Pure potassium, as procured in Sir H. Davy’s original method, by acting upon fused potassa under a film of naphtha, with the negative wire of a powerful voltaic battery, is very like quicksilver. It is semi-fluid at 60° Fahr., nearly liquid at 92°, and entirely so at 120°. At 50° it is malleable, and has the lustre of polished silver; at 32° it is brittle, with a crystalline fracture; and at a heat approaching to redness, it begins to boil, is volatilized, and converted into a green-coloured gas, which condenses into globules upon the surface of a cold body. Its specific gravity in the purest state is 0·865 at 60°. When heated in the air, it takes fire, and burns very vividly. It has a stronger affinity for oxygen than any other known substance; and is hence very difficult to preserve in the metallic state. At a high temperature it reduces almost every oxygenated body. When thrown upon water, it kindles, and moves about violently upon the surface, burning with a red flame, till it be consumed; that is to say, converted into potassa. When thrown upon a cake of ice, it likewise kindles, and burns a hole in it. If a globule of it be laid upon wet turmeric paper, it takes fire, and runs about, marking its desultory path with red lines. The flame observed in these cases is owing chiefly to hydrogen, for it is at the expense of the water that the potassium burns.
Potassa, even in a pretty dilute solution, produces a precipitate with muriate of platinum, a phenomenon which distinguishes it from soda. It forms, moreover, with sulphuric and acetic acids, salts which crystallize very differently from the sulphates and acetates of soda.
POTTERY, PORCELAIN. (Eng. and Fr.; Steingut, Porzellan, Germ.) The French, who are fond of giving far-fetched names to the most ordinary things, have dignified the art of pottery with the title of ceramique, from the Greek noun κεραμος, an earthen pot, compounded of two words which signify, in that language, burned clay. In reference to chemical constitution, there are only two genera of baked stoneware. The first consists of a fusible earthy mixture, along with an infusible, which when combined are susceptible of becoming semi-vitrified and translucent in the kiln. This constitutes porcelain or china-ware; which is either hard and genuine, or tender and spurious, according to the quality and quantity of the fusible ingredient. The second kind consists of an infusible mixture of earths, which is refractory in the kiln, and continues opaque. This is pottery, properly so called; but it comprehends several sub-species, which graduate into each other by imperceptible shades of difference. To this head belong earthenware, stoneware, flintware, fayence, delftware, iron-stone china, &c.
The earliest attempts to make a compact stoneware, with a painted glaze, seem to have originated with the Arabians in Spain, about the 9th century, and to have passed thence into Majorca, in which island they were carried on with no little success. In the 14th century, these articles, and the art of imitating them, were highly prized by the Italians, under the name of Majolica, and porcelana, from the Portuguese word for a cup. The first fabric of stoneware possessed by them, was erected at Fayenza, in the ecclesiastical state, whence the French term fayence is derived. The body of the ware was usually a red clay, and the glaze was opaque, being formed of the oxides of lead and tin, along with potash and sand. Bernhard de Pallissy, about the middle of the 16th century, manufactured the first white fayence, at Saintes, in France; and not long afterwards the Dutch produced a similar article, of substantial make, under the name of delftware, and delft porcelain, but destitute of those graceful forms and paintings for which the ware of Fayenza was distinguished. Common fayence may be, therefore, regarded as a strong, well-burned, but rather coarse-grained kind of stoneware.
It was in the 17th century that a small work for making earthenware of a coarse description, coated with a common lead glaze, was formed at Burslem, in Staffordshire, which may be considered as the germ of the vast potteries now established in that county. The manufacture was improved about the year 1690, by two Dutchmen, the brothers Elers, who introduced the mode of glazing ware by the vapour of salt, which they threw by handfuls at a certain period among the ignited goods in the kiln. But these were rude, unscientific, and desultory efforts. It is to the late Josiah Wedgewood, Esq. that this country and the world at large are mainly indebted for the great modern advancement of the ceramic art. It was he who first erected magnificent factories, where every resource of mechanical and chemical science was made to co-operate with the arts of painting, sculpture, and statuary, in perfecting this valuable department of the industry of nations. So sound were his principles, so judicious his plans of procedure, and so ably have they been prosecuted by his successors in Staffordshire, that a population of 60,000 operatives now derives a comfortable subsistence within a district formerly bleak and barren, of 8 miles long, by 6 broad, which contains 150 kilns, and is significantly called the Potteries.
OF THE MATERIALS OF POTTERY OR PORCELAIN, AND THEIR PREPARATION.
1. Clay.—The best clay from which the Staffordshire ware is made, comes from Dorsetshire; and a second quality from Devonshire: but both are well adapted for working, being refractory in the fire, and becoming very white when burnt. The clay is cleaned as much as possible by hand, and freed from loosely adhering stones at the pits where it is dug. In the factory mounted by Mr. Wedgewood, which may be regarded as a type of excellence, the clay is cut to pieces, and then kneaded into a pulp with water, by engines; instead of being broken down with pickaxes, and worked with water by hand-paddles, in a square pit or water-tank, an old process, called blunging. The clay is now thrown into a cast-iron cylinder, 20 inches wide, and 4 feet high, or into a cone 2 feet wide at top, and 6 feet deep, in whose axis an upright shaft revolves, bearing knives as radii to the shaft. The knives are so arranged, that their flat sides lie in the plane of a spiral line; so that by the revolution of the shaft, they not only cut through every thing in their way, but constantly press the soft contents of the cylinder or cone obliquely downwards, on the principle of a screw. Another set of knives stands out motionless at right angles from the inner surface of the cylinder, and projects nearly to the central shaft, having their edges looking opposite to the line of motion of the revolving blades. Thus the two sets of slicing implements, the one active, and the other passive, operate like shears in cutting the clay into small pieces, while the active blades, by their spiral form, force the clay in its comminuted state out at an aperture at the bottom of the cylinder or cone, whence it is conveyed into a cylindrical vat, to be worked into a pap with water. This cylinder is tub-shaped, being about 4 times wider than it is deep. A perpendicular shaft turns also in the axis of this vat, bearing cross spokes one below another, of which the vertical set on each side is connected by upright staves, giving the movable arms the appearance of two or four opposite square paddle-boards revolving with the shaft. This wooden framework, or large blunger, as it is called, turns round amidst the water and clay lumps, so as to beat them into a fine pap, from which the stony and coarse sandy particles separate, and subside to the bottom. Whenever the pap has acquired a cream-consistenced uniformity, it is run off through a series of wire, lawn, and silk sieves, of different degrees of fineness, which are kept in continual agitation backwards and forward by a crank mechanism; and thus all the grosser parts are completely separated, and hindered from entering into the composition of the ware. This clay liquor is set aside in proper cisterns, and diluted with water to a standard density.
2. But clay alone cannot form a proper material for stoneware, on account of its great contractility by heat, and the consequent cracking and splitting in the kiln of the vessels made of it; for which reason, a siliceous substance incapable of contraction must enter into the body of pottery. For this purpose, ground flints, called flint-powder by the potters, is universally preferred. The nodules of flint extracted from the chalk formation, are washed, heated redhot in a kiln, like that for burning lime, and thrown in this state into water, by which treatment they lose their translucency, and become exceeding brittle. They are then reduced to a coarse powder in a stamping-mill, similar to that for stamping ores; see [Metallurgy]. The pieces of flint are laid on a strong grating, and pass through its meshes whenever they are reduced by the stamps to a certain state of comminution. This granular matter is now transferred to the proper flint-mill, which consists of a strong cylindrical wooden tub, bottomed with flat pieces of massive chert, or hornstone, over which are laid large flat blocks of similar chert, that are moved round over the others by strong iron or wooden arms projecting from an upright shaft made to revolve in the axis of the mill-tub. Sometimes the active blocks are fixed to these cross arms, and thus carried round over the passive blocks at the bottom. See infrà, under [Porcelain], figures of the [flint and felspar mill]. Into this cylindrical vessel a small stream of water constantly trickles, which facilitates the grinding motion and action of the stones, and works the flint powder and water into a species of pap. Near the surface of the water there is a plughole in the side of the tub, by which the creamy-looking flint liquor is run off from time to time, to be passed through lawn or silk sieves, similar to those used for the clay liquor; while the particles that remain on the sieves are returned into the mill. This pap is also reduced to a standard density by dilution with water; whence the weight of dry siliceous earth present, may be deduced from the measure of the liquor.
The standard clay and flint liquors are now mixed together, in such proportion by measure, that the flint powder may bear to the dry clay the ratio of one to five, or occasionally one to six, according to the richness or plasticity of the clay; and the liquors are intimately incorporated in a revolving churn, similar to that employed for making the clay-pap. This mixture is next freed from its excess of water, by evaporation in oblong stone troughs, called slip-kilns, bottomed with fire-tiles, under which a furnace flue runs. The breadth of this evaporating trough varies from 2 to 6 feet; its length from 20 to 50; and its depth from 8 to 12 inches, or more.
By the dissipation of the water, and careful agitation of the pap, an uniform doughy mass is obtained; which, being taken out of the trough, is cut into cubical lumps. These are piled in heaps, and left in a damp cellar for a considerable time; that is, several months, in large manufactories. Here the dough suffers disintegration, promoted by a kind of fermentative action, due probably to some vegetable matter in the water and the clay; for it becomes black, and exhales a fetid odour. The argillaceous and siliceous particles get disintegrated also by the action of the water, in such a way that the ware made with old paste is found to be more homogeneous, finer grained, and not so apt to crack or to get disfigured in the baking, as the ware made with newer paste.