THE AGE OF THE EARTH

The greatest achievement of the “plumbologists” has been the calculation of the age of the earth, first proposed by Houtermans, a German physicist, and independently by Arthur Holmes, a British geologist, in 1946 and finally perfected by C. C. Patterson in 1953. It is actually a rather simple calculation, although the way to discovering it was far from easy. Before we look at it in detail, however, let’s consider some basic assumptions and explain what is meant by “the age of the earth”.

From studying the mechanics of the solar system, scientists have become reasonably certain that the earth and the other planets and their satellites all were formed in a common process in a relatively short period of time, geologically speaking. Perhaps it took a dozen million years or so, but compared to the time that has elapsed since, that is a twinkling. At some time soon afterwards, the earth became molten, or at any rate fluid enough to allow much of its iron to settle toward the center to form the earth’s core. Similar cores presumably formed in other planets. As the iron went down, it took some lead with it, and as the silica went up, uranium followed it toward the surface, because of the chemical affinity between these kinds of elements. In the present earth, we have found, almost all the uranium is concentrated in the top layer, or crust, which is only about 25 miles thick under the continents and even thinner under the oceans.

Internal structure of the earth. The central core is probably an alloy of iron and nickel, surrounded by a mantle of less dense silicate material, with a thin crust of still lighter silicates.

The time of this early and relatively rapid separation of uranium and lead on a worldwide scale is the event that plumbologists can determine, and the period since then is what they mean by “the age of the earth”. When Houtermans first wrote about it, he called it “the age of uranium”.

How is this done? We have said that one of the isotopes of uranium, ²³⁵U, decays faster—about 6.3 times faster—than the other, ²³⁸U. They decay into two different isotopes of lead. Therefore, if we can determine the isotopic composition of average ordinary lead in the earth’s crust today, and if we can somehow obtain a sample of the kind of lead that is locked in the earth’s core, we can calculate how long it took to change the [PRIMORDIAL] lead (like that in the core) into present-day lead in the crust by the gradual addition of radiogenic lead—lead that has resulted from the decay of uranium. Now, someone might logically ask, “Isn’t it necessary to know also the actual amount of uranium involved in the process, and isn’t this difficult to determine?” It turns out to be a remarkable aspect of the Holmes-Houtermans calculation that the uranium-concentration terms cancel out in the equations and only the ratio of the isotopes and their decay constants need be considered. These are all known accurately.

Next, we must decide just what is average present-day lead? It isn’t enough to go to a lead mine and get a sample, because, unfortunately, leads from different mines have widely varied isotopic composition—that is, a different mixture of four natural isotopes, ²⁰⁴Pb, ²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb—as a result of their geologic histories. No, lead samples from a mine won’t do. However, geologists have been able to separate lead from recent marine sediments, obtained from the ocean bottom, far from land. These are of uniform composition, and are good samples of what the world’s rivers bring into the ocean. Other useful samples can be found in plateau basalts, which are enormous bodies of dark volcanic rock that make up the bedrock in many parts of the world. The lead from these basalts is isotopically very much like the lead in the oceans.

Very well, but how about the lead from the core? Where can we hope to find a sample of it? It turns out to be easier than you might think. Astronomers believe it highly probable that most meteorites are fragments of a former planet that broke up for reasons that are not entirely clear. It is pretty definite, however, that this protoplanet (or these protoplanets, for there may have been more than one) had an iron core, and this core (or these cores) is the source of the iron meteorites sailing around in space. A large meteorite hit the earth not too long ago (geologically speaking) and caused the Meteor Crater near Canyon Diablo in Arizona.

Examining ocean-bottom sediments obtained by lowering a tube-like instrument that brings up a long rod-shaped “core”, prior to nuclear age determination of the sample.

Many fragments of the meteorite iron have been found around the crater, and it is reasonable to assume that this is the kind of iron we would expect to find in the core of the earth. Like the core iron, it is mixed with a little lead, which can be isolated and analyzed in a mass spectrometer for its isotopic composition. This lead is found to be much less contaminated with radiogenic lead, and hence is much more primitive than the oldest leads found on earth. Thus, meteorites presumably are as close as we can get to true primordial lead—the lead of the time when the earth (and the protoplanet) first formed.

Once these measurements were available, it was easy to write the Houtermans equation for present-day and primordial leads in this way:

(²⁰⁶Pb²⁰⁴Pb) present - (²⁰⁶Pb²⁰⁴Pb) primordial
²⁰⁶Pb
²⁰⁴Pb
²⁰⁶Pb
²⁰⁴Pb
(²⁰⁷Pb²⁰⁴Pb) present - (²⁰⁷Pb²⁰⁴Pb) primordial
²⁰⁷Pb
²⁰⁴Pb
²⁰⁷Pb
²⁰⁴Pb

= 137.7

(eλ238t - 1)
(eλ235t - 1)

The present ratio of ²³⁸U to ²³⁵U is 137.7.

e = the base of natural logarithms λ = the [DECAY CONSTANT] of each isotope of uranium t = the age of the earth.

Substituting the best experimental lead isotope ratios into the equation and solving for t, Patterson was able to calculate that the earth is 4550 million years (4.55 aeons) old. Subsequent calculations based on other procedures generally have confirmed that result.