A is a pear-shaped pan, charged with the liquid to be evaporated; it is furnished with a dome cover, in which there is an opening with a flange f, for attaching a tube, to conduct the steam wherever it may be required. a is the fire-place; b, the ash-pit. The conical part terminates below in the tube g, furnished with a stop-cock at its nozzle h. Through the tube c d c′, furnished above and below with the stop-cocks c and c′, the liquid is run from the charging back or reservoir. During the operation, the upper cock c is kept partially open, to replace the fluid as it evaporates; but the under cock c′ is shut. The flame from the fire-place plays round the kettle in the space e, and the smoke escapes downwards through the flue i into the chimney. The lower cylindrical part g, remains thus comparatively cool, and collects the crystalline or other solid matter. After some time, the under stop-cock c′, upon the supply-pipe, is to be opened to admit some of the cold liquor into the cylindrical neck. That cock being again shut, the sediment settled, and the large stop-cock (a horizontal slide-valve would be preferable) h opened, the crystals are suffered to descend into the subjacent receiver; after which the stop-cock h is shut, and the operation is continued. A construction upon this principle is well adapted for heating dyeing coppers, in which the sediment should not be disturbed, or exposed to the action of the fire. The fire-place should be built as for the [brewing copper].

[Fig. 384.] represents an oblong evaporating pan, in which the flame, after beating along its bottom, turns up at its further end, plays back along its surface, and passes off into the chimney. A is a rectangular vessel, from 10 to 15 feet long, 4 to 6 feet broad, and 1 or 112 feet deep. The fire-bricks, upon which the pan rests, are so arranged as to distribute the flame equably along its bottom.

EUDIOMETER, is the name of any apparatus subservient to the chemical examination of the atmospheric air. It means a measure of purity, but it is employed merely to determine the proportion of oxygen which it may contain. The explosive eudiometer, in which about two measures of hydrogen are introduced into a graduated glass tube, containing five measures of atmospheric air, and an electric spark is passed across the mixture, is the best of all eudiometers; and of these the syphon form, proposed by me in a paper published by the Royal Society of Edinburgh in 1819, is probably the surest and most convenient. Volta’s explosive eudiometer as made in Paris, costs 3 guineas; mine may be had nicely graduated for 6 or 8 shillings.

EXPANSION (Eng. and Fr.; Ausdehnung, Germ.), is the increase of bulk experienced by all bodies when heated, unless a change of chemical texture takes place, as in the case of clays in the potter’s kiln. [Table I.] exhibits the linear expansion of several solids by an increase of temperature from 32° to 212° Fahr.; [Table II.] exhibits the expansion in bulk of certain liquids.

TABLE I.—Linear Dilatation of Solids by Heat.

Dimensions which a bar takes at 212°, whose length at 32° is 1·000000.

Substances.Authority.Dilatation
in
Decimals.
Dilatation
in Vulgar
Fractions.
Glass tube,Smeaton,1·00083333
Glasdo.Roy,1·00077615
Glasdo.Deluc’s mean,1·0008280011116
Glasdo.Dulong and Petit,1·0008613011148
Glasdo.Lavoisier and Laplace,1·0008116611122
Plate glass,do. do.1·00089089011142
Pldo. crown glass,do. do.1·0008757211114
Pldo.crowdo.do. do.1·0008976011090
Pldo.crowdo.do. do.1·00091751
Pldo. rod,Roy,1·00080787
Deal,Roy, as glass,
Platina,Borda,1·00085655
Pldo.Dulong and Petit,1·0008842011131
Pldo.Troughton,1·00099180
Pldo.na and glass,Berthoud,1·00110000
Palladium,Wollaston,1·00100000
Antimony,Smeaton,1·00108300
Cast-iron prism,Roy,1·00110940
Cast-iron,Lavoisier, by Dr Young1·00111111
Steel,Troughton,1·00118990
Steel rod,Roy,1·00114470
Blistered Steel,Phil. Trans. 1795, 428,1·00112500
Blistedo.Smeaton,1·00115000
Steel not tempered,Lavoisier and Laplace,1·001078751927
Stdo. do.tedo.do. do.1·001079561926
Stdo. tempered yellow,do. do.1·00136900
Stdo.temdo.ed yedo.do. do.1·00138600
Stdo.temdo. ed at a higher heat,do. do.1·001239561807
Steel,Troughton,1·00118980
Hard Steel,Smeaton,1·00122500
Annealed steel,Muschenbroek,1·00122000
Tempered steel,do.1·00137000
Iron,Borda,1·00115600
Ido.Smeaton,1·00125800
Soft iron, forged,Lavoisier and Laplace,1·00122045
Round iron, wire drawn,do. do.1·00123504
Iron wire,Troughton,1·00144010
Iron,Dulong and Petit,1·001182031846
Bismuth,Smeaton,1·00139200
Annealed gold,Muschenbroek,1·00146000
Gold,Ellicot, by comparison,1·00150000
Gdo. procured by parting,Lavoisier and Laplace,1·001466061682
Gdo. Paris standard, unannealed,do. do.1·001551551645
Gdo.Paris s do. dardannealed,do. do.1·001513611661
Copper,Muschenbroek,1·0019100
Codo.Lavoisier and Laplace,1·001722441581
Codo.do. do.1·001712221584
Codo.Troughton,1·00191880
Codo.Dulong and Petit,1·001718211582
Brass,Borda,1·00178300
Bdo.Lavoisier and Laplace,1·00186671
Bdo.do. do.1·00188971
Brass scale, supposed from Hamburg,Roy,1·00185540
Cast brass,Smeaton,1·00187500
English plate-brass, in rod,Roy,1·00189280
Endo.h plado.rass, in a trough form,do.1·00189490
Brass,Troughton,1·00191880
Brass wire,Smeaton,1·00193000
Brass,Muschenbroek,1·00216000
Copper 8, tin 1,Smeaton,1·00181700
Silver,Herbert,1·00189000
Sido.Ellicot, by comparison,1·0021000
Sido.Muschenbroek,1·00212000
Sido.r, of cupel,Lavoisier and Laplace,1·001909741524
Sido.r, Paris standard,do. do.1·001908681524
Silver,Troughton,1·0020826
Brass 16, tin 1,Smeaton,1·00190800
Speculum metal,do.1·00193300
Spelter solder; brass 2, zinc 1,do.1·00205800
Malacca tin,Lavoisier and Laplace,1·001937651516
Tin from Falmouth,do. do.1·002172981462
Fine pewter,Smeaton,1·00228300
Grain tin,do.1·00248300
Tin,Muschenbroek,1·00284000
Soft solder; lead 2, tin 1,Smeaton,1·00250800
Zinc 8, tin 1, a little hammered,do.1·00269200
Lead.Lavoisier and Laplace,1·002848361351
Ldo.Smeaton,1·00286700
Zinc,do.1·00294200
Zinc, hammered out 12 inch per foot,do.1·00301100
Glass, from 32°, to 212°,Dulong and Petit,1·0008613011161
G do. from 212°, to 392°,do. do.1·0009182711089
G do. from 392°, to 572°,do. do.1·001011141987