Practical Hand Book of Gas, Oil and Steam Engines / Stationary, Marine, Traction; Gas Burners, Oil Burners, Etc.; Farm, Traction, Automobile, Locomotive; A simple, practical and comprehensive book on the construction, operation and repair of all kinds of engines. Dealing with the various parts in detail and the various types of engines and also the use of different kinds of fuel.

by John B. Rathbun

(85) Storage Batteries.

The purpose of the storage battery is to store or accumulate the current generated by a dynamo until so that the current will be available when the dynamo is not running. A storage cell does not “store” current in the same way that water is held in a tank, but returns the energy expended on it through the chemical changes caused in the cell by the current.

When the charging current passes through the storage battery chemical changes are produced in the electrodes and electrolyte, and the energy expended on the cell is in the form of latent chemical energy, in which state it remains until the electrodes are connected with one another by a wire or some other conducting medium. When the electrodes are connected through an external circuit, the electrolyte acts on the electrodes causing them to assume their original composition. As they pass into their previous chemical condition the latent chemical energy is converted into electrical energy. The current thus produced may be used in the same way as in a primary cell.

When discharging, the action of a storage battery is similar to that of a primary battery, the current being produced by the action of a fluid on two dissimilar electrodes. Instead of supplying new elements when the battery is discharged, as in the case of the primary cell, the elements are brought back to their original state by passing a current through the cell in the opposite direction to that of the discharge.

There are several combinations of materials which may be used in the making of storage battery electrodes and electrolytes, but with the exception of the lead sulphuric battery and the new Edison battery none have proven a commercial success.

The most common type of storage or secondary cell is the lead-sulphuric type in which the electrolyte is dilute sulphuric acid and the electrodes are lead plates, covered with a chemical composition known as the active material. These plates usually consist of a lead grid, or lattice frame in the pockets of which is pasted the active material. The pockets or lattice bars of the plates are for the purpose of supporting the active material which is of a weak and spongy nature. The active material on the positive plate is usually litharge, while that on the negative plate is red lead.

After charging, the active material on the positive plate is changed to lead peroxide by the action of the current, and the active material on the negative plate is changed into spongy metallic peroxide. The composition of the active material on the plates determines the direction of flow of the discharge, or secondary current. The current flows from the positive plate to the negative through the external circuit.

When fully charged, and in good condition, the positive and negative plates may be readily distinguished by their colors, the positive plate being a dark brown or chocolate color, and the negative a slate or grey color.

The positive active material is hard, while the negative may be easily cut into by the finger nail. The density of the material changes slightly with the charge, as the material expands during the discharge.

The problem of holding the active material securely to the plates during expansion and contraction has been a hard one to solve, each manufacturer having some favorite form of grid or material plug to which he pins his faith. While great improvements have been made in this direction, it is certain that we have not yet reached perfection. Loose active material will cause short circuits and will reduce the output of the cell; loose active material frequently ruins a cell.

The current capacity of a storage battery depends on the area of the plates or electrodes, and in order to increase the capacity of a battery, and consequently the area, it is usual to use a number of plates connected in parallel. A number of small plates of a given area are to be preferred to two large plates of the same area, as the battery will be of a more convenient size.

Customarily there is one more negative plate than positive, so that the extreme end plates in a cell are negative, as the positive and negative plates alternate with each other when assembled.

An ignition battery usually consists of two negative plates and one positive. Cells used for power purposes have as high as sixty plates.

A single cell of storage battery should show about two volts when fairly well charged. If more than two volts are desired more cells should be connected in series. The total voltage will be equal to the number of cells, in series, multiplied by the voltage per cell. The voltage per cell should never be allowed to drop below 1.7 volts, as the cell is likely to be destroyed when operated with a low voltage. Recharge as soon as the voltage drops to 1.8 volts.

The ordinary six volt ignition battery consists of three separate cells connected in series, which are encased in one protecting box.

The plates are prevented from touching each other within the cell by means of a perforated sheet of hard rubber that is inserted in the space between the plates. The perforations allow the liquid to circulate between the plates.

The storage battery is furnished as standard equipment with several well known gas engine builders, and its use is advocated by nearly all. When used in connection with a low tension direct current magneto two independent sources of current are at hand, either of which will ignite the engine in an emergency.

With the magneto-storage battery combination, it is possible to obtain a few small lights at any time, whether the engine is running or not, and the engine is always ready to start on the first “over” with the storage battery and a good mixture.

If a magneto is not used, difficulty is sometimes experienced in obtaining a suitable source of charging current, as many localities do not possess direct current plants. Batteries may be charged from the direct current exciter in an alternating current station, or may be charged by an alternating current rectifier such as is used by automobile garages.

The principal objections to the storage cell are: inconvenience of charging; sulphating of cell when standing without a charge; ease with which the cell is ruined by short circuits; the damage caused by the spilling of the electrolyte; and the fact that the cell gives no warning of failing or discharged condition.

Since the composition of the plates depends on the direction in which the current flows through the cell, it is obvious, that an alternating current which periodically changes its direction of flow will first charge the plates and then discharge them alternately. The result of an attempt at charging with alternating current would be that the plates would be in the same or a worse condition in a short space of time than they were at the beginning. In charging a storage cell care should be taken to determine the character of the current, especially when the cell is to be charged from a magneto. When under charge, the cell is connected to the charging circuit in such a way that the current flows backwards through the cell or in a direction opposite to that when the cell is discharging.