Examples, however, are now accumulating which certainly prove that, in some cases, the vesicles were filled up during the volcanic period. Among the Tertiary basalt-plateaux of the Inner Hebrides, for instance, it can be shown that the lavas were already amygdaloidal before the protrusion of the gabbros and granophyres which mark later stages of the same continuous volcanic history, and even before the outpouring of much of the basalt of these plateaux. Not improbably the mineral secretions were largely due to the influence of hot volcanic vapours during the eruption of the basalts. This subject will be again referred to in the description of the Tertiary volcanic series.
Vesicular structure is more commonly and perfectly developed among the lavas which are basic and intermediate in composition than among those which are acid.
While the existence of a highly vesicular or scoriaceous structure may generally be taken as proof that the rock displaying it flowed out at the surface as a lava, other evidence pointing to the same conclusion may often be gathered from the rocks with which the supposed lava is associated. Where, for example, a scoriaceous lava is covered with stratified deposits which contain pieces of that lava, we may be confident that the rock is an interstratified or contemporaneous sheet. It has been erupted after the deposition of the strata on which it rests, and before that of the strata which cover it and contain pieces of it. In such a case, the geological date of the eruption could be precisely defined. Illustrations of this reasoning will be given in [Chapter iv.], and in the account of the volcanic series of Carboniferous age in Central Scotland, where a basic lava can sometimes be proved to be a true flow and not an intrusive sill by the fact that portions of its upper slaggy surface are enclosed in overlying sandstone, shale or limestone.
2. The presence of GLASS, or of some result of the devitrification of an original glass, is an indication that the rock which exhibits it has once been in a state of fusion. Even where no trace of the original vitreous condition may remain, stages in its devitrification, that is, in its conversion into a stony or lithoid condition, may be traceable. Thus what are called spherulitic and perlitic structures (which will be immediately described), either visible to the naked eye or only observable with the aid of the microscope, afford evidence of the consolidation and conversion of a glassy into a lithoid substance.
Striking evidence of the former glassy, and therefore molten, condition of many rocks now lithoid is to be gained by the examination of thin slices of them under the microscope. Not only are vestiges of the original glass recognizable, but the whole progress of devitrification may be followed into a crystalline structure. The primitive crystallites or microlites of different minerals may be seen to have grouped themselves together into more or less perfect crystals, while scattered crystals of earlier consolidation have been partially dissolved in and corroded by the molten glass. These and other characteristics of once fused rocks have to a considerable extent been imitated artificially by MM. Fouqué and Michel Lévy, who have fused the constituent minerals in the proper proportions.
Since traces of glass or of its representative devitrified structures are so abundantly discoverable in lavas, we may infer the original condition of most lavas to have been vitreous. Where, for instance, the outer selvages of a basic dyke or sill are coated with a layer of black glass which rapidly passes into a fine-grained crystalline basalt, and then again into a more largely crystalline or doleritic texture in the centre, there can be no hesitation in believing that glassy coating to be due to the sudden chilling and consolidation of the lava injected between the cool rocks that enclose it. The part that solidified first may be regarded as probably representing the condition of the whole body of lava at the time of intrusion. The lithoid or crystalline portion between the two vitreous outer layers shows the condition which the molten rock finally assumed as it cooled more slowly.
Some lavas, such as obsidians and pitchstones, have consolidated in the glassy form. More usually, however, a lithoid structure has been developed, the original glass being only discoverable by the microscope, and often not even by its aid. Two varieties of devitrification may be observed among lavas, which, though not marked off from each other by any sharp lines, are on the whole distinctive of the two great groups of acid and basic rocks.
Fig. 3.—Microlites of the Pitchstone of Arran (magnified 70 diameters).
(1) Among the acid rocks, what is called the Felsitic type of devitrification is characteristic. Thus, obsidians pass by intermediate stages from a clear transparent or translucent glass into a dull flinty or horny mass. When thin slices of these transitional forms are examined under the microscope, minute hairs and fibres or trichites, which may be observed even in the most perfectly glassy rocks, are seen to increase in number until they entirely take the place of the glass. Microlites of definite minerals may likewise be observed, together with indefinite granules, and the rock finally becomes a rhyolite, felsite or allied variety ([Fig. 3]).