Utilization of Silver Residues.
All paper or solutions in which there is silver should be saved, as it has been proved by experience that from 50 to 75 per cent. of the whole of the silver used can be recovered by rigid adherence to the careful storage of "wastes."
1. All prints should be trimmed, if practicable, before toning and fixing; in all cases these clippings should be collected. When a good basketful of them is collected, these, together with the bits of blotting-paper attached to the bottom end of sensitized paper during drying, and that used for the draining of plates, should be burnt in a stove, and the ashes collected. These ashes will naturally occupy but a small space in comparison with the paper itself. Care should be taken that the draught from the fire is not strong enough to carry up the ashes.
2. All washings from prints, waters used in the preparation of dry plates, all baths, developing solutions (after use), and old toning baths, should be placed in a tub, and common salt added. This will form silver chloride.
3. The old hyposulphite baths used in printing should be placed in another tub. To this the potassium sulphide of commerce may be added. Silver sulphide is thus formed.
4. To No. 1 nitric acid may be added, and the ashes boiled in it till no more silver is extracted by it. The solution of silver nitrate thus produced is filtered off through white muslin, and put aside for further treatment, when common salt is added to it to form chloride, and added to No. 2.
5. The ashes may still contain silver chloride. This may be dissolved out by adding a solution of sodium hyposulphite, and adding the filtrate No. 3.
6. No. 2, after thoroughly drying, may be reduced to metallic silver in a reducing crucible[30] by addition of two parts of sodium carbonate and a little borax to one of the silver chloride. These should be well mixed together, and placed in the covered crucible in a coke fire, and gradually heated. If the operator be in possession of one of Fletcher's gas furnaces he can employ it economically, and with far less trouble than using the fire. (It is supplied with an arrangement for holding crucibles, which is useful for the purpose.) After a time, on lifting off the cover, it will be found that the silver is reduced to a metallic state. After all seething has finished, the crucible should be heated to a white heat for a quarter of an hour. The molten silver should be turned out into an iron pan (previously rubbed over with plumbago to prevent the molten metal spirting), and immersed in a pail of water. The washing should be repeated till nothing but the pure silver remains.
The silver hyposulphite, having been reduced to the sulphide by the addition of the potassium sulphide, is placed in a crucible, and subjected to a white heat; the sulphur is driven off, and the silver remains behind.
Another method of reducing silver chloride to the metallic state is by placing it in water slightly acidulated with sulphuric acid together with granulated zinc. The zinc is attacked, evolving hydrogen, which, in its turn, reduces the silver chloride to the metallic state, and forming hydrochloric acid. After well washing, the silver may be dissolved up in nitric acid.
Yet another method is to take sugar of milk and a solution of crude potash, when the silver is rapidly reduced. This requires careful washing, and it is well to heat the metal to a dull red heat to get rid of any adherent and insoluble organic matter which may have been formed, before dissolving it in nitric acid.