(86) Care of the Storage Cell.
The storage battery should never be left in an uncharged condition with the acid electrolyte in the cell, for the solution will quickly attack the uncharged plates and combine with them to form lead sulphate. As lead sulphate has a high electrical resistance and is insoluble in the electrolyte the sulphate coating will reduce the output or if present in excess, ruin the cell. The sulphate appears as a white coating on the surface of the plates. The only remedy for this condition at the hands of the average engine operator is a prolonged charge, or over charge, at a slow rate. There are several chemical processes but they are too complicated for the average man.
As sediment collects on the bottom of the battery jars, and is liable to cause a short circuit, the plates should be held about half an inch from the bottom of the jar. Care should be taken that the cells of the stationary type of battery are kept dry and clean. Do not allow dirt to drop into the solution as it is liable to destroy the cell.
A volt meter should be used to determine the condition of the battery, and should be used frequently. An ammeter should never be used on a storage battery, as it is of very low resistance, and would probably cause a rush of current that would destroy both the battery and the instrument.
Never short circuit a storage battery, even for an instant, as excessive current will cause the plates to buckle, or will loosen the active material on the plates.
The plates are immersed in the electrolyte, which should cover the entire plate or active surface. If the solution does not cover the plate, the capacity of the cell will be reduced. Plates that are partially covered with solution deteriorate rapidly from “sulphating.” This is caused by the air and acid acting on the damp inactive portion of the plate.
Usually the electrolyte consists of a dilute solution of sulphuric acid and water, but in some ignition cells the solution is “solidified” by some substance to about the consistency of table jelly. The object of this thickened solution is to prevent the solution from slopping and leaking when the battery is being transported.
The solution used in a storage battery is exceedingly corrosive in its action, and if spilled on metal or wood will destroy it immediately. Care should be taken in handling the electrolyte.
A cell should never be discharged below 1.7 volts for below this point, the plates are likely sulphate. When the solution is replaced by fresh, or water is added for the purpose of restoring the electrolyte to its original level, use only distilled water, free from metallic salts and suspended matter.
Many people “test” their cells by snapping a wire across the terminals to “see if there is a good spark.” Nothing could be more injurious to the battery, and as this test indicates nothing, the practice should be discontinued. Make all your tests either with a hydrometer or a voltmeter, the latter is preferable in the average case.
The electrolyte is a solution containing approximately 10% of chemically pure sulphuric acid and 90% of distilled water. The specific gravity of the fluid should be from 1,210 to 1,212 in all cases. A standard battery hydrometer should be used by all storage battery users to ascertain the exact density of the solution as the specific gravity is a direct index to the condition of the cell. A gasoline hydrometer is useless for a storage battery.
When mixing the electrolyte it should be placed in a glass or porcelain jar, and the process should never be performed in the battery jar in the presence of the plates. The solution is very active chemically and should not be brought into contact with metallic or organic substances because of the danger of contaminating the fluid. The acid should always be poured into the water in a thin stream while the mixture is being stirred with a glass or porcelain rod. Pouring the water into the acid is likely to produce an explosion and should therefore be carefully avoided.
As the acid heats the water during the mixing the hydrometer reading should not be taken until the heat caused by the first addition of acid has been reduced to that of the room. Taking a reading with a hot solution will give inaccurate results, unless, of course, the reading is reduced to normal by the method described in a previous chapter. When the reading has been taken and found to be correct and the solution has been reduced to the temperature of the room, the electrolyte may be poured into the cell through the filler openings in the top of the cell. Pour into each cell sufficient fluid to cover the plates but avoid filling the cell to the top, or flooding it.
At the end of the charging time given by the maker, withdraw a sample of the electrolyte by means of a syringe and test the specific gravity. This should not be over 1,290 for a fully charged cell, and if the solution exceeds this amount, pure water should be added until the proper point is reached. Always correct the specific gravity in this way every time the battery is charged as evaporation and internal chemical changes cause the density to change from time to time. The voltage of a good storage battery will be about 2.1 volts when fully charged. Overcharging is wasteful and finally destroys the cell, the effects being similar to those caused by excessive discharges, that is, buckled plates and loosened active material. Overcharging a sulphated battery may cure the trouble, a little overcharging at intervals being better than a long continued overcharge.
An increase in the specific gravity of the electrolyte of from 30 to 50 degrees, with a corresponding rise of voltage, shows that the cell is fully charged.
After the charging is completed remove all of the solution spilled on the battery, preferably by washing, and wipe bone dry. If the solution is higher in the air, remove the excess with the syringe.