NITRO-PRUS′SIDES. A series of salts discovered by Dr Playfair, and obtained by the action of nitric acid on the ferrocyanides and ferridcyanides. The most important of these salts is the nitroprusside of sodium (NA2 (NO) FeCy5. 2Aq.). Prep. Dissolve 2 parts of powdered ferrocyanide of sodium in 5 parts of common nitric acid, previously diluted with its own volume of water. When the evolution of gas has ceased, digest the solution on a water bath until it no longer yields a blue but slate-coloured precipitate with ferrous sulphate. Cool the liquid, filter, neutralise the filtrate with carbonate of sodium, and again filter. This filtrate, on evaporation, yields crystals consisting of a mixture of nitro-prusside of
sodium and nitrate of potassium; the former, which may be recognised by their rhombic shape and their fine ruling colour, should be picked out and preserved.—Use. As a test for soluble sulphides, with which nitro-prusside of sodium strikes a beautiful violet tint. According to Playfair this is the most delicate test for alkaline sulphides.
NI′TROUS ACID. HNO2 See Nitrous Anhydride, under Nitrogen, Oxides of.
NITROUS OXIDE. See Nitrogen, Oxides of.
NODE. Syn. Nodus, L. A hard tumour proceeding from a bone, and caused by the swelling of its external membrane. The bones of the leg, forehead, and forearm, are those most commonly attacked. Nodes are generally accompanied with considerable pain, and often with caries and loss of vitality.
NOLI ME TANGERE. See Lupus.
NOMENCLATURE (Chemical). The following information will doubtless prove useful to many of our readers, as serving to explain terms which are necessarily of frequent occurrence in this work:
Acids.—a. When a substance produces only one acid compound, the name of this acid is formed by adding the termination -IC to that of the radical, or to the leading or characteristic portion of it; as sulphuric acid, an acid of sulphur. This is Latinised by changing -IC into -ICUM; as, acidum, sulphurICUM.—b. When a body forms two acid compounds containing oxygen, the name of the one containing the smaller proportion of that substance ends in -OUS; as nitrOUS acid, which contains 1 atom of nitrogen and 2 of oxygen; nitrIC acid, containing 1 atom of nitrogen and 3 of oxygen. In this case the Latin name ends in -OSUM; as, acidum nitrOSUM.—c. When a substance forms more than two acids with oxygen, the Greek preposition HYPO- (below or under) is prefixed to the name of the acid in -OUS or -IC next above it; as, HYPOchlorous acid.—d. When a new acid compound of a substance is discovered, containing more oxygen than another acid of the same substances already known, the name of which ends in -IC, the prefix PER- or HYPER- is added; as, PERiodic acid. This may be illustrated by the oxygen acids of chlorine:—
| Hypochlorous | acid | ( | acidum | hypochlorosum) | HClO |
| Chlorous | ” | ( | ” | chlorosum) | HClO2 |
| Chloric | ” | ( | ” | chloricum) | HClO3 |
| Perchloric or Hyperchloric | ” | ( | ” | perchloricum) | HClO4 |
OXIDES. The names of these have, in general, reference to the number of atoms of oxygen which they contain. When a metal forms only one basic compound with oxygen, this compound is simply called the oxide of such base; but as most substances form more than one compound with oxygen, certain prefixes are introduced to express the proportions. In such cases it is generally found that one out of the number has a strongly marked basic character,