

Lavoisier's experiment may be repeated by passing into a measured jar, graduated into five equal volumes, four measures of nitrogen and one measure of oxygen; a glass plate should then be slid over the mouth of the vessel, and it may be turned up and down gently for some little time to mix the two gases, and when the mixture is tested with a lighted taper, it is found neither to increase nor diminish the illuminating power and the taper burns as it would do in atmospheric air. (Fig. 109.)

Fig. 109.

a. Gas jar divided into five equal parts. b B. Section of pneumatic trough, to show the decantation of gas from one vessel to another. The gas is being passed from c to a, through the water.

HYDROGEN.

Hydrogen (υδωρ, water; γενναω, I give rise to), so termed by Lavoisier—called by other chemists inflammable air, and phlogiston. Symbol, H; combining properties, 1. The lightest known form of matter.

Every 100 parts by weight of water contain 11 parts of hydrogen gas; and as the quantity of water on the surface of the earth represents at least two-thirds of the whole area, the source of this gas, like that of oxygen or nitrogen, is inexhaustible. Van Helmont, Mayow, and Hales had shown that certain inflammable and peculiar gases could be obtained, but it was reserved for the rigidly philosophic mind of Cavendish to determine the nature of the elements contained in, and giving a speciality to, the inflammable gases of the older chemists. By acting with dilute acids upon iron, zinc, and tin, Cavendish liberated an inflammable elastic gas; and he discovered nearly all the properties we shall notice in the succeeding experiments, and especially demonstrated the composition of water in his paper read before the Royal Society in the year 1784.

First Experiment.

Hydrogen is prepared in a very simple manner, by placing some zinc cuttings in a bottle, to which is attached a cork and pewter or bent glass tube, and pouring upon the metal some dilute sulphuric or hydrochloric acid. Effervescence and ebullition take place, and the gas escapes in large quantities, water being decomposed; the oxygen passes to the zinc, and forms oxide of zinc, and this uniting with the sulphuric acid forms sulphate of zinc, which may be obtained after the escape of the hydrogen by evaporation and crystallization. (Fig. 110.)

Zn + HO.SO₃ = ZnO.SO₃ + H;
or,
Zn + HCl = ZnCl + H.

In nearly all the processes employed for the generation of hydrogen gas, a metal is usually employed, and this fact has suggested the notion that hydrogen may possibly be a metal, although it is the lightest known form of matter; and it will be observed in all the succeeding experiments that a metallic substance will be employed to take away the oxygen and displace the hydrogen.

Fig. 110.

a. Bottle containing zinc cuttings and water and fitted with a cap and two tubes, the one marked b, containing a funnel, conveys the sulphuric acid to the zinc and water, whilst the gas escapes through the pipe c.

Whenever hydrogen is prepared it should be allowed to escape from the generating vessel for a few minutes before any flame is applied, in order that the atmospheric air may be expelled. The most serious accidents have occurred from carelessness in this respect, as a mixture of hydrogen and air is explosive, and the more dangerous when it takes fire in any closed glass bottle.

Second Experiment.

If a piece of potassium is confined in a little coarse wire gauze cage, attached to a rod, and thrust under a small jar full of water, placed on the shelf of the pneumatic trough, hydrogen gas is produced with great rapidity, and is received into the gas jar. The bit of potassium being surrounded with water, is kept cool, whilst the hydrogen escaping under the water is not of course burnt away, as it is whenever the metal is thrown on the surface of water.

Third Experiment.

Across a small iron table-furnace is placed about eighteen inches of 1-inch gas-pipe containing iron borings, the whole being red-hot; and attached to one end is a pipe conveying steam from a boiler, or flask, or retort, whilst another pipe is fitted to the opposite end, and passes to the pneumatic trough. Directly the steam passes over the red hot iron borings it is deprived of oxygen, which remains with the iron, forming the rust or oxide of iron, whilst the hydrogen, called in this case water gas, escapes with great rapidity. When steam is passed over red-hot charcoal, hydrogen is also produced with carbonic oxide gas, and this in fact is the ordinary process of making water gas, which being purified is afterwards saturated with some volatile hydrocarbon and burnt. At first sight, such a mode of making gas would be thought extremely profitable, and in spite of the numerous failures the discovery (so called) of water gas is reproduced as a sort of chronic wonder; but experience and practice have clearly demonstrated that water gas is a fallacy, and as long as we can get coal it is not worth while going through the round-about processes of first burning coal to produce steam; secondly, of burning coal to heat charcoal, over which the steam is passed to be converted into gas, which has then to be purified and saturated with a cheap hydrocarbon obtained from coal or mineral naphtha; whilst ordinary coal gas is obtained at once by heating coal in iron retorts. (Fig. 111.)

Thus, by the metals zinc, tin, potassium, red-hot iron (and we might add several others), the oxygen of water is removed and hydrogen gas liberated.

Fig. 111.

a. Flask containing water, and producing steam, which passes to the iron tube, b b, containing the iron borings heated red hot in the charcoal stove c. The hydrogen passes to the jar d, standing on the shelf of the pneumatic trough.

Fourth Experiment.

If bottles of hydrogen gas are prepared by all the processes described, they will present the same properties when tested under similar circumstances. A lighted taper applied to the mouths of the bottles of hydrogen, which should be inverted, causes the gas to take fire with a slight noise, in consequence of the mixture of air and hydrogen that invariably takes place when the stopper is removed; on thrusting the lighted taper into the bulk of the gas it is extinguished, showing that hydrogen possesses the opposite quality to oxygen—viz., that it takes fire, but does not support combustion. By keeping the bottles containing the hydrogen upright, when the stopper is removed the gas escapes with great rapidity, and atmospheric air takes its place, so much so that by the time a lighted taper is applied, instead of the gas burning quietly, it frequently astonishes the operator with a loud pop. This sudden attack on the nerves may be prevented by always experimenting with inverted bottles. (Fig. 112.)

Fig. 112.

a. Bottle opened upright, and hydrogen exploding. b. Bottle opened inverted, and hydrogen burning quietly at the mouth.

Fifth Experiment.

Hydrogen is 14.4 lighter than air, and for that reason may be passed into bottles and jars without the assistance of the pneumatic trough. One of the most amusing proofs of its levity is that of filling paper bags or balloons with this gas; and we read, in the accounts of the fêtes at Paris, of the use of balloons ingeniously constructed to represent animals, so that a regular aerial hunt was exhibited, with this drawback only, that nearly all the animals preferred ascending with their legs upwards, a circumstance which provoked intense mirth amongst the volatile Frenchmen. The lightness of hydrogen may be shown in two ways—first, by filling a little gold-beater's skin balloon with pure hydrogen (prepared by passing the gas made from zinc and dilute pure sulphuric acid through a strong solution of potash, and afterwards through one of nitrate of silver), and allowing the balloon to ascend; and then afterwards, having of course secured the balloon by a thin twine or strong thread, it may be pulled down and the gas inhaled, when a most curious effect is produced on the voice, which is suddenly changed from a manly bass to a ludicrous nasal squeaking sound. The only precautions necessary are to make the gas quite pure, and to avoid flame whilst inhaling the gas. It is related by Chaptal that the intrepid (quære, foolish) but unfortunate aeronaut, Mons. Pilate de Rosio, having on one occasion inhaled hydrogen gas, was rash enough to approach a lighted candle, when an explosion took place in his mouth, which he says "was so violent that he fancied all his teeth were driven out." Of course, if it were possible to change by some extraordinary power the condition of the atmosphere in a concert-room or theatre, all the bass voices would become extremely nasal and highly comic, whilst the sopranos would emulate railway whistles and screech fearfully; and supposing the specific gravity of the air was continually and materially changing, our voices would never be the same, but alter day by day, according to the state of the air, so that the "familiar voice" would be an impossibility.

A bell rung in a gas jar containing air emits a very different sound from that which is produced in one full of hydrogen—a simple experiment is easily performed by passing a jar containing hydrogen over a self-acting bell, such as is used for telegraphic purposes. (Fig. 113.)

Fig. 113.

a. Stand and bell. b b. Tin cylinder full of hydrogen, which may be raised or depressed at pleasure, by lifting it with the knob at the top, when the curious changes in the sound of the bell are audible.

Sixth Experiment.

Some of the small pipes from an organ may be made to emit the most curious sounds by passing heavy and light gases through them; in these experiments bags containing the gases should be employed, which may drive air, oxygen, carbonic acid, or hydrogen, through the organ pipes at precisely the same pressure.

Seventh Experiment.

One of those toys called "The Squeaking Toy" affords another and ridiculous example of the effect of hydrogen on sound, when it is used in a jar containing this gas. (Fig. 114.)

Fig. 114.

The squeaking toy, used in a jar of hydrogen.

Eighth Experiment.

An accordion played in a large receptacle containing hydrogen gas demonstrates still more clearly what would be the effect of an orchestra shut up in a room containing a mixture of a considerable portion of hydrogen with air, as the former, like nitrogen, is not a poison, and only kills in the absence of oxygen gas.

Ninth Experiment.

Some very amusing experiments with balloons have been devised by Mr. Darby, the eminent firework manufacturer, by which they are made to carry signals of three kinds, and thus the motive or ascending power may be utilized to a certain extent.

Mr. Darby's attention was first directed to the manufacture of a good, serviceable, and cheap balloon, which he made of paper, cut with mathematical precision; the gores or divisions being made equal, and when pasted together, strengthened by the insertion of a string at the juncture; so that the skeleton of the balloon was made of string, the whole terminating in the neck, which was further stiffened with calico, and completed when required by a good coating of boiled oil. These balloons are about nine feet high and five feet in diameter in the widest part, exactly like a pear, and tapering to the neck in the most graceful and elegant manner. They retain the hydrogen gas remarkably well for many hours, and do not leak, in consequence of the paper of which they are made being well selected and all holes stopped, and also from the circumstance of the pressure being so well distributed over the interior by the almost mathematical precision with which they are cut, and the careful preparation of the paper with proper varnish. One of their greatest recommendations is cheapness; for whilst a gold-beater's skin balloon of the same size would cost about 5l., these can be furnished at 5s. each in large quantities.

A balloon required to carry one or more persons must be constructed of the best materials, and cannot be too carefully made; it is therefore a somewhat costly affair, and as much as 200l., 500l., and even 1000l. have been expended in the construction of these aerial chariots.

The chief points requiring attention are:—first, the quality of the silk; secondly, the precision and scrupulous nicety required in cutting out and joining the gores; thirdly, the application of a good varnish to fill up the pores of the silk, which must be insoluble in water, and sufficiently elastic not to crack.

The usual material is Indian silk (termed Corah silk), at from 2s. to 2s. 6d. per yard.

The gores or parts with which the balloon is constructed require, as before stated, great attention; it being a common saying amongst aeronauts, "that a cobweb will hold the gas if properly shaped" the object being to diffuse the pressure equally over the whole bag or balloon.

The varnish with which the silk is rendered air-tight can be made according to the private recipe of Mr. Graham, an aeronaut, who states that he uses for this purpose two gallons of linseed oil (boiled), two ditto (raw), and four ounces of beeswax; the whole being simmered together for one hour, answers remarkably well, and the varnish is tough and not liable to crack.

For repairing holes in a balloon, Mr. Graham recommends a cement composed of two pounds of black resin and one pound of tallow, melted together, and applied on pieces of varnished silk to the apertures.

The actual cost of a balloon will be understood from information also derived from Mr. Graham. His celebrated "Victoria Balloon," which has passed through so many hairbreadth escapes, was sixty-five feet high, and thirty-eight feet in diameter in the broadest part; and the following articles were used in its construction:—

Thirty-eight thousand cubic feet of coal gas were required to fill this balloon, charged by one company 20l., by others from 9l. to 10l.; and eight men were required to hold the inflated baggy monster.

Such a balloon as described above is a mere soap bubble when compared with the "New Aerial Ship" now building in the vicinity of New York; the details are so practical and interesting, that we quote nearly the whole account of this mammoth or Great Eastern amongst balloons, as given in the New York Times.

"An experiment in scientific ballooning, greater than has yet been undertaken, is about to be tried in this city. The project of crossing the Atlantic Ocean with an air-ship, long talked of, but never accomplished, has taken a shape so definite that the apparatus is already prepared and the aeronaut ready to undertake his task.

"The work has been conducted quietly, in the immediate vicinity of New York, since the opening of spring. The new air-ship, which has been christened the City of New York, is so nearly completed, that but few essentials of detail are wanting to enable the projectors to bring it visibly before the public.

"The aeronaut in charge is Mr. T. S. C. Lowe, a New Hampshire man, who has made thirty-six balloon ascensions.

"The dimensions of the City of New York so far exceed those of any balloon previously constructed, that the bare fact of its existence is notable. Briefly, for so large a subject, the following are the dimensions:—Greatest diameter, 130 feet; transverse diameter, 104 feet; height, from valve to boat, 350 feet; weight, with outfit, 3½ tons; lifting power (aggregate), 22½ tons; capacity of gas envelope, 725,000 cubic feet.

"The City of New York, therefore, is nearly five times larger than the largest balloon ever before built. Its form is that of the usual perpendicular gas-receiver, with basket and lifeboat attached.

"Six thousand yards of twilled cloth have been used in the construction of the envelope. Reduced to feet, the actual measurement of this material is 54,000 feet—or nearly 11 miles. Seventeen of Wheeler and Wilson's sewing machines have been employed to connect the pieces, and the upper extremity of the envelope, intended to receive the gas-valve, is of triple thickness, strengthened with heavy brown linen, and sewed in triple seams. The pressure being greatest at this point, extraordinary power of resistance is requisite. It is asserted that 100 women, sewing constantly for two years, could not have accomplished this work, which measures by miles. The material is stout and the stitching stouter.

"The varnish applied to this envelope is a composition the secret of which rests with Mr. Lowe. Three or four coatings are applied, in order to prevent leakage of the gas.

"The netting which surrounds the envelope is a stout cord, manufactured from flax expressly for the purpose. Its aggregate strength is equal to a resistance of 160 tons, each cord being capable of sustaining a weight of 400 lbs. or 500 lbs.

"The basket which is to be suspended immediately below the balloon is made of rattan, is 20 feet in circumference and 4 feet deep. Its form is circular, and it is surrounded by canvas. This car will carry the aeronauts. It is warmed by a lime-stove, an invention of Mr. O. A. Gager, by whom it was presented to Mr. Lowe. A lime-stove is a new feature in air voyages. It is claimed that it will furnish heat without fire, and is intended for a warming apparatus only. The stove is 1½ feet high, and 2 feet square. Mr. Lowe states that he is so well convinced of the utility of this contrivance, that he conceives it to be possible to ascend to a region where water will freeze, and yet keep himself from freezing. This is to be tested.

"Dropping below the basket is a metallic lifeboat, in which is placed an Ericsson engine. Captain Ericsson's invention is therefore to be tried in mid-air. Its particular purpose is the control of a propeller, rigged upon the principle of the screw, by which it is proposed to obtain a regulating power. The application of the mechanical power is ingeniously devised. The propeller is fixed in the bow of the lifeboat, projecting at an angle of about forty-five degrees. From a wheel at the extremity twenty fans radiate. Each of these fans is 5 feet in length, widening gradually from the point of contact with the screw to the extremity, where the width of each is 1½ feet. Mr. Lowe claims that by the application of these mechanical contrivances his air-ship can be readily raised or lowered, to seek different currents of air; that they will give him ample steerage way, and that they will prevent the rotatory motion of the machine. In applying the principle of the fan, he does not claim any new discovery, but simply a practical development of the theory advanced by other aeronauts, and partially reduced to practice by Charles Green, the celebrated English aeronaut.

"Mr. Lowe contends that the application of machinery to aerial navigation has been long enough a mere theory. He proposes to reduce the theory to practice, and see what will come of it. It is estimated that the raising and lowering power of the machinery will be equal to a weight of 300 lbs., the fans being so adjusted as to admit of very rapid motion upward or downward. As the loss of three or four pounds only is sufficient to enable a balloon to rise rapidly, and as the escape of a very small portion of the gas suffices to reduce its altitude, Mr. Lowe regards this systematic regulator as quite sufficient to enable him to control his movements and to keep at any altitude he desires. It is his intention to ascend to a height of three or four miles at the start, but this altitude will not be permanently sustained. He prefers, he says, to keep within a respectable distance of mundane things, where 'he can see folks.' It is to be hoped his machinery will perform all that he anticipates from it. It is a novel affair throughout, and a variety of new applications remain to be tested. Mr. Lowe, expressing the utmost confidence in all the appointments of his apparatus, assured us that he would certainly go, and, as certainly, would go into the ocean, or deliver a copy of Monday's Times in London on the following Wednesday. He proposes to effect a landing in England or France, and will take a course north of east. A due easterly course would land him in Spain, but to that course he objects. He hopes to make the trip from this city to London in forty-eight hours, certainly in sixty-four hours. He scouts the idea of danger, goes about his preparations deliberately, and promises himself a good time. As the upper currents, setting due east, will not permit his return by the same route, he proposes to pack up the City of New York, and take the first steamer for home.

"The air-ship will carry weight. Its cubical contents of 725,000 feet of gas suffice to lift a weight of 22½ tons. With outfit complete its own weight will be 3½ tons. With this weight 19 tons of lifting power remain, and there is accordingly room for as many passengers as will care to take the venture. We understand, however, that the company is limited to eight or ten. Mr. Lowe provides sand for ballast, regards his chances of salvation as exceedingly favourable, places implicit faith in the strength of his netting, the power of his machinery, and the buoyancy of his lifeboat, and altogether considers himself secure from the hazard of disaster. If he accomplish his voyage in safety, he will have done more than any air navigator has yet ventured to undertake. If he fail, the enterprise sinks the snug sum of 20,000 dollars. Wealthy men who are his backers, sharing his own enthusiasm, declare failure impossible, and invite a patient public to wait and see."

A night ascent witnessed at any of the public gardens is certainly a stirring scene, particularly if the wind is rather high. On approaching the balloon, swayed to and fro by the breeze, it seems almost capable of crushing the bold individual who would venture beneath it; seen as a large dark mass in the yet dimly-lighted square, it appears to be incapable of control; when the inflation is completed, the aeronaut, all importance, seats himself in the car, and blue lights, with other fireworks, display the victim who is to make a "last ascent," or perhaps descent. Finally the word is given, the ropes are cast off, and the bulky chariot rises majestically to the sound of the National Anthem. The crowd see no more, but the next day's Times reports the end of the aerial journey.

Balloons can never be of any permanent value as means of locomotion until they can be steered; and this is a problem, the solution of which is something like perpetual motion. In the first place, a balloon of any size exposes an enormous surface to the pressure and force of the winds; and when we consider that they move at the rate of from three to eighty miles per hour, it will be understood that the fabric of the balloon itself must give way in any attempt to tear, work, or pull it against such a force. Secondly and lastly, the power has not yet been created which will do all this without the inconvenience of being so heavy that the steering engine fixes the balloon steadily to the earth by its obstinate gravity. When engines of power are constructed without the aeronaut's obstacle of weight—when balloons are made of thin copper or sheet-iron, then we may possibly hear of the voyage of the good ship Aerial, bound for any place, and quite independent of dock, port, and the host of dues (quere), which the sea-going ships have to disburse. It is, however, gratifying to the zeal and perseverance of those who dream of aerial navigation, to know that a balloon is not quite useless; and here we may return to the consideration of Mr. Darby's signals, which are of various kinds, and intended to appeal to the senses by night as well as by day; and first, by audible sounds. Such means have long been recognised, from the ancient float and bell of the "Inchcape Rock," to the painful minute-gun at sea, or the shrill railway whistle and detonating signals employed to prevent the horrors of a collision between two trains. The signal sounds are produced by the explosion of shells capable of yielding a report equal to that of a six-pounder cannon, and they are constructed in a very simple manner. A ball, composed of wood or copper, and made up by screwing together the two hemispheres, is attached to a shaft or tail of cane or lance-wood, properly feathered like an arrow; at the side opposite to that of the arrow—viz., at its antipodes, is placed a slight protuberance containing a minute bulb of glass filled with oil of vitriol, and surrounded with a mixture of chlorate of potash and sugar, the whole being protected with gutta-percha, and communicating by a touch-hole with the interior, which is of course filled with gunpowder. These shells are attached to a circular framework by a strong whipcord, which passes to a central fuse, and are detached one after the other as the slow fuse (made hollow on the principle of the argand lamp) burns steadily away. Directly a shell falls to the ground, the little bulb containing the oil of vitriol breaks, and the acid coming in contact with the chlorate of potash and sugar, causes the mixture to take fire, when the gunpowder explodes. During the siege of Sebastopol many similar mines were prepared by the Russians in the earth, so that when an unfortunate soldier trod upon the spot, the concealed mine blew up and seriously injured him; such petty warfare is as bad as shooting sentries, and a cruel application of science, that unnecessarily increases the miseries of war without producing those grand results for which the truly great captains, Wellington and Napoleon, only warred. (Fig. 115.)

Fig. 115.

a. Ring attached to balloon, carrying an hexagonal framework with six shells. b. Hollow fuse, which burns slowly up to the strings, and detaches each shell in succession. c. Section of shell. The shaded portion represents the gunpowder.

The bill distributor consists of a long piece of wood, to which are attached a number of hollow fuses, with packets of bills, protected from being burned or singed by a thin tin plate; 10,000 or 20,000 bills can thus be delivered, and the wind assists in scattering them, whilst the balloon travels over a distance of many miles. It must be recollected that in each case the shells and the bills are detached by the string burning away as the fire creeps up from the fuse. (Fig. 116.)

Fig. 116.

The bill distributor, consisting of three hollow fuses, with bills attached in packets.

Another most ingenious arrangement, also prepared by Mr. Darby, is termed by the inventor, the "Land and Water Signal," and may be thus described:—A short hollow ball of gutta-percha, or other convenient material, five or six inches in diameter, and filled with printed bills, or the information, whatever it may be, that is required to be sent, is attached to a cap to which a red flag, having the words "Open the shell" and four cross sticks, canes, or whalebones with bits of cork at equal distances, are fitted. The whole is connected by a string to the fuse as before described. These signals are adapted for land and water: in either case they fall upright, and in consequence of the sticks projecting out they float well in the water, and can be seen by a telescope at a distance of three miles. (Fig. 117.) Many of these signals were sent away by Mr. Darby from Vauxhall; one was picked up at Harwich, another at Brighton, a third at Croydon; in the latter case it was found by a cottager, who, fearing gunpowder and combustibles, did not examine the shell, but having mentioned the circumstance to a gentleman living near him, they agreed to cut it open; and intelligence of their arrival, in this and the other cases, was politely forwarded to Mr. Darby at Vauxhall Gardens.

Fig. 117.

The land and water signal, which remains upright on land, or floats on the surface of water. a. The water-tight gutta-percha shell, containing the message or information. b b b. Sticks of cane to keep the flag in an upright position; at the ends are attached cork bungs.

Balloons, like a great many other clever inventions, have been despised by military men as new-fangled expedients, toys, which may do very well to please the gaping public, but are and must be useless in the field. Over and over again it has been suggested that a balloon corps for observation should be attached to the British army, but the scheme has been rejected, although the expense of a few yards of silk and the generation of hydrogen gas would be a mere bagatelle as compared with the transport and use of a single 32-pounder cannon. The antiquated notions of octogenarian generals have, however, received a great shock in the fact that the Emperor Napoleon III. was enabled, by the assistance of a captive balloon, to watch the movements and dispositions of the Austrian troops; and with the aid of the information so obtained, he made his preparations, and was rewarded by the victory of Solferino; and as soon as the battle was over Napoleon III. occupied at Cavriana the very room and ate the dinner prepared for his adversary, the Emperor Francis Joseph.

Over and over again the most excellent histories have been written of aerostation, but they all tend to one truth, and that is, the great danger and risk of such excursions; and to enable our readers to form their own judgment, a chronological list of some of the most celebrated aeronauts, &c., is appended.

1675. Bernair attempted to fly—killed.
1678. Besnier attempted to fly.
1772. L'Abbé Desforges announced an aerial chariot.
1783. Montgolfier constructed the first air balloon.
" Roberts frères, first gas balloon, destroyed by the peasantry of
Geneva, who imagined it to be an evil spirit or the moon.
1784. Madame Thiblé, the first lady who was ever up in the clouds;
she ascended 13,500 feet.
" Duke de Chartres, afterwards Egalité Orleans, travelled 135
miles in five hours in a balloon.
" Testu de Brissy, equestrian ascent.
" D'Achille, Desgranges, and Chalfour—Montgolfier balloon.
" Bacqueville attempted a flight with wings.
" Lunardi—gas balloon.
" Rambaud—Montgolfier balloon, which was burnt.
" Andreani—Montgolfier balloon.
1785. General Money—gas balloon, fell into the water, and not rescued
for six hours.
" Thompson, in crossing the Irish Channel, was run into with the
bowsprit of a ship whilst going at the rate of twenty miles
per hour.
" Brioschi—gas balloon ascended too high and burst the balloon;
the hurt he received ultimately caused his death.
" A Venetian nobleman and his wife—gas balloon—killed.
" Pilatre de Rozier and M. Romain—gas balloon took fire—both
killed.
1806. Mosment—gas balloon—killed.
" Olivari—Montgolfier balloon—killed.
1808. Degher attempted a flight with wings.
1812. Bittorf—Montgolfier balloon—killed.
1819. Blanchard, Madame—gas balloon—killed.
1819. Gay Lussac—gas balloon, ascended 23,040 feet above the level of
the sea. Barometer 12.95 inches; thermometer 14.9 Fah.
" Gay Lussac and Biot—gas balloon for the benefit of science.
Both philosophers returned safely to the earth.
1824. Sadler—gas balloon—killed.
" Sheldon—gas balloon.
" Harris—gas balloon—killed.
1836. Cocking—parachute from gas balloon—killed.
1847. Godard—Montgolfier balloon fell into and extricated from the
Seine.
1850. Poitevin, a successful French aeronaut.
" Gale, Lieut.—gas balloon—killed.
" Bixio and Barral—gas balloon.
" Graham, Mr. and Mrs.—gas balloon.—Serious accident ascending
near the Great Exhibition in Hyde Park.
" Green, the most successful living aeronaut of the present time.

Of the 41 persons enumerated, 14 were killed, and nearly all the aeronauts met with accidents which might have proved fatal.

Fig. 118.

Flying machine (theoretical).

Tenth Experiment.

Soap bubbles blown with hydrogen gas ascend with great rapidity, and break against the ceiling; if interrupted in their course with a lighted taper they burn with a slight yellow colour and dull report.

Eleventh Experiment.

By constructing a pewter mould in two halves, of the shape of a tolerably large flask, a balloon of collodion may be made by pouring the collodion inside the pewter vessel, and taking care that every part is properly covered; the pewter mould may be warmed by the external application of hot water, so as to drive off the ether of the collodion, and when quite dry the mould is opened and the balloon taken out. Such balloons may be made and inflated with hydrogen by attaching to them a strip of paper, dipped in a solution of wax and phosphorus, and sulphuret of carbon; as the latter evaporates, the phosphorus takes fire and spreads to the balloon; which burns with a slight report. The pewter mould must be very perfectly made, and should be bright inside; and if the balloons are filled with oxygen and hydrogen, allowing a sufficient excess of the latter to give an ascending power, they explode with a loud noise directly the fire reaches the mixed gases.

Twelfth Experiment.

In a soup-plate place some strong soap and water; then blow out a number of bubbles with a mixture of oxygen and hydrogen; a loud report occurs on the application of flame, and if the room is small the window should be placed open, as the concussion of the air is likely to break the glass.

Thirteenth Experiment.

Any noise repeated at least thirty-two times in a second produces a musical sound, and by producing a number of small explosions of hydrogen gas inside glass tubes of various sizes, the most peculiar sounds are obtained. The hydrogen flame should be extremely small, and the glass tubes held over it may be of all lengths and diameters; a trial only will determine whether they are fit for the purpose or not.

Fourteenth Experiment.

Flowers, figures, or other designs, may be drawn upon silk with a solution of nitrate of silver, and the whole being moistened with water, is exposed to the action of hydrogen gas, which removes the oxygen from the silver, and reduces it to the metallic state.

In like manner designs drawn with a solution of chloride of gold are produced in the metallic state by exposure to the action of hydrogen gas. Chloride of tin, usually termed muriate of tin, may also be reduced in a similar manner, care being taken in these experiments that the fabric upon which the letters, figures, or designs are painted with the metallic solution be kept quite damp whilst exposed to the hydrogen gas.

Fifteenth Experiment.

A mixture of two volumes of hydrogen with one volume of oxygen explodes with great violence, and produces two volumes of steam, which condense against the sides of the strong glass vessel, in which the experiment may be made, in the form of water. As the apparatus called the Cavendish bottle, by which this experiment only may be safely performed, is somewhat expensive, and requires the use of an air-pump, gas jars with stop-cocks, and an electrical machine and Leyden jar, other and more simple means may be adopted to show the combination of oxygen and hydrogen, and formation of water.

If a little alcohol is placed in a cup and set on fire, whilst an empty cold gas jar is held over the flame, an abundant deposition of moisture takes place from the combustion of the hydrogen of the spirits of wine. Alcohol contains six combining properties of hydrogen, with four of charcoal and two of oxygen. If a lighted candle, or an oil, camphine, Belmontine, or gas flame, is placed under a proper condenser, large quantities of water are obtained by the combustion of these substances (Fig. 119).

Fig. 119.

a. A burning candle, or oil or gas lamp. Copper head and long pipe fitting into b c, the receiver from which the condensed water drops into d. e e. Two corks fitted, between which is folded some wet rag.

Sixteenth Experiment.

During the combustion of a mixture of two volumes of hydrogen with one of oxygen, an enormous amount of heat is produced, which is usefully applied in the arrangement of the oxy-hydrogen blowpipe. The flame of the mixed gases produces little or no light, but when directed on various metals contained in a small hole made in a fire brick, a most intense light is obtained from the combustion of the metals, which is variously coloured, according to the nature of the substances employed. With cast-iron the most vivid scintillations are obtained, particularly if after having fused and boiled the cast-iron with the jet of the two gases, one of them, viz., the hydrogen, is turned off, and the oxygen only directed upon the fused ball of iron, then the carbon of the iron burns with great rapidity, the little globule is enveloped in a shower of sparks, and the whole affords an excellent notion of the principle of Bessemer's patent method of converting cast-iron at once into pure malleable iron, or by stopping short of the full combustion of carbon, into cast-steel.

The apparatus for conducting these experiments is of various kinds, and different jets have been from time to time recommended on account of their alleged safety. It may be asserted that all arrangements proposed for burning any quantity of the mixed gases are extremely dangerous: if an explosion takes place it is almost as destructive as gunpowder, and should no particular damage be done to the room, there is still the risk of the sudden vibration of the air producing permanent deafness. If it is desired to burn the mixed gases, perhaps the safest apparatus is that of Gurney; in this arrangement the mixed gases bubble up through a little reservoir of water, and thus the gas-holder—viz., a bladder, is cut off from the jet when the combustion takes place. (Fig. 120.) This jet is much recommended by Mr. Woodward, the highly respected President of the Islington Literary and Scientific Institution, and may be fitted up to show the phenomena of polarized light, the microscope, and other interesting optical phenomena.

Fig. 120.

Gurney's jet. a. Pipe with stop-cock leading from the gas-holder. b. The little reservoir of water through which the mixed gases bubble. c. The jet where the gases burn. d. Cork, which is blown out if the flame recedes in the pipe, c.

Mr. Woodward states, that a series of experiments, continued during many years, has proved, that while the bladder containing the mixed gases is under pressure, the flame cannot be made to pass the safety chambers, and consequently an explosion is impossible; and even if through extreme carelessness or design, as by the removal of pressure or the contact of a spark with the bladder, an explosion occurs, it can produce no other than the momentary effect of the alarm occasioned by the report; whereas, when the gases are used in separate bags under a pressure of two or three half hundredweights, if the pressure on one of the bags be accidentally removed or suspended, the gas from the other will be forced into it, and if not discovered in time, will occasion an explosion of a very dangerous character; or if through carelessness one of the partially emptied bags should be filled up with the wrong gas, effects of an equally perilous nature would ensue.

Fig. 121.

a. The bladder of mixed gases, pressed by the board, b b, attached by wire supports to another board, c c, which carries the weights, d d. e e. Pipe to which the bladder, a, is screwed, and when a is emptied, it is re-filled from the other bladder, r. f f f. Pipe conveying mixed gases to the lantern, g g, where they are burnt from a Gurney's jet, h.

In the oxy-hydrogen blowpipe usually employed, the gases are kept quite separate, either in gasometers or gas bags, and are conveyed by distinct pipes to a jet of very simple construction, devised by the late Professor Daniell, where they mix in very small volumes, and are burnt at once at the mouth of the jet. (Fig. 122.)

Fig. 122.

Daniell's jet. o o. The stop-cock and pipe conveying oxygen, and fitting inside the larger tube h h, to which is attached a stop-cock, h, connected with the hydrogen receiver. a. The orifice near which the gases mix, and where they are burnt.

The gases are stored either in copper gasometers or in air-tight bags of Macintosh cloth, capable of containing from four to six cubic feet of gas, and provided with pressure boards. The boards are loaded with two or three fifty-six pound weights to force out the gas with sufficient pressure, and of course must be equally weighted; if any change of weight is made, the stop-cocks should be turned off and the light put out, as the most disastrous results have occurred from carelessness in this respect. (Fig. 123.)

Fig. 123.

Fig. 123. Gas bag and pressure boards.

The oxy-hydrogen jet is further varied in construction by receiving the gases from separate reservoirs, and allowing them to mix in the upper part of the jet, which is provided with a safety tube filled with circular pieces of wire gauze. (Fig. 124.) With this arrangement a most intense light is produced, called the Drummond or lime light, and coal gas is now usually substituted for hydrogen.

Fig. 124.

a a. Board to which b b is fixed. o. Oxygen pipe. h. Hydrogen pipe. c c. Space filled with wire gauze. d. Lime cylinder.

Seventeenth Experiment.

There are many circumstances that will cause the union of oxygen and hydrogen, which, if confined by themselves in a glass vessel, may be preserved for any length of time without change; but if some powdered glass, or any other finely-divided substance with sharp points, is introduced into the mixed gases at a temperature not exceeding 660° Fahrenheit, then the gases silently unite and form water.

This curious mode of effecting their combination is shown in a still more interesting manner by perfectly clear platinum foil, which if introduced into the mixed gases gradually begins to glow, and becoming red-hot causes the gases to explode. Or still better, by the method first devised by Dobereiner, in 1824, by which finely prepared spongy platinum—i.e., platinum in a porous state, and exposing a large metallic surface—is almost instantaneously heated red-hot by contact with the mixed gases. When this fact became known, it was further applied to the construction of an instantaneous light, in which hydrogen was made to play upon a little ball of spongy platinum, and immediately kindled. These Dobereiner lamps were possessed by a few of the curious, and would no doubt be extensively used if the discovery of phosphorus had not supplied a cheaper and more convenient fire-giving agent. When the spongy platinum is mixed with some fine pipeclay, and made into little pills, they may (after being slightly warmed) be introduced into a mixture of the two gases, and will silently effect their union. The theory of the combination is somewhat obscure, and perhaps the simplest one is that which supposes the platinum sponge to act as a conductor of electric influences between the two sets of gaseous particles; although, again, it is difficult to reconcile this theory with the fact that powdered glass at 660°, a bad conductor of electricity, should effect the same object. The result appears to be due to some effects of surface by which the gases seem to be condensed and brought into a condition that enables them to abandon their gaseous state and assume that of water.

When Sir H. Davy invented the safety-lamp, he was aware that, in certain explosive conditions of the air in coal mines, the flame of the lamp was extinguished, and in order that the miner should not be left in the dreary darkness and intricacies of the galleries without some means of seeing the way out, he devised an ingenious arrangement with thin platinum wire, which was coiled round the flame of the lamp, and fixed properly, so that it could not be moved from its proper place by any accidental shaking. When the flame of the safety-lamp, having the platinum wire attached, was accidentally extinguished by the explosive atmosphere in which it was burning, the platinum commenced glowing with an intense heat, and continued to emit light as long as it remained in the dangerous part of the mine. Sir H. Davy warned those who might use the platinum to take care that no portion of the thin wire passed outside the wire gauze, for the obvious reason that, if ignited outside the wire gauze protector, it would inflame the fire-damp.

Eighteenth Experiment.

Water is decomposed by passing a current of voltaic electricity through it by means of two platinum plates, which may be connected with a ten-cell Grove's battery. The gases are collected in separate tubes, and the experiment offers one of the most instructive illustrations of the composition of water. (Fig. 125.)

Fig. 125.

p p. Two platinum plates connected with wires to the cups. The wires are passed through holes in the finger-glass, b b, and are fixed perfectly steady by pouring in cement composed of resin and tallow to the line l l. Two glass tubes filled with water acidulated with sulphuric acid, and placed over the platinum plates in finger-glass, which also contains dilute sulphuric acid to improve the conducting power of the water. The wires of the battery are placed in the cups, and the arrows show the direction of the current of electricity.

There is a current of electricity passing from and between two platinum plates decomposing water, offering the converse of the Dobereiner experiment, and highly suggestive of the probability of the theory already advanced in explanation of the singular combination of oxygen and hydrogen in the presence of clean platinum foil, and more especially when we consider the operation of Grove's gas battery, in which a current of electricity is produced by pieces of platinum foil covered with finely-divided platinum, called platinum black; each piece is contained in a separate glass tube filled alternately with oxygen and hydrogen, and by connecting a great number of these tubes a current of electricity is obtained, whilst the oxygen and hydrogen are slowly absorbed and disappear, having combined and formed water, although placed in separate glass tubes. (Fig. 126.)

Fig. 126.

Grove's gas battery consists of tubes containing oxygen and hydrogen alternately, and having a thin piece of platinum foil, p, inserted by the blowpipe in each glass tube. The foil hangs down the full length of the interior of the glass. Each pair of tubes is contained in a little glass tumbler containing some dilute sulphuric acid, and the hydrogen tube, h, of one pair, is connected with the oxygen tube, o, of the next. w w. The terminal wires of the series.

The analysis of water is shown very perfectly on the screen by fitting up some very small tubes and platinum wires in the same manner as shown in fig. 125. The vessel in which the tubes and wires are contained with the dilute sulphuric acid must be small, and arranged so as to pass nicely into the space usually filled by the picture in an ordinary magic lantern, or, still better, in one lighted by the oxy-hydrogen or lime light. If the dilute acid is coloured with a little solution of indigo, the gradual displacement of the fluid by the production of the two gases is very perfectly developed on the screen when the small voltaic battery is attached to the apparatus; and of course a large number of persons may watch the experiment at the same time.

With respect to the application of the light produced from a jet of the mixed gases thrown upon a ball of lime, it may be stated that for many years the dissolving view lanterns and other optical effects have been produced with the assistance of this light; and more lately Major Fitzmaurice has condensed the mixed gases in the old-fashioned oil gas receivers, and projected them on a ball of lime; and it was this light thrown from many similar arrangements that illuminated the British men-of-war when Napoleon III. left her Majesty's yacht at night in the docks at Cherbourg.

Fig. 127.

Cherbourg.

Mr. Sykes Ward, of Leeds, has also proposed a most simple and excellent application of the oxy-hydrogen light for illumination under the surface of water, and for the convenience of divers, who are frequently obliged to cease their operations in consequence of the want of light. Mr. Ward's submarine lamp consists of a series of very strong copper tubes, which are filled with the mixed gases by means of a force-pump; and in order to prevent the lamp being extinguished, it burns under double glass shades, which are desirable in order to prevent the glass immediately next to the light cracking by contact with the cold water.

Fig. 128.

a a. Tube reservoir to hold the mixed gases. b. The jet and lime ball. d. The first glass shade, held down by a cap and screw. c. The second glass shade. e e. The handle by which it is lowered into the water.

The author tried this lamp at Ryde, and although the coast-guards objected to the production of a brilliant light at night, which they stated might be mistaken for a signal and would cause some confusion amongst the war vessels in the immediate neighbourhood, enough experiments were made, to show that the Ward lamp would burn for a considerable time under water, and could be kept charged with the gas by means of a process that was easily workable in the boat. The gases were taken out mixed in gas bags, and pumped into the reservoir when required. With a much larger reservoir greater results could be obtained; and if nautilus diving bells are to be used in modern warfare, they will require a powerful light to show them their prey, so that they may attach the explosives which are to blow great holes in the men-of-war.

Fig. 129.

Submarine lamp.

CHAPTER XI.

CHLORINE, IODINE, BROMINE, FLUORINE.

The four Halogens, or Producers of Substances like Sea Salt.

Chlorine (χλωρος, green). Symbol, Cl. Combining proportion, 35.5. Specific gravity, 2.44. Scheele termed it dephlogisticated muriatic acid; Lavoisier, oxymuriatic acid; Davy, chlorine.

The consideration of the nature of this important element introduces to our notice one of the most original chemists of the eighteenth century—viz., the illustrious Scheele, who was born at Stralsund, in 1742, and in spite of every obstacle, fighting his "battle of life" with sickness and sorrow, he succeeded in making some of the most valuable discoveries in science, and amongst them that of chlorine gas. It was in the examination of a mineral solid—viz., of manganese—that Scheele made the acquaintance of a new gaseous element; and in a highly original dissertation on manganese, in 1774, he describes the mode of procuring what he termed dephlogisticated muriatic acid—a name which is certainly to be regretted, from its absurd length, but a title which was strictly in accordance with the then established theory of phlogiston; and if the latter is considered synonymous with hydrogen, quite in accordance with our present views of the nature of this element. Scheele discovered the leading characteristics of chlorine, and especially its power of bleaching, which is alone sufficient to place this gas in a high commercial position, when it is considered that all our linen used formerly to be sent to Holland, where they had acquired great dexterity in the ancient mode of bleaching—viz., by exposure of the fabric to atmospheric air or the action of the damps or dews, assisted greatly by the agency of light. Some idea may be formed of the present value of chlorine, when it is stated that the linen goods were retained by the Dutch bleachers for nine months; and if the spring and summer happened to be favourable, the operation was well conducted; on the other hand, if cold and wet, the goods might be more or less injured by continual exposure to unfavourable atmospheric changes. At the present time, as much bleaching can be done in nine weeks as might formerly have been conducted in the same number of months; and the whole of the process of chlorine bleaching is carried on independent of external atmospheric caprices, whilst the money paid for the process no longer passes to Holland, but remains in the hands of our own diligent bleachers and manufacturers.

First Experiment.

As Scheele first indicated, chlorine is obtained by the action of the black oxide of manganese, on "the Spirit of Salt," or hydrochloric acid; and the most elementary and instructive experiment showing its preparation can be made in the following manner:—

Fig. 130.

a. Flask containing the fuming hydrochloric acid, which is gently boiled by the heat of the spirit lamp. b. Tube passing to the Wolfe's bottle, containing pumice-stone or asbestos moistened with sulphuric acid. c. Second tube passing into a dry empty bottle, which receives the hydrochloric acid gas.

Place in a clear Florence oil-flask, to which a cork and bent tube have been first fitted, some strong fuming hydrochloric acid. Arrange the flask on a ring-stand, and then pass the bent tube either to a Wolfe's bottle containing some pumice-stone moistened with oil of vitriol, or to a glass tube containing either pumice or asbestos wetted with the same acid. Another glass tube, bent at right angles, passes away from the Wolfe's bottle into a receiving bottle. (Fig. 130). On the application of heat, the hydrochloric gas is driven off from its solution in water, and any aqueous vapour carried up is retained by the asbestos or pumice stone wetted with oil of vitriol; the application of the latter is called drying the gas—i.e., depriving it of all moisture; sometimes the salt called chloride of calcium is used for the same purpose, and it must be understood by the juvenile chemist that gases are not dried like towels, by exposure to heat, or by putting them in bladders before the fire, as we once heard was actually recommended, but by causing the gas charged with invisible steam to pass over some substance having a great affinity for water. The dry hydrochloric gas falls into the bottle, and displaces the air, being about one-fourth heavier than the latter, and gradually overflowing from the mouth of the vessel, produces a white smoke, which is found to be acid by litmus paper, but has no power to bleach, and is not green; it is, in fact, a combination of one combining proportion of chlorine with one of hydrogen, and to detach the latter, and set the chlorine free, it is necessary to convey the hydrochloric gas to some body which has an affinity for hydrogen. Such a substance is provided in the use of the black oxide of manganese, which is placed either in a small flask or in a tube provided with two bulbs, and when heated with the lamp it separates the hydrogen from the hydrochloric gas, and forms water, which partly condenses in the second bulb. And now the gas that escapes is no longer acid and fuming with a white smoke on contact with the air; but is green, has a strong odour, bleaches, and is so powerful in its action on all living tissues, that it must be carefully avoided and not inhaled; if a small quantity is accidentally inhaled, it produces a violent fit of coughing, which lasts a considerable time, and is only abated by inhaling the diluted vapour of ammonia, or ether, or alcohol, and swallowing milk and other softening drinks. (Fig. 131).

Fig. 131.

a. The flask containing the fuming hydrochloric acid, heated by spirit lamp. b. Tube passing to Wolfe's bottle, containing the pumice-stone or asbestos wetted with oil of vitriol. c. Second tube, which passes into a wide-mouthed small flask containing black oxide of manganese, partly in powder and partly in lump; and the third tube conveys the chlorine to any convenient vessel. The double bulb tube, e e, may be substituted for the flask, the oxide of manganese being contained in the bulb m.—N.B. Any tube may be joined on to another by a bit of india-rubber tubing, which is tied by string.

Tube a is joined to tube b by the caoutchouc pipe c, tied with packthread.

Second Experiment.

The mode of preparing chlorine, as already given, though very instructive, is troublesome to perform; a more simple process may therefore be described:—

Pour some strong hydrochloric acid upon powdered black oxide of manganese contained in a Florence oil-flask, taking care that the whole of the black powder is wetted with the acid so that none of it clings to the bottom of the flask in the dry state to cause the glass to crack on the application of heat. A cork and bent glass tube is now attached, and conveyed to the pneumatic trough; on the application of heat to the mixture in the flask the chlorine is evolved, and may be collected in stoppered bottles, the first portion that escapes, although it contains atmospheric air, should be carefully collected in order to prevent any accident from inhaling the gas, and it will do very well to illustrate the bleaching power of the gas, and therefore need not be wasted. The above process may be described in symbols, all of which are easily deciphered by reference to the table of elements, [page 86].

MnO₂ + 2 HCl = MnCl + 2 HO + Cl.

Third Experiment.

Another and still more expeditious mode of preparing a little chlorine, is by placing a small beaker glass, containing half an ounce of chlorinated lime, usually termed chloride of lime or bleaching powder, carefully at the bottom of a deep and large beaker glass, and then, by means of a tube and funnel, conveying to the chloride of lime some dilute oil of vitriol, composed of half acid and half water; effervescence immediately occurs from the escape of chlorine gas, and as it is produced it falls over the sides of the small beaker glass into the large one, when it may be distinguished by its green colour. If a little gas be dipped out with a very small beaker glass arranged as a bucket, and poured into a cylindrical glass containing some dilute solution of indigo, and shaken therewith, the colour disappears almost instantaneously; and if a piece of Dutch metal is thrown into the beaker glass it will take fire if enough chlorine has been generated, or some very finely-powdered antimony will demonstrate the same result. Thus, with a few beaker glasses, some chloride of lime, sulphuric acid, a solution of indigo, and a little Dutch metal, the chief properties of chlorine may be displayed. (Fig. 132.)

Fig. 132.

a a. The large beaker glass. b. The small one, containing the chloride of lime. c. The tube and funnel down which the dilute sulphuric acid is poured. d d. Sheet of paper over top of large glass, with hole in centre to admit the tube. e. The little beaker used as a bucket.

Fourth Experiment.

Into a little platinum spoon place a small pellet of the metal sodium, and after heating it in the flame of a spirit lamp, introduce the metal into a bottle of chlorine, when a most intense and brilliant combustion occurs, throwing out a vivid yellow light, and the heat is frequently so great that the bottle is cracked. After the combustion, and when the bottle is cool, it is usually lined with a white powder, which will be found to taste exactly the same as salt, and, in fact, is that substance, produced by the combination of chlorine, a virulent poison, with the metal sodium, which takes fire on contact with a small quantity of water; and hence the use of salt for the preparation of chlorine gas when it is required on the large scale.

Fifth Experiment.

Some Dutch metal, or powdered antimony, or a bit of phosphorus, immediately takes fire when introduced into a bottle containing chlorine gas, forming a series of compounds termed chlorides, and demonstrating by the evolution of heat and light, the energetic character of chlorine, and that oxygen is not the only supporter of combustion; chlorine gas has even, in some cases, greater chemical power, because some time elapses before phosphorus will ignite in oxygen gas, whilst it takes fire directly when placed in a bottle of chlorine.

Sixth Experiment.

The weight and bleaching power of chlorine are well shown by placing a solution of indigo in a tall cylindrical glass, leaving a space at the top of about five inches in depth. By inverting a bottle of chlorine over the mouth of the cylindrical glass, it pours out like water, being about two and a half times heavier than atmospheric air, and then, after placing a ground glass plate over the top of the glass, the chlorine is recognised by its colour, whilst the bleaching power is demonstrated immediately the gas is shaken with the indigo solution.

Seventh Experiment.

As a good contrast to the last experiment, another cylindrical jar of the same size may be provided, containing a solution of iodide of potassium with some starch, obtained by boiling a teaspoonful of arrowroot with some water; any chlorine left in the bottle (sixth experiment) may be inverted into the top of this glass and shaken, when it turns a beautiful purple blue in consequence of the liberation of iodine by the chlorine, whose greater affinity for the base produces this result. The colour is caused by the union of the iodine and the starch, which form together a beautiful purple compound, and thus the apparent anomaly of destroying and producing colour with the same agent is explained.

Eighth Experiment.

Dry chlorine does not bleach, and this fact is easily proved by taking a perfectly dry bottle, and putting into it two or three ounces of fused chloride of calcium broken in small lumps, then if a bottle full of chlorine is inverted over the one containing the chloride of calcium, taking the precaution to arrange a few folds of blotting paper with a hole in the centre on the top of the latter to catch any water that may run out of the chlorine bottle at the moment it is inverted, the gas will be dried by contact with the chloride of calcium, and if a piece of paper, with the word chlorine written on it with indigo, and previously made hot and dry, is placed in the chlorine, no change occurs, but directly the paper is removed, dipped in water, and placed in a bottle of damp chlorine, the colour immediately disappears. (Fig. 133.)

Fig. 133.

a a. Dry bottle, containing chloride of calcium. b. Bottle of chlorine. The arrow indicates the gas. c c. The blotting-paper, to catch any water from the bottle, b. d. The bottle closed, and containing the paper.

This experiment shows that chlorine is only the means to the end, and that it decomposes water, setting free oxygen, which is supposed to exert a high bleaching power in its nascent state, a condition which many gases are imagined to assume just before they take the gaseous state, a sort of intermediate link between the solid or fluid and the gaseous condition of matter. The nascent state may possibly be that of ozone, to which we have already alluded as a powerful bleaching agent.

Ninth Experiment.

A piece of paper dipped in oil of turpentine emits a dense black smoke, and frequently a flash of fire is perceptible, directly it is plunged into a bottle containing chlorine gas; here the gas combines only with the hydrogen of the turpentine, and the carbon is deposited as soot.

Tenth Experiment.

If a lighted taper is plunged into a bottle of chlorine it continues to burn, emitting an enormous quantity of smoke, for the reason already explained, and demonstrating the perfection of the atmosphere in which we live and breathe, and showing that had oxygen gas possessed the same properties as chlorine, the combustion of compounds of hydrogen and carbon would have been impossible, in consequence of the enormous quantity of soot which would have been produced, so that some other element that would freely enter into combination with it must have been provided to produce both artificial light and heat. Chlorine is a gas which cannot be inhaled, and ozone presents the same features, as a mouse confined for a short time with an excess of ozone soon died; but ozone is the extraordinary condition of oxygen; the element in the ordinary state is harmless, and is the one which enters so largely into the composition of the air we breathe.

Eleventh Experiment.

When one volume of olefiant gas (prepared by boiling one measure of alcohol and three of sulphuric acid) is mixed with two volumes of chlorine, and the two gases agitated together in a long glass vessel for a few seconds, with a glass plate over the top, which should have a welt ground perfectly flat, they unite on the application of flame, with the production of a great cloud of black smoke, arising from the deposited carbon, whilst a sort of roaring noise is heard during the time that the flame passes from the top to the foot of the glass. (Fig. 134.)

Fig. 134.

Remarkable deposition of carbon during the combustion of one volume of olefiant gas with two of chlorine.

Twelfth Experiment.

Formerly Bandannah handkerchiefs were in the highest estimation, and no gentleman's toilet was thought complete without one. The pattern was of the simplest kind, consisting only of white spots on a red or other coloured ground. These spots were produced in a very ingenious manner by Messrs. Monteith, of Glasgow, by pressing together many layers of silk with leaden plates perforated with holes; a solution of chlorine was then poured upon the upper plate, and pressure being applied it penetrated the whole mass in the direction of the holes, bleaching out the colour in its passage. This important commercial result may be imitated on the small scale by placing a piece of calico dyed with Turkey red between two thick pieces of board, each of which is perforated with a hole two inches in diameter, and corresponding accurately when one is placed upon the other. The pieces of board may be squeezed together in any convenient way, either by weights, strong vulcanized india-rubber bands or screws, and when a strong solution of chlorine gas or of chloride of lime is poured into the hole and percolates through the cloth, the colour is removed, and the part is bleached almost instantaneously by first wetting the calico with a little weak acid, and then pouring on the solution of chloride of lime. On removing and washing the folded red calico it is found to be bleached in all the places exposed to the solution, and is now covered with white spots. (Fig. 135.)

Fig. 135.

a. Circular hole in the upper piece of wood, a similar one being perforated in the lower one. b b. The strong india-rubber bands. The bleaching solution is poured into a.

IODINE.

Iodine (Ιωδης, violet coloured). Symbol, I; combining proportion, 127.1; specific gravity, 4.948. Specific gravity of iodine vapour, 8.716.

In the previous chapter, devoted to the element chlorine, little or nothing has been said of that inexhaustible storehouse of chlorine, iodine, and bromine—viz., the boundless ocean. Some one has remarked that, as it is possible the air may contain a little of everything capable of assuming the gaseous form, so the ocean may hold in a state of solution a modicum of every soluble substance, in proof of which we have lately read of some very important experiments resulting in the separation of the metal silver from sea water, not certainly in any profitable quantity, but quite enough to prove its presence in the ocean.

No elaborate research is necessary to ascertain the presence of chlorine, when it is remembered that Schafhäutl has calculated, that all the oceans on the globe contain three millions fifty-one thousand three hundred and forty-two cubic geographical miles of salt, or about five times more than the mass of the Alps.

Now, salt contains about 60 per cent. of chlorine gas, and therefore the bleachers can never stand still for want of it; but iodine is not so plentiful, and was discovered by M. Courtois, of Paris, in kelp, a substance from which he prepared carbonate of soda, or washing soda; but as this is now more cheaply prepared from common salt, the kelp is at present required only for the iodine salts it contains, as also for the chloride of potassium. Kelp is obtained by burning dried sea-weeds in a shallow pit; the ashes accumulate and melt together, and this fused mass broken into lumps forms kelp. The ocean bed no doubt has its fertile and barren plains and mountains, and amongst the so-called "oceanic meadows" are to be mentioned the two immense groups and bands of sea-weed called the Sargasso Sea, which occupy altogether a space exceeding six or seven times the area of Germany.

The iodine is contained in the largest proportion in the deep sea plants, such as the long elastic stems of the fucus palmatus, &c. The kelp is lixiviated with water, and after separating all the crystallizable salts, there remains behind a dense oily-looking fluid, called "iodine ley," to which sulphuric acid is added, and after standing a day or two the acid "ley" is placed in a large leaden retort, and heated gently with black oxide of manganese. The chlorine being produced very slowly, liberates the iodine, as already demonstrated in experiment seven, p. 133, and it is collected in glass receivers.

Iodine, when quite pure and well crystallized, has a most beautiful metallic lustre, and presents a bluish-black colour, affording an odour which reminds one at once of the "sea smell."

First Experiment.

A few grains of iodine placed in a flask may be sublimed at a very gentle heat, and afford a magnificent violet vapour, which can be poured out of the flask into a warm bottle. If the bottle is cold the iodine condenses in minute and brilliant crystals. (Fig. 136.)

Fig. 136.

a. Flask containing iodine heated by spirit lamp. b. Cold flask above to receive the vapour. c C. Sheet of cardboard to cut off the heat from the spirit lamp.

Second Experiment.

Upon a thin slice of phosphorus place a few small particles of iodine; the heat produced by the combination of the two elements soon causes the phosphorus to take fire.

Third Experiment.

Heat a brick, and then throw upon it a few grains of iodine; by holding a sheet of white paper behind, the splendid violet colour of the vapour is seen to great advantage. It was by the discovery of iodine in the ashes of sponge—which had long been used as a remedy for goitre, a remarkable glandular swelling—that this element began to be used for medical purposes, and the important salt called iodide of potassium is now used in large quantities, not only in medicine, but likewise for that most fascinating art, which has made its way steadily, and is now practised so extensively, under the name of photography.

THE ART OF PHOTOGRAPHY.

It was the great George Stephenson who asked the late Dean Buckland the posing question, "Can you tell me what is the power that is driving that train?" alluding to a train which happened to be passing at the moment. The learned dean answered, "I suppose it is one of your big engines." "But what drives the engine?" "Oh, very likely a canny Newcastle driver." "What do you say to the light of the sun?" "How can that be?" asked Buckland. "It is nothing else," said Stephenson. "It is light bottled up in the earth for tens of thousands of years; light, absorbed by plants and vegetables, being necessary for the condensation of carbon during the process of their growth, if it be not carbon in another form; and now, after being buried in the earth for long ages in fields of coal, that latent light is again brought forth and liberated, made to work—as in that locomotive—for great human purposes."

Such was the opinion of the most original and practical man that ever reasoned on philosophy; and could he have lived to realize the thorough adaptation and business use of light in the art of photography, he would have said, man is only imitating nature, and in producing photographs he must employ the same agent which in ages past assisted to produce the coal.

In another part of this elementary work we shall have to consider the nature of light; here, however, the chemical part only of the process of photography will be discussed.

Many years ago (in the year 1777) Jenny Lind's most learned countryman, Scheele, discovered that a substance termed chloride of silver, obtained by precipitating a solution of chloride of silver with one of salt, blackened much sooner in the violet rays than in any other part of the spectrum. He says, "Fix a glass prism at the window, and let the refracted sunbeams fall on the floor; in this coloured light put a paper strewed with luna cornua (horn silver or chloride of silver), and you will observe that this horn silver grows sooner black in the violet ray than in any of the other rays."

In 1779, Priestley directed especial attention to the action of light on plants; and the famous Saussure, following up these and other experiments, determined that the carbonic acid of plants was more generally decomposed into carbon and oxygen in the blue rays of the spectrum; these facts probably suggested the bold theory of Stephenson already alluded to. Passing by the intermediate steps of photography, we come to the second year of the present century, and find in the Journal of the Royal Institution a paper by Wedgwood, entitled "An Account of a Method of Copying Paintings upon Glass, and of making Profiles, by the Agency of Light upon Nitrate of Silver; with observations, by H. Davy." Such a paper would lead the reader to suppose that very little remained to be effected, and that mere details would quickly establish the art; but in this case the experimentalists were doomed to disappointment, as, after producing their photographs, they could not make them permanent; they had not yet discovered the means of fixing the pictures. Nearly fourteen years elapsed, when the subject was again taken up by Niépcè, of Chalons, with little success, so far as the fixing was concerned; and twenty-seven years had passed away since the experiments of Wedgwood and Davy, when, in 1829, Niépcè and Daguerre executed a deed of co-partnership for mutually investigating the matter. These names would suggest a rapid progress; but, strange to relate, ten years again rolled away, the father Niépcè had in the meantime died, and a new contract was made between the son and M. Daguerre, when, in January, 1839, the famous discovery was made known to the world, and in July of the same year the French Government granted a pension for life of six thousand francs to Daguerre, and four thousand to the son of Niépcè, who had so worthily continued the experiments commenced by his father. The triumph of the industrious French experimentalists was not, however, to be unique; across the Channel another patient and laborious philosopher had completed on paper precisely the same kind of results as those obtained by Daguerre on silver plates. Mr. Fox Talbot, in England, had immortalized himself by a discovery which was at once called the Talbotype, and for which a patent was secured in 1841. Having thus hastily sketched a brief history of the art, we may now proceed to the details of the process.

First Experiment.

A photogenic drawing, so called, but now termed a positive copy, is prepared by placing some carefully selected paper, which is free from spots or inequalities (good paper is now made by several English manufacturers, although some kinds of French paper, such as Cansan's, are in high repute), in a square white hard porcelain dish containing a solution of common salt in distilled water, 109 grains of salt to the pint. The paper is steeped in this solution for ten minutes, and then taken out and pressed in a clean wooden press, or it should be dabbed dry on a clean flat surface with a clean piece of white calico, which may be kept specially for this duty and not used for anything else, and it is well that all would-be photographers should understand that neatness and cleanliness are perfectly indispensable in conducting these processes. If a design were required for the armorial bearings of the art of photography, it might certainly be most fanciful, but the motto must be cleanliness and neatness, and in preparing paper it should not be unnecessarily handled, but lifted by the corners only. The object of dabbing the paper is to prevent the salt accumulating in large quantities in one part of the paper and the reverse in another, and to distribute the salt equally through the whole. The paper being now dried, is called salted paper, and is rendered sensitive when required by laying it down on a solution of ammonio-nitrate of silver, prepared by adding ammonia to a solution containing sixty grains of nitrate of silver to the ounce of distilled water, until the whole of the oxide of silver is re-dissolved, except a very small portion. A few drops of nitric acid are also recommended to be added, and after allowing the solution to stand, it may be poured off quite clear, and is ready for use either in the bath, or if economy must be rigidly adhered to, the salted paper may be laid flat on a board, and held in its place with four pins at the corners, and then just enough to wet the surface of the paper may be run along the side of a glass spreader, and the liquid gently drawn over the surface of the salted paper, which is allowed to dry on a flat surface for a few minutes, and afterwards hung up by one corner to a piece of tape stretched across the room, until quite dry, and then placed in a blotting-book fitting into a case which completely excludes the light. Copying-paper should be made at night, as the day is then free for all photographic operations requiring an abundance of light. It will not keep long, and should be used the next day.

Fig. 137.

a. The glass spreader with cork handle. b. The silver solution clinging to rod and paper by capillary attraction. c c c C. Four pins holding down the paper on a board.—N.B. The spreader is made of glass rod three-eighths thick.

A piece of lace, a skeleton leaf, a sharp engraving on thin paper, and above all things, a negative photograph on glass or paper, is easily copied by placing the prepared paper with the prepared side (carefully protected from the light) upwards on any flat surface, such as plate glass; upon this is arranged the bit of lace or the negative photograph with the face or picture downwards, another bit of plate glass is then placed over it, and weights arranged at the corners; after exposure to the sun's rays for thirty minutes, more or less (according to the dullness or bright aspect of the day), the picture is brought into a dark room and examined by the light of a candle or by the light from a window covered with yellow calico, and after placing a paper weight on one corner of the lace, or negative picture, or copying paper, it may be carefully lifted in one part, and if the copy is sufficiently dark, is ready for fixing, but if it is faint the lifted corner is carefully replaced, the upper glass is laid on, and the picture again exposed to the light. Should the position of the lace or negative be changed during the examination, re-exposure is useless, and would only produce a double and confused picture, as it would be impossible to lay the lace or the negative exactly in the same place again on the copying paper.

The manipulations just described are much facilitated by using a copying-frame or press, which consists of a square wooden frame with a thick plate-glass window; upon this are placed the negative picture and the copying paper, and the two are brought in close contact by means of a board at the back pressed by a hand-screw. (Fig. 138.) After the photogenic drawing or positive copy is taken, it is fixed by being placed in a solution of hyposulphite of soda, consisting of one fluid ounce of saturated solution to eight of water. The saturated solution of hyposulphite of soda is conveniently kept in a large bottle for use, and in order to improve the colour a very little chloride of gold is added to the fixing solution, the picture must now be thoroughly washed, dried, and pressed.

Fig. 138.

The back of the copying-frame, showing the hand-screw and pressure-board. The plate glass inside is set in the base of the frame, and is of course the part exposed to the light.

Second Experiment.

Another mode of preparing the copying paper, called albumen paper, is to take the whites of four eggs, and four ounces of distilled water containing one hundred and sixty grains of chloride of ammonium; these are beaten up with a fork or a bundle of feathers, and as the froth is produced it is skimmed off by a silver spoon into another basin, or a beaker glass, and being allowed to settle for twelve hours it is strained through fine muslin, and is ready for use. The best paper is floated on the surface of this liquid for three minutes, taken out, and dried at once on a hot plate.

In floating paper one corner is first laid down, and care taken not to enclose any air bubbles, which would prevent the fluid wetting the paper, whilst the remainder of the paper is slowly laid upon the surface of the fluid.

The albumen paper is excited by laying it for five minutes on a solution of nitrate of silver, seventy-two grains to the ounce of water, and when dry it will keep for three days. This copying paper is used in the same manner as the last, and fresh eggs only must be used in its preparation, because stale ones soon cause the copy to change and blacken all over from the liberation of sulphur, which unites with the silver. The colour of the copy is sometimes improved by a solution of hot potash, and by dipping the well-washed picture, after the use of the hyposulphite of soda, in a very dilute solution of hydrosulphuret of ammonia.

Third Experiment.

In the Daguerreotype process, a silver plate, after being thoroughly cleaned and polished, is exposed to the vapour of iodine, and is thus rendered so sensitive that it may be at once exposed in the camera. In the Talbotype process, the same principle is apparent, and paper is prepared by first covering its surface with iodide of silver, which is afterwards rendered sensitive to the action of light by means of an excess of nitrate of silver, as follows:—

One side of a sheet of selected Cansan's paper is first covered (by means of a spreader) with a solution of nitrate of silver (thirty grains to the ounce of water), hung up in a dark room and dried; it is then immersed in a solution of iodide of potassium of five hundred grains to a pint of distilled water, for five or ten minutes, and immediately changes to a yellow colour in consequence of the precipitation of the yellow iodide of silver; it is then well washed with plenty of water, and being dried, may be kept for any length of time, and is called "iodized paper." Light has no action whatever upon it. To render the paper sensitive, three solutions are prepared in separate bottles, and marked 1, 2, 3.

No. 1, contains a solution of nitrate of silver, fifty grains to the ounce of water.

No. 2, glacial acetic acid.

No. 3, a saturated solution of gallic acid.

With respect to No. 3, Mr. William Crookes has shown, that when a saturated solution of gallic acid is required in large quantities, that it is better to dissolve at once two ounces of gallic acid in six ounces of alcohol (60° over proof); to hasten solution, the flask may be conveniently heated by immersion in hot water; when cold it should be filtered, mixed with half a drachm of glacial acetic acid, and preserved in a stoppered bottle for use; so prepared it will keep unaltered for a considerable length of time. The gallic acid is not precipitated from this solution by the addition of water; consequently, if in any case desirable, the development of a picture may be effected with a much stronger bath than the one usually employed. To obtain a solution of about the same strength as a saturated aqueous solution, such as No. 3, half a drachm of the alcoholic solution is mixed with two ounces of water; but for my particular purpose, says Mr. Crookes, referring to the wax-paper process, "I prefer a weaker bath, which is prepared by mixing half a drachm with ten ounces of water." In either case it will be found necessary to add solution of nitrate of silver in small quantities, as the developing picture seems to require it.

Returning again to the solutions marked 1, 2, 3, the numbers will assist the memory in mixing the proportions of each. If the paper is required to be used at once, a drachm of each may be mixed together and spread over the iodized paper (of course, in a dark room), which is then transferred to a clean blotting-book of white bibulous paper, and being placed in the paper-holder may be taken to the camera and exposed at once. If the paper is not required to be used immediately, the solutions are mixed in the proportions of the numbers—viz., one of No. 1, two of No. 2, three of No. 3; and in making the mixture, it is advisable to keep a measure specially for No. 3, the gallic acid, or else the measure, if used for the three solutions, will have to be washed out every time, which is very troublesome, particularly where water is not plentiful.

If the excited paper is required to be kept some hours before use, No. 3 must be added in still larger proportion, as much as ten or even twenty measures of No. 3 to two of No. 2, and one of No. 1, being used, and even this large dilution is frequently insufficient to prevent the paper spoiling in hot weather; therefore if the temperature is high, too much reliance must not be placed on this paper, as it is peculiarly disappointing, after walking some miles to romantic and beautiful scenery, to find, when developing the pictures in the evening, that the paper used was all spoilt before exposure; and it will be seen presently that when the excited paper is to be carried about for use, it is better to adopt the wax-paper process.

After the excited iodized paper is exposed in the camera—and the time of exposure cannot be taught, as that speciality is only acquired by experience, and may vary from five to thirty minutes, or even more—the invisible picture is developed and rendered visible, not by exposure to the vapour of mercury, as in Daguerre's process with silver plates, but by a mixture of one of No. 1 with four of No. 3. The development is carefully watched by looking through the negative placed before a lighted candle, and the time of development may vary from ten to thirty minutes, and all the time the picture must be kept wet with the solution, so that it is better perhaps to make a bath of the solution and lay the picture on its surface than to pour the liquid over the picture. After the development is matured, the picture is now washed in clean water, and fixed temporarily, if required, by immersion in a bath containing 200 grains of bromide of potassium in one pint of water, or permanently by the hyposulphite of soda, made by mixing one part of a saturated solution with five or ten of water, or one ounce of the salt to six or twelve of water; but, as before mentioned, it is better to keep a Winchester quart full of a saturated solution of hyposulphite of soda, and then it is always ready for use instead of employing the weights and scales, and continually weighing out portions of the salt. The picture after fixing is thoroughly washed with water, and being dried is now placed between the folds of a wax book—i.e., some leaves of blotting-paper are kept saturated with white wax, and when a picture is placed between them, and a hot iron passed over the outside sheet, the wax enters the pores of the paper, and after removing any excess of wax by passing the picture through a book of bibulous paper, over which the hot flat iron is passed, the negative picture at last is ready for use, and any number of positive copies may be taken from it, as already described in the first experiment, [page 139.]

This mode of manipulation is called the Talbotype, and before dismissing the subject another process of iodizing the paper may be explained.

To a solution of nitrate of silver of twenty, thirty, or fifty grains to the ounce of water, a sufficient number of the crystals of iodide of potassium is added, first to produce the yellow iodide of silver, and then to dissolve it, so that the yellow precipitate appears with a small quantity, and disappears with an excess of the iodide. If this solution is spread over sheets of paper, and these latter then placed in a bath of water, the iodide of silver is precipitated on the surface, and after plenty of washing to remove the excess of iodide of potassium, the paper may be dried, and will keep for any length of time without change. This paper may be excited, exposed, developed, fixed, and waxed, as already explained.

Fourth Experiment. The Wax-paper Process.

This mode of taking negative photographs begins where the talbotype ends—viz., by first waxing the paper perfectly and evenly, as already explained, Cansan's negative paper being preferred. The wax paper is now well soaked in a bath, made by dissolving one hundred grains of iodide of potassium, six grains of cyanide of potassium, four grains of fluoride of potassium, ten grains of bromide of potassium, ten grains of chloride of sodium, in one pint of fresh whey, with the addition of a little alcohol and a few grains of iodine. When soaked in this solution for about one hour, the paper is taken out and hung up to dry.

N.B. With respect to iodizing the wax paper, it is almost better to obtain it ready prepared, and then every sheet may be relied on. Mr. Melhuish, of Blackheath and Holborn, supplies it in any quantity, and his paper never fails; the operator has then only to perform the sensitizing and developing processes. To render the iodized paper sensitive it is immersed for about six minutes in a bath containing a solution of nitrate of silver (thirty-five grains to the ounce of water, with forty drops of glacial acetic acid); the paper is now removed, and washed in two trays of common clear rain-water or distilled water, and is then dried on between folds of blotting-paper.

This process may be performed on the previous evening by the light of a candle, or by day in a room lit by one window covered with four thicknesses of yellow calico, and after the paper is dry it will keep for three weeks or a month, and may be exposed in a camera with a three-inch lens of eighteen-inch focus, with the inch diaphragm, on a bright day from five to fifteen minutes; in bad weather the exposure must be longer. The picture may be carried home and rendered visible or developed by immersion in a bath containing a saturated solution of gallic acid, and as the developing continues, a few drops of the sensitizing solution of nitrate of silver and glacial acetic acid may be added. Finally, the picture is fixed by immersion for a quarter of an hour in a solution of hyposulphite of soda (four ounces of the crystal to one pint of water, or one part of the saturated solution to eight of water), and being well washed, is then dried, hung before the fire to melt the wax, and is now ready to print from.

Fifth Experiment. Albumen on Glass Process.

Albumen is the scientific name for the white of egg, of which four ounces by measure are mixed with one ounce and a half of distilled water, and after being whisked to a froth, are removed by a spoon into another basin or a beaker glass, and allowed to stand for several hours and then filtered. Mr. Crookes has recommended a very ingenious, simple, and useful filter. (Fig. 139.) He says: "This simple and inexpensive piece of apparatus, which any instrument maker or glass-blower can supply at a few hours' notice, will be found invaluable in almost every photographic process on glass. The sponge has this great advantage over all other kinds of filters, that thick gelatinous liquids—e.g., honey, albumen, gelatine, meta-gelatine, or the various preservative syrups—flow through it with the utmost readiness; whilst at the same time dust, air bubbles, or froth, and dried particles floating in the liquid, are effectually kept back, and if fitted with stoppers, collodion might be filtered in it; or if the ends were fitted together with a bit of flexible pipe, the stoppers might be dispensed with altogether.

Fig. 139.

a b. Glass tube, bent as in picture. c. Piece of damp sponge squeezed into the head of the tube. Any liquid poured in at b will flow through the sponge until it has attained the same level in a.

Having poured the albumen on a perfectly clean glass plate, taking care to have sufficient to run freely over the surface of the glass, the excess is then gently drained off and the plate turned so as to have the coated side downwards; it is then fixed in a sling made by taking a stout bit of string about three feet long, which is doubled and knotted at the fold, leaving the two ends free; two small triangles or stirrups of silver wire looped at one corner are now tied on to the ends of the string, and these form a support for the opposite edges of the glass plate to rest on; the two strings are knotted together at a convenient distance from the stirrups to prevent the glass slipping out, and the plate is now rotated rapidly over a heated metallic surface, such as an iron box containing some burning charcoal or the warming pan, care being taken to avoid dust as much as possible, and to use only the whites of new-laid eggs. (Fig. 140.) The glass plate, covered with dry albumen, is now iodized to a straw colour by exposure over a box containing iodine, as in the Daguerreotype process, and is sensitized by immersion for three or four minutes in a bath containing a solution of nitrate of silver (twenty-five grains to an ounce of water); the plate is afterwards washed in distilled water and left to dry spontaneously, of course in a darkened room. The plates may then be placed ready for use in a very ingenious tin box devised by Mr. Crookes, which keeps them perfectly light-tight even in the sun, and at the same time is less bulky than the ordinary wooden ones. It is made of tin plate, the cover sliding tight over the top, and more than half way down the sides; light is further excluded by means of an outer jacket of tin, which is soldered to the box a little below the centre. The cover thus slides between the case and the jacket, and renders injury to the plates by the entrance of light an impossibility. (Fig. 141.)

Fig. 140.

a. Loop for finger. b. The knot which prevents the stirrups of silver wire, c c, slipping off the corners of the glass plate. d d. The opposite corners of the glass plate on which the stirrups are placed.

a a. Tin box, with partitions to hold glass plates, b b. The outer jacket, between which and the box, a, the lid or cover, c, slides.

The sensitive albumenized glass plate is exposed in the camera from fifteen to thirty minutes, and developed (much in the same way as the paper pictures) with one ounce of a saturated solution of gallic acid containing ten or fifteen drops of the sensitizing solution. The plate is usually placed on a levelling stand, and the solution poured on the glass plate; the development is slow, and may be quickened sometimes by the application of heat.

The picture is fixed by immersion for a short time in a bath containing one part of a saturated solution of hyposulphite of soda in eight of water. The pictures produced by this process are exquisitely defined, provided always the camera is well focussed, and to assist this operation a magnifying glass may be employed. After removal from the hyposulphite of soda the plate is well washed with water, and being allowed to dry spontaneously, is now ready to print from.

Sixth Experiment. The Collodion on Glass Process.

The glass plates for this, as well as the albumen on glass process, should be cleaned by rubbing them over first with a mixture of Tripoli powder and ammonia, which is washed off under a tap, and the glass being drained is rubbed dry and polished with a clean calico duster kept exclusively for this purpose.

The iodized collodion is now poured on, and the excess returned to the bottle. Collodion can be made very easily, but if prepared without due precautions, it cannot be used afterwards, and reminds one of the old story of the enthusiastic son, who, when asking his father's permission to espouse the beloved, enumerated amongst her other accomplishments, the fact that she could make a pudding, and was answered by the bluff question, "But can you eat it afterwards?" So it is with collodion: a great deal of messing and loss of time is saved by purchasing it of the various makers, amongst whom may be specially noticed Mr. Richard Thomas, of 10, Pall Mall, who has devoted the whole of his attention to the preparation of this important photographic chemical, and with a success which his numerous patrons can well testify. The collodion is sold either mixed with the iodizing solution, or the two can be obtained separately, with directions on the bottles as to the quantities to be mixed together.

The plate covered with the iodized collodion is quickly transferred to a bath containing a solution prepared in the following manner:—Dissolve four ounces of nitrate of silver in eight ounces of water, and to this add twenty grains of iodide of potassium in one ounce of water; shake them together, and then pour the whole into fifty-six ounces of distilled water, and in half an hour add one ounce of alcohol and half an ounce of ether; agitate the whole and filter the next morning. The collodion plate is kept in this solution for a certain period, only learnt by experience, and should be occasionally lifted out to see if a uniform transparency is obtained; say that the immersion may be continued for five minutes, it is now ready for the camera, and may be exposed from about one to two minutes, or more if the light is deficient; the time of exposure is also a matter of practice, mere directions can be of no use in this stage of the process.

The picture is developed on a levelled stand, with a solution of three grains of pyrogallic acid in three ounces of water, to which sixty drops of glacial acetic acid have been added. When fully developed the plate is washed with water and fixed with a solution of hyposulphite of soda, consisting of one part of the saturated solution to eight of water, again thoroughly but gently washed, so as not to endanger the separation of the film from the glass; it is allowed to dry spontaneously, and being coated with amber varnish (a solution of amber in chloroform) is now ready to print from. It is, perhaps, hardly necessary to add, that the sensitizing and developing processes must be performed in a dark room.

Fig. 142.

a. Glass or gutta-percha bath to hold the sensitizing solution. b. Glass, with piece cemented on the end to hold the prepared glass plate, c, whilst dipped in the bath, a. The plate c has a cross in one corner to show prepared side.

Fig. 143.

First effect of peripatetic photography on the rural population.

BROMINE.