CONDUCTION OF HEAT
We have seen that the ice-lens was not affected by the passage of heat through it. If we now take hold of the lens we shall experience a feeling of cold, and the lens will begin to melt. Heat has passed from our hand into the ice. The process by which heat passes from one body to another in contact with it is called conduction. The fundamental law of conduction is, that heat always passes from a warm body to a cold one. Clerk Maxwell illustrated this law in a series of very simple experiments. He placed a silver teaspoon in a cup of hot tea, and noted that the handle became warm gradually from the hot tea; the heat passed from the bowl of the spoon in the tea to successive parts of the handle until the whole spoon was hot. His second experiment was to put two cold spoons, one of silver and one of German silver, into the tea, when he found that the same phenomenon took place, but that the silver 103 spoon became hot much more quickly than did the German silver one. He then put three spoons into the tea, made respectively of silver, of German silver, and of bone. In the result, he found that when the other two were hot, the bone spoon hardly showed any sign of heat at the end of its handle.
The conclusion to be drawn from these experiments is that heat passes at different rates through different substances. Substances through which heat passes quickly are called good conductors of heat. The law of the conductivity of heat is that in a homogeneous body the flow is continuous, and is from the region of high temperature to the region of low temperature, and that it continues until the body is of uniform temperature throughout. The law is the same for bodies of different materials when in contact one with another.
The conduction of heat is in operation in every department of domestic life. People live in houses and are clothed to protect them from the vicissitudes of the weather, including the cold of winter and the heat of summer; use is made of the phenomenon in warming the house and in the preparation of food.
In selecting materials for various purposes, account has to be taken of their conductivities, for in some cases it is desirable that the transfer of heat should take place slowly, and in others that it should take place quickly. It might be thought that the conductivity of a substance could 104 be estimated by touch, but a little reflection will show that this cannot be the case. The flow of heat between two bodies depends upon the difference of temperature between them, and if there should be no difference of temperature between them at the moment of touch there will be no flow of heat, though both are bodies of greater or less conductivity. Let us take, for example of the uncertainty of estimation by touch, a well-known experiment. Suppose we have a basin of hot water and a basin of cold water, and place a hand in each for a few moments; suppose we withdraw the hands and plunge them into a basin of tepid water, we shall find that the tepid water feels cold to the hand that was in the hot water and warm to the hand that was in the cold water.
Luckily, it has been found possible in the laboratory to refer substances to a common standard and to assign numerical values to them in order of their conductivities, so that substances can be compared and a selection made for any desired purpose. Pure silver has the highest conductivity; other useful materials take the following order: copper, zinc, lead, iron, steel, marble, glass, brick, slate, wood, fur, cotton, flannel, water, air. Fur and wool no doubt owe much of their warmth to the fact that they consist of fibres which enclose a good deal of air, but as a matter of fact the warmth of loosely woven woollen and knitted articles in general is often overrated; they are very warm as under garments or in calm 105 weather, but in windy weather the air in them is rapidly changed and the cold seems to blow through them. If for any purpose we select a material from its place in a table of comparative conductivities, and use it without reference to the law of conduction of heat, we shall probably be disappointed with the result. We know that cotton burns easily; if we stretch a cotton handkerchief over the back of a gold watch and place a red-hot cinder from the fire on the handkerchief on the watch, the handkerchief will not be burnt.
Many interesting problems present themselves when a house has to be built or rented. There is often opportunity for some choice of material in walls or roof, and some peculiarities to be considered. Are the top rooms of a thatched cottage warmer or colder than the top rooms of a house covered with slates? Is a wooden or an iron building warmer? What difference does it make if the iron building is lined with wood? If the iron walls were twice as thick, what would be the effect inside the room? Would the walls of such a building be always dry inside? It sometimes happens that the end wall of a row of houses is covered with slates to preserve it from the effects of storms of wind and rain; will that inside wall be always dry?
But the housewife is probably more interested in those articles in use in the house which it is her business to provide. Shall the stoves be of slate or iron? In olden days warming-pans were made of copper. What change in the manner of 106 use justifies making them of earthenware or India-rubber? The slow transmission of heat through thick woollen materials has been applied to the construction of Norwegian cooking-stoves (Fig. 5). These stoves consist of a wooden box, lined with well-padded felt. The cooking vessels are of metal; the food when at boiling point is placed in these vessels and the lids put on, a thick padded felt is placed on the vessels and entirely fills the wooden lid of the box which is then closed; the heat is preserved so that the cooking is continued without further attention. Would it be possible to use the Norwegian stove as a refrigerator? Would it keep an ice pudding cold without any alteration? In connection with this we may ask why freezing machines have the inner vessel in which the freezing takes place of zinc, and the outer vessel which contains the ice and salt of wood? What would be the effect of interchanging the materials?
Fig. 5.
It is possible that the excellence of some continental cookery is due to the extensive use on the continent of earthenware cooking utensils through which heat passes very slowly. The growing 107 fashion of using enamelled cooking vessels must have some effect on the food cooked in them as heat certainly passes quickly through them. Reference has been made to them simply to demonstrate the universality of the application of physical laws, and we may now return to the house and its arrangement for the comfort of the inmates.