At the same time it should be observed that, even in the vitreous condition of a lava, definite crystals of an early consolidation were generally already present. Felspars and quartz, usually in large porphyritic forms, may be seen in the glass, often so corroded as to indicate that they were in course of being dissolved in the magma at the time of the cooling and solidification of the mass. In obsidians and pitchstones such relics of an earlier or derived series of crystallized minerals may often be recognized, while in felsites and quartz-porphyries they are equally prominent. Where large dispersed crystals form a prominent characteristic in a rock they give rise to what is termed the Porphyritic structure.
| Fig. 4.—Perlitic structure in Felsitic Glass, Isle of Mull (magnified). | Fig. 5.—Spherulitic structure (magnified). |
Accompanying the passage of glass into stone, various structures make their appearance, sometimes distinctly visible to the naked eye, at other times only perceptible with the aid of the microscope. One of these structures, known as Perlitic ([Fig. 4]), consists in the formation of minute curved or straight cracks between which the vitreous or felsitic substance, during its contraction in cooling, assumed a finely globular form.
Another structure, termed Spherulitic ([Fig. 5]), shows the development of globules or spherules which may range from grains of microscopic minuteness up to balls two inches or more in diameter. These not infrequently present a well-formed internal fibrous radiation, which gives a black cross between crossed Nicol prisms. Spherulites are more especially developed along the margins of intrusive rocks, and may be found in dykes, sills and bosses (see Figs. [375] and [377]). Where the injected mass is not thick it may be spherulitic to the very centre, as can be seen among the felsitic and granophyric dykes of Skye.
Some felsitic lavas possess a peculiar nodular structure, which was developed during the process of consolidation. So marked does this arrangement sometimes become that the rocks which display it have actually been mistaken for conglomerates. It is well exhibited among the Lower Silurian lavas of Snowdon, the Upper Silurian lavas of Dingle, and the Lower Old Red Sandstone lavas near Killarney.
| Fig. 6.—Micropegmatitic or Granophyric structure in Granophyre, Mull (magnified). | Fig. 7.—Ophitic structure in Dolerite, Gortacloghan, Co. Derry (magnified). |
A marked structure among some intrusive rocks, especially of an acid composition, is that called Micropegmatitic or Granophyric. It consists in a minute intergrowth of two component minerals, especially quartz and felspar, and is more especially characteristic of certain granitic or granitoid rocks which have consolidated at some distance from the surface and occur as bosses, sills and dykes. It is also met with, however, in some basic sills. Examples of all these and other structures will occur in the course of the following description of British volcanic rocks.
(2) The second type of devitrification, conspicuous in rocks of more basic composition, is marked by a more complete development of crystallization. Among basic, as among acid rocks, there are proofs of the consolidation of definite minerals at more than one period. Where the molten material has suddenly cooled into a black glass, porphyritic felspars or other minerals are often to be seen which were already floating in the magma in its molten condition. During devitrification, however, other felspars of a later period of generation made their appearance, but they are generally distinguishable from their predecessors. Probably most basic and intermediate rocks, when poured out at the surface as lavas, were no longer mere vitreous material, but had already advanced to various stages of progress towards a stony condition. These stages are still to some extent traceable by the aid of the microscope.
Microlites of the component minerals are first developed, which, if the process of aggregation is not arrested, build up more or less perfect crystals or crystalline grains of the minerals. Eventually the glass may be so completely devitrified by the development of its constituent minerals as to be wholly used up, the rock then becoming entirely crystalline, or to survive only in scanty interstitial spaces. In the family of the basalts and dolerites the gradual transition from a true glass into a holocrystalline compound may be followed with admirable clearness. The component minerals have sometimes crystallized in their own distinct crystallographic forms (idiomorphic); in other cases, though thoroughly crystalline, they have assumed externally different irregular shapes, fitting into each other without their Proper geometric boundaries (allotriomorphic).
A specially characteristic feature of many basic rocks is the presence of what is termed an Ophitic structure ([Fig. 7]). Thus the component crystals of pyroxene occur as large plates separated and penetrated by small needles and crystals of felspar. The portions of pyroxene, divided by the enclosed felspar, are seen under the microscope to be in optical continuity, and to have crystallized round the already formed felspar. This structure is never found in metamorphic crystalline rocks. It has been reproduced artificially from fusion by Messrs. Fouqué and Michel Lévy.