Lead and Zinc
Lead mining was one of the earliest industries of Illinois. The early settlers’ need for bullets for procuring food and for defense of their lives and property made lead an important commodity, and the deposits of lead ore in the northwestern corner of Illinois were quickly exploited. The ore was the mineral galena ([fig. 5]), for which the city of Galena in Jo Daviess County is believed to have been named.
Figure 5—Galena with cubic cleavage blocks in foreground.
Galena is a dark, shiny mineral that breaks readily into cubes or combinations of cubes. It is composed of lead and sulfur (PbS). Galena itself is not suitable for use as a metal; the lead must first be separated from the sulfur.
The earliest method of recovering lead from galena was crude. A pile of logs, smaller pieces of wood, and ore was built on sloping ground. Just below it a pit was dug. When the wood was set on fire, the heat caused the lead and sulfur to separate, and the molten lead trickled down into the pit. The smelting process was later improved, and stone “furnaces” were built to house the operations.
Crevice Deposits and Residual Deposits.—Most of the lead ore mined in the early days of the northwestern Illinois mining district came from crevice deposits in the dolomite bedrock and from residual deposits at or near the surface of the ground. The crevices were vertical narrow joints or fissures. Ore was not continuously present along them but occurred from place to place in “pods” ([fig. 6] and [fig. 7]). Dimensions of the pods varied, but typical ones were about 3 feet wide, 5 feet high, and a few to a few hundred feet long. The galena, for the most part, occurred in a mixture of clay and weathered dolomite that filled, or partly filled, the crevices.
The residual deposits were found where the action of the weather for many thousands of years had dissolved the dolomite from the outcropping parts of a crevice deposit and left behind a residue of brown or red clay containing galena.
Some of the crevice and residual deposits worked by the early miners cropped out at the surface, but most of them were covered by earth. Other crevices were exposed in the bluffs of the Mississippi River and extended back into them for 1,000 feet or more.
Figure 6—Diagrammatic cross section of two crevice deposits. A reaches ground surface and is filled with clay; B is only partly clay filled. Galena coats parts of the walls and occurs as pieces scattered through the clay. Typical crevices are about 3 feet wide and 5 feet high.
SOIL A GALENA CLAY AND ROTTED DOLOMITE B GALENA CLAY AND ROTTED DOLOMITE DOLOMITE
When the richer deposits of ore in the crevices were worked out, some mines were deepened into the dolomite bedrock, but usually less rather than more galena was found.
As the amount of galena decreased, however, another mineral, which had been present before in only small amounts, was found in increasing quantities. This was sphalerite—a yellow, brown, or black mineral of resinous appearance that is composed of zinc and sulfur (ZnS). It does not look like a metallic ore.
At first the sphalerite was not used because there were no smelters in the area that could separate the zinc from the sulfur with which it was combined in the ore. Between 1850 and 1870, however, smelters were built in northwestern Illinois and southern Wisconsin and the ore was shipped there. Sphalerite is now the principal ore mineral produced in northwestern Illinois.
The sphalerite and galena of southern Illinois, described later, are similar to that found in northwestern Illinois.
Figure 7—Crevice lead mine. Miner pries ore loose and pushes it into car at bottom of crevice. Shiny galena layer occurs above his head and another at level of his waist.
Mining and Milling.—One large mine is producing zinc and lead near Galena at present. Smaller mines operate irregularly. The ore may occur as pockets, irregularly shaped rather flat masses, vertical or inclined veins ([fig. 8]), or small particles scattered through the dolomite. The principal ore bodies that have been worked in recent years have been of irregular shape, both horizontally and vertically, and usually have been between 50 and 200 feet wide and from a few to as much as 100 feet high. They lie at a depth of roughly 300 feet.
Blasting is required to loosen and break the ore. At the large mine the ore is brought to the surface by a hoist. In some relatively shallow mines an inclined tunnel has been driven to the ore body and the ore brought to the surface in trucks.
Figure 8—Diagrammatic cross section of a zinc ore deposit showing flats and pitches. The deposit occurs in limestone and dolomite. Much of the ore is a mixture of dolomite, limestone, calcite, and sphalerite. Typical dimensions of such a deposit are about 30 feet high and 100 to 200 feet wide.
ORE PITCHES FLATS
Because the ore consists of galena and sphalerite attached to and scattered through dolomite, it must be milled to free and separate the metals from the rock. Crushing, grinding, and other operations are involved. The dolomite is discarded and the galena and sphalerite concentrates are shipped away to be smelted. No smelters have operated in the Galena area for some time.
Aids to Prospecting.—Finding deposits of ore 300 feet underground is not easy. Inspection of the surface usually tells little. To find and outline a commercial ore deposit many holes often must be drilled to explore the unexposed rock strata. Because this is a costly process, every possible means is employed to drill the holes where ore is most likely to be found. This is where geologists are useful—geologists of the mining companies and of the Illinois Geological Survey. Three examples of how their investigations help to find ore are given here.
It was noted early in the development of the northwestern Illinois mining district that zinc ore deposits were most common along small downfolds in the bedrock, called synclines, that were a few hundred feet wide and a mile or so long. The synclines were associated with much larger synclines that extended for several miles. A map prepared by the Illinois Geological Survey shows the possible location and extent of many of these downfolds and has had much practical use in the selection of the most promising areas for test drilling to find ore.
The Survey also collects the records of borings made by companies and individuals in their search for ore. The records are on permanent file at the Survey offices and are valuable in several ways. Some indicate where no ore was found and where it is, therefore, useless to drill further; others show only traces of ore but suggest that more drilling in the vicinity might discover a deposit large enough to be mined profitably. Still other records are of borings that encountered rich ore in which mines have been developed.
The third aid to prospecting is the study of ore bodies and their minerals to determine how the deposits were formed. The ore bodies have been and are being studied in the mines. Ore specimens are carefully examined in the Survey laboratories. If geologists can learn how the known deposits were formed, it may be possible to direct exploration into promising new areas.